• 한국염색가공학회지
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• 제20권1호
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• pp.8-15
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• 2008

We presented the modified decal-transfer lithography (DTL) and light stamping lithography (LSL) as new powerful methods to generate patterns of poly(dimethylsiloxane) (PDMS) on the substrate. The microstructures of PDMS fabricated by covalent binding between PDMS and substrate had played as barrier to locally control wettability. The transfer mechanism of PDMS is cohesive mechanical failure (CMF) in DTL method. In the LSL method, the features of patterned PDMS are physically torn and transferred onto a substrate via UV-induced surface reaction that results in bonding between PDMS and substrate. Additionally we have exploited to generate the patterning of rhodamine B and quantum dots (QDs), which was accomplished by hydrophobic interaction between dyes and PDMS micropatterns. The topological analysis of micropatterning of PDMS were performed by atomic force microscopy (AFM), and the patterning of rhodamine B and quantum dots was clearly shown by optical and fluorescence microscope. Furthermore, it could be applied to surface guided flow patterns in microfluidic device because of control of surface wettability. The advantages of these methods are simple process, rapid transfer of PDMS, modulation of surface wettability, and control of various pattern size and shape. It may be applied to the fabrication of chemical sensor, display units, and microfluidic devices.

• 한국수소및신에너지학회논문집
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• 제28권5호
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• pp.433-439
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• 2017

The high temperature performance of PEM type electrolyser at $120^{\circ}C$ based on covalently cross-linked sulfonated poly ether ether ketone (SPEEK) composie membrane was investigated. Ion conductivity and other properties of SPEEK membrane were improved by adding heteropoly acid and Ceria. The membrane electrode assemblies were prepared using commercial PtC and nano-sized $IrRuO_2$ catalyst by electro-spraying and decal process. Voltage efficiency of MEA equipped with SPEEK membrane was slightly better than that of $Nafion^{(R)}$ membrane, due to its higher proton conductivity at high temperature. The cell performance of MEA with CL-SPEEK/Cs-TSiA/Ceria is 1.71 V at $1A/cm^2$ and $120^{\circ}C$.

• Biotechnology and Bioprocess Engineering:BBE
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• 제7권2호
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• pp.76-84
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• 2002

On-line conversion estimation of enzymatic esterification reactions in solvent-free media was investigated. In principle, conversion to ester can be determined from the amount of water produced by the reaction, because water is formed as a by-product in a stoichiometric manner. In this study, we estimated the water production rate only from some measurements of relative humidity and water balances without using any analytical methods. In order to test the performance of the on-line conversion estimation, the lipase-catalyzed esterification of n-capric acid and n-decal alcohol in solvent-free media was performed whilst controlling water activity at various values. The reaction conversions estimated on-line were similar to those determined by offline gas chromatographic analysis. However, when the water activity was controlled at higher values, discrepancies between the estimated conversion values and the measured values became significant. The deviation was found to be due to the inaccurate measurement of the water content in the reaction medium during the initial stages of the reaction. Using a digital filter, we were able to improve the accuracy of the on-line conversion estimation method considerably. Despite the simplicity of this method, the on-line estimated conversions were in good agreement with the off-line measured values.

• 한국정밀공학회지
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• 제18권12호
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• pp.116-123
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• 2001

An automated injection molding design methodology has been developed to optimize multiple quality attributes, which are usually in conflict with each other, in injection molded parts. For the optimization, commercial CAE simulation tools and optimization techniques are integrated into the methodology. To decal with the multiple objective problem the relative closeness computed in TOPSIS(Technique for Order Preference by Similarity to Ideal Solution) is used as a performance measurement index for optimization multiple part defects. To attain robustness against process variation, Taguchi's quadratic loss function is introduced in the TOPSIS. Also, the modified complex method is used as an optimization tool to optimize objective function. The verification of the developed design methodology was carried out on simulation software with an actual model. Applied to production this methodology will be useful to companies in reducing their product development time and enhancing their product quality.

