• 제목/요약/키워드: crystal engineering

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Exploring the Properties and Potential of Single-crystal NCM 811 for Lithium-ion Batteries

  • Yongseok Lee;Seunghoon Nam
    • Corrosion Science and Technology
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    • 제22권1호
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    • pp.36-43
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    • 2023
  • Single-crystal Ni-rich NCM is a material that has drawn attention in the field of lithium-ion batteries due to its high energy density and long cycle life. In this study, we investigated the properties of single-crystal NCM 811 and its potential for use in lithium-ion batteries. High-quality single crystals of NCM 811 were successfully synthesized by crystal growth via a flux method. The single-crystal nature of the samples was confirmed through detailed characterization techniques, such as scanning electron microscopy and x-ray diffraction with Rietveld refinement. The crystal structure and electrochemical performances of the single-crystal NCM 811 were analyzed and compared to its poly-crystal counterpart. The results indicated that single-crystal NCM 811 had electrochemical performance and thermal stability superior to poly-crystalline NCM 811, making it a suitable candidate for high-performance batteries. The findings of this study contribute to a better understanding of the characteristics and potential of single-crystal NCM 811 for lithium-ion batteries.

6H-SiC 종자 결정을 사용하여 PVT법으로 성장된 AlN 결정 연구 (Crystal structure investigation of AlN crystal grown on 6H-SiC seed by a physical vapor transport method)

  • 신희원;이동훈;김황주;박미선;장연숙;이원재;김정곤;정성민;이명현;서원선
    • 한국결정성장학회지
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    • 제26권1호
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    • pp.49-52
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    • 2016
  • 본 연구에서는 AlN 결정 성장시 중요한 공정변수 중의 하나인 성장 압력과 온도 조건에 따라 다르게 성장되는 AlN 결정상의 결과에 대하여 고찰하였다. AlN 결정 성장은 6H-SiC 종자 결정을 사용하여 PVT(Physical Vapor Transport)법을 적용하여 성장시켰다. 성장 압력과 온도에 따라 AlN 결정의 특성이 변화하였고, Raman 분석을 통해 다양한 방향을 갖는 AlN 결정이 SiC 종자 결정 위에 성장되는 것을 확인하였다.

Vertical Alignment Nematic Liquid Crystal Display with Patterned Electrode Using Positive Liquid Crystal Materials

  • Shin, Hun-Ki;Yoon, Tae-Hoon;Kim, Jae-Chang
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권1호
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    • pp.499-501
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    • 2007
  • We propose a vertical-alignment liquid crystal display with patterned electrodes using a positive dielectric anisotropic liquid crystal. In this structure, the threshold and on-state voltages are reduced compared with previous vertical-alignment configuration with positive liquid crystal.

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미세중력장 CdTe 흘로우팅존 생성에서 결정체-용융액 계면주위의 열응력 (Thermal Stresses Near the Crystal-Melt Interface During the Floating-Zone Growth of CdTe Under Microgravity Environment)

  • 이규정
    • 한국전산유체공학회지
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    • 제3권1호
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    • pp.100-107
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    • 1998
  • A numerical analysis of thermal stress over temperature variations near the crystal-melt interface is carried out for a floating-zone growth of Cadmium Telluride (CdTe). Thermocapillary convection determines crystal-melt interfacial shape and signature of temperature in the crystal. Large temperature gradients near the crystal-melt interface yield excessive thermal stresses in a crystal, which affect the dislocations of the crystal. Based on the assumption that the crystal is elastic and isotropic, thermal stresses in a crystal are computed and the effects of operating conditions are investigated. The results show that the extreme thermal stresses are concentrated near the interface of a crystal and the radial and the tangential stresses are the dominant ones. Concentrated heating profile increases the stresses within the crystal, otherwise, the pulling rate decreases the stresses.

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Fabrication and electro optical properties of stressed liquid crystal cell

  • Lee, Jung-Min;Park, Jin-Seol;Kang, Dae-Seung
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.681-682
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    • 2009
  • We fabricated a stressed liquid crystal cell by mixing liquid crystal with a photo-polymer. By carefully choosing the mixing ratio between liquid crystal and the polymer, and by suitable mechanical shearing of the substrates, we demonstrated feasible electro optical properties for displays.

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Shearing and Electro-optical Properties of Stressed Cholesteric Liquid Crystal Cells

  • Lee, Jung-Min;Kang, Dae-Seung
    • Journal of Information Display
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    • 제11권2호
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    • pp.91-93
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    • 2010
  • The shearing effects on the electro-optical properties of a stressed cholesteric liquid crystal were investigated. A photopolymer was dispersed in the cholesteric liquid crystal cell. By carefully choosing the mixing ratio between the liquid crystal and the photoreactive monomer, and by applying suitable mechanical shearing on the substrates, a cholesteric liquid crystal display with a low threshold voltage and no alignment layer was demonstrated.

