• Journal of the Korean Society for Heat Treatment
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• v.12 no.3
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• pp.206-214
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• 1999

The effect of cooling rate on carbide precipitation during quenching of austenitic manganese steel was investigated by optical microscopy, image analyzer and numerical analysis. A computer program based on the finite difference method for analyzing heat treatment processes was developed in order to evaluate cooling rates and the possibility of carbide precipitation during quenching. The area ratio of carbide precipitated in the austenite matrix was measured by the image analyzer, and used to determine the critical point of carbide precipitation. Temperature-dependent critical cooling rates at the critical points were calculated using the present simulation program, The calculated results showed a good agreement with the experimental ones.

• Korean Journal of Materials Research
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• v.10 no.8
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• pp.581-588
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• 2000

Phase transition of the Lennard-Jonesian binary system with a free surface was studied by employing molecular dynamics simulation. The main focus of this study was to investigate the effect of size misfit and solute concentration on phase transition during heating and quenching. For a binary system with a free surface, the melting point and the critical quenching rate decrease as size misfit and solute concentration increase.

• Journal of the Korean Ceramic Society
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• v.34 no.7
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• pp.767-773
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• 1997

Thermal shock behavior of alumina ceramics were studied by quenching the heated alumina specimen into the water of various temperatures over 0~10$0^{\circ}C$. The critical thermal shock temperature difference ( Tc) of the specimen decreased almost linearly from 275$^{\circ}C$ to 20$0^{\circ}C$ with increase in the cooling water temperature over 0~6$0^{\circ}C$. It is probably due to the increase of the maximum cooling rate which is dependent of the convection heat transfer coefficient. The convection heat transfer coefficient is a function of the temperature of the cooling water. However, the critical thermal shock temperature difference( Tc) of the specimen increased at 25$0^{\circ}C$ over 80~10$0^{\circ}C$ due to the film boiling of the cooling water. The maximum cooling rate, which brings about the maximum thermal stress of the specimen in the cooling process, was observed to increase linearly with the increase in the quenching temperature difference of the specimen due to the linear relationship of the convection heat transfer coefficient with the water temperature over 0~6$0^{\circ}C$. The critical maximum cooling rate for thermal shock fracture was observed almost constant to be about 260$\pm$1$0^{\circ}C$/s for all water temperatures over 0~6$0^{\circ}C$. Therefore, thermal shock behavior of alumina ceramics is greatly influenced by the convection heat transfer coefficient of the cooling water.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.13 no.1
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• pp.45-71
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• 1987

${\beta}$-Carotene has been known as an effective quenching agent of singlet oxygen and the carotenoid pigments in general are expected to protect cells against photosensitized oxidations. We are determined the quenching rate constants of several Ketocarotenoids including capsanthin, capsanthin diester, astaxanthin and fucoxanthin, and the relative quenching actiyities against singlet oxygen were compared with those of ${\beta}$-carotene and reported carotenoids. Nevertheless the ketocarotenoids exhibited lower quenching rate constants than ${\beta}$-carotene, they showed more pronounced protective activitives than ${\beta}$-carotene against photohemlysis induced by singlet oxygen. Among the ketocarotenoids investigated, fucoxanthin indicated a significant protective activity for the cell. The results suggested that. 1) 1O2 may be alikely initiator of photohemolysis, but this reaction is followed by slow dark reactions involving secondary reactive species. 2) For protection of RBC against photodynamic action with carotenoids, carotenoids having functional groups such as -C=0 and -OH groups are most efficient. This suggests that partition of carotenoids between the buck and the mombrane and/or their specific binding to membrane proteins are more critical for the photo-protection by carotenoids than is a diffusional quenching of 1O2.

