• Title/Summary/Keyword: cyclic curing

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Effect on the Residual Stress of Cure Profiles, Fillers and Mold Constraints in an Epoxy System

  • Moon, Chang-Kwon;Nam, Ki-Woo
    • Journal of Ocean Engineering and Technology
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    • v.23 no.4
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    • pp.1-5
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    • 2009
  • A dilatometer was used to investigate the effect of cure conditions, mold types and the presence of filler in an epoxy system. These studies showed shrinkage in the cured epoxy when heating it through the glass transition temperature region. The magnitude of the shrinkage, related to stress build up in the epoxy during curing, was influenced by the processing conditions, filler presence and the nature of the mold used to contain the resin. Cure and cyclic cure at a lower temperature, prior to a post cure, decreased the magnitude of observed shrinkage. Cure shrinkage decreased with the number of cyclic cures. Post cured samples outside the mold led to less shrinkage compared with samples in the mold. Sample cured in a silicon mold represented less shrinkage than sample cured in an aluminum mold. Sample containing kaolin filler showed less shrinkage than unfilled sample.

An experimental investigation on dynamic properties of various grouted sands

  • Hsiao, Darn-Horng;Phan, Vu To-Anh;Huang, Chi-Chang
    • Geomechanics and Engineering
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    • v.10 no.1
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    • pp.77-94
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    • 2016
  • Cyclic triaxial and resonant column tests were conducted to understand the beneficial effects of various grouted sands on liquefaction resistance and dynamic properties. The test procedures were performed on a variety of grouted sands, such as silicate-grouted sand, silicate-cement grouted sand and cement-grouted sand. For each type of grout, sand specimen was mixed with a 3.5% and 5% grout by volume. The specimens were tested at a curing age of 3, 7, 28 and 91 days, and the results of the cyclic stress ratio, the maximum shear modulus and the damping ratio were obtained during the testing program. The influence of important parameters, including the type of grout, grout content, shear strain, confining pressure, and curing age, were investigated. Results indicated that sodium silicate grout does not improve the liquefaction resistance and shear modulus; however, silicate-cement and cement grout remarkably increased the liquefaction resistance and shear modulus. Shear modulus decreased and damping ratio increased with an increase in the amplitude of shear strain. The effect of confining pressure on clean sand and sodium silicate grouted sand was found to be insignificant. Furthermore, a nonlinear regression analysis was used to prove the agreement of the shear modulus-shear strain relation presented by the hyperbolic law for different grouted sands, and the coefficients of determination, $R^2$, were nearly greater than 0.984.

Manufacture of Cement-Bonded Particleboards from Korean Pine and Larch by Curing of Supercritical CO2 Fluid

  • Suh, Jin-Suk;Hermawan, Dede;Kawai, Shuichi
    • Journal of the Korean Wood Science and Technology
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    • v.28 no.4
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    • pp.41-50
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    • 2000
  • Cement-bonded particleboard is being used as outdoor siding material all over the world, because this composite particularly bears a light weight, high resistance against fire, decay, and crack by cyclic freezing and thawing, anti-shock property, and strength enhancement. Construction systems are currently changing into a frame-building style and wooden houses are being constructed with prefabrication type. Therefore, they require a more durability at outdoor-exposed sides. In this study, the cement hydration property for Korean pine particle, Japanese larch particle and face- and middle layer particles (designated as PB particle below) used in Korean particleboard-manufacturing company was investigated, and the rapid manufacturing characteristics of cement-bonded particleboard by supercritical $CO_2$ curing was evaluated. Korean pine flour showed a good hydration property, however, larch flour showed a bad one. PB particle had a better hydration property than larch flour. The addition of $Na_2SiO_3$ indicated a negative effect on hydration, however, $MgCl_2$ had a positive one. Curing by supercritical $CO_2$ fluid gave a conspicuous enhancement in the performances of cement-bonded particleboards compared to conventional curing. $MgCl_2$ 3%-added PB particle had the highest properties, and $MgCl_2$ 1%-added Korean pine particle had the second class with the conditions of cement/wood ratio of 2.7, a small fraction-screened particle and supercritical curing. On the contrary, the composition of non-hammermilled or large fraction-screened particle at cement/wood ratio of 2.2 was poorer. Also, the feasibility for actual use of 3%-added, small PB particle-screened fraction was greatest of all the conventional curing treatments. Relative superiority of supercritical curing vs. conventional curing at dimensional stability was not so apparent as in strength properties. Through the thermogravimetric analysis, it was ascertained that the peak of a component $CaCO_3$ was highest, and the two weak peaks of calcium silicate hydrate and ettringite and $Ca(OH)_2$ were present in supercritical treatment. Accordingly, it was inferred that the increased formation of carbonates in board contributes to strength enhancement.

