• Title/Summary/Keyword: crack separation

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Development of Ceramic Composite Membranes for Gas Separation: V. Synthesis of Nanoparticulate Silica Membranes by the Pressurized Sol-Gel Coating Technique (기체분리용 세라믹 복합분리막의 개발 : V. 가압 졸-겔 코팅법에 의한 rrmaltp입자 실리카 막의 합성)

  • 현상훈;윤성필;김준학
    • Journal of the Korean Ceramic Society
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    • v.30 no.3
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    • pp.189-198
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    • 1993
  • A new pressurized sol-gel coating technique forming membrane layers inside pores of the porous support by the simple operation has been developed. Crack-free and reproducible nanoparticulate silica membranes supported on the porous $\alpha$-alumina tube are synthesized by pressurized coating at 600kPa for 2hr. The pore radius and N2 gas permiability at the room temperature of silica membrane layers are 8$\AA$ and 7.0$\times$10-7mol/$m^2$.s.Pa, respectively. The mechanism of N2 gas transfer through synthesized membrane layers is the perfect Knudeen flow, and the thermal stability of the silica composite membranes is excellent upto 40$0^{\circ}C$.

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Development of Ceramic Composite Membranes for Gas Separation: II. Preparation and Coating Characteristics of Nanoparticulate $TiO_2$ Sols (기체분리용 세라믹 복합분리막의 개발: II. 극미세 입자 $TiO_2$ 졸의 제조 및 코팅 특성)

  • 현상훈;박준수;최세영
    • Journal of the Korean Ceramic Society
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    • v.29 no.9
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    • pp.739-749
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    • 1992
  • The sols prepared by dialyzing solutions, in which the hydrolyzed precipitates of TEOT or directly Ti(OC3H7)4 were resolved, were the nanoparticulate sol with the average particle size less than 7 nm and the anatase crystal phase. In the pH range of 1.5 to 2.9, the particle size of the nanoparticulate TiO2 sols (0.09 mol/ι) increased gradually upto 15 nm~26nm with the increase of pH in the initial aging state but the sols were transparent all the time, and stable without growin any more after 30 days. When the slipcasted porous alumina tubes were coated by the sol-gel dipping method, the minimum particle size and the aging time for forming the coated gel layer at the given pH were optimized. For obtaining the very thin crack-free and reproducible membrane coating, the use of a nanoparticulate TiO2 sol (0.09 mol/ι) aged for about 30 dyas at pH=2.0 was found to be the best.

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A Study on the Engineering Properties of Concrete according to Water Content (단위수량 변화에 따른 콘크리트의 공학적 특성에 관한 연구)

  • 이병상;김기정;양경석;심영태;정용희;한천구
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.27-30
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    • 2003
  • This study is investigated the various properties and drying shrinkage of concrete according to water content under the condition proper fluidity is adjusted, in order to suggest the method for reduction of crack by drying shrinkage. According to the results, though water content varies, slump and air content are satisfied to the planed values, but shear slump and separation happen at water content of 120 and 140kg/$m^3$ due to the overuse of superplasticizer(SP). As water content is diminished, setting time is retarded by an increase of the using amount of SP, and compressive and tensile strength increase in the range of 160-180kg/㎥ of water content, but decrease significantly at 120 and 140kg/$m^3$. Length change by drying shrinkage decrease with a decrease of water content. Therefore, considering not only drying shrinkage but also fluidity, setting time and strength, it proves that the most appropriate water content of concrete is 160kg/$m^3$ in the condition of this experiment.

