• Title/Summary/Keyword: dcp-1

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Electrical Properties of XLPE Power Cable by DCP and TMPTA Content (전력 cable용 XLPE의 제조과정 중 가교제와 가교조제의 함량이 미치는 전기적 특성)

  • Kim, Gyu-Sik;Lim, Kee-Joe;Ryu, Boo-Hyung;Park, Soo-Gil
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.2077-2080
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    • 2000
  • We studied about electrical, chemical and mechanical characteristics of XLPE by dicumyl peroxide(DCP) and trimethylolpropane triacrylate(TMPTA) content ratio. DCP content was changed from 1.0 to 2.5phr increasing 0.5phr. TMPTA content was changed 0.5 to 1.5phr increasing 0.5phr. Thermal analysis (DSC) was carried out in order to observe tendency of 79 according to DCP and TMPTA content. In experimental results, content DCP 2.0phr and TMPTA 1.0phr has highest breakdown strength. Content DCP 2.0phr and TMPTA 0.5phr has lowest dielectric constant. Tendency of Tg did not affected by DCP and TMPTA content. Breakdown strength and Specific inductive capacity was measured.

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1,3-Dichloro-2-Propanol (1,3-DCP) Induced Cell Damage (1,3-Dichloro-2-Propanol (1,3-DCP)에 의한 세포의 손상기전)

  • Jeong, Ji-Hak;Sin, Ik-Jae;Sin, Yeong-Min;Park, Heung-Jai;An, Won-Gun
    • Journal of Environmental Science International
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    • v.16 no.2
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    • pp.219-225
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    • 2007
  • Endocrine disrupting compounds (EDC's) are chemicals that either mimic endogenous hormones interfering with pharmacokinetics or act by other mechanisms. Some endocrine disrupters were reported to be chemical substances that cause apoptosis in cells. A number of reports have indicated that 1,3-DCP, one of the EDC's may act as an endocrine disrupter and also has possible carcinogenic effects. 1,3-DCP, present in commercial protein hydrolysates used for human nutrition, are genotoxic and 1,3-dichloro-2-propanol induced tumors in rats. In the present study, it was investigated whether 1,3-DCP induces ROS generation and apotosis in A549 adenocarcinoma cells. Here we show that 1,3-DCP inhibits the growth of lung cancer cell lines and generates reactive oxygen species (ROS), a major cause of DNA damage and genetic instability, It was investigated that 1,3-DCP increases G1 phase cells after 12 hours, thereafter abruptly draws A549 cells to G0 state after 24 hours by flow cytometric analysis. 1,3-DCP induces p53 and $p21^{Cip1/WAF1}$ activation time- and dose-dependently by 24 hours, while the level $p21^{Cip1/WAF1}$ was decreased after 48 hours. These results suggest that 1,3-DCP, an EDC's generates ROS and regulates genes involved with cell cycle and apoptosis.

Survey of Contaminants of 3-MCPD and 1,3-DCP in Soy Sauce Using GC/MSD (GC/MSD를 이용한 간장 중 3-MCPD와 1,3-DCP의 오염도 조사)

  • Kim Myung-Gill;Kim Young-Sug;Lee Myung-Jin;Kim Jae-Kwan;Kim Kyung-A;Park Eun-Mi;Ko Hoan-Uck;Son Jin-Seok
    • Journal of Food Hygiene and Safety
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    • v.21 no.3
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    • pp.153-158
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    • 2006
  • The contamination levels of 3-MCPD(3-Monochloropropane-1,2-diol) and 1,3-DCP(1,3-Dichloro-2-Propanol) in soy sauce, sauces was monitored. 105 samples were collected from June 2005 to August 2005 in Gyeonggi-do. 3-MCPD and 1,3-DCP were analyzed by GCMSD. As results, the detection range of 3-MCPD concentration was between 0.02 mg/kg and 0.27 mg/kg in soy sauce. However any samples were not detected with 1,3-DCP. The contaminated rates of 3-MCPD in soy sauce was 17.1%. Soy sauce is the representative vegetable protein hydrolyzed food. The reliable analytical method f3r the toxic 3-MCPD and 1,3-DCP in Soy sauce has been studied. The derivatization studies of 3-MCPD and 1,3-DCP were performed mainly as Silylation with BSA(N,O-Bis(trimethylsilyl)-acetamide). The retention times of derivative, BSA-MCPD, BSA-DCP were 11.30 and 10.12 minutes.