• 한국의상디자인학회지
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• 제17권1호
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• pp.53-68
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• 2015

The purpose of this study is to analyze check pattern of nail art from 2011 to 2013. The results of this study are as follows; 1) Check pattern of nail art is total 257 patterns, and there are 84 argyle, 29 tartan, 24 harlequin, 24 over, 23 window-pane, 15 stitcheds, 13 hound tooth, 10 block, 10 madras, 8 gingham, 8 gradation, 7 shepherd, and 2 tattersall check patterns. Through this result, in nail art, the relatively simple patterns such as a vertical pattern, a horizontal pattern, and cross or overlap diagonal line are used more than elaborate and complex check patterns of a fibrous tissue from a weaving process. 2) In check pattern of nail art, N-affiliated color and R-affiliated color are remarkably well-used, because of the effects of argyle, tartan, window-pane, harlequin, stitched, over, and hound tooth check patterns used the most during the past three years. Especially, most tartan, harlequin, over, and hound tooth check patterns use their own special colors such as R-affiliated colors and N-affiliated colors as it is, and argyle, window-pane, stitched, and over check patterns use well by arranging N-affiliated colors and R-affiliated colors. 3) The most used expressive technique is hand painting to express check pattern in nail art, because new products related to UV gel are well launched. These materials can draw fine line that is hard to express by existing polish easily and simply, and not only have set quickly hard, so procedure time is very short, so it is compatible to draw check pattern personally, but also it is well covered, so check pattern is more clearly expressed.

• 디지털융복합연구
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• 제15권8호
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• pp.359-366
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• 2017

삶의 질이 높아지고 상품의 미적가치가 강조되면서 상품을 디자인하는데 있어 소비자의 감성을 고려하는 경향이 커지고 있다. 상품의 구매요인이 제품의 기능 중심에서 감성 중심으로 이동함에 따라 스토리텔링의 중요성이 과거보다 더욱 부각되고 있다. 이에 본 논문에서는 스토리텔링을 적용한 감성마케팅 공예디자인 개발에 목적을 두고 스토리텔링 개념의 이해와 스토리텔링을 적용한 공예디자인 사례 분석을 하고 이를 바탕으로 도자접시에 설화인 별주부전의 이야기를 과거와 현재가 융합되어 위트 있게 변형되어진 내용으로 재구성하여 스토리가 담긴 공예품을 만들고자 하였다. 공예는 상품으로의 가치나 미적 가치에 용이한 분야로 디자인의 다양성과 독창성이 추구될 수 있는 무한한 잠재력을 지니고 있다. 이제 표현적 가치뿐 아니라 의미적 가치의 부여와 함께 소비자의 감성과 욕구 충족을 시켜주는 공예디자인 개발이 필요하며 본 연구가 공예산업이 좀 더 고부가가치 산업으로 자리매김 할 수 있는 토대에 활용 되었으면 한다.

• 디지털융복합연구
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• 제15권5호
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• pp.333-338
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• 2017

현대 도자예술은 다양한 표현기법을 가지고 있다. 그 중에서 현대사회의 디지털화로 인하여 전사기법이 발전하게 되었고 전사기법은 현대도예의 표현매체로 활용되어지고 있다. 그러나 전사기법은 단순히 획일적이며 대량생산을 위한 현장에서의 적극적 활용에 비해 소공예 작가들이 전사기법을 활용해 그들의 작품에 응용할 예술적, 이론적인 충분한 정보를 주지 못하고 있다. 이에. 본 논문에서는 전사기법의 의미를 이해하고 작가의 개성과 예술성을 전사기법으로 표현한 현대 도예작가들의 작품을 고찰해 봄으로써 전사기법이 현대도예의 표현 매체로 도자공예의 미적 예술적 효과를 높일 수 있으며 좀 더 고부가가치 산업으로 자리매김 할 수 있는 토대를 마련하고자 한다.

