• Title/Summary/Keyword: degenerate system

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A Comparative Study of the DFT and MP2 Methods Molecular Structure of Diphosphadithiatetrazocine

  • Jeong, Gyu Seong;Lee, Deok Hwan
    • Bulletin of the Korean Chemical Society
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    • v.21 no.3
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    • pp.300-304
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    • 2000
  • The B3LYP method based on the density functional theory(DFT) is shown to be much better than the ab initio MP2 method for structural determination of diphosphadithiatetrazocine systems having transannular S--S bonding. The presence of bonding between the two sulfur atoms across the cyclic ring is theoretically confirmed in the case of the neutral diphosphadithiatetrazocine. The S--S dobding disappears in the ionized species. The planarity of the dicationic heterocyclic ring system turns out to be closely associated with the $\pi-electron$ delocalization over the entire ring as well as the N-S-N bonds, which become stiffened upon ionizaiton. In the case of dianionic species, the chair-boat and chair conformers are nearly degenerate and far more stable than the crown conformer.

Defending and Detecting Audio Adversarial Example using Frame Offsets

  • Gong, Yongkang;Yan, Diqun;Mao, Terui;Wang, Donghua;Wang, Rangding
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.15 no.4
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    • pp.1538-1552
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    • 2021
  • Machine learning models are vulnerable to adversarial examples generated by adding a deliberately designed perturbation to a benign sample. Particularly, for automatic speech recognition (ASR) system, a benign audio which sounds normal could be decoded as a harmful command due to potential adversarial attacks. In this paper, we focus on the countermeasures against audio adversarial examples. By analyzing the characteristics of ASR systems, we find that frame offsets with silence clip appended at the beginning of an audio can degenerate adversarial perturbations to normal noise. For various scenarios, we exploit frame offsets by different strategies such as defending, detecting and hybrid strategy. Compared with the previous methods, our proposed method can defense audio adversarial example in a simpler, more generic and efficient way. Evaluated on three state-of-the-arts adversarial attacks against different ASR systems respectively, the experimental results demonstrate that the proposed method can effectively improve the robustness of ASR systems.

Correlation Effects in Superconducting $Sr_2VO_3FeAs$ (초전도 $Sr_2VO_3FeAs$에서 상관효과)

  • Lee, K.W.
    • Progress in Superconductivity
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    • v.12 no.1
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    • pp.46-50
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    • 2010
  • In the superconducting $Sr_2VO_3FeAs$, containing bimetallic layers, with maximum $T_c{\approx}\;46\;K$ correlation effects on V ions have been investigated using LDA+U method. Within the local density approximation (LDA) this system has the one-third filled $t_{2g}$ manifold of V, decomposed into $d_{xy}$ of bandwidth W=2 eV and nearly degenerate $d_{zx}d_{yz}$ of W=1 eV. Consideration of correlation effects leads to a metal-insulator transition on V ions $t^{2\uparrow}_{2g}\;{\rightarrow}\;d^{1\uparrow}_{xz}\;d^{1\uparrow}_{yz}$ at the critical on-site Coulomb repulsion $U_c$= 3.5 eV. At U=4 eV, the electronic structure, in which V ions are insulating, leads to several van Hove singularities near $E_F$ and similar Fermiology with other pnictides. Applying U to V ions results in increasing Fe moment as well as V moment, indicating somewhat hybridization between Fe and V ions even though this system is strongly 2-dimesional. Our results show possible importance of correlation effects on this system.

Finite Element Analysis for Improvement of Folding Defects in the Forging Process of Subminiature Screws (초소형 나사 단조시 접힘결함 향상을 위한 유한요소해석)

  • Lee, Ji Eun;Kim, Jong Bong;Park, Keun
    • Journal of the Korean Society for Precision Engineering
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    • v.32 no.6
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    • pp.509-515
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    • 2015
  • Recent trends to reduce the size of mobile electronics products have driven miniaturization of various components, including screw parts for assembling components. Considering that the size reduction of screws may degenerate their joining capabilities, the size reduction should not be limited to the thread region but should be extended to its head region. The screw head is usually manufactured by forging in which a profiled punch presses a billet so that plastic deformation occurs to form the desired shape. In this study, finite element (FE) analysis was performed to simulate the forging process of a subminiature screw; a screw head of 1.7 mm diameter is formed out of a 0.82 mm diameter billet. The FE analysis result indicates that this severe forging condition leads to a generation of folding defects. FE analyses were further performed to find appropriate punch design parameters that minimize the amount of folding defects.