Insulation properties of XLPE by adding Cross-linking Agent and Cross-linking Agent and Cross-linking Co-agent (가교제와 가교조제 함량에 따른 XLPE의 절연특성)

  • 김규식;임기조;손원근;박수길
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.715-718
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    • 2000
  • We studied about electrical, chemical and mechanical characteristics of XLPE by dicumyl peroxide(DCP) and trimethylolpropane triacrylate(TMPTA) content ratio. DCP content was changed from 1.0 to 2.Sphr increasing 0.5phr. TMPTA content was changed 0.5 to 1.5phr increasing 0.5phr. Thermal analysis (DSC) was carried out in order to observe tendency of Tg according to DCP and TMPTA content. Tensile strength was measured in order to observe mechanical strength. In experimental results, content DCP 2.0phr and TMPTA 1.0phr has highest breakdown strength. Content DCP 2.0phr and TMPTA 0.5phr has lowest dielectric constant. Tendency of Tg did not affected by DCP and TMPTA content. Breakdown strength and Specific inductive capacity was measured.

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Expression of rpr, grim, dcp-1, diapl, and diap2 during Drosophila Development (노랑초파리 발생과정에서 rpr, grim, dcp-1, diapl, diap2의 발현)

  • Park, Ji-Gweon;Chung, Ki-Wha;Kim, Se-Jae
    • Development and Reproduction
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    • v.5 no.2
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    • pp.131-136
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    • 2001
  • The developmental profiles of rpr, grim, dcp-1, diapl, diap2 transcripts, which were involved in programmed cell death, were analyzed using competitive RT-PCR in whole animals during Drosophila development. The fluctuation patterns of transcript levels of the apoptotic initiators(rpr and grim) were similar to those of the ecdysone titer in Drosophila life cycle. The transcript of dcp-1, which is considered as effector caspase, was expressed strong1y at early embryo and female adult stages. However, the transcript levels of anti-apoptotic factors diap1 and diap2, showed the reverse pattern comparing with those of apoptotic factors(rpr and grim). Also, the transcript levels of rpr, diap2 and dcp-1 were quantified in the salivary glands and wing discs dissected from the wandering late third instar larva. The transcript levels of rpr and diap2 were changed reversely each other in both tissues from wandering stage to puparium formation. These results suggest that the expressions of cell death related genes are regulated by the ecdysone signals during normal development.

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Effect of Feeding of Citrus Byproduct on the Physicochemical Properties and Palatability of Pork Loin during Growing Period (성장기에 급여한 감글 부산물이 돈육등심의 이화학적 특성 및 기호성에 미치는 영향)

  • Jung, In-Chul;Moon, Yoon-Hee;Yang, Sung-Joo
    • Journal of Life Science
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    • v.16 no.7 s.80
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    • pp.1164-1168
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    • 2006
  • This study was carried out to investigate the possible for utilization of garbage in pig feed by investigating the functional characteristics of pork from pigs fed dried citrus byproduct. The samples consisted of the pork loin from pigs not fed with dried citrus pulp (DCP-0) and fed with 6% and 10% dried citrus pulp during growing and fattening period (DCP-1) there is no respective comparison here The pH, VBN content, TBARS value, bacterial counts, surface color, water holding capacity, loss degree and rheological properties of the samples were determined by physicochemical properties, and the sensory scores were evaluated. The pH, VBN content, surface color, water holding capacity and loss degree were not different between the samples, but the TBARS value and bacterial counts of DCP-1 were significantly lower than those of the DCP-0 (p<0.05). The cohesiveness, gumminess, chewiness, shear forte value, taste, flavor, tenderness, juiciness and palatability were not different between the samples, but the hardness of DCP-0 was higher than that of the DCP-1 and the springiness of DCP-1 was higher than that of the DCP-0 (p<0.05).

Development of On-Site Process for Refractory 2,4-Dichlorophenol Treatment (난분해성 2,4-Dichlorophenol 처리를 위한 원위치 처리 프로세스 개발 연구)

  • Park, Kyeong-Deok;Kim, Il-Kyu
    • Journal of Power System Engineering
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    • v.20 no.1
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    • pp.42-49
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    • 2016
  • This study showed that on-site ferrate(VI) solution was synthesized by wet oxidation method and applied aqueous 2,4-dichlorophenol(DCP) solution to evaluate the degradation efficiency. On-site ferrate(VI) solution was synthesized by putting $FeCl_3{\cdot}6H_2O$ in the strong alkali solution with NaClO and NaOH and applied DCP solution directly. DCP solution was extracted by the liquid-liquid method and analyzed by GC-ECD. The factors such as pH, DCP initial concentration, injected ferrate(VI) dosage, temperature were investigated. The optimum pH and temperature conditions of DCP degradation were obtained in neutral condition and $35^{\circ}C$. And the experimental results showed that DCP removal efficiency also increased with the decrease of DCP initial condition and the injected ferrate(VI) dosage.

