• Computers and Concrete
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• 제20권2호
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• pp.165-176
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• 2017

Textile Reinforced Cementitious Composite (TRCC) became the most common construction material lately and have excellent properties. TRCC can be employed in the manufacture of thin-walled facade elements, load-bearing integrated formwork, tunnel linings or in the strengthening of existing structures. These composite materials are a combination of matrix and textile materials. There isn't much research done about the usage of polymer modified matrices in textile reinforced cementitious composites. In this study, matrix materials named as fine grained concretes ($d_{max}{\leq}1.0mm$) were investigated. Air entraining effect of polymer modifiers were analyzed and air void content of fine grained concretes were identified with different methods. Aim of this research is to study the effect of polymer modification on the air content of fine grained concretes and the role of defoamer in controlling it. Polymer modifiers caused excessive air entrainment in all mixtures and defoamer material successfully lowered down the air content in all mixtures. Latex polymer modified mixtures had higher air content than redispersible powder modified ones. Air void analysis test was performed on selected mixtures. Air void parameters were compared with the values taken from air content meter. Close results were obtained with tests and air void analysis test found to be useful and applicable to fine grained concretes. Air void content in polymer modified matrix material used in TRCC found significant because of affecting mechanical and permeability parameters directly.

• 한국응용과학기술학회지
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• 제25권2호
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• pp.115-122
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• 2008

The hydrosilylation is an addition reaction of Si-H bond to unsaturated double bonds, which provides a convenient mechanism to synthesize poly(dimethylsiloxane-co-methylsiloxane)copolymer having siloxy units in polymer backbone. In this study, Poly(dimethylsiloxane-co-methylsiloxane) copolymer was synthesized through the polymerization reaction of cyclopentasiloxane with poly(methyl-hydrogen) siloxane. Silicone-hydrogen functional group of the poly(dimethylsiloxane-co-methylsiloxane) copolymer was substituted to the alkyl groups by hydrosilylation. And their structure was analyzed with FT-IR, H-NMR and GPC instruments, respectively. Surface tension of the synthetic compounds is increased from 22dyne/cm to 25dyne/cm according to increase additional EO moles. The cmc which was evaluated by surface tension was ranged $10^{-5}$ to $10^{-4}mol/L$ and it was decreased according to increase of dimethyl siloxyl content. HLB number of these surfactants was evaluated 9.5 to 11.5 range. These silicone surfactants is applied to self-emulsifier defoamer and personal care products as surface tension depressant, emulsifier, foam control agent.

• 공업화학
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• 제16권5호
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• pp.614-619
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• 2005

폴리올, 실리콘 수지, 변성 실리콘 수지 등을 유화제로 유화시켜 수용성 소포제를 제조하였다. 제조한 소포제에 대하여 소포성, 상분리 시간, 점도 등을 측정하였다. PPG 혼합물의 상분리 시간은 PPG 400>PPG 3000>PPG 1000이었다. PPG 1000을 혼합하였을 때는 다른 것에 비하여 뛰어난 소포성을 나타내었다. 실리콘 수지 혼합물의 상분리 시간은 TSF-451-350>TSF-451-200>TSF-451-50이었다. TSF-451-50을 혼합하였을 때는 상용성 부족으로 혼합물의 부피가 증가되었다. 고분자량의 실리콘 수지를 사용할수록 소포성은 좋지 않았다. 변성 실리콘 수지는 물에 잘 분산되었지만 폴리올에 대한 상용성은 좋지 않았다. 유화제에 대한 소포성은 SPAN 20>SPAN 60>SPAN 80의 순이었다. SPAN 80은 실리콘 수지에 대하여 혼합성이 좋지 않았지만 YAS 6406이나 PPG 1000에 대해서는 좋은 혼합성을 나타내었다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
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• pp.289-292
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• 2006

The purpose of this study was to evaluate a performance of latex-modified repair material applied to the substrate concrete. The experimental variables were latex-cement ratios (5, 10, 15%), polymer(0.5%, 1%) and admixtures. The flow, air content, compressive strength, flexural strength were tested. Test results showed that compressive and flexural strength decreased by adding hydroxyethyl cellulose and increasing water-binder ratio. The compressive and flexural strength were increased when addition of defoamer.

• 한국환경보건학회지
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• 제22권2호
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• pp.104-113
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• 1996

Cadmium uptake by growing and nongrowing (intact) cells of a chdmium-tolerant yeast Hansenula anomala B-7 in the presence of surfactants was studied. In growing cultures the addition of Triton X-100 or Tween 80 increased cadmium uptake by about 30% with no inhibition of cell growth, and in intact cells Triton X-100 increased cadmium accumulation by about 80% compared to surfactant-free controls. Considering balance between increased uptake and pollution, the addition of 0.1% Triton X-100 was preferable. By the mixed addition with defoamer silicone, during growth of cells Tween 80 or Triton X-100 enhanced uptake efficiency of cadmium compared to its single addition, whereas in intact biomass each of surfactants tested had no significant effect on cadmium uptake. The uptake of cadmium was observed to rise sharply to a maximum and then declined with increasing pH, and maximum accumulation of cadmium by growing and intact cells occurred at the pH of 6.0 and 7.0, respectively. A significant increase in cadmium uptake occurred with shaking culture. Cadmium uptake by growing and intact cells was almost completed during the culture time of 72 or 24 hrs, respectively. Scalded cells sorbed much more cadmium-ion than living cells.