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Adhesion Characteristics of Surface Treated Polyurethane Foam Core Sandwich Structures (표면 처리된 폴리우레탄 폼 샌드위치 구조의 접합 특성)

  • Lee, Chang-Sup;Lim, Tae-Seong;Lee, Dai-Gil
    • Proceedings of the KSME Conference
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    • 2001.11a
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    • pp.38-43
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    • 2001
  • The interfacial adhesive joining characteristics of the foams are very important for the structural integrity of sandwich structures. Peel strength is one of the best criteria for the interfacial characteristics of the sandwich structures and peel energy is most commonly used for the interfacial characteristics. The peel strength is the first peak force per unit width of bond line required to produce progressive separation by the wedge or other crack opening type action of two adherends where one or both undergo significant bending and the peel energy is the surface active energy per unit width of bond line. In this work, to investigate the strengthening effect of resin treatment on the interfacial surface of foam material, peel strength and peel energy of epoxy resin treated polyurethane foam core sandwich structures were obtained by the cleavage peel tests and compared with those of non surface treated polyurethane foam core sandwich structures.

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Fatigue Properties of Friction Weld According to the Location of Small Artificial Defect (미소인공결함의 위치에 따른 마찰용접부의 피로특성)

  • 이상열;정재강
    • Journal of Welding and Joining
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    • v.19 no.6
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    • pp.608-613
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    • 2001
  • In this study, the rotary bending fatigue test was carried out with two kinds of base metal, martensite stainless steel STR3 and austenite stainless steel STR35 and the dissimilar friction welded material with them. To compare the fatigue fifes according to the notch positions, the small circular defect was worked on the bonded line, 1.0mm and 0.5mm distance form the bonded line. The fatigue limits of the STR3 and STR35 base metal were 429.0MPa and 409.4MPa respectably. In comparison with fatigue life at the same notch positions, the STR35 specimens showed about 190% for base metal, 82% for 1.0mm distance notched specimens higher than that of the STR3. But the fatigue life of the 0.5mm distance notched STR35 specimen showed about 35% lower than that of the STR3 specimen. And the bonded line notched specimen was much lower fatigue life than the other specimens because of separation of the bonded line.

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Computational modeling of cracking of concrete in strong discontinuity settings

  • Oliver, J.;Huespe, A.;Pulido, M.D.G.;Blanco, S.
    • Computers and Concrete
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    • v.1 no.1
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    • pp.61-76
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    • 2004
  • The paper is devoted to present the Continuum Strong Discontinuity Approach (CSDA) and to examine its capabilities for modeling cracking of concrete. After introducing the main ingredients of the CSDA, an isotropic continuum damage model, which distinguishes tension and compression states, is used to implicitly induce a projected traction separation-law that rules the cracking phenomena. Criteria for onset and propagation of material failure and specific finite elements with embedded discontinuities are also briefly sketched. Finally, some representative numerical simulations of cracking, in plain and reinforced concrete specimens, using the CSDA are presented.

Interfacial shear resistance of angle shear connectors welded to concrete filled U-shaped CFS beam

  • Oh, Hyoung Seok;Shin, Hyeongyeop;Ju, Youngkyu;Kang, Thomas H.K.
    • Steel and Composite Structures
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    • v.43 no.3
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    • pp.311-325
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    • 2022
  • For multi-story structural systems, Korean steel industry has fostered development of a steel-concrete composite beam. Configuration of the composite beam is characterized by steel angle shear connectors welded to a U-shaped cold formed-steel beam. Effects of shear connector orientation and spacing were studied to evaluate current application of the angle shear connector design equation in AC495. For the study, interfacial shear resistance behavior was investigated by conducting 24 push-out tests and attuned using unreinforced push-out specimens. Interfacial shear to horizontal slip response was reported along with corresponding failure patterns. Pure shear connector strength was also evaluated by excluding concrete shear contribution, which was estimated in relation to steel beam-slab interface separation or interfacial crack width.

