• Title/Summary/Keyword: critical parameters

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Effect of Salts and Isomeric Butanols on the Mixed Micellar Properties of Cetylpyridinium Chloride with Triton X-100 (Cetylpyridinium Chloride와 Triton X-100의 혼합 미셀화에 미치는 염 및 부탄올 이성질체들의 효과)

  • Chung, Jong-Jae;Lee, Sang-Hak;Kim, Yung-Cheol;Lee, Byung-Hwan
    • Applied Chemistry for Engineering
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    • v.9 no.7
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    • pp.968-973
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    • 1998
  • The critical micelle concentrations($CMC^*$) of the mixed surfactant systems of cationic surfactant cetylpyridinium chloride(CPC) and nonionic surfactant Triton X-100(TX-100) in aqueous solutions of salts(KCl and $Na_2CO_3$) and isomeric butanols(tert-butanol, iso-butanol and n-butanol) were determined by UV spectroscopy method. The various thermodynamic values in aqueous solutions of salts and isomeric butanols were compared with the values in pure water, calculated by means of the equation derived from the pseudo-phase separation model. Thermodynamic parameters($X_1$, $\beta$, ${\gamma}i$, $ai^M$, $C_i$ and ${\Delta}H_{mix}$) were found to have great effects of salts and isomeric butanols on the mixed micellization of CPC/TX-100 mixtures, and also in good agreements with the nonideal mixed micelle model. They showed all negative deviations from the ideal mixed micellar behavior.

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Membrane fouling reduction using electro-coagulation aided membrane bio-reactor (전기응집 분리 막 생물반응기의 막 오염 저감)

  • Kim, Wan-Kyu;Hong, Sung-Jun;Chang, In-Soung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.8
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    • pp.105-114
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    • 2018
  • Membrane fouling in EC-MBR (Electro-Coagulation aided Membrane Bio-Reactor) processes was evaluated according to the operating parameters, such as current density and contact time. In addition, the fouling mechanism was investigated. Compared to the control (i.e., no electro-coagulation), membrane fouling for filtration of the activated sludge suspension after electro-coagulation was reduced significantly. Membrane fouling was improved further when the contact time was doubled under a low current density of $2.5A/m^2$. On the other hand, membrane fouling was not mitigated further, as expected, even though the contact time was doubled from 12 to 24 hr. at a current density of $10A/m^2$. This indicates that the overall decrease in membrane fouling is a function of the product of the current density and contact time. The particle size of the activated sludge flocs after electro-coagulation was changed slightly, which means that the membrane fouling reduction was not attributed to a larger particle size resulting from electro-coagulation. The experimental confirmed that the dynamic membrane made from aluminum hydroxide, Al(OH)3, and/or aluminum phosphate, Al(PO4), which had been formed during the electro-coagulation, played a key role on the reduction of membrane fouling. The dynamic membrane prevents the particles in the feed solution from deposition to the membrane pores and cake layers. Dynamic membrane formation as a result of electro-coagulation plays a critical role in the mitigation of membrane fouling in EC-MBR.

Estimation of Water Production Cost from Seawater Reverse Osmosis (SWRO) Plant in Korea (국내 해수담수화 플랜트 생산수 단가 추정)

  • Hwang, Moon-Hyun;Han, Doseon;Kim, In S.
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.4
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    • pp.169-179
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    • 2017
  • This study was conducted to supply information that can be utilized as data for desalination plant construction in the future by estimating unit cost of water production in the potential site of Incheon, Daesan, Yeosu, Busan, Ulsan and Sokcho in Korea. The production costs in Sokcho and Ulsan were similar to those of Busan and Yeosu. Those four sites showed better economic range due to low construction cost for intake facility compared to Incheon and Daesan. Although the salinity measured in the above 6 sites did not show perceptible effect on the production cost, the difference of seasonal seawater temperature needs to be considered due to the change of flux in reverse osmosis (RO) membrane. It turned out that the most critical parameters are the amortization in a year by the analysis of life cycle and the capacity of plant. Incheon and Daesan showed the difference of production cost up to 29% at the condition of amortization in 25 year, and up to 22% depending on plant capacity. However, the production cost in this study did not take into account of other indirect costs, therefore, this should be considered as the minimum cost.

