• Archives of Plastic Surgery
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• v.35 no.1
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• pp.7-12
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• 2008

Purpose: Since the report of artificial dermis manufacturing method using collagen by Yannas in 1980, collagen has been effectively used as dermal substitute with its merits such as, lower antigeneicity, controllable biodegradation rate, and minimal inflammatory cytotoxic properties in the dermal tissue engineering field. However, weak mechanical durability was the main drawback of collagen dermal substitute. To improve its stability, mechanical or chemical cross-linking was used. Despite of such process, its clinical use was restricted due to weak durability. To improve the durability of collagen matrix, we designed elastin-incorporated collagen matrix and compared its durability with conventional collagen matrix. Methods: 15mm diameter with 4mm thick collagen dermal matrix was made according to Yannas protocol by mixing 0.5% bovine collagen and chondroitin-6-sulfate followed by degassing, freeze drying, dehydrodermal cross-linking and chemical cross-linking procedure. In elastin incorporated collagen matrix, same procedure was performed by mixing elastin to previous collagen matrix in 4:1 ratio(collagen 80% elastin 20%). In comparison of the two dermal matrix in vitro tests, matrix contracture rate, strain, tensile strength, was measured and stiffness was calculated from comparative analysis. Results: In terms of matrix contracture, the elastin-incorperated added collagen dermis matrix showed 1.2 times more contraction compared to conventional collagen matrix. However, tensile strength showed 1.6 times and stiffness showed 1.6 times increase in elastin-incorporated matrix. Conclusion: Elastin incorperated collagen matrix manufactured by our team showed increased durability due to improvement in tensile strength and stiffness compared to previous collagen matrix($Integra^{(R)}$).

• Journal of the Korean Chemical Society
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• v.20 no.6
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• pp.441-447
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• 1976

The infrared spectra obtained in the region of $4000∼1200 $cm^{-1}$ has been measured for pyridine, tertiary butylamine, and ethylenediamine adsorbed on various cation-exchanged silicates at various degassing temperature. It was possible to distinguish between protonic and aprotonic acid sites of all cation-exchanged silicates which exhibited both Bronsted and Lewis acidity. The sodium form appeared to be the least reactive towards adsorbates. The relative ratio of the band intensities of tertiary butylamine was directly related to the polarizing power of exchanged cations. Ethylenediamine was less easily desorbed from silicate surface than tertiary butylamine due to the additional amino group to react with surface active site, and probably to form ether hydrogen bond with surface oxgen by liberating migrating proton besides the coordination bond with Lewis acid site and the formation of$NH3^+$ species with Bronsted acid site.

• The Journal of the Acoustical Society of Korea
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• v.26 no.1E
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• pp.33-38
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• 2007

Compressional wave velocity and shear wave velocity were measured for gassy sediments collected from Jinhae Bay, Korea. To distinguish inhomogeneities of gassy sediments, Computed Tomography (CT) was carried out for gassy sediment using CT Scanner. The cored sediments are composed of homogeneous and soft mud (greater than $8{\Phi}$ in mean grain size) containing clay content more than 50%. In depth interval of gassy sediments, compressional wave velocity is significantly decreased from 1480m/s to 1360m/s, indicating that the gas greatly affects compressional wave velocity due to a gas and/or degassing cracks. Shear wave velocity shows a slight increasing pattern from ${\sim}55\;m/s$ in the upper part of the core to ${\sim}58\;m/s$ at 320 cm depth, and then decreases to ${\sim}54\;m/s$ in the lower part of the core containing a small amount of gas. But shear wave velocity in the gassy sediments is slightly greater than that of non-gassy sediments in the upper part of the core. Thus, the Vp/Vs ratio is decreased (from 30 to 25) in gas charged zone. The Vp/Vs ratio is well correlated with shear wave velocity, but no correlation with compressional wave velocity. This suggests that low concentrations of gas have little affects on shear wave velocity. By CT images, the gas in the sediments is mostly concentrated around inner edge of core liner due to a long duration after sediment collection.

