• Title/Summary/Keyword: critical concentration

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Settling Mode of the Dredged Soil (준설토의 침강형태에 관한 연구)

  • 윤상묵;장병욱;차경섭
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.45 no.1
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    • pp.63-73
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    • 2003
  • The settling of the dredged soil may vary with mineral composition, grain size distribution, initial water content and salt concentration of suspension of the site. A series of settling column test was performed to investigate the behaviour of solid suspension material from dredging and reclamation. Settling mode was divided into four types from the observation of interface and settling curves of clay minerals and marine clay samples, and the relationship charts of salt concentration and the initial water content were established to use in the dredging operation with any salt concentration. The critical initial water content which was defined as a threshold of zone settling and the consolidation settling was varied with salt concentration of water and was proportional to the plasticity of soil in sea water.

On the Micellization of ${\alpha}$-Amino Capric Acid (${\alpha}$-아미노카프르산의 Micelle 형성을 위한 한계농도에 관하여)

  • Ryu, Ji-Yong;Chang, Sei-Hun
    • Journal of the Korean Chemical Society
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    • v.10 no.4
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    • pp.161-165
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    • 1966
  • The critical concentrations of ${\alpha}$-amino capric acid for micelle formation have been determined by the surface tension measurements in both acidic and alkaline solutions, and also by the dye titration using Rhodamine B in alkaline solutions. The critical micelle concentrations obtained by the two methods show the good agreements within experimental errors. Since ${\alpha}$-amino acid is an ampholyte, it may aggregate to form the micelles in both more acidic and basic media than its isoelectric point. It is found that the basic media are rather preferable for the micelle formation than the acidic media. The effect of gegen ions upon the critical concentration for micelle formation in alkaline media is similar to that expected from the salt effect on the CMC (Critical Micelle Concentration).

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Effects of Operation Parameters on Critical Flux During Submerged-Type Membrane Filtration System (침지형 분리막 여과공정에서 운전조건에 따른 임계플럭스에 대한 연구)

  • Kim, Jun-Sung;Ahn, Kyu-Hong
    • Journal of Korean Society of Water and Wastewater
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    • v.16 no.6
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    • pp.717-725
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    • 2002
  • A bench-scale submerged-type membrane filtration system (SMFS) was constructed to study a feasibility of membrane filtration for solid-liquid separation in water and wastewater treatment processes. In the case of applying the SMFS to a biological wastewater treatment process, so-called membrane bioreactor, aeration underneath membrane modules is usually employed in order to provide oxygen demand for microbial growth as well as to control membrane fouling. A study was investigated the effects of operation parameters by aeration intensity, feed concentration, foulant type and airlift pore size on critical flux. Critical flux tends to increase with aeration rate. Optimal aeration flow rate was found to be 10 L/min/module. Feed concentration and foulant type has a significant effect on membrane fouling and filtration performance. But downward position and pore size of airlift has no a significant effects on membrane fouling and filtration performance.

Thermodynamic Parameters for Micelle Formation of Dodecylpyridinium Chloride (Dodecylpyridinium Chloride의 micelle 形成의 熱力學變數)

  • Han, Man-Un
    • Journal of the Korean Chemical Society
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    • v.10 no.2
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    • pp.103-108
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    • 1966
  • The effect of temperature on the critical micelle concentration of dodecylpyridinium chloride has been determined by electrical conductance method over the range from $5^{\circ}C\;to\;50^{\circ}C$. The values of the change in heat content, ${\Delta}H_m$, and the other thermodynamic parameters have been estimated using the equation of temperature dependence on the critical micelle concentration for the same temperature range. The significance of these thermodynamic quantities and their relations to the various current theories of micelle forming processes were discussed.

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The Effect of Temperature on the Critical Micelle Concentration of Hexadecyl Trimethyl Ammonium Bromide (界面活性劑 Hexadecyl Trimethyl Ammonium Bromide의 C. M. C. 의 溫度效果)

  • Kun Moo Lee
    • Journal of the Korean Chemical Society
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    • v.13 no.1
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    • pp.1-4
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    • 1969
  • Temperature effect on the critical micelle concentration of hexadecyl trimetyl ammonium bromide over the range of $2^{\circ}-50^{\circ}C$ has been investigated by the method of electrical conductivity. The values obtained have been formulated as a power series in T. Several thermodynamic parameters have been calculated for the temparature range examined and their values have been discussed in the light of current theories on the participation of solvent in micelle formation.

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POSITIVE SOLUTION AND GROUND STATE SOLUTION FOR A KIRCHHOFF TYPE EQUATION WITH CRITICAL GROWTH

  • Chen, Caixia;Qian, Aixia
    • Bulletin of the Korean Mathematical Society
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    • v.59 no.4
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    • pp.961-977
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    • 2022
  • In this paper, we consider the following Kirchhoff type equation on the whole space $$\{-(a+b{\displaystyle\smashmargin{2}{\int\nolimits_{{\mathbb{R}}^3}}}\;{\mid}{\nabla}u{\mid}^2dx){\Delta}u=u^5+{\lambda}k(x)g(u),\;x{\in}{\mathbb{R}}^3,\\u{\in}{\mathcal{D}}^{1,2}({\mathbb{R}}^3),$$ where λ > 0 is a real number and k, g satisfy some conditions. We mainly investigate the existence of ground state solution via variational method and concentration-compactness principle.