Optimization of Triple Response Systems by Using the Dual Response Approach and the Hooke-Jeeves Search Method

  • Fan, Shu-Kai S.;Huang, Chia-Fen;Chang, Ko-Wei;Chuang, Yu-Chiang
    • Industrial Engineering and Management Systems
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    • v.9 no.1
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    • pp.10-19
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    • 2010
  • This paper presents an extended computing procedure for the global optimization of the triple response system (TRS) where the response functions are nonconvex (nonconcave) quadratics and the input factors satisfy a radial region of interest. The TRS arising from response surface modeling can be approximated using a nonlinear mathematical program involving one primary (objective) function and two secondary (constraints) functions. An optimization algorithm named triple response surface algorithm (TRSALG) is proposed to determine the global optimum for the nondegenerate TRS. In TRSALG, the Lagrange multipliers of target (secondary) functions are computed by using the Hooke-Jeeves search method, and the Lagrange multiplier of the radial constraint is located by using the trust region (TR) method at the same time. To ensure global optimality that can be attained by TRSALG, included is the means for detecting the degenerate case. In the field of numerical optimization, as the family of TR approach always exhibits excellent mathematical properties during optimization steps, thus the proposed algorithm can guarantee the global optimal solution where the optimality conditions are satisfied for the nondegenerate TRS. The computing procedure is illustrated in terms of examples found in the quality literature where the comparison results with a gradient-based method are used to calibrate TRSALG.

Perfect Substitution and Aggregation in A System of Marginal Valuation Functions (한계가치함수체계의 완전대체성과 상품결합성)

  • Park, Hoanjae
    • Environmental and Resource Economics Review
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    • v.12 no.3
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    • pp.427-452
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    • 2003
  • Demand analyses often assume perfect substitution and some level of aggregation before analysis and data collection. Earlier works on this subject are carried out in the context of ordinary demand systems. However, perfect substitution is a degenerate special case in the systems and it is much more easily handled in a system of marginal value functions and no previous analysis has used the marginal value functions to test for perfect substitution and make possible aggregation with prior restrictions. In this article, we present the empirical results on a system of marginal value functions in fisheries and pose testable results of perfect substitution and aggregation. The contribution of this article is new establishment of a set of restrictions implying perfect substitutability among all commodities and the application to the problem of commodity aggregate. A system of marginal value functions is estimated in fisheries and its implication of perfect substitution is reasonably drawn.

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A Wide Dynamic Range NUC Algorithm for IRCS Systems

  • Cai, Li-Hua;He, Feng-Yun;Chang, Song-Tao;Li, Zhou
    • Journal of the Korean Physical Society
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    • v.73 no.12
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    • pp.1821-1826
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    • 2018
  • Uniformity is a key feature of state-of-the-art infrared focal planed array (IRFPA) and infrared imaging system. Unlike traditional infrared telescope facility, a ground-based infrared radiant characteristics measurement system with an IRFPA not only provides a series of high signal-to-noise ratio (SNR) infrared image but also ensures the validity of radiant measurement data. Normally, a long integration time tends to produce a high SNR infrared image for infrared radiant characteristics radiometry system. In view of the variability of and uncertainty in the measured target's energy, the operation of switching the integration time and attenuators usually guarantees the guality of the infrared radiation measurement data obtainted during the infrared radiant characteristics radiometry process. Non-uniformity correction (NUC) coefficients in a given integration time are often applied to a specified integration time. If the integration time is switched, the SNR for the infrared imaging will degenerate rapidly. Considering the effect of the SNR for the infrared image and the infrared radiant characteristics radiometry above, we propose a-wide-dynamic-range NUC algorithm. In addition, this essasy derives and establishes the mathematical modal of the algorithm in detail. Then, we conduct verification experiments by using a ground-based MWIR(Mid-wave Infared) radiant characteristics radiometry system with an Ø400 mm aperture. The experimental results obtained using the proposed algorithm and the traditional algorithm for different integration time are compared. The statistical data shows that the average non-uniformity for the proposed algorithm decreased from 0.77% to 0.21% at 2.5 ms and from 1.33% to 0.26% at 5.5 ms. The testing results demonstrate that the usage of suggested algorithm can improve infrared imaging quality and radiation measurement accuracy.