• Journal of Biomedical Engineering Research
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• v.22 no.6
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• pp.511-518
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• 2001

In vitro corrosion resistance of the commercially used 76.5wt.%Pd-17.6%Cu-7.2%Ga and 77.3%Pd-6.0%Ga dental Prostheses high-Palladium system alloys in cast, degassing and porcelain-firing heat treatment conditions were evaluated by the potentiodynamic polarization technique in the de-aerated 0.9%NaCl and a modified Fusayama electrolyte. From the corrosion rate experimental results, we found that there is a small difference in the corrosion resistance depending on the microstructure. However. it was so small that there is no significant problem as a dental material. The 77.3%Pd-6.0%Ga showed better corrosion resistance than the 76.5%Pd-11.6%Cu-7.2%Ga dental Prostheses high-palladium system alloys. These experimental observations in 76.5%Pd-11.6%Cu-7.2%Ga alleys are mainly due to a rapid quenching and Cu in the alloy which accelerate the eutectic reaction with a segregation and Precipitates in the microstructure. On the ocher hand, 77.3%Pd-6.0%Ga alloys, which are solid-solution matrix, show much better col·lesion resistance compared with that of 76.5%Pd-11.6%Cu-7.2%Ga alloys.

• Journal of the Korean Vacuum Society
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• v.12 no.4
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• pp.201-206
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• 2003

A residual gas analyzer was used to study the outgassing behavior of stainless steel 304 chamber as a function of bake-out temperature up to $235 ^{\circ}C$ and to identify the gas species evolved during turn on and degassing of the three different types of hot cathode ionization gauges. It was found that $H_2O$, CO, and $H_2O$ were the dominent outgassing species in the vacuum chamber during bake-out but finally $H_2$ and CO(mass 28) persisted at room temperature. Dominant outgassing species were also $H_2$ and $H_2O$ while fuming on the ionizations and then $H_2$,$H_2O$ and CO were found to be the main species degassed gauges. It was appeared that the outgassing species and quantity were not agreed to the three different types of hot cathode ionization gauges.

• Korean Journal of Materials Research
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• v.15 no.9
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• pp.589-593
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• 2005

Nanoimprinting lithography (NIL) is known as a suitable technique for fabricating nano and micro structures of high definition. Hot embossing is one of NIL techniques and can imprint on thin films and bulk polymers. Key issues of hot embossing are time and expense needed to produce a stamp withstanding a high temperature and pressure. Fabrication of a metal stamp such as an electroplated nickel is cost intensive and time consuming. A ceramic stamp made by silicon is easy to break when the pressure is applied. In this paper, a plastic stamp using a high temperature epoxy was fabricated and tested. The plastic stamp was relatively inexpensive, rapid to produce and durable enough to withstanding multiple hot embossing cycles. The merits of low viscosity epoxy solutions were a fast degassing and a rapid filling the microstructures. The hot embossing process with plastic stamp was performed on PMMA substrates. The hot embossing was conducted at 12.6 bar, $120^{\circ}C$ and 10 minutes. An imprinted PMMA wafer was almost same value of the plastic stamp after 10 times embossing. Entire fabrication process from silicon master to plastic stamp was completed within 12 hours.

• Proceedings of the Korea Water Resources Association Conference
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• 2022.05a
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• pp.209-209
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• 2022

Reservoirs play a key role in the carbon cycle between terrestrial and marine systems and are pathways that release greenhouse gases(GHGs), CO₂, CH₄, and N₂O, into the atmosphere by decomposing organic matters. Developed countries have been actively conducting research on carbon emission assessment of dam reservoirs for over 10 years under the leadership of UNESCO/IHA, but associated research is very rare in Korea. In particular, the GHGs footprint evaluation, which calculates the change in net carbon emission considering the watershed environment between pre- and post- impoundment, is very important in evaluating the carbon emission of hydroelectric dams. The objective of this study was to estimate the GHG emissions and footprints in Daecheong Reservoir using the G-res Tool, an online platform developed by UNESCO/IHA. The G-res Tool estimates CO₂ and CH₄ emissions in consideration of diverse pathway fluxes of GHGs from the reservoir and characterizes changes in GHG fluxes over 100 years based on the expected lifetime of the dam. The input required to use the G-res Tool include data related to watersheds, reservoirs, and dams, and most were collected through the government's public portal. As a result of the study, the GHG footprint of Daecheong Reservoir was estimated to be 93 gCO₂eq/m²/yr, which is similar to that of other reservoirs around the world in the same climate zone. After impoundment, the CH₄ diffusion emission from the reservoir was 73 gCO₂eq/m²/yr, also similar to those of the overseas reservoirs, but the CH₄ bubbling emission, degassing emission, and CO₂ diffusion emissions were 44, 34, 252 gCO₂eq/m²/yr, respectively, showing a rather high tendency. Since the dam reservoir carbon footprint evaluation is essential for the Clean Development Mechanism evaluation of hydroelectric power generation, continuous research is needed in the future. In particular, experimental studies that can replace the emission factors obtained from the overseas dam reservoirs currently used in the G-res Tool should be promoted.