Analysis of Peroxide Curing Agents in EVA Compounds and Vulcanizates

  • Chae, Eunji;Choi, Sung-Seen
    • Elastomers and Composites
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    • v.55 no.1
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    • pp.6-12
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    • 2020
  • Poly(ethylene-co-vinyl acetate) compounds and vulcanizates containing dicumyl peroxide (DCP) (HD) were prepared, and the curing agent and reaction products were analyzed using gas chromatography/mass spectrometry (GC/MS). Samples containing trially cyanurate (TAC) and DCP (HDT) were also prepared and analyzed. Some raw DCP were decomposed in the injector region of GC to produce acetophenone. DCP was detected in the HD compound but was not observed in the HD vulcanizate, and instead acetophenone and 2-phenyl-2-propanol were detected. Both DCP and TAC were observed in the HDT compound but not in the HDT vulcanizate, where acetophenone and 2-phenyl-2-propanol were detected. Thus, some of the DCP decomposed during the compounding process. The formation mechanism for acetophenone and 2-phenyl-2-propanol during the crosslinking reaction was identified, and differences in the crosslinking reactions of HD and HDT compounds were discussed.

Physical and Chemical Properties of Cross Linked Polyethylene (Cross Linked Polyethylene의 물리적 및 화학적 성질)

  • 김한주;김규식;박종은;박수길;임기조
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.516-519
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    • 1999
  • XLPE (Cross-Linked Polyethylene) which has good electric and physical characteristic is ideal material for Insulating material with force high volumetric resistance arid high dielectric constant. We study abort electric characteristics of XLPE by DCP and TMPTA content ration. DCP (Dicumylperoxide), which was used cross-linked agent contest, was changed from 1.0 to 0.5phr. TMPTA (Trimethyl-olpropane), which was used co cross-linked agent content, was changed from 0.5 to 1.5phr. Thermal analysis by DSC in order to observe tendency of Tg according to DCP and TMPTA content. Specimen 3 that content DCP 2.0phr and TMPTA 0.5phr has the highest value Breakdown strength cf specimen 3 (DCP 2.Ophr, TMPTA 1.0phr) is the highest, value and it increased in specific inductive capacity. This due to difference from cross-linked state by DCP and TMPTA content ratio.

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Analysis of 3-MCPD and 1,3-DCP in Various Foodstuffs Using GC-MS

  • Kim, Wooseok;Jeong, Yun A;On, Jiwon;Choi, Ari;Lee, Jee-yeon;Lee, Joon Goo;Lee, Kwang-Geun;Pyo, Heesoo
    • Toxicological Research
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    • v.31 no.3
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    • pp.313-319
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    • 2015
  • 3-Monochloro-1,2-propanediol (3-MCPD) and 1,3-dichloro-2-propanol (1,3-DCP) are not only produced in the manufacturing process of foodstuffs such as hydrolyzed vegetable proteins and soy sauce but are also formed by heat processing in the presence of fat and low water activity. 3-MCPD exists both in free and ester forms, and the ester form has been also detected in various foods. Free 3-MCPD and 1,3-DCP are classified as Group 2B by the International Agency for Research on Cancer. Although there is no data confirming the toxicity of either compound in humans, their toxicity was evidenced in animal experimentation or in vitro. Although few studies have been conducted, free 3-MCPD has been shown to have neurotoxicity, reproductive toxicity, and carcinogenicity. In contrast, 1,3-DCP only has mutagenic activity. The purpose of this study was to analyze 3-MCPD and 1,3-DCP in various foods using gas chromatography-mass spectrometry. 3-MCPD and 1,3-DCP were analyzed using phenyl boronic acid derivatization and the liquid-liquid extraction method, respectively. The analytical method for 3-MCPD and 1,3-DCP was validated in terms of linearity, limit of detection (LOD), limit of quantitation, accuracy and precision. Consequently, the LODs of 3-MCPD and 1,3-DCP in various matrices were identified to be in the ranges of 4.18~10.56 ng/g and 1.06~3.15 ng/g, respectively.