• 제목/요약/키워드: critical concentration

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Decylpyridinium Chloride 용액의 Critical Micelle Concentration에 미치는 온도의 영향 (Effect of Temperature on the Critical Micelle Concentration of Decylpyridinium Chloride)

  • 한만운;이종만
    • 대한화학회지
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    • 제16권4호
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    • pp.201-204
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    • 1972
  • Decylpyridinium Chloride 수용액의 c.m.c를 $10^{\circ}$부터 $50^{\circ}$사이의 온도에서 전기전도도법으로 결정하였던바 온도에 따른 c.m.c. 변화는 $15^{\circ}$근처에서 최소값을 보였다. Clausius-Clapeyron형의 식과 log(c.m.c)의 온도방법식으로 부터 micelle화 과정에 따른 ${\Delta}Hm$, ${\Delta}$Fm^{\circ}$, ${\Delta}$Sm, ${\Delta}Sm^{\circ}$${\Delta}$Cpm을 얻어 dodecylpyridinium chloride와 dodecylpyridinium bromide의 값들과 비교 검토하였다.

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Combinatorial continuous non-stationary critical excitation in M.D.O.F structures using multi-peak envelope functions

  • Ghasemi, S. Hooman;Ashtari, P.
    • Earthquakes and Structures
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    • 제7권6호
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    • pp.895-908
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    • 2014
  • The main objective of critical excitation methods is to reveal the worst possible response of structures. This goal is accomplished by considering the uncertainties of ground motion, which is subjected to the appropriate constraints, such as earthquake power and intensity limit. The concentration of this current study is on the theoretical optimization aspect, as is the case with the majority of conventional critical excitation methods. However, these previous studies on critical excitation lead to a discontinuous power spectral density (PSD). This paper introduces some critical excitations which contain proper continuity in frequency domain. The main idea for generating such continuous excitations stems from the combination of two continuous functions. On the other hand, in order to provide a non-stationary model, this paper attempts to present an appropriate envelope function, which unlike the previous envelope functions, can properly cover the natural earthquakes' accelerograms based on multi-peak conditions. Finally, the proposed method is developed into the multiple-degree-of-freedom (M.D.O.F) structures.

국내 원전주변 주민 방사선 피폭선량 평가 - 입력변수의 영향 (Evaluation of Residential Radiation Doses from Korean Atomic Power Plants - Effect of Socioenvironmental Inputs)

  • 조대철;이갑복
    • 한국산학기술학회논문지
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    • 제4권3호
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    • pp.223-229
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    • 2003
  • ICRP-60 신권고에 맞게 수정된 방사선피폭선량 계산프로그램인 K-DOSE 60을 4개 발전소 (고리, 월성, 울진, 영광)에 적용하여 주변주민 최대개인피폭선량을 평가하였다 핵종, 장기, 경로별로 결정변수값들을 도출한 결과, 경로는 성인의 경우 농작물, 유아의 경우 우유가, 핵종은 ³H, /sup 133/Xe, /sup 60/Co (고리 1,2발전소), /sup 14/C, /sup 41/Ar(월성 1,2발전소)로 나타났으며, 모든 장기에 대한 피폭선량차이가 매우 작았다. "출력 대 입력" 변동에 근거한 민감도 분석결과, 핵종의 화학적 형태가 타 입력변수들보다 10² factor만큼 높은 민감도를 보였으며, 전이/농축계수에 의한 민감도는 섭취량이나 방출량의 그것에 비하여 상대적으로 매우 낮았다. PCC를 이용한 상관성 민감도의 경우는 4가지 입력변수 모두 0.97 이상의 높은 상관성을 보였다.

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저온-저염 절임기술이 절임배추의 품질 특성에 미치는 영향 (Effects of the Low Temperature and Low Salt Solution on the Quality Characteristics of Salted Chinese Cabbage)

  • 이석원;조선래;한성희;이철
    • 한국식품영양학회지
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    • 제22권3호
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    • pp.377-386
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    • 2009
  • The principal objective of this study was to evaluate the influence of temperature and salt concentration on the physicochemical properties of salted Chinese cabbage. Salted Chinese cabbage samples were prepared with various concentrations of salt(4, 5, 6 and 7%), and were stored for 10 days at three temperatures(8, 14, and $25^{\circ}C$). The salting ratio of Chinese cabbage evidenced a decreasing trend regardless of the salting temperature and salt concentration, and their decrement appeared relatively high as the salting temperature increased. The period required to achieve a critical salting ratio(85%) decreased with increases in the salt concentration at $25^{\circ}C$, and a similar trend was observed at lower temperatures(8 and $14^{\circ}C$). The salinity of all samples evidenced an increasing trend during the salting period, and at $25^{\circ}C$, in particular, a continuous increment was observed. At salt concentrations of 4%, the critical salinity(2.2%) was not achieved regardless of the temperature and salting period. The pH of salted Chinese cabbage achieved critical pH in 3 days at a salting temperature of $25^{\circ}C$, but the critical pH 5.5 of samples at 8 and $14^{\circ}C$ appeared after a long period of approximately 4 to 10 days. The average hardness values of salted Chinese cabbage at a salting ratio of 85% were approximately 1.49 MPa, 1.87 MPa, and 1.97 MPa, respectively, at three temperatures($25^{\circ}C$, $14^{\circ}C$, and $8^{\circ}C$). The initial reducing sugar content of cabbage juice was 11.8 mg/$m{\ell}$, and this value decreased substantially to 3 to 5 mg/$m{\ell}$ on day 1.

