• 제목/요약/키워드: crystal impedance

검색결과 104건 처리시간 0.026초

압전 단결정 재료를 이용한 이식형 인공중이용 적층 액츄에이터 개발 (Development of a Multi-Layer Actuator With Piezoelectric Single Crystals for an Implantable Hearing Aid)

  • 이상구;노용래;선주헌
    • 한국음향학회지
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    • 제24권3호
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    • pp.127-132
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    • 2005
  • 이식형 인공중이용 트랜스듀서는 주파수 특성 및 구동 성능이 우수해야 하고 크기가 작아야 한다. 이러한 트랜스듀서로서 단결정 압전 재료인 PMN-PT를 이용한 적층형 액츄에이터를 제안하였고, 유한요소해석 및 제작실험을 통해 그 타당성을 밝혔다. 실험에서는 두께 $0.2{\cal}mm$를 갖는 시편을 14층으로 쌓아 최종적으로 $1{\cal}mm{\times}1{\cal}mm{\times}2.8{\cal}mm$ 크기의 PMN-PT 적층형 액츄에이터를 제작하였다. 제작된 PMN-PT 액츄에이터의 성능은 Impedance Spectrum과 구동변위 측정을 통해 PZT 액츄에이터와 비교, 평가하였고, 이를 통해 단결정 재료인 PMN-PT를 이용할 경우 우수한 성능의 인공중이용 액츄에이터 제작이 가능함을 확인하였다.

Mg와 Zn의 복합치환에 따른 LiMn2-yMyO4 정극 활물질의 결정 구조 및 전기화학적 특성 (Crystal Structure and Electrochemical Properties of LiMn2-yMyO4 Cathode Material by Complex Substitution of Mg and Zn)

  • 정인성;정해덕;구할본
    • 한국전기전자재료학회논문지
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    • 제15권4호
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    • pp.361-366
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    • 2002
  • Spinel $LiMn_{2-y}M_yO_4$ and $LiMn_{2-y}M_yO_4$ (M=Mg, Zn) powders were synthesized by solid-state method at $800^{\circ}C$ for 37h. Crystal structure and electrochemical properties were analyzed by X-ray diffraction, charge-discharge test, cyclic voltammetry and ac impedance to $LiMn_{2-y}M_yO_4$. All cathode material showed spinel structure in X-ray diffraction. Ununiform distortion which calculated by (111) face and (222) face was almost constant in spite of the change of the kind and the substituting ratio of the metal cation in $LiMn_{2-y}M_yO_4$ (M=Mg, Zn). $LiMn_{1.9}Mg_{0.05}Zn_{0.05}O_4/Li$ cell substituted $Mg^{+2}$ and $Zn^{+2}$ showed excellent discharge capacities than other cells, which it presented about 120mAh/g at the 1st cycle and about 73mAh/g at the 250th cycle, respectively. AC impedance of $LiMn_{2-y}M_yO_4/Li$ cells showed the similar resistance of about 65~110$\Omega$ before cycling.

$LiMn_{2-y}M_{y}O_4$ 정극 활물질의 전기화학적 특성 - I. $LiMn_{2-y}Mg_{y}O_4$의 결정 구조 및 AC Impedance 특성 (The Electrochemical Characterization of $LiMn_{2-y}M_{y}O_4$ Cathode Material - I. Crystal Structure and AC Impedance Properties of $LiMn_{2-y}Mg_{y}O_4$)

  • 정인성;김종욱;구할본;김형곤;손명모
    • 한국전기전자재료학회논문지
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    • 제14권4호
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    • pp.309-315
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    • 2001
  • Crystallized $LiMn_{2-y}Mg_{y}O_4$ powder was prepared by calcing the mixture of LiOH.$H_2O$, $MnO_2$ and MgO at $800^{\circ}C$ for 36h in an air atmosphere. The structure of $LiMn_{2-y}Mg_{y}O_4$ crystallites was analyzed from powder X-ray diffraction data as a cubic spinel, space group Fd3m. Though all cathode material showed spinel phase based on cubic phase in X-ray diffraction, other peaks gradually exhibited and became intense with increasing y value in $LiMn_{2-y}Mg_{y}O_4$. However, ununiform which calculated by (111) face and (222) face was constant in spite of the increase of y value, except pure $LiMn_2O_4$. AC impedance of Li/$LiMn_{2-y}Mg_{y}O_4$ cells revealed the similar resistance of about $70\Omega$ before cycling. In addition, The impedance of Li/$LiMn_{1.9}Mg_{0.1}O_4$ cell changed during charge and discharge or after cycling.