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Strength and Durability Properties of Concretes Using Ground Granulated Blast-Furnace Slag According to Steam Curing Types (고로(高爐)슬래그 미분말(微分末)을 사용한 콘크리트의 증기양생(蒸氣養生)에 따른 강도(强度) 및 내구특성(耐久特性))

  • Hong, Chang-Woo;Jang, Ho-Sung;Jeong, Won-Kyong
    • Resources Recycling
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    • v.15 no.4 s.72
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    • pp.52-59
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    • 2006
  • The purpose of this study was to evaluate the effects of ground granulated blast-furnace slag on strength development and durability of ordinary portland cement concrete (OPC) with steam curing types. Main experimental variables were slag contents(0%, 10%, 30%, 50%, 70%) and curing types (standard, accelerated curing). It were performed to check the basic properties of concretes that compressive strength, rapid chloride ion permeability and chemical resistance. From the result, we have found that increasing the amount of blast-furnace slag produced concrete with increased compressive strength and permeability resistance. Rapid freezing-thawing test showed that they were good enough to protect the concrete structures and to carry out cyclic freezing and thawing. The freeze-thaw resistance of blast-furnace slag produced concretes maintained above 90% of relative dynamic modulus after 300 freezing-thawing cycles. Increasing the amount of blast-furnace slag produced concretes with increased chemical resistance.

Characteristic evaluation of settlement and stiffness of cement-treated soils with the change of fines content under cyclic dynamic loading (세립분 함량 변화에 따른 반복 동하중을 받는 시멘트 혼합토의 침하 및 강성 특성평가)

  • Kim, Dae Sang
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.10
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    • pp.23-29
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    • 2020
  • The soil structures settle down continuously under cyclic dynamic loading after opening railway lines. This study examined the characteristics of the settlement and stiffness of cement-treated soils with the change in the content of fines under cyclic dynamic loading. Eighteen cases of the test were carried out with the changes in the fines content of soils, cement content, and curing days. Based on the test results, cement-treated soils containing more than 3% of cement could decrease settlement sufficiently even with a high portion of fines under cyclic dynamic loading. In addition, the elastic and plastic settlements could be reduced using 3 to 4% cement to the level of 1/4 and 1/6, respectively. In the viewpoint of stiffness, the resilient modulus of cement-treated soils increases with increasing cement content. Using more than 3% of cement, the 80MPa compaction stiffness standard for the upper subgrade of railways was satisfied, even with 40% of fines content of soils.

Cyclic behavior of RT-cement treated marine clay subjected to low and high loading frequencies

  • Al-Bared, Mohammed A.M.;Harahap, Indra S.H.;Marto, Aminaton;Mohamad, Hisham;Abad, Seyed Vahid Alavi Nezhad Khalil;Mustaffa, Zahiraniza
    • Geomechanics and Engineering
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    • v.21 no.5
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    • pp.433-445
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    • 2020
  • The weakening and softening behavior of soft clay subjected to cyclic loading due to the build-up of excess pore water pressure is well-known. During the design stage of the foundation of highways and coastal high-rise buildings, it is important to study the mechanical behavior of marine soils under cyclic loading as they undergo greater settlement during cyclic loading than under static loading. Therefore, this research evaluates the cyclic stress-strain and shear strength of untreated and treated marine clay under the effects of wind, earthquake, and traffic loadings. A series of laboratory stress-controlled cyclic triaxial tests have been conducted on both untreated and treated marine clay using different effective confining pressures and a frequency of 0.5 and 1.0 Hz. In addition, treated samples were cured for 28 and 90 days and tested under a frequency of 2.0 Hz. The results revealed significant differences in the performance of treated marine clay samples than that of untreated samples under cyclic loading. The treated marine clay samples were able to stand up to 2000 loading cycles before failure, while untreated marine clay samples could not stand few loading cycles. The untreated marine clay displayed a higher permanent axial strain rate under cyclic loading than the treated clay due to the existence of new cementing compounds after the treatment with recycled tiles and low amount (2%) of cement. The effect of the effective confining pressure was found to be significant on untreated marine clay while its effect was not crucial for the treated samples cured for 90 days. Treated samples cured for 90 days performed better under cyclic loading than the ones cured for 28 days and this is due to the higher amount of cementitious compounds formed with time. The highest deformation was found at 0.5 Hz, which cannot be considered as a critical frequency since smaller frequencies were not used. Therefore, it is recommended to consider testing the treated marine clay using smaller frequencies than 0.5 Hz.