The Roles of Economic Benefits and Identity Salience: Inducing Factors in the Behavioral Intent to Use Outlet Shopping Centers (아울렛 쇼핑센터의 이용의도에서 아이덴티티 현저성의 요인과 경제성의 역할)

  • Choi, Nak-Hwan;Lim, Ah-Young;An, Lina
    • Journal of Distribution Science
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    • v.11 no.6
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    • pp.41-50
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    • 2013
  • Purpose - Inducing consumers' behavioral intent to use an outlet shopping center is a critical issue for managers since it can be used as a guide for developing marketing strategies. Low prices could lead to a growth in retail purchases, but there might also be a positive relationship between prices and customer perceptions of product quality. The extent to which consumers use price as a predictor of quality may differ according to the availability of important alternative cues such as brand, store name, and identity salience triggered by the store. Consumers can obtain non-economic benefits from marketing exchanges that go beyond basic economic achievement. We argue that identity salience can play a crucial mediating role when consumers, acting as exchange partners, seek to obtain social benefits. This study shows that identity salience could mediate the relationship between identity salience-inducing factors such as multi-finality, prestige and role performance, and consumers' behavioral intent to use an outlet shopping center. Research design, data and methodology - The survey was conducted on college students enrolled in marketing classes. A total of 200 questionnaires were distributed, of which only 194 were returned. After five incomplete questionnaires were excluded, a final sample of 189 was used for empirical analysis. Using a covariance structural analysis in Amos17, we confirmed the fit of the research model and estimated its parameters by using the maximum likelihood method. Results - The results of the hypotheses testing are as follows. First, both identity salience and economic benefits have positive effects on the behavioral intent to use an outlet shopping center. Second, role performance, prestige, and multi-finality have positive effects on identity salience. Finally, the additive analysis of the direct effects of identity salience-inducing factors shows that the role performance, prestige, and multi-finality factors have no direct effects on the behavioral intent to use an outlet shopping center, suggesting that identity salience plays a positive mediating role. Conclusions - This study informs marketers that not only price but shoppers' identity salience directly affects their intent to visit an outlet shopping center. To strengthen shoppers' identity salience, marketers should find ways to help shoppers fulfill their multiple social roles, realize their multiple goals, and achieve prestige. In other words, outlet shopping centers must improve their personal service environment in order to enhance their employees' service quality and assist the execution of multi-finality by minimizing the perceived costs (e.g., travel time, effort) associated with shopping trips, thus making it easier for consumers to combine visits to multiple stores in outlet shopping centers and buy the items required for their consumption goals. Outlet shopping centers must also offer assortments with both breadth and depth in order to help consumers play the social roles their social networks have given them.

Construction of Surface Boundary Conditions for the Regional Climate Model in Asia Used for the Prevention of Disasters Caused by Climate Changes (기상방재 대책수립을 위한 아시아지역 기상모형에 필요한 지표경계조건의 구축)

  • Choi, Hyun-Il
    • Journal of the Korean Society of Hazard Mitigation
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    • v.7 no.5
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    • pp.73-78
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    • 2007
  • It has been increasing that significant loss of life and property due to global wanning and extreme weather, and the climate and temperature changes in Korea Peninsula are now greater than the global averages. Climate information from regional climate models(RCM) at a finer resolution than that of global climate models(GCM) is required to predictclimate and weather variability, changes, and impacts. The new surface boundary conditions(SBCs) development is motivated by the limitations and inconsistencies of existing SBCs that have influence on model predictability. A critical prerequisite in constructing SBCs is that the raw data should be accurate with physical consistency across all relevant parameters and must be appropriately filled for missing data if any. The aim of this study is to construct appropriate SBCs for the RCM in Asia domain which will be used for the prevention of disasters due to climate changes. As all SBCs have constructed onto the 30km grid-mesh of the RCM suitable for Asia applications, they can be also used for other distributed models for climate and hydrologic studies.

