• 한국수소및신에너지학회논문집
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• 제28권6호
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• pp.657-662
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• 2017

This paper presents the reversible electrolysis characteristics of a solid oxide fuel cell (SOFC) using a $10{\times}10cm^2$ anode supported planar cell with an active area of $81cm^2$. In this work, current-voltage characteristic test and reversible electrolysis cycle test were carried out sequentially for 2,114 hours at a furnace temperature of $700^{\circ}C$. The current-voltage characteristics for reversible electrolysis mode was measured at a current of ${\pm}26.7A$ under various $H_2O$ utilization conditions. The reversible electrolysis cycle was performed 50 times at a current of ${\pm}32.4A$. As a result, The performance degradation of SOEC mode was larger than that of SOFC mode.

• 한국방사성폐기물학회:학술대회논문집
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• 한국방사성폐기물학회 2017년도 추계학술논문요약집
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• pp.63-64
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• 2017

• 한국정밀공학회지
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• 제16권6호
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• pp.45-51
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• 1999

The semi-solid forging is a new forging technology in which the billet is heated to the semi-solid state coexisting liquid and solid phase for making globular microstructure and subsequently formed. As the semi-solid forging is compared with conventional casting such as die casting and squeeze casting for the characteristics of its process, the product without inner defects such as gas porosity and segregation can be obtained and its microstructure is globular grain. Simutaneously, its mechanical properties are improved by globular microstructure and the lower temperature of the slug causes the cycle time of manufacturing to be shortened and the die life to be lengthened. As it is compared with conventional cold and hot forging, it is possible to minimize the equipment of production owing to a lower forming load and reduce the number of process by a followed treatment for complex shaped product. Therefore it is needed to confirm the quality of a semi-solid forged product by defining its characteristics quantitatively under these advantages. This paper investigates the formability of a master cylinder by its forming variables. And the microstructural characteristics and mechanical property of it is also studied.

• 한국수소및신에너지학회논문집
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• 제17권1호
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• pp.82-89
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• 2006

The redox behaviors of anode-supported flat tube for solid oxide fuel cell has been studied. The mass change of the extruded NiO/YSZ anode flat tube during redox cycling was examined by thermogravimetric analysis(TGA). The result of TGA was shown a rapidly mass change in the range of $455\;-\;670^{\circ}C$ and the reoxidation of the NiO/YSZ anode was almost completed at $750^{\circ}C$. The starting temperature of reoxidation and the maximum temperature of oxidation rate decreased with increasing the reoxidation cycle, which is attributed to the increased porosity caused by volume change. Bending strengths of the NiO/YSZ anode after redox cycling were 96 - 80 MPa and the bending strength decreased slightly with increasing the redox cycle. On the other hand, the bending strength of the NiO/YSZ anode with electrolyte showed 130 MPa after first redox cycling but decreased rapidly with increasing the redox cycle. From the results of the bending test and the microstructure observation, we conclude that the crack initiation of the electrolyte-coated NiO/YSZ anode was induced easily at interface of electrolyte/anode tube and propagated cross the electrolyte.

• 한국전기전자재료학회논문지
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• 제14권5호
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• pp.383-390
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• 2001

We have investigated the L $i_{1+x}$M $n_2$ $O_4$system as a cathode material for lithium rechargeable batteries. To improve the cycle performance of spinel LiM $n_2$ $O_4$ as the cathode of 4V class lithium secondary batteries, spinel phase L $i_{1+x}$M $n_2$ $O_4$(x=0, 0.025, 0.05, 0.075) was prepared at 75$0^{\circ}C$ for 48h. The preparation of L $i_{1+x}$M $n_2$ $O_4$ from L $i_2$ $O_3$ and Mn $O_2$ under air is studied. The compounds were synthesized by using solid-state reaction. Structural refinements were carried out with a Rietveld-refinement program. Electrochemical properties were examined using the Li/L $i_{1+x}$M $n_2$ $O_4$ cells. The capacity of L $i_{1+x}$M $n_2$ $O_4$ decreases with increases lithium content, while the cycle life improves. The initial discharge capacity are 118mAh/g and 116mAh/g for LiM $n_2$ $O_4$ decreases with increases lithium content, while the cycle life improves. The initial discharge capacity are 118mAh/g and 116mAh/g for LiM $n_2$ $O_4$ and L $i_{1.025}$M $n_2$ $O_4$, respectively.pectively.