Studies on the Viscoelasticities of Acetal Type Nonionic Surfactants (아세탈형(型) 비(非)이온성(性) 계면활성제(界面活性劑)의 점탄성(粘彈性)에 관한 연구(硏究))

  • Shon, Joo-Hwan;Lee, Seung-Youl;Nam, Ki-Dae;Kim, Yu-Bae
    • Journal of the Korean Applied Science and Technology
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    • v.5 no.1
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    • pp.53-62
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    • 1988
  • Properties of aqueous solution, that is, the viscosities and solubilities of benzene were observed in relation to critical micelle concentration of each alkyl aldehyde polyoxyethylene glycol acetal type surfactant. These showed that the mininum points in specific viscosity/concentration-concentration curves were corresponded with the critical micelle concentration obtained by surface tension and appeared the remarkable increase of non-Newtonics according to the increase of the number of carbon in hydrophobic groups. The fluidity of non-Newtonics is not observed by a little increase of the degree of polymerization in polyoxyethylene glycol groups.

Structural Characterization of Silk Fiber Treated with Calcium Nitrate (질산칼슘 처리 농도에 따른 수축견사의 구조특성)

  • 이광길;이용우
    • Journal of Sericultural and Entomological Science
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    • v.39 no.2
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    • pp.186-196
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    • 1997
  • The IR crystallinity index of Calcium nitrate treated silk fiber decreased proportionally to the concentration of calcium nitrate. A partial change of conformation was observed in the concentration of over 46.4-47.6% changing from $\beta$-sheet or to random coil in the crystalline region. This is in coincidence with the result of crystallinity index, which was started to be reduced in the concentration range of 46.4-47.6%. A same trend was observed for the X-ray order factor, birefringence, degree of orientation and surface structure. These structural parameters were remarkably changed on the treatment of silk fibers with concentration of 46.4-17, 6% calcium nitrate. Therefore, it seems that there exists a critical concentration of calcium nitrate in affection the structure and morphology of silk fibers. According to the examination of surface morphology, the fine stripe was observed in the direction of fiber axis at 46.4% concentration. However, the treated concentration was exceeded by 47.6%, the cracks were appeared severely on the fiber surface in the transverse direction as well as fiber axis direction. This result might be related to the tensile properties, specially a tenacity of silk fibers. As a result of quantitative analysis of a dilute acid hydrolysis, three different regions, which are known as a amorphous, semi-crystalline and crystalline region, could be obtained. The hydrolysis rate curves were different with various concentrations of treatment and the relative contents of each region could be calculated.

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The Effects of the Surfactant Type on the Nanofluids Stability (계면활성제 특성에 따른 나노입자 분산안정도 향상 연구)

  • Kang, Chi-Hoon;Hong, Sung-Wook;Kang, Yong-Tae;Koo, June-Mo
    • Proceedings of the SAREK Conference
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    • 2008.11a
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    • pp.275-280
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    • 2008
  • The effects of the surfactant type, i.e., CTAB(cationic), SDS(anionic), and GA(polymeric), on the stability of 0.1 vol.% $Al_2O_3$ nanofluids were investigated. The changes in size and zeta potential of nanoparticles in nanofluids with pH, surfactant concentration, and time were experimentally observed. The nanofluids adding CTAB, which ionizes of the same charge with the bare particle surface, was found to have the best stability regardless of the surfactant concentration, whereas those with SDS became unstable under low surfactant concentration conditions, i.e. lower than the critical micellel concentration(CMC), before the charge reversal occurred. With higher SDS concentration over CMC, they became stable. Gum Arabic, which had been used often to stabilize the nanofluids, was also tested. In result, it was found that the type and concentration of surfactants to add should be selected considering pH and the sign of the bare particle surface charge.

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Synthesis and Properties of Anionic Sulfonate Surfactants Using Fatty Alcohol (Fatty alcohol을 이용한 음이온 술폰산계 계면활성제의 합성 및 물성)

  • Cho, Jung-Eun;Shin, Hye-Lin;Jeong, Noh-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.3
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    • pp.579-586
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    • 2018
  • In this study, surfactants were synthesized using fatty alcohols of 8, 10, 12 and 14 carbon chains length. The structures of the synthesized surfactants was confirmed by FT-IR and $^1H$-NMR analysis. The surface tension of the diluted surfactant was measured as 26~32 mN/m depending on the carbon length and the critical micelle concentration was measured as $10^{-3}{\sim}10^{-5}mol/L$.The minimum value per molecule of the synthesized sulfonic acid surfactant is 1.68 to $1.30nm^2$. The physical properties of the synthesized surfactants were determined by measuring the critical micelle concentration, foaming power, emulsifying stability, and contact angle.