Mixing Analysis of Oil Spilled into the River by GPS-equipped Drifter Experiment and Numerical Modeling (GPS 부자 실험과 수치모델링에 의한 하천에 유입된 유류오염물질의 거동 해석)

  • Jang, Juhyoung;Jong, Jaehun;Mun, Hyunsaing;Kim, Kyunghyun;Seo, Ilwon
    • Journal of Korean Society on Water Environment
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    • v.32 no.3
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    • pp.243-252
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    • 2016
  • In cases of water pollution accidents, accurate prediction for arrival time and concentration of contaminants in a river is essential to take proper measures and minimize their impact on downstream water intake facilities. It is critical to fully understand the behavior characteristics of contaminants on river surface, especially in case of oil spill accidents. Therefore, in this study, the effects of main parameters of advection and diffusion of contaminants were analyzed and validated by comparing the results of Lagrangian particle tracking (LPT) simulation of Environmental Fluid Dynamic Code (EFDC) model with those of Global Position System (GPS)-equipped drifter experiment. Prevention scenario modeling was accomplished by taking cases of movable weir operation into account. The simulated water level and flow velocity fluctuations agreed well with observations. There was no significant difference in the speed of surface particle movement between 5 and 10 layer modeling. Therefore, 5 layer modeling could be chosen to reduce computational time. It was found that full three dimensional modeling simulated wind effects on surface particle movements more sensitively than depth-averaged two dimensional modeling. The diffusion range of particles was linearly proportional to horizontal diffusivity by sensitivity analysis. Horizontal diffusivity estimated from the results of GPS-equipped drifter experiment was 0.096 m2/sec, which was considered to be valid for applying the LPT module in this area. Finally, the scenario analysis results showed that particle movements could be stagnant when discharge from the upstream weir was reduced, implying the possibility of securing time for mitigation actions such as oil boom installation and wiping oil contaminants. The outcomes of this study can help improve the prediction accuracy of particle tracking simulation to establish the most suitable mitigation plan considering the combination of movable weir operation.

Estimation of Land Surface Energy Fluxes using CLM and VIC model (CLM과 VIC 모형을 활용한 지표 에너지 플럭스 산정)

  • Kim, Daeun;Ray, Ram L.;King, Seokkoo;Choi, Minha
    • Journal of Wetlands Research
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    • v.18 no.2
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    • pp.166-172
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    • 2016
  • Accurate understanding of land surface is essential to analyze energy exchanges between earth surface and atmosphere. For the quantization of energy fluxes, the various researches about Land Surface Model(LSM) have been progressed. Among the various LSMs, the researches using Common Land Model(CLM) and Variable Infiltration Capacity(VIC) model are performed briskly. The CLM which is advanced LSM can calculate realistic results with few user defined parameters. The VIC model which is also typical LSM is widely used for estimation of energy fluxes and runoff in various fields. In this study, the energy fluxes which are net radiation, sensible heat flux, and latent heat flux were estimated using CLM and VIC model at Southern Sierra-Critical Zone Observatory(SS-CZO) site in California, United States. In case of net radiation and sensible heat flux, both models showed good agreement with observations, however, the CLM showed underestimated patterns of net radiation and sensible heat flux during precipitation period. In case of latent heat flux, the CLM represented better estimation of latent heat flux than VIC model which underestimated the latent heat flux. Through the estimation of energy fluxes and analysis of models' pros and cons, the applicability of CLM and VIC models and need of multi-model application were identified.

Rotordynamic Analysis of a Dual-Spool Turbofan Engine with Focus on Blade Defect Events (블레이드 손상에 따른 이축식 터보팬 엔진의 동적 안정성 해석)

