• 제목/요약/키워드: crystal analysis

검색결과 2,011건 처리시간 0.027초

EFG법에 의한 ${\gamma}-6Bi_2O_3 {\cdot}SiO_2$(BSO)단결정의 육성 (Growth of ${\gamma}-6Bi_2O_3 {\cdot}SiO_2$( Single Crystals by EFG Method)

  • 김호건;유건종
    • 한국결정성장학회지
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    • 제1권1호
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    • pp.26-38
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    • 1991
  • 광기능소자로 응용성이 넓은 전기광학결정 $r-6Bi_2O_3{\cdot}SiO_2$(이하 BSO로 약칭)을 EFG(Edge-defined Film-fed Growth)법에 의하여 판상단결정으로 육성하는 기초적 조건을 조사하고 육성된 판단결정의 characterization 및 평가와 물성측정을 하였다. 본 연구에서 얻어진 최적성장조건은 온도구배가 $24^{\circ}C/cm$, 인상속도는 2.0mm/h이었다. 결정성장 최적조건에서 육성된 BSO결정은 제 2상의 석출이 없고 grain boundary가 존재하지 않으며 X선 분석으로도 단결정임이 확인되었다. 육성된 판상단결정의 판면은 (100)면이었고 결정성장 방위는 <100>이었다. 육성된 판상단결정은 편광현미경하에서는 pore, void, inclusion, striation 등의 성장결함이 없는 양질의 단결정이었으나 미세결함인 전위(dislocation)의 존재가 확인되었고 전위밀도는 $5.1{\times}10^5/\textrm{cm}^2$이었다.

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Isolation and Characterization of Strain of Bacillus thuringiensis subsp. kenyae Containing Two Novel cry1-Type Toxin Genes

  • Choi, Jae-Young;Li, Ming Shun;Shim, Hee-Jin;Roh, Jong-Yul;Woo, Soo-Song;Jin, Byung-Rae;Boo, Kyung-Saeng;Je, Yeon-Ho
    • Journal of Microbiology and Biotechnology
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    • 제17권9호
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    • pp.1498-1503
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    • 2007
  • To identify novel crystal proteins, Bacillus thuringiensis 2385-1 was isolated from Korean soil samples and characterized. The H-serotype of 2385-1 was identical to that of subsp. kenyae (H4a4c), and its crystal toxin was bipyramidal-shaped. However, 2385-1 showed a much higher toxicity towards Plutella xylostella and Spodoptera exigua larvae than subsp. kenyae. In addition, the crystal protein profile and plasmid DNA pattern of 2385-1 differed from those of subsp. kenyae. To verify the crystal protein gene types of 2385-1, a PCR-RFLP analysis was performed, and the results revealed that 2385-1 contained two novel cry1-type crystal protein genes, cryl-5 and cry1-12, in addition to the crylJal gene. The deduced amino acid sequences of cryl-5 and cry1-12 showed a 97.9% and 75.7% sequence similarity with the CrylAb and CrylJa crystal proteins, respectively. Among the novel crystal proteins, Cry1-5 showed a high toxicity towards P. xylostella and S. exigua larvae. In conclusion, B. thuringiensis 2385-1 is a new isolate in terms of its gene types, and should be a promising source for an insecticide to control lepidopteran larvae.

Two dimensional analysis of axial segregation by convection-diffusion model in batchwise and continuous Czochralski process

  • Wang, Jong-Hoe;Kim, Do-Hyun
    • 한국결정성장학회:학술대회논문집
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    • 한국결정성장학회 1997년도 Proceedings of the 13th KACG Technical Meeting `97 Industrial Crystallization Symposium(ICS)-Doosan Resort, Chunchon, October 30-31, 1997
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    • pp.117-121
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    • 1997
  • It is shown theoretically that uniform axial dopant concentration distribution can be made throughout the crystal by continuous Czochralski process. Numerical simulation are performed for the transient two-dimensional convection-diffusion model. A typical value of the growth and system parameters for Czochralski growth of p-type, 4 inches silicon crystal was used in the numerical calculations. Using this model with proper model parameter, the axial segregation in batchwise Czochralski growth can be described. It is studied by comparing with the experimental data. With this model parameter, the uniform axial concentration distribution of dopant is predicted in continuous Czochralski process.

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α-In2S3:Co2+ 단결정의 광학적 특성에 관한 연구 (Optical Properties of α-In2S3:Co2+ Single Crystal)

  • 박광호;현승철;정진;오석균
    • 한국전기전자재료학회논문지
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    • 제21권12호
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    • pp.1057-1062
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    • 2008
  • The ${\alpha}-In_2S_3:Co^{2+}$ single crystal with a good quality and stabilized property were gained successfully by the CTR(Chemical Transport Reaction)method. XRD analysis showed that the grown single crystals were cubic structure. The optical absorption spectra of ${\alpha}-In_2S_3:Co^{2+}$ single crystal showed impurity absorption peaks due to cobalt impurity. These impurity absorption pesks were assigned to the ligand transition between the split energy levels of $Co^{2+}$ ions sited in $T_d$ symmetry of these semiconductor host lattice.