LPE법에 의한 고품질 $Er:LiNbO_3$ 단결정 박막의 성장 (Growth of $Er:LiNbO_3$ single crystal thin film with high crystal quality by LPE method)

  • Shin, Tong-Il;Lee, Hyun;Shur, Joong-Won;Byungyou Hong;Yoon, Dae-Ho
    • 한국결정성장학회:학술대회논문집
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    • 한국결정성장학회 1999년도 PROCEEDINGS OF 99 INTERNATIONAL CONFERENCE OF THE KACG AND 6TH KOREA·JAPAN EMG SYMPOSIUM (ELECTRONIC MATERIALS GROWTH SYMPOSIUM), HANYANG UNIVERSITY, SEOUL, 06월 09일 JUNE 1999
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    • pp.305-320
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    • 1999
  • It was grown Er2O3 doped LiNbO3 single crystal thin films with high crystal quality by liquid phase epitaxial (LPE) method. Er2O3 was doped with a concentration of 1, 3, and 5 mol% respectively. After the growth of single crystal thin film, we examined the crystallinity and the lattice mismatch along the c-axis between the film and the substrate with the variation of Er2O3 dopant using X-ray double crystal technique. There were no lattice mismatches along the c-axis for the undoped and the films doped with 1 and 3 mol% of Er2O3. For 5 mol% of Er2O3 doped film, there was a lattice mismatch of 7.86x10-4nm along the c-axis.

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Growth of Er : $LiNbO_{3}$ single crystal thin film with high crystal quality by LPE method

  • Tong-Ik Shin;Hyun Lee;Joong-Won Shur;Byungyou Hong;Dae-Ho Yoon
    • 한국결정성장학회지
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    • 제9권3호
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    • pp.295-298
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    • 1999
  • High quality of $Er_{2}O_{3}$ doped $LiNbO_{3}$ single crystal thin films were grown by the liquid phase epitaxial (LPE) method using $Er_{2}O_{3}$ doped at concentrations of 1,3, and 5 mol% respectively. After the growth of single crystal thin film, the crystallinity and the lattice mismatch along the c-axis between the film and the substrate was examined as a function of the variations of{{{{{Er}_{2}{O}_{3}}}}} dopant concentration using a X-ray double crystal technique. There was no lattice mismatch along the c-axis for the undoped film and those doped with 1 and 3 mol% of $Er_{2}O_{3}$. For 5 mol% of $Er_{2}O_{3}$ doped film, the lattice mismatch was $7.86{\times}10^{-4}$nm along the c-axis.

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다이아몬드 결정구조를 모티브한 주얼리 디자인 개발에 관한 연구 (A study on the development of jewelry design based on the diamond crystal structure)

  • 박은주;문소이;석정원
    • 한국결정성장학회지
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    • 제33권4호
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    • pp.158-164
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    • 2023
  • 다이아몬드 결정구조가 갖는 의미와 결정형태의 조형적 아름다움을 새로운 관점에서 디자인하여 주얼리로 표현하고자 하였다. 본 연구에서는 다이아몬드의 결정구조에 대한 문헌 조사와 다이아몬드 결정구조의 조형적 특징을 모티브로 한 주얼리 디자인 사례를 분석하였다. 다이아몬드 결정구조의 의미와 가치를 새롭게 해석하고, 다이아몬드의 결정구조를 주얼리로 디자인함으로써 결정구조가 갖는 미적 효과를 나타낼 수 있는 조형적 디자인을 연구하였다. 다이아몬드 결정구조가 주는 대칭의 효과와 조형미가 주는 반복의 특징을 살려 주얼리 디자인을 제시함으로써 보석이 주는 근원적인 아름다움, 문화적 의미가 새롭게 재인식되길 기대해 본다.

경막형 용융결정화에 의한 벤젠-사이클로헥산 혼합물로부터 벤젠의 결정화-결정의 불순물 내포현상- (Crystallization of Benzene from Benzene-Cyclohexane Mixtures by Layer Melt Crystallization - Phenomena of Impurity Inclusion in Crystal -)

  • 김광주;이정민;유승곤
    • 공업화학
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    • 제8권3호
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    • pp.389-394
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    • 1997
  • 경각형 결정화에 의하여 벤젠-사이클로헥산 혼합물로부터 벤젠의 결정화에서 결정에 내포된 불순물(사이클로헥산)의 분포가 조사되었다. 결정의 순도에 미치는 결정성장속도의 영향을 파악하였으며 모든 실험결과는 Wintermantel 모델에 의해 도시될 수 있었다. 결정의 순도는 과냉각 정도가 클수록, 주입조성이 낮을 수록, 결정성장속도가 클 수록 낮았으며 결정성장속도는 불순물의 내포를 지배하는 가장 중요한 변수이다. 결정화 초기에 형성된 결정은 불순물을 많이 내포하고 있으며 결정의 두께가 증가함에 따라 불순물은 잔여용융액쪽으로 이동되어 배제됨을 알 수 있었다. 경막결정화에서 결정에 내포된 불순물은 일정두께의 결정층에 온도구배를 이용하여 결정을 부분용해시키면 불순물의 확산에 의하여 제거될 수 있음을 알 수 있었다.

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