니스타틴의 응집 특성 및 용혈 활성 (The Aggregation State and Hemolytic Activity of Nystatin)

  • 유봉규
    • Journal of Pharmaceutical Investigation
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    • 제31권1호
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    • pp.1-5
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    • 2001
  • The aggregation behavior of nystatin (NYS) in the presence of pluronic F127, triblock copolymer of poly (ethylene oxide) (PEO) and poly (propylene oxide) (PPO), was measured and correlated with hemolytic activity. Antifungal activity was also studied using Saccharomyces cerevisiae as a model strain. The critical aggregation concentrations (CAC) of the drug were 50.1, 108.0, 134.2, 154.3, and $217.9\;{\mu}M$ at 0.1%, 0.5%, 1.0%, 1.5%, and 2.0% pluronic F127 solution, respectively. The levels of NYS required to start lysis of erythrocytes were about 80, 100, 125, 150, and $200\;{\mu}M$ at 0.1%, 0.5%, 1.0%, 1.5%, and 2.0% pluronic F127 solution, respectively. It was $50\;{\mu}M$ in the absence of the polymer. Minimal inhibitory concentration (MIC) and minimal fungicidal concentration (MFC) of NYS-pluronic F127 lyophilizate were same at $3\;{\mu}g/ml$, while MIC and MFC of pure NYS are $3\;{\mu}g/ml$ and $12\;{\mu}g/ml$, respectively. By modulating the aggregation behavior of NYS, pluronic F127 was able to reduce the toxicity of the drug without compromising the MIC and MFC.

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Iodine Stress Corrosion Cracking of Zircaloy-4 Tubes

  • Moon, Kyung-Jin;Lee, Byung-Ho
    • Nuclear Engineering and Technology
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    • 제10권2호
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    • pp.65-72
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    • 1978
  • 원자로 가동시, 정상상태에서 벗어나 갑작스럽게 출력이 바뀔 때 발생하는 응력의 집중과 핵 분열시 발생하는 요오드의 부식에 의해서 생기는 피복물질의 응력 부식파괴현상을 이해하기 위하여, 이번 실험에서는 지르칼로이-4(Zicaloy-4)관을 사용하여 요오드응력부식 실험을 원자로 안의 상태에 가깝도록 30$0^{\circ}C$의 상태아래서 행하였다. 요오드 농도에 따라서 지르칼로이-4, 관(Tube)의 응력부식에 한 파괴시간을 구했고, 응력부식을 일으킬 수 있는 임계요오드 농도 및 임계접선방향의 응력을 구하였다. 요오드에 의한 응력부식이 화학석인 반응이라기 보다는 기계적인 반응성격을 갖기 때문에 응력부식을 파괴 역학적인 관점에서 설명하고자 응력과 파괴시간을 함수관계로 다음과 같이 표시해 보았다. log t$_{F}$ =5.5- (3/2) log$_{c}$-4log$\sigma$ t$_{F}$ : 파괴시간(") c : 요오드농도(mg/㎤) $\sigma$ : 응력 ($10^4$psi).

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Si 모재 위의 $Si_xGe_{1-x}$ 박막에서 부정합 전위와 임계두께에 관한 연구 (Study on Misfit Dislocations and Critical Thickness in a $Si_xGe_{1-x}$ Epitaxial Film on a Si Substrate)

  • 신정훈;김재현;엄윤용
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 춘계학술대회논문집A
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    • pp.298-303
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    • 2001
  • The critical thickness of an epitaxial film on a substrate in electronic or optoelectronic devices is studied on the basis of equilibrium dislocation analysis. Two geometric models, a single dislocation and an array of dislocations in heteroepitaxial system, are considered respectively to calculate the misfit dislocation formation energy. The isotropic linearly elastic stress fields for the models are obtained by means of complex potential method combined with alternating technique, and are used for calculating the formation energies. As a result, the effect of elastic mismatch between film and substrate on critical thickness is presented and $Si_xGe_{1-x}/Si$ epitaxial structure is analyzed to predict the critical thickness with varying germanium concentration.

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Scattering법을 이용한 BaMgAl10O17:Eu2+ 청색형광체의 구조와 발광특성 연구 (A Study of the Structure and Luminescence Properly of BaMgAl10O17:Eu2+ Blue Phosphor using Scattering Method)

  • 김광복;김용일;구경완;천희곤;조동율
    • 한국전기전자재료학회논문지
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    • 제15권1호
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    • pp.67-74
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    • 2002
  • A phosphor for Plasma Display Panel, BaMgAl$_{10}$ O$_{17}$ :Eu$^{2+}$, showing a blue emission band at about 450nm was prepared by a solid-state reaction using BaCO$_3$, $Al_2$O$_3$, MgO, Eu$_2$O$_3$ as starting materials wish flux AlF$_3$. The study of the behaviour of Eu in BAM phosphor was carried out by the photoluminescence spectra and the Rietveld method with X-ray and neutron powder diffraction data to refine the structural parameters such as lattice constants, the valence state of Eu, the preferential site of Mg atom and the site fraction of each atom. The phenomenon of the concentration quenching was abound 2.25~2.3wt% of Eu due to a decrease in the critical distance for energy transfer of inter-atomic Eu. Through the combined Rietveld refinement, R-factor, R$_{wp}$, was 8.11%, and the occupancy of Eu and Mg was 0.0882 and 0.526 at critical concentration. The critical distance of Eu$^{2+}$ in BAM was 18.8$\AA$ at 2.25% Eu of the concentration quenching. Furthermore, c/a ratio was decreased to 3.0wt% and no more change was observed over that concentration. The maximum entropy electron density was found that the modeling of $\beta$-alumina structure in BaMgAl$_{10}$ O$_{17}$ :Eu$^{2+}$correct coincided showing Ba, Eu, O atoms of z= 1/4 mirror plane.e.ane.e.