Silk I형 결정을 얻기 위한 투석의 pH조건 (Dialytic pH Condition for Obtaining Silk I Type Structure)

  • 김동건
    • 한국잠사곤충학회지
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    • 제39권1호
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    • pp.67-72
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    • 1997
  • As a condition for obtaining the silk I type crystal that has stability and high reproducibility, after dissolving silk fibroin crystalline part (Fcp), the changes of recrystallized crystal structure according to dialytic pH were examined by x-ray diffraction and differential thermal analysis. The Fcp was obtained from the aqueous solution of silk fibroin enzymatic proteolyzed by chymotrypsin. The crystal structure of Fcp showed silk II type. When the Fcp was dissolved by 10M LiBr aqueous solution, the Fcp1 showed the silk II type at pH 9. However, besides the silk II type, the silk I type structure begins to appear at pH 8 and only the silk I type structure was found below pH 6. On the other hand, the Fcp2 that calcium chloride was used in the dissolution found only the silk I type crystal structure below pH8.

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Response of a rocksalt crystal to electromagnetic wave modeled by a multiscale field theory

  • Lei, Yajie;Lee, James D.;Zeng, Xiaowei
    • Interaction and multiscale mechanics
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    • 제1권4호
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    • pp.467-476
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    • 2008
  • In this work, a nano-size rocksalt crystal (magnesium oxide) is considered as a continuous collection of unit cells, while each unit cell consists of discrete atoms; and modeled by a multiscale concurrent atomic/continuum field theory. The response of the crystal to an electromagnetic (EM) wave is studied. Finite element analysis is performed by solving the governing equations of the multiscale theory. Due to the applied EM field, the inhomogeneous motions of discrete atoms in the polarizable crystal give rise to the change of microstructure and the polarization wave. The relation between the natural frequency of this system and the driving frequency of the applied EM field is found and discussed.

수정진동자의 임피던스 분석을 이용한 LB막의 전기적 특성 (Electric Properties of LB films Using Impedance Analysis of Quartz Crystal)

  • 진철남;박재철;권영수
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1998년도 추계학술대회 논문집 학회본부 C
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    • pp.878-880
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    • 1998
  • Quartz crystal in contact with viscoelastic medium is described directly in terms of the electrical equivalent circuit of the system. Stearic acid is used as viscoelastic medium and deposited on the surface of quartz crystal using the Langmuir-Blodgett(LB) method. Impedance properties of quartz crystal coated with LB films which were investigated and the possibility of applying the technique to chemical sensing introduced.

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축퇴 4 광파 혼합에 의한 광섬유에서의 광영상 직접전송에 관한 연구 (A Study on the One-way Optical Image Transmission Through Optical Fiber by Degenerate Four Wave Mixing)

  • 안병구;이우상;김은수;양인응
    • 대한전자공학회논문지
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    • 제25권4호
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    • pp.460-466
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    • 1988
  • In this paper, the theory and experiments on the one-way optical image transmission through optical fiber by using degenerate four wave mixing in BSO single crystal are demonstrated. From the theoretical analysis, the diffraction efficiency of phase conjugate wave in BSO single crystal is greatly dependent on applied electric field intensity, diffraction grating period formed in the crystal and incident beam ratio, those are also in good agreement with the experimental results. Based on the experimental results, we have arranged the typical degenerate four wave mixing system in the optimal conditions (applied electric field, E. = 5kV/cm` diffraction grating period, 3\ulcorner` beam ratio of backward pump wave versus signal wave, 2.7) and realized one-way optical image transmission system through optical fiber using BSO single crystal.

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CMSMPR 결정화기의 시동 특성 연구 (Start-up dynamics in a CMSMPR crystallizer)

  • 신영준;이철수
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 1986년도 한국자동제어학술회의논문집; 한국과학기술대학, 충남; 17-18 Oct. 1986
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    • pp.200-204
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    • 1986
  • Particle size distribution in a Continuous Mixed Suspension Mixed Crystal Removal (CMSMPR) crystallizer has been analyzed using the Population Balance (PB) model. This method presents difficulties when the growth rate of crystal depends on the crystal size. Recent studies indicate that in many cases the growth rate is dependent on size when the crystal sizes are small. In this study, a Residence Time Distribution(RTD) model was proposed to take the size dependence into account together with an appropriate numerical scheme. When compared with the approximate results based on PB model, RTD model results showed improvements also a nucleation effect which is normally unimportant for steady state analysis. Start-up data for NaCl-Water-Ethanol system was compared with computed values.

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Olefin Polymerization Activity and Crystal Structure of Alkyliron(Ⅲ) Porphyrin Complexes

  • Oh, Yung-Hee;Swenson, Dale;Goff, Harold M.
    • Bulletin of the Korean Chemical Society
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    • 제24권2호
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    • pp.167-172
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    • 2003
  • Alkyliron(Ⅲ) porphyrins, n-butyliron(Ⅲ) tetraphenylporphyrin, (TPP)Fe-Bu and n-butyliron(Ⅲ) tetrakis-(pentafluorophenyl)porphyrin, $(F_{20}TPP)Fe-Bu$ have been evaluated as suitable for olefin free-radical polymerization. Butyl radicals dissociated from n-butyliron(Ⅲ) porphyrin initiated the polymerization reaction, but the ratio of the propagation was low. The GCMS analysis of the reaction mixture of nbutyliron(Ⅲ) porphyrin and styrene has revealed several products containing two butyl groups, while traces of b-hydrogen-abstracted products were observed. The crystal structure of (TPP)Fe-Bu has been determined. The structure of the n-butyliron(Ⅲ) porphyrin reveals the compound containing five-coordinated iron with the average Fe-N distance of 1.973(1) Å and Fe-C of 2.030(2) Å. The iron atom is displaced by 0.137Å from a four nitrogen mean plane. Crystal system is triclinic, and space group is P-1.