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고주파의 2개 주파수 임피던스 변화를 이용한 토양내 수분함량 정밀측정 (Precision Measurement of Water Content in Soil Using Dual RF Impedance Changes)

  • 김기복;김상천;주대성;윤동진
    • Journal of Biosystems Engineering
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    • 제28권4호
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    • pp.369-376
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    • 2003
  • This study was conducted to develop a precision measurement method of water content in soil (find sand and silty sand) using dual RF impedance changes. The electrically stable perpendicular plate capacitive sensor was fabricated and utilized to sense the water content in soil. Crystal oscillators of 5 and 20 MHz and related circuits were designed to detect the capacitance changes of a perpendicular plate capacitive sensor with soil samples at various volumetric water contents. A multiple regression model for volumetric water content having dual oscillation frequency changes at 5 and 20 MHz as independent variables resulted in coefficient of determination of 0.963 and standard error calibration of 0.030 cm$^3$/cm$^3$ for calibration and coefficient of determination of 0.966, standard error of prediction of 0.027 cm$^3$/cm$^3$ and bias of 0.001 cm$^3$/cm$^3$ for prediction.

도전재 종류에 따른 $LiMn_2O_4$정극의 AC Impedance 측정 및 충방전 특성 (AC Impedance analysis and charge/discharge characteristics of $LiMn_2O_4$ cathode according to conductive agent)

  • 정인성;성창호;박복기;구할본
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1997년도 하계학술대회 논문집 C
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    • pp.1594-1596
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    • 1997
  • $LiMn_2O_4$ is prepared by reacting stoichiometric mixture of LiOH $H_2O$ and $MnO_2$ (mole ratio 1 : 2) and calcinating at $800^{\circ}C$ for 24h, 36h, 48h, 60h and 72h. At X-ray diffraction, cathode active materials calcined at $800^{\circ}C$ for 36h. (111)/(311) peak ratio was 0.37. It was that crystal structure is formed very well. In the result of charge/discharge test, when heated at $800^{\circ}C$ for 36h, charge/discharge characteristics of $LiMn_2O_4$ is the best and Super-s-black sort of conductive agent showed well property. Also, AC impedance creased gradually during cycling and stabilized after 10cycle.

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급격히 꺾인 Taper를 갖는 Traveling-wave Coplanar Waveguide형 $LiNbO_34$전기광학변조기 전송선로의 전기적 특성 (Electrical Properties of Traveling-wave Coplanar Waveguide Transmission Line with a Abruptly broken Input-Output-taper for $LiNbO_3$Optical Modulator Electrode)

  • 정운조;김성구
    • 한국전기전자재료학회논문지
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    • 제13권12호
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    • pp.1051-1057
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    • 2000
  • A traveling-wave CPW(coplanar waveguide) electrode with abruptly broken input/output-taper for LiNbO$_3$optical modulator was designed and fabricated. The electrical characteristics of traveling-wave electrode on z-cut LiNbO$_3$crystal with SiO$_2$buffer layers were measured by network analyzer. To confirm the possibility of the electro-optic modulator electrode, detailed calculations of the impedance, microwave effective index and attenuation constants are presented as a function of the microwave electrode thickness, but the buffer layer thickness is fixed as 1${\mu}{\textrm}{m}$. These characteristics are discussed from the viewpoint of the device optimization and are expected to be design guides for the LiNbO$_3$modulator’s electrodes.

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Dielectric Properties of Orthorhombic Dysprosium Manganites

  • Wang, Wei Tian
    • 한국재료학회지
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    • 제29권12호
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    • pp.753-756
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    • 2019
  • Orthorhombic dysprosium manganite DyMnO3 with single phase is synthesized using solid-state reaction technique and the crystal structure and dielectric properties as functions of temperature and frequency are investigated. Thermally activated dielectric relaxations are shown in the temperature dependence of the complex permittivity, and the respective peaks are found to be shifted to higher temperatures as the measuring frequency increases. In Arrhenius plots, activation energies of 0.32 and 0.24 eV for the high- and low-temperature relaxations are observed, respectively. Analysis of the relationship between the real and imaginary parts of the permittivity and the frequencies allows us to explain the dielectric behavior of DyMnO3 ceramics by the universal dielectric response model. A separation of the intrinsic grain and grain boundary properties is achieved using an equivalent circuit model. The dielectric responses of this circuit are discerned by impedance spectroscopy study. The determined grain and grain boundary effects in the orthorhombic DyMnO3 ceramics are responsible for the observed high- and low-temperature relaxations in the dielectric properties.

