• Title/Summary/Keyword: degradation efficiency

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Electrochemical Degradation of Textile Effluent Using PbO2 Electrode in Tube Electrolyzer

  • Chao Wang; Yongqiang Li;Junmin Wan;Yi Hu;Yi Huang
    • Journal of Electrochemical Science and Technology
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    • v.15 no.1
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    • pp.190-197
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    • 2024
  • A commercial PbO2 mesh cylinder electrode was utilized as the anode for the electrochemical degradation of the textile effluent after the biological treatment with the titanium cylinder as the cathode in a self-made tube electrolyzer. The electrochemical performances of the PbO2 electrode in tube electrolyzer under different initial pH, electrolyte flow rates, current densities and times of the electrochemical degradation were investigated. The experimental results illustrated that the PbO2 electrode can reduce the chemical oxygen demand (COD) of the textile effluent from 94.0 mg L-1 to 65.0 mg L-1 with the current efficiency of 88.3%, the energy consumption of 27.7 kWh kg-1 (per kilogram of degraded COD) and the carbon emissions of 18.0 kg CO2 kg-1 (per kilogram of degraded COD) under the optimal operating conditions. In addition, the COD of the textile effluent could be reduced from 94.0 mg L-1 to 22.0 mg L-1 after the fifth electrochemical degradation. Therefore, PbO2 mesh cylinder electrode in the tube cylinder was promising for the electrochemical degradation of the textile effluent.

Degradation of Salicylic Acid by Free and Immobilized Cells of Pseudomonas sp. Strain NGK1

  • Patil, Neelakanteshwar-K.;Sharanagouda, U.;Niazi, Javed-H.;Kim, Chi-Kyung;Karegoudar, Timmanagouda-B.
    • Journal of Microbiology and Biotechnology
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    • v.13 no.1
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    • pp.29-34
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    • 2003
  • A Pseudomonas sp. strain NGK1 (NCIM 5120) capable of utilizing salicylate was immobilized in alginate and polyurethane foam (PUF). The degradation rate of salicylate by freely suspended cells was compared with the degradation rate by immobilized cells. In an initial 20 and 40 mM salicylate, free cells ($2{\times}10^{11}\;cfu\;ml^{-1}$) degraded to 16 and 14 mM, alginate-entrapped cells degraded to 18 and 26 mM, and PUF-entrapped cells degraded to 20 and 32 mM salicylate, respectively, in batch cultures. The alginate-and PUF-entrapped cells were used in repeated batch and continuous culture systems. The efficiency of both the immobilized systems f3r the degradation of salicylate was compared. It has been observed that the PUF-entrapped cells could be reused for more than 20 cycles whereas alginate-entrapped cells could be reused for a maximum of only 12 cycles, after which a decrease in degradation rat was observed with the initial 20 and 40 mM salicylate. The continuous degradation of sallcylate by freely suspended cells showed a negligible degradation rate of salicylate when compared with immobilized cells. With the immobilized cells in both alginate and polyurethane foam, the degradation rate increased with an increase in the dilution rate up to $2\;h^{-1}$ for 20 mM, and $1.5\;h^{-1}$ for 40 mM salicylate. The results revealed that PUF-entrapped cells were more efficient for the degradation of salicylate than alginate-entrapped cells and freely suspended cells.

A Study on the Isolation of the Oil-degradation Microbes and Treatment Efficiency in the Oil Contaminated Soil with Peat Moss (유류오염토양에서 유류분해 미생물의 분리 및 peat moss를 이용한 오염토양 처리에 관한 연구)

  • Chun, Mi-Hee;Son, Hee-Jeong;Kim, Chul
    • Journal of Environmental Health Sciences
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    • v.33 no.5
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    • pp.462-469
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    • 2007
  • Isolation and application of oil-degradation microbes from the oil-contaminated soil and the determination of optimal operation conditions about the peat moss, the addition for the oil-biodegradation. After all experiments, we have acquired three important conclusions: First, we found out the 4 microbes, Pseudomonas fluorescens, Pseudomonas aeruinosa, Kurtia sp., Bacillus ceres, with excellent capability for the oil-degradation; Second, the optimal operating conditions of the peat moss for TPH treatment were pH $7{\sim}8$, temperature $25{\sim}30^{\circ}C$, water content 20%, mixing 2 times/ day, addition volume 2%; Third, in case of the application to the oil-contaminated soil with 4 mixed microbes, the removal efficiency of TPH was increased from 54% to 83% in oil-contaminated soil and from 65% to 85% in oil-contaminated soil with the peat moss.

Degradation of Monoethanolamine during Continuous Operation of a Laboratory Scale CO2 Absorption System (실험실 규모 이산화탄소 흡수장치의 연속운전시 모노에탄올아민 열화 특성)

  • Kang, Ji-A;Woo, Wongu;Lim, Ho-Jin
    • Journal of Environmental Science International
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    • v.25 no.3
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    • pp.385-393
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    • 2016
  • Oxidative and thermal degradation of alkanolamines for a promising $CO_2$ capture technology of absorption might cause decrease in $CO_2$ capture efficiency and formation of hazardous byproducts. In this study, characteristics of a representative absorbent of monoehtanolamine (MEA) were examined for a long term operation using a laboratory scale absorption system. An $CO_2$ absorption system with ID 56 mm and absorption zone height 100 cm was developed for the characterization. Absorption solution of 30 wt% MEA was circulated at 100 mL/min to treat air with 15% $CO_2$ and 1 ppm NO at 10 L/min. Temperatures of absorber and stripper were maintained at $40^{\circ}C$ and $120^{\circ}C$, respectively. For the course of 5 weeks continuous operation, MEA concentration was decreased approximately by 70% and $CO_2$ removal efficiency was dropped from 95% to 65%. Ionic byproducts of $NH_4{^+}$, $NO_2{^-}$, and $NO_3{^-}$ were accumulated up to 48 g/mL, 0.2 g/mL, and 1.5 g/mL, respectively, tracking the variation of MEA concentration. Formation of various organic byproducts were also observed.