Interfacial Properties and Residual Stress of Carbon Fiber/Epoxy-AT PEI Composite with Matrix Fracture Toughness using Microdroplet Test and Electrical Resistance Measurements (Microdroplet 시험법과 전기저항 측정을 이용한 탄소섬유 강화 Epoxy-AT PEI 복합재료의 수지파괴인성에 따른 잔류응력 및 계면물성)

  • Kim, Dae-Sik;Kong, Jin-Woo;Park, Joung-Man;Kim, Minyoung;Kim, Wonho;Ahn, Byung-Hyun;Park, In-Seo
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2002.05a
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    • pp.109-113
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    • 2002
  • Interfacial and electrical properties for the carbon fiber reinforced epoxy-amine terminated (AT) PEI composites were performed using microdroplet test and electrical resistance measurements. As AT PEI content increased, the fracture toughness of epoxy-AT PEI matrix increased, and IFSS was improved due to the improved toughness and energy absorption mechanisms of AT PEI. The microdroplet in the carbon fiber/neat epoxy composite showed brittle microfailure mode. At 15 wt% AT PEI content, ductile microfailure mode appeared because of improved fracture toughness. After curing, the changes of electrical resistance (ΔR) with increasing AT PEI content increased gradually because of thermal shrinkage. The matrix fracture toughness was correlated to IFSS, TEC and electrical resistance. In cyclic strain test, the maximum stress and their slope of the neat epoxy case were higher than those of 15 wt% AT PEI. The results obtained from electrical resistance measurements under curing process and reversible stress and strain were consistent well with matrix toughness properties.

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Effects of Cyclic Thermal Load on the Signal Characteristics of FBG Sensors Packaged with Epoxy Adhesives (주기적인 반복 열하중이 패키징된 FBG 센서 신호 특성에 미치는 영향)

  • Kim, Heonyoung;Kang, Donghoon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.41 no.4
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    • pp.313-319
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    • 2017
  • Fiber optics sensors that have been mainly applied to aerospace areas are now finding applicability in other areas, such as transportation, including railways. Among the sensors, the fiber Bragg grating (FBG) sensors have led to a steep increase due to their properties of absolute measurement and multiplexing capability. Generally, the FBG sensors adhere to structures and sensing modules using adhesives such as an epoxy. However, the measurement errors that occurred when the FBG sensors were used in a long-term application, where they were exposed to environmental thermal load, required calibration. For this reason, the thermal curing of adhesives needs to be investigated to enhance the reliability of the FBG sensor system. This can be done at room temperature through cyclic thermal load tests using four types of specimens. From the test results, it is confirmed that residual compressive strain occurs to the FBG sensors due to an initial cyclic thermal load. In conclusion, signals of the FBG sensors need to be stabilized for applying them to a long-term SHM.

Strength Properties of Polymer-Modified Repair Mortars According to Curing Conditions and Repair Methods (양생조건 및 보수방법에 따른 폴리머시멘트모르타르의 강도 성상)

  • Kim, Wan-Ki;Jo, Young-Kug
    • Journal of the Korea Concrete Institute
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    • v.19 no.4
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    • pp.457-465
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    • 2007
  • In this paper, polymer-modified repair materials using polymer dispersions with six repair methods are prepared with various polymer-cement ratios, and tested for compressive and flexural strengths through each curing condition such as dry cure, water cure, and freezing and thawing cyclic action. And, the adhesive interface between the polymer-modified mortar and mortar substrate is observed by a scanning electron microscope. From the test results, the compressive and flexural strengths of cement mortar repaired by polymer-modified mortar are improved with a rise in the polymer-cement ratio regardless of the type of polymer and curing conditions. Such an improvement in the strengths of polymer-modified repair materials to ordinary cement mortar is explained by the high adhesion of polymer-modified mortar. Strength reduction of polymer-modified repair materials after freezing and thawing cyclic actions is recognized, but it is lower than that of unmodified mortar. Especially, cement mortar repaired by polymer-modified mortar with a St/BA emulsion has good strength properties compared with those of SBR latex and PA emulsion. Accordingly, it is judged that polymer-modified mortars with a St/BA emulsion are possible to use as repair materials to ordinary cement mortar and concrete.

Preparation and Properties of Polydimethylsiloxane Modified Urea with Multi Acrylate Group Coating Materials (Multi Acrylate기를 갖는 Polydimethylsiloxane 변성 Urea 코팅 액의 제조와 그 특성)

  • Bak, Seung Woo;Kang, Ho-Jong;Kang, Doo Whan
    • Polymer(Korea)
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    • v.38 no.6
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    • pp.720-725
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    • 2014
  • Aminopropyl terminated polydimethylsiloxane was synthesized by hydrosilylation reaction with hydride terminated polydimethlysiloxane and allyl amine. Polydimethylsiloxane modified urea with isocyanate group was prepared from cyclic trimer of hexamethyldiisocyanate with aminopropyl terminated polydimethylsiloxane. Polydimethylsiloxane modified urea/acrylate resin (PUA) was prepared from the urethane reaction of PU with isocyanate group and 2-hydroxyethylmethacrylate. PUA structure was analyzed by FTIR and NMR. Coating materials were prepared by mixing PUA, acrylic monomer, photo-initiator, and solvent and coated on PET film to obtain flexible hard coating film by UV irradiation.