• Journal of the Korean Electrochemical Society
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• v.6 no.2
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• pp.119-129
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• 2003

The Langmuir adsorption isotherms of the over-potentially deposited hydrogen (OPD H) fur the cathodic $H_2$ evolution reaction (HER) at the poly-Au and $Rh|0.5M\;H_2SO_4$ aqueous electrolyte interfaces have been studied using cyclic voltammetric and ac impedance techniques. The behavior of the phase shift $(0^{\circ}{\leq}{-\phi}{\leq}90^{\circ})$ for the optimum intermediate frequency corresponds well to that of the fractional surface coverage $(1{\geq}{\theta}{\geq}0)$ at the interfaces. The phase-shift profile $({-\phi}\;vs.\;E)$ for the optimum intermediate frequency, i.e., the phase-shift method, can be used as a new electrochemical method to determine the Langmuir adsorption isotherm $({\theta}\;vs.\;E)$ of the OPD H for the cathodic HER at the interfaces. At the poly-Au|0.5M $H_2SO_4$ aqueous electrolyte interface, the equilibrium constant (K) and the standard free energy $({\Delta}G_{ads})$ of the OPD H are $2.3\times10^{-6}$ and 32.2kJ/mol, respectively. At the poly-Rh|0.5M $H_2SO_4$ aqueous electrolyte interface, K and ${\Delta}G_{ads}$ of the OPD H are $4.1\times10^4\;or\;1.2\times10^{-2}$ and 19.3 or 11.0kJ/mol depending on E, respectively. In contrast to the poly-Au electrode interface, the two different Langmuir adsorption isotherms of the OPD H are observed at the poly-Rh electrode interface. The two different Langmuir adsorption isotherms of the OPD H correspond to the two different adsorption sites of the OPD H on the poly-Rh electrode surface.

• Journal of the Institute of Electronics and Information Engineers
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• v.50 no.11
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• pp.78-89
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• 2013

This paper proposes a high-throughput and multi-mode quasi-cyclic (QC) low-density parity-check (LDPC) decoder based on a fully parallel structure. The proposed QC-LDPC decoder employs the fully parallel structure to provide very high throughput. The high interconnection complexity, which is the general problem in the fully parallel structure, is solved by using a broadcasting-based sum-product algorithm and proposing a low-complexity cyclic shift network. The high complexity problem, which is caused by using a large amount of check node processors and variable node processors, is solved by proposing a combined check and variable node processor (CCVP). The proposed QC-LDPC decoder can support the multi-mode decoding by proposing a routing-based interconnection network, the flexible CCVP and the flexible cyclic shift network. The proposed QC-LDPC decoder is operated at 100 MHz clock frequency. The proposed QC-LDPC decoder supports multi-mode decoding and provides 8.1 Gbps throughput for a (1944, 1620) QC-LDPC code.

• Journal of Sensor Science and Technology
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• v.17 no.5
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• pp.369-374
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• 2008

A novel fiber optic surface plasmon resonance (SPR) sensor using cyclic olefin copolymer (COC) prism with the spectral modulation is presented. The SPR sensor chip is fabricated using the SU-8 photolithography, Ni-electroplating and COC injection molding process. The sidewall of the COC prism is partially deposited with Au/Cr (45/2.nm thickness) by e-beam evaporator, and the thermal bonding process is conducted for micro fluidic channels and optical fibers alignment. The SPR spectrum for a phosphate buffered saline (0.1.M PBS, pH.7.2) solution shows a distinctive dip at 1300.nm wavelength, which shifts toward longer wavelength with respect to the bovine serum albumin (BSA)concentrations. The sensitivity of the wavelength shift is $1.16\;nm{\cdot}{\mu}g^{-1}{\cdot}{\mu}l^{-1}$. From the wavelength of SPR dips, the refractive indices (RI) of the BSA solutions can be theoretically calculated using Kretchmann configuration, and the change rate of the RI was found to be $2.3{\times}10^{-5}RI{\cdot}{\mu}g^{-1}{\cdot}l^{-1}$. The realized fiber optic SPR sensor with a COC prism has clearly shown the feasibility of a new disposable, low cost and miniaturized SPR biosensor for biochemical molecular analyses.

• The Journal of the Korea institute of electronic communication sciences
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• v.13 no.2
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• pp.333-340
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• 2018

This paper introduces a BCH code decoder using parallel CRC(: Cyclic Redundancy Check) generation. Using a conventional parallel syndrome generator with a LFSR(: Linear Feedback Shift Register), it takes up a lot of space for a short code. The proposed decoder uses the parallel CRC method that is widely used to compute the checksum. This scheme optimizes the a syndrome generator in the decoder by eliminating redundant xor operation compared with the parallel LFSR and thus minimizes chip area and propagation delay. In simulation results, the proposed decoder has accomplished propagation delay reduction of 2.01 ns as compared to the conventional scheme. The proposed decoder has been designed and synthesized in $0.35-{\mu}m$ CMOS process.

• Journal of the Korea Society of Computer and Information
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• v.17 no.3
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• pp.1-10
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• 2012

A low-complexity Multiplication over GF(2m) and multiplier circuit has been proposed by using cyclic-shift coefficients and the irreducible trinomial. The proposed circuit has the parallel input/output architecture and shows the lower-complexity than others with the characteristics of the cyclic-shift coefficients and the irreducible trinomial modular computation. The proposed multiplier is composed of $2m^2$ 2-input AND gates and m (m+2) 2-input XOR gates without the memories and switches. And the minimum propagation delay is $T_A+(2+{\lceil}log_2m{\rceil})T_X$. The Proposed circuit architecture is well suited to VLSI implementation because it is simple, regular and modular.