Photocatalytic Characteristics of PbS/ZnO/TiO2 Nanotube Composite (PbS/ZnO/TiO2 나노복합체의 광촉매 특성)

  • Lee, Jong-Ho;Heo, Sujeong;Youn, Jeong-Il;Kim, Young-Jig;Kim, In-Ki;Jang, Kyung-Wook;Oh, Han-Jun
    • Korean Journal of Materials Research
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    • v.27 no.10
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    • pp.569-575
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    • 2017
  • To improve photocatalytic performance, a $PbS/ZnO/TiO_2$ nanotube catalyst was synthesized, and its surface characteristics and photocatalytic efficiency were investigated. The hybrid photocatalysts were produced by anodic oxidation and successive ionic layer adsorption and reaction(SILAR). The photocatalytic efficiency was evaluated using the dye degradation rate. The $PbS/ZnO/TiO_2$ photocatalyst significantly enhanced the photocatalytic activity for dye degradation, which was ascribed to the synergistic effect of their better absorption of solar light and a decrease in the rate of excited electron-hole recombination.

Synthesis of N-doped Titania using Ammonium Hydroxide and Photocatalytic Degradation of Humic Acid (암모니아수를 이용한 N-doped TiO2 제조 및 부식산의 광촉매 분해)

  • Cho, A-Young;Nam, Yun-Seon;Rhee, Dong-Seok
    • Journal of Industrial Technology
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    • v.32 no.A
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    • pp.95-102
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    • 2012
  • To advance luminance efficiency of Titania at visible range, N-doped $TiO_2$ was prepared by using ammonium hydroxide as a source of nitrogen. The photoactivities of the synthesized $TiO_2$ were evaluated on the basis of degradation of humic acid in aqueous solutions with different light sources, UV-C, UV-A and fluorescent lamp. As a result, at UV-C is high efficiency $UV_{254}$ decrease and TOC removal. In this study, the best synthetic conditions of N-doped $TiO_2$ were 5.0 M of ammonium hydroxide concentration and calcination temperature of $550^{\circ}C$. The degradation rate of humic acid as an evaluation of photoactivities of the catalysts were conducted with pH variation, decrease rate of molecular absorption, removal rate of total organic carbon and fluorescece evolution for humic acid solution. XRD and SEM were applied for analysis of surface analysis of the catalysts.

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Turbine Performance Degradation due to Blade Surface Roughness (블레이드 표면 거칠기에 따른 터빈 성능저하)

  • Park, Il-Young;Yun, Yong-Il;Song, Seung-Jin
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.2012-2017
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    • 2003
  • This paper reports on the influence of blade surface roughness on turbine efficiency. The performance of a low speed one-stage axial turbine with roughened blade surfaces was evaluated. Sandpaper with equivalent sandgrain roughness ($k_s$) was used to roughen the blades. Efficiency (${\eta}/{\eta}_0$) decreases by 4.5 % with sandgrain size of 400 ${\mu}m$ on the stator suction surface.

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Degradation of PLEDs and a Way to Improve Device Performances

  • Kim, Sung-Han;Hsu, Che;Zhang, Chi;Skulason, Hjalti;Uckert, Frank;Lecloux, Dan;Cao, Yong;Parker, Ian
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.183-187
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    • 2004
  • The most significant degradation problem of PLED has been described and new buffer layer material aimed for use as HTL in PLED to solve this issue has been studied. This approach has enabled the increase of the green device efficiency (${\sim}$2x) and lifetime (${\sim}$5-6x).

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A Study on Contamination Sensitivity and Condition Monitoring for a Pump (펌프의 오염 민감도와 성능 감시에 대한 연구)

  • 이재천
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1998.04a
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    • pp.124-130
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    • 1998
  • A mathematical model describing gear pump flow degradation in the presense of abrasive particles is presented. The model considers the operating parameters as Sommerfeld number, so that contamination sensitivity test results could be conversed to field application to predict contamination service life. A method to estimate the volumetric efficiency and the contamination level of a pump is proposed by measuring the temperature differences in the fluid. Test results show the validity of the theoretical establishments.

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Air-Water Two-phase Flow Patterns and Pressure Distributions in a Screw-type Centrifugal Pump

  • Kim, You-Taek
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.8
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    • pp.1203-1210
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    • 2004
  • It was reported recently that the pump head degradation near the best efficiency point from single-phase flow to the break-down due to air entrainment became less in a screw-type centrifugal pump than in a general centrifugal pump. In this paper, I carried out internal pressure measurements and visualizations, and investigated the various physical phenomena occurring inside a screw-type centrifugal pump operated in air-water two-phase flow. The results could give some characteristics about the degradation of pump performance on air-water two-phase flow.