Characterization of Ln0.8Sr0.2CoO3-δ (Ln=Gd, Nd, Pr, Sm, or Yb) as Cathode Materials for Low-Temperature SOFCs

  • Choi, Jung-Woon;Kang, Ju-Hyun;Kim, Han-Ji;Yoo, Kwang-Soo
    • 한국세라믹학회지
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    • 제43권12호
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    • pp.758-763
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    • 2006
  • Perovskites with nominal compositions $Ln_{0.8}Sr_{0.2}CoO_{3-\delta}$ (Ln=Gd, Nd, Pr, Sm, or Yb) were fabricated as cathode materials using a solid-state reaction method for low-temperature operating Solid-Oxide Fuel Cells (SOFCs). X-ray diffraction analysis and microstructure observation for the sintered samples were performed. The ac complex impedance was measured in the temperature range of $600-900^{\circ}C$ in air and fitted with a Solartron ZView program. The crystal structure, microstructure, electrical conductivity, and polarization resistance of $Ln_{0.8}Sr_{0.2}CoO_{3-\delta}$ were characterized systematically.

Czochralski법을 이용한 금속 단결정의 성장과 구조적, 전기적 성질에 관한 연구 (The Fabrication of the Single Crystal Wire from Cu Single Crystal Grown by the Czochralski Method and its Physical Properties)

  • 박정훈;차수영;박상언;김성규;조채룡;박혁규;김형찬;정명화;정세영
    • 한국결정학회지
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    • 제16권2호
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    • pp.141-148
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    • 2005
  • It is well known that the general metals have a lot of grain boundaries. The grain boundaries play a negative role to increase the resistivity and to decrease the conductivity. The small resistivity and the large conductivity have been a goal of the material scientists, and no signal noise, perfect signal transfer, and the realization of the real sound are the dream of electronic engineers and audio manias. Generally, oxygen free copper (OFC) and Ohno continuous casting (OCC) copper cables have been used for the purpose of the precise signal transfer and low noise. However they still include a lot of grain boundaries. In our study, we have grown the single crystal by the Czochralski method and succeeded to produce single crystal wires from the crystal in the dimension of $0.5{\times}0.5{\times}2500mm$. The produced wire still possesses very good single crystal properties. We observed the structure of the wire, and measured the resistance and impedance. Glow Discharge Spectrometer (GDS) was used for analyzing the compositions of copper single crystals and commercial copper. Current-Voltage curve, resistance, total harmonic distortion and speaker frequency response were measured for comparing electrical and acoustic properties of two samples.

수정 진동자를 이용한 근접장광학계 (Near-Field Scanning Optical Microscope) 제작 및 특성연구 (A study on the feedback control system for near field scanning optical microscope based on the tuning fork oscillator)

  • 윤선현
    • 한국광학회지
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    • 제10권4호
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    • pp.267-272
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    • 1999
  • 근접장광학계 (Near-Field Scanning Optical Microscope :NSOM)의 표본과 팁의 거리 유지를 위해 소리굽쇠모양의 수정발진자 (tuning forktype quartz crystal unit)의 한쪽 다리에 광섬유를 고정시키고 광섬유 팁을 수정발진자와 같이 진동하게 만들어 사용하였다. 수정 진동자는 광섬유 팁이 시료에 얼마나 가까이 갔느냐에 따라 진폭이 바뀌게 되고 이 변화를 일반적인 방법인 레이저 빛에 의하여 읽어내는 것이 아니라 바로 수정 발진자의 임피던스 변화에 따른 전압 변화를 측정하여 알아냈다. 팁이 표면에 접근함에 따라 수정발진자 진동폭의 변화와 팁을 통해 들어오는 빛의 세기 변화 등을 측정하여 계의 감도를 조사하였다.

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