• 펄프종이기술
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• 제32권3호
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• pp.25-31
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• 2000

It is required to use substantial amount of wet strength resin for producing multi-functional mulch papers since these paper products shold maintain its strength properties when they exposed to outdoor weather for several months. While producing mulch papers it is usual to observe significant amount of foam at white water silo. Thus it is imperative to use defoaming or antifoaming agents. In this study diverse defoaming and antifoaming agents have been tested for their effective-ness in eliminating foams that produced. It was shown that combined use of a silicone type defoamer and a fatty acid type anti-foaming agent was msot effective in eliminating foams. These chemicals were used in trial production of mulch papers and their influence on paper-making wet end system was examined including one pass retention cationic demand con-ductivity pH etc. It was found that the defoaming agents were very effective for removing foams in trial production. Tensile strengths of the mulch papers produced were significantly greater than commericial mulch papers produced in Japan.

• Fibers and Polymers
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• 제7권3호
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• pp.286-294
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• 2006

This study has examined the flexural properties of natural and chemically modified coir fiber reinforced cementitious composites (CFRCC). Coir fibers of two different average lengths were used, and the longer coir fibers were also treated with a 1% NaOH solution for comparison. The fibers were combined with cementitious materials and chemical agents (dispersant, defoamer or wetting agent) to form CFRCC. The flexural properties of the composites, including elastic stress, flexural strength, toughness and toughness index, were measured. The effects of fiber treatments, addition of chemical agents and accelerated ageing of composites on the composites' flexural properties were examined. The results showed that the CFRCC samples were 5-12 % lighter than the conventional mortar, and that the addition of coir fibers improved the flexural strength of the CFRCC materials. Toughness and toughness index, which were associated with the work of fracture, were increased more than ten times. For the alkalized long coir fiber composites, a higher immediate and long-term toughness index was achieved. SEM microstructure images revealed improved physicochemical bonding in the treated CFRCC.

• 한국안전학회지
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• 제13권3호
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• pp.102-111
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• 1998

This study was concerned with the development of a heavy duty rust-converting agent, the function of which is to form metal complex coatings, containing vinyl halide-acrylic terpolymer emulsion, defoamer, emulsifying agent, glass flakes, chelating agent such as gallotannic acid, gallic acid, and pyrogallic acid, and other additives. The resulted emulsion products(Sample No.1~No.5) were characterized through test either in the forms of emulsions, which include Viscosity, Penetration rate, Acidity and Film drying rate test, or in the forms of coated layer on rusty steel substrates by FT-IR, which include hardness, gloss, salt spray, adhesion and flame retardant test. The test results are as follows ; Penetration rate(0.1~0.4 mm/min), Solid content(70%), Acidity (pH 1.8~2.0), Specific gravity(1.30~1.35), Film drying rate(108min, RH 40% ; 150min, RH 80%), Gloss(83~92, incident angle $60^{\circ}$; 88~97, incident angle $85^{\circ}$), Pencil hardness(4H~5H), Adhesion (100/100), Salt spray test(>720Hr), LOI(%) value(38%), Vertical burning test(UL 94-v-l). According to the various performance of specimens show above, the evaluation of the availability of this heavy duty rust-converting agent can be concluded that all the samples(No.1~No.5) are capable of being used in the field of chemical plant and in the hazard areas of fire and explosion potential. It was observed that the properties of sample No.2, especially gloss and hardness, were much better than that of the other samples.

• 한국포장학회지
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• 제11권1호
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• pp.33-40
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• 2005

This study was carried out for effective utilization of recycling resources to investigate the repulping conditions of car air filter waste paper and to evaluate the application into corrugating medium papermaking by blending these repulped pulps. Car air filter waste paper was made of virgin BKP and it was dipped into phenol resin solution. It was well disintegrated by laboratory Valley beater with 10%(basis on oven-dried pulp weight) NaOH addition and defoamer usage. The optimal temperature, beating consistency and treatment time were mainly $40^{\circ}C$, 1% and $30{\sim}40$ minutes, respectively. Handsheets were prepared with various blending ratios between air filter recycled pulp and KOCC. In the case of $10{\sim}20%$ substitution with air filter recycled pulp, physical properties reductions as compressive strength and burst strength of sheets were lower than others. These results showed more favour than the partial substitution of KOCC for corrugating medium even though some strength reduction of paper. It was also observed that the waste water of air filter recycling was not affective to environmental problems.

• Elastomers and Composites
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• 제35권3호
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• pp.196-204
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• 2000

방수제로 사용하는 EVA 에멀젼 수지에 라텍스 형태의 아크릴 수지, 에폭시 수지, 우레탄 수지, SBR 수지를 전체 혼합물 중에 $0{\sim}50%$ 혼합하여 소포성, 기계적 물성, 내수성 등을 조사하였다. 소포제의 소포효과는 BYK-021이 가장 우수하였으며 적절한 사용량은 전체 혼합물에 대하여 0.3phr이었다. 수축율은 수지간의 상용성과 기공형성도에 영향을 받았으며 기계적 강도는 수지 분자간의 응집력, 수지와 시멘트의 결합력, 시멘트 입자간의 응집력 등에 영향을 받았다. 라텍스를 혼합한 것은 혼합하지 않은 것보다 수축율, 굴곡강도, 접착강도, 충격강도 등에서 우수한 물성을 나타내었다. EVA에 시멘트를 혼합했을 때에는 혼합하지 않았을 때보다 내수성이 떨어졌다.