• Coupled systems mechanics
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• v.12 no.6
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• pp.531-537
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• 2023

Municipal solid waste landfills are unpredictable bioreactors which in cases of mishandling and bad supervision presents numerous risks. The key to municipal waste landfills is to approach them from the point of prevention of the possible consequences, which means using methods of organized waste disposal, and also utilizing landfill gas, as an unavoidable consequence with disposal of municipal solid waste with a high share of biodegradable organic matter. This paper presents an overview about problems of solid municipal waste management, type and composition of waste, and an overview of waste management condition. Further, the problem of landfill and landfill gasses is described with the calculation models of landfill production, as well as the use of the SWM GHG Calculator and LandGEM software on a specific example of gas production for the central zone at Sarajevo landfill "Smiljevici". Main focus of this thesis is the analysis of potentials of greenhouse gas emission reduction measures from the waste management. Overview of the best available techniques in waste management is presented as well as the methodology used for calculations. Scenarios of greenhouse gas emission reduction in waste management were defined so that emissions were calculated using the appropriate model. In the final section of the paper, its description of the problem of collection and utilization the landfill gas at the sanitary landfill "Smiljevici", and implementation of the system for landfill gas collection and solution suggestion for the gasification and exploitation of gas. Energy, environmental and economic benefits can be accomplished by utilizing municipal solid waste as fuel in industry and energy and moreover by utilizing energy generation from landfill gas, which this thesis emphasizes.

• Tribology and Lubricants
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• v.39 no.5
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• pp.197-202
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• 2023

Recently, research on experimental and analytical techniques utilizing microfluidic devices has been pursued. For example, lab-on-a-chip devices that integrate micro-devices onto a single chip for processing small sample quantities have gained significant attention. However, during sample preparation, unnecessary gases can be introduced into the internal channels, thus, impeding device flow and compromising specific function efficiency, including that of analysis and separation. Several methods have been proposed to mitigate this issue, however, many involve cumbersome procedures or suffer from complexities owing to intricate structures. Recently, some approaches have been introduced that utilize hydrophobic device structures to remove gases within channels. In such cases, the permeability of gases passing through the structure becomes a crucial performance factor. In this study, a method involving the deposition and sintering of diluted Ag-ink onto a silicon wafer surface is presented. This is followed by unstructured nano-pattern creation using a Metal Assisted Chemical Etching (MACE) process, which yields a nanostructured surface with unstructured pillar shapes. Subsequently, gas permeability in the spaces formed by these surface structures is investigated. This is achieved by experiments conducted to incorporate a pressure chamber and measure gas permeability. Trends are subsequently analyzed by comparing the results with existing theories. Finally, it can be confirmed that the significance of this study primarily lies in its capability to effectively evaluate gas permeability through unstructured pillar-like nanostructures, thus, providing quantitative values for the appropriate driving pressure and expected gas removal time in practical device operation.

• Journal of the korean academy of Pediatric Dentistry
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• v.32 no.1
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• pp.144-151
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• 2005

Erosion is believed to be the predominant cause of teeth wear in children and young adults, although there will at ways be a contribution from attrition and abrasion. The pH of cola is known to be low and have, therefore, been implicated in the increasing incidence of erosion. The aim of present study was to evaluate the effect of cola on the progression of erosive demineralization in human enamel using demineralization model in vitro. Six groups of human enamel slap were immersed(5 min each bath) in fresh cola, with immersions taking place with or without agitation, and under 3 regimes of frequency intake(low intake, 1 immersion/day; medium, 5/day; high, 10/day). Quantitative assessments of surface erosion were done over an 8-day interval using surface microhardness testing. 1. The average pH of cola was 2.5, which was acidic enough to cause tooth erosion. 2. All the enamel specimen exposed to cola showed erosion like lesions and surface hardness decreased in proportion to the length of immersion (p<0.05). 3. The surface hardness of enamel decreased in proportion to the frequency of immersion (p<0.05). 4. Increased degassing from the drink by gitation accelerated the enamel softening compared with those without agitation.