  • Kim, Sitae;Jung, Kihyun;Lee, Junho;Park, Kihyun;Yang, Kwangjin
    • Tribology and Lubricants
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    • v.36 no.2
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    • pp.105-115
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    • 2020
  • This paper presents a numerical study on the rotordynamic analysis of a dual-spool turbofan engine in the context of blade defect events. The blades of an axial-type aeroengine are typically well aligned during the compressor and turbine stages. However, they are sometimes exposed to damage, partially or entirely, for several operational reasons, such as cracks due to foreign objects, burns from the combustion gas, and corrosion due to oxygen in the air. Herein, we designed a dual-spool rotor using the commercial 3D modeling software CATIA to simulate blade defects in the turbofan engine. We utilized the rotordynamic parameters to create two finite element Euler-Bernoulli beam models connected by means of an inter-rotor bearing. We then applied the unbalanced forces induced by the mass eccentricities of the blades to the following selected scenarios: 1) fully balanced, 2) crack in the low-pressure compressor (LPC) and high pressure compressor (HPC), 3) burn on the high-pressure turbine (HPT) and low pressure compressor, 4) corrosion of the LPC, and 5) corrosion of the HPC. Additionally, we obtained the transient and steady-state responses of the overall rotor nodes using the Runge-Kutta numerical integration method, and employed model reduction techniques such as component mode synthesis to enhance the computational efficiency of the process. The simulation results indicate that the high-vibration status of the rotor commences beyond 10,000 rpm, which is identified as the first critical speed of the lower speed rotor. Moreover, we monitored the unbalanced stages near the inter-rotor bearing, which prominently influences the overall rotordynamic status, and the corrosion of the HPC to prevent further instability. The high-speed range operation (>13,000 rpm) coupled with HPC/HPT blade defects possibly presents a rotor-case contact problem that can lead to catastrophic failure.

Prediction of dryout-type CHF for rod bundle in natural circulation loop under motion condition

  • Huang, Siyang;Tian, Wenxi;Wang, Xiaoyang;Chen, Ronghua;Yue, Nina;Xi, Mengmeng;Su, G.H.;Qiu, Suizheng
    • Nuclear Engineering and Technology
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    • v.52 no.4
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    • pp.721-733
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    • 2020
  • In nuclear engineering, the occurrence of critical heat flux (CHF) is complicated for rod bundle, and it is much more difficult to predict the CHF when it is in natural circulation under motion condition. In this paper, the dryout-type CHF is investigated for the rod bundle in a natural circulation loop under rolling motion condition based on the coupled analysis of subchannel method, a one-dimensional system analysis method and a CHF mechanism model, namely the three-fluid model for annular flow. In order to consider the rolling effect of the natural circulation loop, the subchannel model is connected to the one-dimensional system code at the inlet and outlet of the rod bundle. The subchannel analysis provides the local thermal hydraulic parameters as input for the CHF mechanism model to calculate the occurrence of CHF. The rolling motion is modeled by additional motion forces in the momentum equation. First, the calculation methods of the natural circulation and CHF are validated by a published natural circulation experiment data and a CHF empirical correlation, respectively. Then, the CHF of the rod bundle in a natural circulation loop under both the stationary and rolling motion condition is predicted and analyzed. According to the calculation results, CHF under stationary condition is smaller than that under rolling motion condition. Besides, the CHF decreases with the increase of the rolling period and angular acceleration amplitude within the range of inlet subcooling and mass flux adopted in the current research. This paper can provide useful information for the prediction of CHF in natural circulation under motion condition, which is important for the nuclear reactor design improvement and safety analysis.

Using Ridge Regression to Improve the Accuracy and Interpretation of the Hedonic Pricing Model : Focusing on apartments in Guro-gu, Seoul (능형회귀분석을 활용한 부동산 헤도닉 가격모형의 정확성 및 해석력 향상에 관한 연구 - 서울시 구로구 아파트를 대상으로 -)

  • Koo, Bonsang;Shin, Byungjin
    • Korean Journal of Construction Engineering and Management
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    • v.16 no.5
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    • pp.77-85
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    • 2015
  • The Hedonic Pricing model is the predominant approach used today to model the effect of relevant factors on real estate prices. These factors include intrinsic elements of a property such as floor areas, number of rooms, and parking spaces. Also, The model also accounts for the impact of amenities or undesirable facilities of a property's value. In the latter case, euclidean distances are typically used as the parameter to represent the proximity and its impact on prices. However, in situations where multiple facilities exist, multi-colinearity may exist between these parameters, which can result in multi-regression models with erroneous coefficients. This research uses Variance Inflation Factors(VIF) and Ridge Regression to identify these errors and thus create more accurate and stable models. The techniques were applied to apartments in Guro-gu of Seoul, whose prices are impacted by subway stations as well as a public prison, a railway terminal and a digital complex. The VIF identified colinearity between variables representing the terminal and the digital complex as well as the latitudinal coordinates. The ridge regression showed the need to remove two of these variables. The case study demonstrated that the application of these techniques were critical in developing accurate and robust Hedonic Pricing models.