• Proceedings of the Materials Research Society of Korea Conference
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• 1999.11a
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• pp.42-42
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• 1999

• Proceedings of the Materials Research Society of Korea Conference
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• 1999.05a
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• pp.86-86
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• 1999

• Journal of the Korean Society of Combustion
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• v.9 no.2
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• pp.18-29
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• 2004

Partial quenching structure of diffusion flames in a turbulent mixing layer has been investigated by the method of flame hole dynamics in oder to develope a prediction model for the phenomenon of turbulent flame lift off. The present study is specifically aimed to remedy the shortcoming of the stiff transition of the conditioned partial burning probability across the crossover condition by employing the level-set method which enables us to include the effect of finite flame edge propagation speed. In light of the level-set simulation results with two models for the edge propagation speed, the stabilizing conditions for turbulent lifted flame are suggested. The flame hole dynamics combined with the level-set method yields a temporally evolving turbulent extinction process and its partial quenching characteristics is compared with the results of the previous model employing the flame-hole random walk mapping based on three critical scalar dissipation rates. The probability to encounter reacting state, conditioned with scalar dissipation rate, demonstrated that the conditional probability has a rather gradual transition across the crossover scalar dissipation rate. Such a smooth transition is attributed to the finite response of the flame edge propagation.

• Bulletin of the Korean Chemical Society
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• v.19 no.10
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• pp.1063-1068
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• 1998

The nature of F electronic excitation energy transfer to OH- vibrational levels in KCl crystals is the exchange interaction, although the transfer process exhibits three temporally distinguishable components depending on the distance between excited F center and OH-. The critical distance as well as rate of the major energy transfer process in randomly distributed samples increases rapidly as OH- librational motions become active with temperature rise. The excited state character introduced into the OH- ground electronic state by perturbation is essential for the exchange interaction. The perturbation is brought about by the expanded electron cloud of excited F center for OH- associated to F center, whereas by librations and lattice vibrations perpendicular to the bond axis for isolated OH- . F excitation quenching efficiency by OH- is dependent on the variation of the critical distance rather than the rate as the rate is much faster than the normal F bleach recovery rate.

• Membrane and Water Treatment
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• v.15 no.2
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• pp.51-57
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• 2024

The removal of phosphorus, especially phosphate-form phosphorus, is necessary in wastewater treatment. Biofouling induced by the quorum sensing mechanism is also a major problem in membrane bioreactor (MBR), which reduces membrane flux. This study introduces lanthanum-doped quorum quenching (QQ) beads into MBR, confirming their inhibitory effect on biofouling due to Rhodococcus sp. BH4 and their capacity for phosphorus removal through lanthanum adsorption. A batch test was conducted to access the phosphate adsorption of lanthanum-QQ (La-QQ) beads and lab-scale MBR to verify the effect of inhibition. The study aimed to identify distinctions among the MBR, QQ MBR, and La-QQ MBR. In the batch test, the phosphate removal rate increased as the volume of beads increased, while the unit volume removal rate of phosphate decreased. In the lab-scale MBR, the phosphate removal rates were below 20% in the control MBR and QQ MBR, whereas the La-QQ MBR achieved a phosphate removal rate of 74%. There was not much difference between the ammonia and total organic carbon (TOC) removal rates. Regarding the change in transmembrane pressure(TMP), 3.7 days were taken for the control MBR to reach critical pressure. In contrast, the QQ-MBR took 9.8 days, and the La-QQ MBR took 6.1 days, which confirms the delay in biofouling. It is expected that La-QQ can be used within MBR to design a more stable MBR process that regulates biofouling and enhances phosphate removal.

• Journal of Advanced Marine Engineering and Technology
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• v.13 no.4
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• pp.40-53
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• 1989

Boiling heat transfer phenomena is widely applied to BWR and electrical heating system because of its high heat transfer coefficient. In these systems, steady state heat transfer is dependent on nucleate boiling. When the heat generating rate is sharply increased or the cooling capacity of coolant is sharply decreased, sharp wall temperature rise is occurred under the critical heat flux(CHF) condition. This paper presents the simple wall temperature fluctuation model of transition mechanism in the repeating process of overheating and quenching, when coalescent bubble passes relatively slowly on the wall and simultaneously the transition from nucleate boiling to film boiling is carried at especially onset of the CHF state. The values calculated by the present model are resulted comparatively good with the measured.