• Title/Summary/Keyword: crystalline temperature

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Effect of carbonization temperature on crystalline structure and properties of isotropic pitch-based carbon fiber

  • Kim, Jung Dam;Roh, Jae-Seung;Kim, Myung-Soo
    • Carbon letters
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    • v.21
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    • pp.51-60
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    • 2017
  • Isotropic pitch-based fibers produced from coal tar pitch with the melt-blowing method were carbonized at temperatures ranging from 800 to $1600^{\circ}C$ to investigate their crystalline structure and physical properties as a function of the carbonization temperature. The in-plane crystallite size ($L_a$) of the carbonized pitch fiber from X-ray diffraction increased monotonously by increasing the carbonization temperature resulting in a gradual increase in the electrical conductivity from 169 to 3800 S/cm. However, the variation in the $d_{002}$ spacing and stacking height of the crystallite ($L_c$) showed that the structural order perpendicular to the graphene planes got worse in carbonization temperatures from 800 to $1200^{\circ}C$ probably due to randomization through the process of gas evolution; however, structural ordering eventually occurred at around $1400^{\circ}C$. For the carbonized pitch powder without stabilization, structural ordering perpendicular to the graphene planes occurred at around $800-900^{\circ}C$ indicating that oxygen was inserted during the stabilization process. Additionally, the shear stress that occurred during the melt-blowing process might interfere with the crystallization of the CPF.

A Study On Crystalline Structure Change by Isothermally Annealed after Elevated heating of drawn PP filaments (연신한 PP filament의 승온열처리에 의한 결정구조 변화에 관한 연구)

  • Lee, Eun-Woo
    • Journal of the Korean Society of Industry Convergence
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    • v.3 no.4
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    • pp.345-351
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    • 2000
  • The change of crystalline structure of drawn PP filaments were investigated. Samples were treated by isothermally annealed after elevated heating from $20^{\circ}C$. Measurements were carried out with XRD for crystallite size and density gradient tube for crystallinity. Isothermally heat treatment were carried out at the temperature of $100^{\circ}C$, $120^{\circ}C$ and $140^{\circ}C$ for 10min., 30min. and 60min. in dry oven. The isothermal heat treatment after elevated heating from $20^{\circ}C$ were carried out at the temperature of $100^{\circ}C$, $120^{\circ}C$ and $140^{\circ}C$ for 10min., 30min. and 60min. with heating rate of $1^{\circ}C$/min., $5^{\circ}C$/min. and $10^{\circ}C$/min. From the results of this study, it found the following facts. It was found that the crystallinity and crystallite size of (110) plane of sample were increased with increasing of annealed temperature and time. Also crystallinity and crystallite size of samples which were isothermally annealed after elevated heating from $20^{\circ}C$ were higher than those of isohtermally annealed samples.

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Study on the Long-term Reliability of Solar Cell by High Temperature & Humidity Test (고온고습 시험을 통한 태양전지의 장기 신뢰성에 관한 연구)

  • Kang, Min-Soo;Jeon, Yu-Jae;Kim, Do-Seok;Shin, Young-Eui
    • Journal of Energy Engineering
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    • v.21 no.3
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    • pp.243-248
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    • 2012
  • In this study, The report analysed the characteristics of power drop and damage of surface in solar cell through high temperature and humidity test. The solar cells were tested during the 1000hr in $85^{\circ}C$ temperature and 85% humidity conditions, that excerpted standard of PV Module(KS C IEC-61215). An analysis of the cell surface through EL(Electroluminescence), the cell has partly change of surface in yearly. Single-crystalline Solar cell efficiency is decreased from 17.7% to 15.6% and decreasing rate is 11.9%. On the other hand, Poly-crystalline Solar cell efficiency is decreased from 15.5% to 14.0% and decreasing rate is 9.3%. A comparison of the fill factor for analysis of electro characteristic in yearly, Single-crystalline Solar cell efficiency is decreased from 78.7% to 78.1% and decreasing rate is 4.7%. On the other hand, Poly-crystalline Solar cell efficiency is decreased from 78.1% to 76.7% and decreasing rate is 1.8%. Single-crystalline has more bigger power drop than poly-crystalline by the silicon purity and silicon atom arrangement. Also, FF decreasing rate has more bigger drop than efficiency decreasing rate for the reason that the damage of surface by exterior environmental factor is the more influence in cell than other reason that is decreasing FF by damage of p-n junction.

Surface Texturing and Anti-Reflection Coating of Multi-crystalline Silicon Solar Cell (다결정 실리콘 태양전지의 표면 텍스쳐링 및 반사방지막의 영향)

  • Jun, Seong-Uk;Lim, Kyung-Muk;Choi, Sock-Hwan;Hong, Yung-Myung;Cho, Kyung-Mox
    • Journal of Surface Science and Engineering
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    • v.40 no.3
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    • pp.138-143
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    • 2007
  • The effects of texturing and anti-reflection coating on the reflection properties of multi-crystalline silicon solar cell have been investigated. The chemical solutions of alkaline and acidic etching solutions were used for texturing at the surface of multi-crystalline Si wafer. Experiments were performed with various temperature and time conditions in order to determine the optimized etching condition. Alkaline etching solution was found inadequate to the texturing of multi-crystalline Si due to its high reflectance of about 25%. The reflectance of Si wafer texturing with acidic etching solution showed a very low reflectance about 10%, which was attributed to the formation of homogeneous. Also, deposition of ITO anti-reflection coating reduced the reflectance of multi-crystalline si etched with acidic solution($HF+HNO_3$) to 2.6%.