• 전기화학회지
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• 제11권1호
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• pp.16-21
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• 2008

직접메탄올 연료전지 (DMFC)의 핵심 구성 요소 중에서 하나는 고분자 전해질막과 촉매층 (연료극과 공기극)으로 구성된 전해질/전극 접합체 (MEA)이다. 그중에서 촉매층은 브러싱법, 전시법, 스프레이 코팅법, 스크린 프린팅법과 같은 다양한 방법을 사용하여 carbon paper나 carbon cloth등과 같은 전극 지지체 위에 코팅한다. 그러나 이러한 촉매 코팅방법들은 전극 지지체 위에 촉매를 균일한 두께로 코팅하기 어렵고, 촉매의 손실이 많으며, 또한 코팅 시간이 많이 필요하다는 단점들이 있다. 본 연구에서는 DMFC용 MEA의 전극층을 바코팅 방법 (bar-coating method)을 사용하여 한 번에 원하는 양의 촉매가 코팅되도록 제조하였다. 이렇게 제조한 전극 촉매층 표면과 단면의 형태를 SEM을 사용하여 관찰하였다. 제조한 MEA의 성능과 저항은 단위전지와 임피던스 분석기를 사용하여 측정하였다.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2006년도 춘계학술대회
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• pp.110-112
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• 2006

Membrane electrode assembly (MEA) for polymer electrolyte fuel cell (PEFC) are commonly prepared in the research laboratory by spraying, screen-printing and brushing catalyst slurry onto membrane or other support material like carbon paper or polyimide film in a batch style. These hand applications of the catalyst slurry are painstaking process with respect to precision of catalyst loading and reproducibility. It has been generally mentioned that the adoption of continuous process is very helpful to develop the reliable product. In the present work, we report the results of using continuous type coater with doctor-blade to coat catalyst slurry for preparing the MEA catalyst layers In a faster and highly reproducible fashion. We show that while expectedly faster than batch style, the machine coater requires the use of slurry of appropriate composition and a properly selected transfer decal material in order to achieve superior MEA plat lnw loading reproducibility. To make highly viscous catalyst slurry that is imperative for using coater, we use 40wt.% Nafion solution and minimize the content of organic solvent. And the choice of proper high surface area catalyst is important in the viewpoint of making well-dispersed slurry. After catalyst coating onto the support material, we transferred the catalyst layer to both sides of Nafion membrane by hot-pressing In this case, the degree of transfer was Influenced by hot-pressing condition including temperature, pressure, and time. To compare the transferring ability, we compared so many films and detaching papers. And among the support, polyethylene terephthalate(PET) film shows the prominent result.

• Journal of Electrochemical Science and Technology
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• 제10권1호
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• pp.22-28
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• 2019

To maximize the oxygen evolution reaction (OER) in the electrolysis of water, nano-grade $IrO_2$ powder with a low specific surface was prepared as a catalyst for a solid polymer electrolyte (SPE) system, and a membrane electrode assembly (MEA) was prepared with a catalyst loading as low as $2mg\;cm^{-2}$ or less. The $IrO_2$ catalyst was composed of heterogeneous particles with particle sizes ranging from 20 to 70 nm, having a specific surface area of $3.8m^2g^{-1}$. The anode catalyst layer of about $5{\mu}m$ thickness was coated on the membrane (Nafion 117) for the MEA by the decal method. Scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS) confirmed strong adhesion at the interface between the membrane and the catalyst electrode. Although the loading of the $IrO_2$ catalyst was as low as $1.1-1.7mg\;cm^{-2}$, the SPE cell delivered a voltage of 1.88-1.93 V at a current density of $1A\;cm^{-2}$ and operating temperature of $80^{\circ}C$. That is, it was observed that the over-potential of the cell for the oxygen evolution reaction (OER) decreased with increasing $IrO_2$ catalyst loading. The electrochemical stability of the MEA was investigated in the electrolysis of water at a current density of $1A\;cm^{-2}$ for a short time. A voltage of ~2.0 V was maintained without any remarkable deterioration of the MEA characteristics.