• Journal of the Earthquake Engineering Society of Korea
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• v.10 no.3 s.49
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• pp.47-55
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• 2006

Seismic performance and retrofit of reinforced concrete (RC) two-column piers widely used at roadway bridges in Korea was experimentally evaluated. Ten two-column piers that were 400 mm in diameter and 2,000 mm in height were constructed. These piers were subjected to hi-directional cyclic loadings under a constant axial load of $0.1f_{ck}A_g$. Test parameters were the confinement steel ratio, loading pattern, lap splice of longitudinal reinforcing bars, and retrofitting method. Specimens with lap-spliced longitudinal bars were retrofitted with steel jacket, pre-stressing steel wire, and steel band. Test result showed that while the specimens subjected to bi-directional lateral cyclic loadings which consisted of two main amplitudes in the transverse axis and two sub amplitudes in longitudinal axis, referred to as a T-series cyclic loadings, exhibited plastic hinges both at the top and bottom parts of the column, the specimens subjected to bi-directional lateral cyclic loadings in an opposite way, referred to as a L-series cyclic loadings, exhibited a plastic hinge only at the bottom of the column. The displacement ductility of the specimen under the T-series loadings was bigger than that of the specimen under the L-series loadings. Specimen retrofitted with pre-stressing steel wires exhibited poor ductility due to the upward shift of the plastic hinge region because of over-reinforcement, but specimens retrofitted with steel jacket and steel band showed the required displacement ductility. Steel band can be an effective retrofitting scheme to improve the seimsic performance of RC bridge piers, considering its practical construction.

• Proceedings of the Korea Electromagnetic Engineering Society Conference
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• 2003.11a
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• pp.403-406
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• 2003

In this paper, we have proposed a carrier recovery algorithm of OFDM/QPSK-DMR(Orthogonal Frequency Division Multiplexing/Quadrature Phase Shift Keying Modulation-Digital Microwave Radio)system using BL-PSF(Band Limited-Pulse Shaping Filter) and have analyzed the carrier phase MSE(Mean Square Error) performance of OFDM/QPSK and single carrier DMR systems. The existing OFDM/QPSK-DMR system using windowing requires training sequence or CP(Cyclic prefix) to synchronize a receive. carrier frequency. Because in the OFDM/QPSK-DMR system using BL-PSF there is no training sequence or CP(Cyclic Prefix), we also propose a carrier recovery useful to the system. The simulation results confirm that the proposed carrier recovery algorithm has the same carrier phase MSE(Mean Square Error) performance for the single carrier DMR system under AWGN(Additive White Gaussian Noise) environment.

• Proceedings of the Korea Electromagnetic Engineering Society Conference
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• 2003.11a
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• pp.394-397
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• 2003

In this paper, we have proposed a clock recovery algorithm of OFDM/QPSK-DMR(Orthogonal Frequency Division Multiplexing/Quadrature Phase Shift Keying Modulation-Digital Microwave Radio)system using BL-PSF(Band Limited-Pulse Shaping Filter) and have analyzed the clock phase error variance performance of OFDM/QPSK and single carrier DMR systems. The existing OFDM/QPSK-DMR system using the windowing requires training sequence or CP(Cyclic Prefix) to synchronize a receiver clock frequency Because there is no training sequence or CP(Cyclic prefix) in our proposed DMR system, the proposed clock recovery algorithm is useful to the OFDM/QPSK-DMR system using BL-PSF, The simulation results confirm that the proposed clock recovery algorithm has the same clock phase error variance performance in a single carrier DMR system under AWGN(Additive White Gaussian Noise) environment.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.19 no.3
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• pp.246-249
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• 2006

We fabricated self-assembled monolayers(SAMs) onto quartz crystal microbalance(QCM) using viologen, which has been widely used as electron acceptor and electron transfer mediator. We determined the time dependence on resonant frequency shift during self-assembly process and observed the morphology of self-assembled monolayers by STM and investigated the electrochemical behavior of SAMs by cyclic voltammetry. Electrochemical deposition of viologen was investigated using electrochemical quartz crystal microbalance(EQCM). The redox reactions of viologen were highly reversible and the EQCM has been employed to monitor the electrochemically induced adsorption of SAMs during the redok reactions. The total frequency change was about 9.5 Hz, and 7.1 Hz. From the data, we could know the mass change was about 10.16 ng and 7.60 ng, respectively. Finally, the EQCM has been employed to monitor the electrochemically induced adsorption of self-assembled monolayers on Au surfaces.

• Archives of Pharmacal Research
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• v.24 no.2
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• pp.100-104
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• 2001

Differential pulse polarographic(DPP) analytical procedure for the rifampicin antibiotic, which can be applied to monitor its synthetic process from the starting antibiotic of rifamycin B or rifamycin SV has been developed based on the electrochemical reduction of an azomethine group. Rifampicin exhibited a cathodic peak due to the azomethine group in the side chain of 3-[(4-methyl-1-piperazinyl)imino]methyl moiety and another cathodic peak due to the carbonyl group in rifamycin SV by DPP. The experimental peak potential shift of an azomethine reduction was -73 mV/pH in the pH range between 3.0 and 7.5, agreeing with involvement of 4 e-and 5 $H^5$ in its reduction. By the cyclic voltammetric(CV) studies, the azomethine and the carbonyl reductions in rifampicin were processed irreversibly on the mercury electrode. The plot of peak currents vs. concentrations of rifampicin ranging $1.0{\times}10^{-7} M~$1.0{\times}10^{-5} M yielded a straight line with a correlation coefficient of 0.9996. The detection limit was $1.0{\times}10^{-8} M with a modulation amplitude of 50 mV DPP has been successfully applied for the determination of rifampicin in the pharmaceutical preparations.