• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.338-339
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• 2006

The solubility of Cr in cubic carbides in the systems WC-Co-TaC and WC-Co-ZrC has been determined using equilibrium samples. Thermodynamic calculations were used to design the alloys through extrapolations of Gibbs energy expressions. The alloys were designed to have a microstructure containing the following phases: WC, liquid, $M_7C_3$, graphite and cubic carbide. The alloys were investigated using scanning electron microscopy and analyzed using energy-dispersive X-ray spectrometry. The present work shows how the Cr solubility depends on which cubic carbide former that is present. The WC-Co-Cr-Zr alloy has no detectable amount of Cr whereas the WC-Co-Cr-Ta alloy has 12% Cr in the cubic carbide.

• 한국정밀공학회지
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• 제20권9호
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• pp.55-62
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• 2003

This paper investigates the micro-cutting of cemented carbides using PCD (polycrystalline diamond) and PCBN (polycrystalline cubic boron nitride) cutting tools are performed with SEM direct observation method. The purpose of this study is to make clear the cutting mechanism of cemented carbides and the fracture of WC particles at the plastic deformation zone in orthogonal micro-cutting. And also to achieve systematic understanding, the effect of machining parameter on chip formation and machined surface was studied, including cutting speed, depth of cut and various tool rake angle. Summary of the results are shown below. (1) Three type of chip formation process have been proposed by the results of the direct observation in orthogonal micro-cutting of cemented carbide materials. (2) From the whole observation of chip formation, primary WC particles are crushed and/or fine grained in the shearing deformation zone. A part of them are observed to collide directly with a cutting edge of tool by following the micro-cutting. (3) Surface finish, surface morphology and surface integrity is good to obtain by cutting with PCD cutting tool compared with PCBN. (4) The machined surface has the best quality near the low cutting speed of 10${\mu}m$/sec with a cutting depth of 10 ${\mu}m$ using 0$^\circ$ rake angle and 3$^\circ$ flank angle in this condition, but it was found that excessively low speed, for example the extent of 1 ${\mu}m$/sec, is not good enough to select for various reason.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2003년도 춘계학술대회 논문집
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• pp.604-607
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• 2003

This study investigates the micro-cutting of cemented carbides using PCD(polycrystalline diamond) and PCBN(polycrystalline cubic boron nitride) cutting tools are performed with SEM direct observation method. The purpose of this study is to make clear the cutting mechanism of cemented carbides and the fracture of WC particles at the plastic deformation zone in orthogonal micro-cutting. And also to achieve systematic understanding, the effect of machining parameter on chip formation and machined surface was investigated, including cutting speed. depth of cut and various tool rake angle.

• 한국주조공학회지
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• 제40권4호
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• pp.118-127
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• 2020

Microstructural evolution during a heat treatment and high-temperature tensile properties have been investigated in conventionally cast CM247LC. In as-cast specimens, MC carbides with high amounts of Ta, Ti, Hf, and W were found to exist in the interdendritic regions, and γ' was observed in the form of cubes and octocubes prior to decomposition into cubes. In the heat-treated condition, some portion of eutectic γ-γ' remained, and uniform cubic γ' was observed in both interdendritic regions and dendrite core. Three types of carbides with different stoichiometries and compositions were found at the grain boundaries. MC carbides with high Hf contents were observed in the vicinity of eutectic γ-γ'. The highest tensile strength value was found at 750℃, whereas the greatest ductility appeared at 649℃. The effect of the temperature on the tensile properties was closely related to the dislocation structure. With increase in the test temperature, the density of dislocations inside γ' decreased, whereas that in the γ matrix increased. Stacking faults generated in γ' at 750℃ had a strengthening effect, whereas thermally activated dislocation motion at a high temperature was considered to have the opposite effect.

• International Journal of Precision Engineering and Manufacturing
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• 제5권3호
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• pp.35-42
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• 2004