Structural and Electrical Characteristics of IGZO thin Films deposited at Different Substrate Temperature (기판온도에 따른 IGZO 박막의 구조적 및 전기적 특성)

  • Lee, Mingyu;Lee, Kyu Mann
    • Journal of the Semiconductor & Display Technology
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    • v.15 no.1
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    • pp.1-5
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    • 2016
  • In this study, we have investigated the effect of the substrate temperature on the characteristics of IGZO thin films for the TCO(transparent conducting oxide). For this purpose, IGZO thin films were deposited by RF magnetron sputtering at various substrate temperature (room temperature ${\sim}400^{\circ}C$). IGZO thin films deposited at room temperature show amorphous structure, whereas IGZO thin films deposited at $250^{\circ}C$ or more show crystalline structure having an (222) preferential orientation. The electrical resistivity of IGZO film increased with increasing temperature. The change of electrical resistivity with increasing temperature was mainly interpreted in terms of the charge carrier concentration rather than the charge carrier mobility. The electrical resistivity of the amorphous-IGZO films deposited at R.T. was lower than that of the crystalline-IGZO thin films deposited at $300^{\circ}C$. The transmittance of the IGZO films deposited at $300^{\circ}C$ was decreased deposited with hydrogen gas.

Investigation of Ni Silicide formation for Ni/Cu contact formation crystalline silicon solar cells (Ni/Cu 금속 전극이 적용된 결정질 실리콘 태양전지의 Ni silicide 형성의 관한 연구)

  • Lee, Ji-Hun;Cho, Kyeong-Yeon;Lee, Soo-Hong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.434-435
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    • 2009
  • The crystalline silicon solar cell where the solar cell market grows rapidly is occupying of about 85% or more. high-efficiency and low cost endeavors many crystalline silicon solar cells. the fabrication processes of high-efficiency crystalline silicon solar cells necessitate complicated fabrication processes and Ti/Pd/Ag contact, however, this contact formation processed by expensive materials. Ni/Cu contact formation is good alternative. in this paper, according to temperature Ni silicide makes, produced Ni/Cu contact solar cell and measured conversion efficiency.

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The study of recrystallization of willemite crystal in ceramic glaze (도자기용 아연 결정유의 재결정화 연구)

  • Lee, Hyun-Soo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.4
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    • pp.136-142
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    • 2020
  • Crystallization of zinc crystalline glaze requires demanding conditions such as the formation of a nucleating agent and the amount of nucleating agent, and growth of crystalline. Zinc crystalline glaze is hard to utilize in the industry because of its narrow range of the firing temperature, and the crystallization's dependency on the quality of zinc. Stimulation of zinc crystallization and formation of frit enable zinc crystalline glaze to be reconstituted in a various range of firing schedules, leading to the development of a competitive industrial glaze.

Fabrication of poly-crystalline silicon ingot for solar cells by CCCC method (CCCC법에 의한 태양전지용 다결정 실리콘 잉고트의 제조)

  • Shin J. S.;Lee D. S.;Lee S. M.;Moon B. M.
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.94-97
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    • 2005
  • For the fabrication of poly-crystalline silicon ingot, CCCC (Cold Crucible Continuous Casting) method under a high frequency alternating magnetic field, was utilized in order to prevent crucible consumption and ingot contamination and to increase production rate. In order to effectively and continuously melt and cast silicon, which has a high radiation heat loss due to the high melting temperature and a low induction heating efficiency due to a low electric conductivity, Joule and pinch effects were optimized. Throughout the present investigation, poly-crystalline Si ingot was successfully produced at the casting speed of above 1.5 mm/min under a non-contact condition.

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Degradation of Crystalline Cellulose by the Brown-rot Basidiomycete Fomitopsis palustris

  • Yoon Jeong-Jun;Kim Young-Kyoon
    • Journal of Microbiology
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    • v.43 no.6
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    • pp.487-492
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    • 2005
  • This study demonstrated that the brown rot basidiomycete Fomitopsis palustris was able to degrade crystalline cellulose (Avicel). This fungus could also produce the three major cellulases (exoglucanases, endoglucanases, and $\beta-glucosidase$) when the cells were grown on $2.0\%$ Avicel. Avicel degraded by F. palustris showed a decrease in relative crystallinity from $83\%\;to\;78.5\%$ after 14 days of incubation. The characterization study indicated that optimum pH was 4.5 and optimum temperature was $70^{\circ}C$ for exoglucanase (cellobiohydrolase) activity. Hydrolysis of Avicel by the crude enzyme from F. palustris yielded 1.6 mg/ml of glucose after 43 h, which corresponded to a cellulose conversion degree of $3.2\%$. Therefore, this study revealed for the first time that the brown rot basidiomycete F. palustris produces cellulases capable of yielding soluble sugars from crystalline cellulose.

ICOSAHEDRAL CLUSTERS AND MAGNETIC PROPERTIES OF $LaCo_{13}$ AMORPHOUS AND CRYSTALLINE ALLOYS

  • Fukamichi, K.;Fujita, A.;Ohashi, N.;Hashimoto, M.;Matsubara, E.;Waseda, Y.
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.767-771
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    • 1995
  • The atomic structure and magnetic properties of $LaCo_{13}$ amorphous alloy have been investigated and compared with those of its crystalline counterpart. It has been confirmed that the amorphous alloy is composed of the icosahedral clusters with a $NaZn_{13}$-type structure. The magnetic moment and the spin- wave stiffness constant obtained from the magnetic measurements in the amorphous state are larger than those in the crystalline state. The Curie temperature estimated from the reduced magnetization curve for the former is much higher than the value for the latter. The localized magnetic moment character in the amorphous state is stronger than that in the crystalline state.

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