Characterization of the Bovine Endogenous Retrovirus β3 Genome

  • Xiao, Rui;Kim, Juhyun;Choi, Hojun;Park, Kwangha;Lee, Hoontaek;Park, Chankyu
    • Molecules and Cells
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    • v.25 no.1
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    • pp.142-147
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    • 2008
  • We recently used degenerate PCR and locus-specific PCR methods to identify the endogenous retroviruses (ERV) in the bovine genome. Using the ovine ERV classification system, the bovine ERVs (BERVs) could be classified into four families. Here, we searched the most recently released bovine genome database with the partial nucleotide sequence of the pro/pol region of the BERV ${\beta}3$ family. This allowed us to obtain and analyze the complete genome of BERV ${\beta}3$. The BERV ${\beta}3$ genome is 7666 nucleotides long and has the typical retroviral organization, namely, 5'-long terminal repeat (LTR)-gag-pro-pol-env-LTR-3'. The deduced open reading frames for gag, pro, pol and env of BERV ${\beta}3$ en- code 507, 271, 879 and 603 amino acids, respectively. BERV ${\beta}3$ showed little amino acid similarity to other betaretroviruses. Phylogenetic analysis showed that it clusters with HERV-K. This is the first report describing the genetic structure and sequence of an entire BERV.

Studies on the population biology of some clonal plants in a coastal reclaimed land

  • Choung, Yeon-Sook;Joon-Ho Kim
    • The Korean Journal of Ecology
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    • v.14 no.3
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    • pp.327-343
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    • 1991
  • Clonal growth and rhizome architecture of calmagrostis epigeios, were studied in a 15-year old coastal reclamed land. As c. epigeios patch grew from center to margin radially over time, concentric annuli were added. the radial increases of the mature patch were 80~130cm/yr. the patch ages of c. epigeios estimated by relationships between the diameter and is radial increament, were 1~6year old. There were the marked variations of density, phytomass, shoot height and inflorecence frequency with increasing age of rhizome system within the patch. the maximum performance occurred at 2-year-old concentric annuli of the patch. The growth phasic continuum with aging was divided into 5 grwth phases ; pioneer, building, matyre, senile and degenerate. The rhizome aging had a more significant effect on the inflorescence frequency than on the other attributes. new rhizomes tended to diverge from the direction of the parent ramet by sympodial growth. in a 1-year-old patch, average length of rhizome segment was 7cm, average number of internode was 6, and the tillering frequency was 27%. The tillering in the early stage resultd in the increase of shoot density and the producation of multibranching rhizome. as the result of that, circular patchwas formed in a year. The branching structure based on such facts was represented graphically in branching degree of 60 and 100. therefore, c. epigeios with clonal growth may establish and grow vigorously earlier than other glycophytes in high salt conditions such as the coastal reclaimed land.

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Sequence-Based Screening for Putative Polyketide Synthase Gene-Harboring Clones from a Soil Metagenome Library

  • JI SANG CHUN;KIM DOCKYU;YOON JUNG-HOON;OH TAE-KWANG;LEE CHOONG-HWAN
    • Journal of Microbiology and Biotechnology
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    • v.16 no.1
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    • pp.153-157
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    • 2006
  • A soil metagenomic library was constructed using an E. coli-fosmid cloning system with environmental DNAs extracted from Kwangreung forest topsoil. We targeted the genes involved in the biosynthesis of bacterial polyketides. Initially, a total of 36 clone pools (10,800 clones) were explored by the PCR-based method using the metagenomic DNAs from each pool and a degenerate primer set, which has been designed based on the highly conserved regions among ketoacyl synthase (KS) domains in actinomycete type I polyketide synthases (PKS Is). Six clone pools were tentatively selected as positive and further examined through a hybridization-based method for selecting a fosmid clone containing PKS I genes. Colony hybridization was performed against fosmid clones from the 6 positive pools, and finally 4 clones were picked out and confirmed to contain the conserved DNA fragment of KS domains. In this study, we present a simple and feasible sorting method for a desired clone from metagenomic libraries.