This research describes that the cutting characteristics and tool wear behavior in the micro cutting of three kinds of wear resistant cemented carbides (WC-Co; V40, V50 and V60) using PCD (Poly Crystalline Diamond) and PCBN (Poly crystalline Cubic Boron Nitride) cutting tools by use of the SEM (Scanning Electron Microscope) direct observation method. The purpose of this research is to present reasonable cutting conditions from the viewpoint of high efficient cutting refer to a precise finished surface and tool wear. Summary of the results is as follows: (1) The cutting forces tend to increase as the increase of the weight percentage of WC particles, and the thrust forces was larger than the principal forces in the cutting of WC-Co. These phenomena were different from the ordinary cutting such as cutting of steel or cast iron. (2) The cutting speed hardly influenced the thrust force, because of the frictional force between the cutting tool edge and small WC particles at low cutting speed region such as 2$\mu\textrm{m}$/s. It seemed that the thrust cutting force occurred by the contact between the flank face and work material near the cutting edge. (3) The wear mechanism for PCD tools is abrasion by hard WC particles of the work materials, which leads diamond grain to be detached from the bond. (4) From the SEM direct observation in cutting the WC-Co, it seems that WC particles are broken and come into contact with the tool edge directly. This causes tool wear, resulting in severe tool damage. (5) In the orthogonal micro cutting of WC-Co, the tool wear in the flank face was formed bigger than that in the rake face on orthogonal micro cutting. And the machining surface integrity on the side of the cutting tool with a negative rake angle was better than that with a positive one, as well as burr in the case of using the cutting tool with a negative rake angle was formed very little compared to the that with a positive one.

• Advances in materials Research
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• 제7권1호
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• pp.17-28
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• 2018

Niobium is a candidate base for new alloys devoted to applications at especially elevated temperatures. Elaborating and shaping niobium-based alloys by conventional foundry may lead to mechanically interesting microstructures. In this work a series of charges constituted of pure elements were subjected to high frequency induction melting in cold crucible to try obtaining cast highly refractory Nb-xCr and Nb-xCr-0.4 wt.%Calloys(x=27, 34 and 37 wt.%). Melting and solidification were successfully achieved. The as-cast microstructures of the obtained alloys were characterized by electron microscopy and X-ray diffraction and their hardness were specified by Vickers macro-indentation. The obtained as-cast microstructures are composed of a body centered cubic (bcc) niobium dendritic matrix and of an interdendritic eutectic compound involving the bcc Nb phase and a $NbCr_2$ Laves phase. The obtained alloys are hard to cut and particularly brittle at room temperature. Hardness is of a high level (higher than 600Hv) and is directly driven by the chromium content or the amount of {bcc Nb - $NbCr_2$} eutectic compound. Adding 0.4 wt.% of carbon did not lead to carbides but tends to increase hardness.

• 한국결정성장학회지
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• 제27권6호
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• pp.313-318
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• 2017

본 연구에서는 가스터빈용 Co계 합금인 ECY768 as-cast 합금 시편의 melt/mold 온도에 따른 결정구조 및 미세조직 및 변화를 고찰하였다. As-cast ECY768 샘플들은 전반적으로 amorphous 특성을 보여주고 있으며 기지인 Co상과 금속탄화물상으로 구성되어 있음을 확인하였으며, mold의 온도에 따른 XRD 패턴에서의 결정성 변화를 고찰하였다. 광학현미경(OM)을 이용하여 as-cast 샘플들의 결정립계에 석출물을 관찰하였다. 또한 FE-SEM에 의한 미세구조 분석시 Co기지상과 금속 탄화물의 석출물이 발견되는 영역이 관찰하였으며 EDS 분석에 의해 금속과 탄소의 화학양론이 확연히 다른 $M_{23}C_6$ 및 MC-type 조직으로 확인할 수 있었다. 여기서 $M_{23}C_6-type$의 탄화물은 Cr 원소를 주성분으로 하는 것을 확인할 수 있었으며, MC-type 탄화물은 Ta 원소가 주성분임을 확인할 수 있었다.

• Nuclear Engineering and Technology
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• 제53권2호
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• pp.592-602
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• 2021

Thorium compounds have attracted immense scientific and technological attention with regard to both fundamental and practical implications, owing to unique chemical and physical properties like high melting point, high density and thermal conductivity. Hereby, we investigate the mechanical and thermodynamic stability and report on the structural, electronic and magnetic properties of new silicon-doped cubic ternary thorium phosphides ThSi_xP_1-x (x = 0, 0.25, 0.5, 0.75 and 1). The first-principles density functional theory procedure was adopted within full-potential linearized augmented plane wave (FP-LAPW) method. The exchange and correlation potential terms were treated within Generalized-Gradient-Approximation functional modified by Perdew-Burke-Ernzerrhof parameterizations. The proposed compounds showed mechanical and thermodynamic stable structure and hence can be synthesized experimentally. The calculated lattice parameters, bulk modulus, total energy, density of states, electronic band structure and spin magnetic moments of the compounds revealed considerable correlation to the Si substitution for P and the relative Si/P doping concentration. The electronic and magnetic properties of the doped compounds rendered them non-magnetic but metallic in nature. The main orbital contribution to the Fermi level arises from the hybridization of Th(6d+5f) and (Si+P)3p states. Reported results may have potential implications with regard to both fundamental point of view and technological prospects such as fuel materials for clean nuclear energy.