• Journal of Pharmaceutical Investigation
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• 제36권1호
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• pp.1-9
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• 2006

Human solid tumors exhibit a multicellular resistance (MCR) resulting from limited drug penetration and decreased sensitivity of tumor cells when interacting with their microenvironments. Multicellular cultures represent solid tumor condition in vivo and provide clinically relevant data. There is little data on antitumor effect of paclitaxel (PTX) in multicellular cultures although its MCR has been demonstrated. In the present study, we evaluated antiproliferative effects of PTX in multicellular layers (MCL) of DLD-1 human colorectal carcinoma cells. BrdU labeling index (LI), thickness of MCL, cell cycle distribution and cellular uptake of calcein were measured before and after exposure to PTX at 0.1 to 50 ${\mu}M$ for 24, 48 and 72 hrs. BrdU LI and thickness of MCL showed a concentration- and time-dependent decrease and the changes in both parameters were similar, i.e., 34.2% and 40.6% decrease in BrdU LI and thickness, respectively, when exposed to $50\;{\mu}M$ for 72 hr. The DLD-1 cells grown in MCL showed increase in $%G_{0}/G_{1}$ and resistance to cell cycle arrest and apoptosis compared to monolayers. Calcein uptake in MCL did not change upon PTX exposure, indicating technical problems in multicellular system. Overall, these data indicate that antitumor activity of PTX may be limited in human solid tumors (a multicellular system) and MCL may be an appropriate model to study further pharmacodynamics of PTX.

• International Journal of Internet, Broadcasting and Communication
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• 제5권1호
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• pp.6-8
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• 2013

In this paper, we present an intelligent digital controller circuit which can be applied to automatic voltage regulation. The proposed solid state transformer with Pspice simulation model shows that our approach is very efficient and produces the desirable output. It is comparable to an ordinary magnetic coupled autotransformer.

• 한국세라믹학회지
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• 제42권12호
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• pp.777-786
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• 2005

The Solid Oxide Fuel Cell (SOFC) is an electrochemical device to convert chemical energy of a fuel into electricity at temperatures from about 600 to $1000^{\circ}C$. The SOFC offers certain advantages over lower temperature fuel cells, notably its ability to use CO as a fuel rather than being poisoned by it, and high grade exhaust heat for combined heat and power, or combined cycle gas turbine applications. This paper reviews the operating principle, materials for different cell and stack components, cell designs, and applications of SOFCs. Among all designs of Solid Oxide Fuel Cells (SOFCs), the most progress has been achieved with the tubular design. However, the electrical resistance of tubular SOFCs is high, and specific power output $(W/cm^2)$ and volumetric power density $(W/cm^3)$ low. Planar SOFCs, in contrast, are capable of achieving very high power densities.

• 한국세라믹학회지
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• 제48권6호
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• pp.531-536
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• 2011

Al doped $LiMn_2O_4$ ($LiMn_2O_4:Al$) synthesized by several Al doping process and Solid State method. The Al contents in $Mn_{1-x}Al_xO_2$ for $LiMn_2O_4:Al$ were analyzed 1.7 wt% by EDS. The $LiMn_2O_4:Al$ confirmed cubic spinel structure and approximately 5 ${\mu}m$ particles regardless of three kinds of doping process by solid state method. In the result of electrochemical performances, initial discharge capacity had 115 mAh/g in case of $LiMn_2O_4$ and 111 mAh/g of $LiMn_2O_4:Al$ after 100th cycle at room temperature. But the capacity retention results showed that $LiMn_2O_4$ and $LiMn_2O_4:Al$ were 44% and 69% respectively in the 100th cycle at 60$^{\circ}C$. Therefore we are confirmed that $LiMn_2O_4:Al$ increased the capacity retention about 25% than $LiMn_2O_4$, thus the effect of Al dopping on $LiMn_2O_4$ capacity retention.

• 한국전자파학회논문지
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• 제28권8호
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• pp.603-609
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• 2017

전개형 솔리드 안테나에서 패널 전개 시 발생할 수 있는 구조적인 오차가 안테나 성능에 미치는 영향을 분석하였다. 위성에서 활용되는 전개형 안테나는 지상에서 접힌 상태로 발사되어 우주 공간에서 펼쳐지며, 전개 시 발생할 수 있는 오차의 형태를 분류하여 각각의 경우에 성능에 미치는 영향을 분석하였다. 패널 하나에만 전개 오차가 있을 때는 불완전 전개 패널에 해당하는 쪽에서 안테나 성능의 열화가 발생하였다. 패널 전개 오차가 코사인 함수의 형태로 분포한다고 가정하여 오차의 크기와 오차 형태에 따른 영향을 계산하고 분석하였다. 안테나 패널 오차가 균일한 경우에는 오차크기에 비례하여 이득이 감소하고, 패턴은 대칭이다. 코사인 1 또는 3주기의 패널 오차에 대해서는 주엽의 기울어짐이 나타나며, 코사인 2 또는 4주기의 패널 오차에 대해서는 패턴은 대칭이며, 이득이 감소한다.