Numerical Modeling of Hydrogen Embrittlement-induced Ductile Fracture Using a Gurson-Cohesive Model (GCM) and Hydrogen Diffusion (Gurson-Cohesive Model(GCM)과 수소 확산 모델을 결합한 수소 취화 파괴 해석 기법)

  • Jihyuk Park;Nam-Su Huh;Kyoungsoo Park
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.37 no.4
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    • pp.267-274
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    • 2024
  • Hydrogen embrittlement fracture poses a challenge in ensuring the structural integrity of materials exposed to hydrogen-rich environments. This study advances our comprehension of hydrogen-induced fracture through an integrated numerical modeling approach. In addition, it employs a ductile fracture model named the Gurson-cohesive model (GCM) and hydrogen diffusion analysis. GCM is employed as a fracture model that combines the Gurson model to illustrate the continuum damage evolution and the cohesive zone model to describe crack surface discontinuity and softening behavior. Moreover, porosity and stress triaxiality are considered as crack initiation criteria . A hydrogen diffusion analysis is also integrated with the GCM to account for hydrogen enhanced decohesion (HEDE) mechanisms and their subsequent impacts on crack initiation and propagation. This framework considers the influence of hydrogen on the softening behavior of the traction-separation relationship on the discontinuous crack surface. Parametric studies explore the sensitivity to diffusion properties and hydrogen-induced fracture properties. By combining numerical models of hydrogen diffusion and the ductile fracture model, this study provides an understanding of hydrogen-induced fracture and thereby contributes significantly to the ongoing efforts to design materials that are resilient to hydrogen embrittlement in practical engineering applications.

Secondary Growth of Sodium Type Faujasite Zeolite Layers on a Porous $\alpha-Al_2O_3$ Tube and the $CO_2/N_2$ Separation (Na형 Faujasite 제올라이트 분리막 형성 및 $CO_2/N_2$ 분리)

  • Cho, Churl-Hee;Yeo, Jeong-Gu;Ahn, Young-Soo;Han, Moon-Hee;Kim, Yong-Ha;Hyun, Sang-Hoon
    • Membrane Journal
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    • v.17 no.3
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    • pp.254-268
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    • 2007
  • Sodium type faujasite(FAU) zeolite layers with diverse materials characteristics(Si/Al ratio, thickness, and structural discontinuity) were hydrothermally grown on a porous $\alpha-Al_2O_3$ tube, and then the $CO_2/N_2$ separation was evaluated at $30^{\circ}C$ for an equimolar mixture of $CO_2$ and $N_2$. Among hydrothermal conditions, $SiO_2$ content in hydrothermal solution seriously affected materials characteristics: with an increment in the $SiO_2$ content, Si/Al ratio, thickness, and structural discontinuity of grown FAU zeolite layer simultaneously increased. The present study reveals that structural discontinuity(intercrystalline voids due to an incomplete densification and cracks induced by GIS Na-P1 phase) is the most important variable affecting the $CO_2/N_2$ separation. Also, it was suggested that the $CO_2$ desorption in permeate side be the rate-determining(slowest) step in the overall $CO_2$ permeation.

Evaluation on Flexural Performance of Steel Plate Reinforced GLT Beams (강판 보강 집성재 보의 휨성능 평가 연구)

  • Park, Keum-Sung;Lee, Sang-Sup;Kwak, Myong-Keun
    • Journal of Korean Association for Spatial Structures
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    • v.20 no.2
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    • pp.39-49
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    • 2020
  • In this study, we will develop a hybrid cross-sectional shape of steel inserted type glued-laminated timber that can improve the strength of structural glued-laminated timber and maximize the ductility by using steel plate with excellent tensile and deformation ability. A total of three specimens were fabricated and the flexural performance test was carried out to evaluate the structural performance of the steel inserted type glued-laminated timber. In order to compare the effect of steel inserted glued-laminated timber, one structural glued-laminated timber test specimen composed of pure wood was manufactured. In addition, in order to evaluate the adhesion performance of the steel inserted, one each of a screw joint test specimen and a polyurethane joint test specimen was prepared. As a result, all the specimens showed the initial crack in the finger joint near the force point. This has been shown to be a cause of crack diffusion and strength degradation. The use of finger joints in the maximum moment section is considered to affect the strength and ductility of the glued-laminated timber beam. Polyurethane-adhesive steel inserted glued-laminated timber showed fully-composite behavior with little horizontal separation between the steel plate and glued-laminated timber until the maximum load was reached. This method has been shown to exhibit sufficient retention bending performance.