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CONCENTRATION DEPENDENCES OF GROUND-STATE AND EXCITED-STATE INTRAMOLECULAR PROTON TRANSFER OF PIROXICAM IN METHANOL

  • Cho, Dae-Won;Kang, Seong-Gwan;Kim, Yong-Hee;Yoon, Min-Joong;Kim, Dong-Ho
    • Journal of Photoscience
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    • v.1 no.1
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    • pp.15-23
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    • 1994
  • The absorption and fluorescence spectral properties of piroxicam (PRX) in the hydrogenbonding solvents show the most sensitive dependence on the concentration ranging from 8 x 10$^{_5}$ to 2 x10$^{_5}$ M. These are attributed to both the solvent-mediated ground-state intermolecular proton transfer (GSIerPT) leading to formation of the ground state anion and the excited-state intmmolecular proton transfer (ESIraPT). The concentration dependences of the time-resolved emission kinetics at both room temperature and 77 K have also been investigated. It is shown that in the excited state, the ESIraPT of PRX is the dominant process to form a keto tautomer at the high concentration, whereas at the low concentration the excited-state conformational change of the anion is an additional process leading to formation of a zwitterion. The ESI~PT of PRX in the hydrogenbonding solvent is coupled with the ultrafast excited-state solvent reorganization.

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Numerical studies on shear connectors in push-out tests under elevated temperatures

  • Wang, Aaron J.
    • Structural Engineering and Mechanics
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    • v.39 no.3
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    • pp.317-338
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    • 2011
  • Three-dimensional thermal and mechanical coupled finite element models are proposed to study the structural behaviours of shear connectors under fire. Concrete slabs, steel beams and shear connectors are modelled with eight-noded solid elements, and profiled steel deckings are modelled with eight-noded shell elements. Thermal, mechanical and geometrical nonlinearities are incorporated into the models. With the proper incorporation of thermal and mechanical contacts among steel beams, shear connectors, steel deckings and concrete slabs, both of the models are verified to be accurate after the validation against a series of push-out tests in the room temperature or under the standard fire. Various thermal and mechanical responses are also extracted and observed in details from the results of the numerical analyses, which gives a better understanding of the structural behavior of shear connectors under elevated temperatures.

A Application Method of Engine-Generator Power System in Ambulance (긴급 구난차량의 발전시스템에 관한 연구)

  • Jung, Won-Seok;Lee, Bong-Seok;Sim, Han-Sub
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.11 no.3
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    • pp.187-192
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    • 2012
  • Recently, the electric device has been launching owing to the development of industry. That development also can maximize the efficiency of generator. The emergency rescue vehicle operation differs from ordinary vehicles in engine life and usage distances. For the application of this system, this research proposes the ways to operate the emergency rescue vehicle operations more efficiently. Currently, many power systems, especially motors, developed with a large output of power. It is possible to produce electricity in the engine room with enough space and to operate all equipment within the rating load capacity.

Study on Non-uniform Thermal Comfort in Hybrid Air-Conditioning System with CFD Analysis (CFD 해석을 통한 하이브리드 공조시스템의 인체 온열감의 불균일성에 관한 연구)

  • Nam, Yu-Jin;Sung, Min-Ki;Song, Doo-Sam
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.23 no.3
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    • pp.216-222
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    • 2011
  • Recently, hybrid air-conditioning system has been proposed and applied to achieve building energy saving. One example is a system combining radiation panel with natural wind-induced cross-ventilation. However, few research works have been conducted on the non-uniformity of thermal comfort in such hybrid air-conditioning system. In this paper, both thermal environment and non-uniform thermal comfort of human thermal model under various air-conditioning system, including hybrid system, were evaluated in a typical office room using coupled simulation of computation fluid dynamics, radiation model and a human thermal model. The non-uniformity of thermal comfort was evaluated from the deviation of surface temperature of human thermal model. Flow fields and temperature distribution in each case were represented.

A Design of the Diplexer for Satellite Transponder using Waveguide E-plane Discontinuities (도파관 전계면 불연속 구조를 이용한 위성 중계기용 다이플렉서의 설계)

  • 최상윤;강우정;이상웅;최성진;라극환
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.30A no.4
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    • pp.1-10
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    • 1993
  • This paper presents the designing/manufacturing scheme of the diplexer for satellite transponder which is composed of 2-channel bandpass filters, coupled with E-plane T-junction, having symmetrical waveguide E-plane step discontinuity structures. The 2-channel bandpass filters of the diplexer are designed by the scheme of connecting ${\lambda}_{g}$/2 shunt stub to the waveguide E-plane, playing the role of heat sinks without attaching a special heat sinks and to give the profitable productivity and allow the low-cost manufacturing at mass production, tuning screws are eliminated which have been used to compensate the operating characteristics of manufactured filters. The 2 channel bandpass filters of manufactured 14/12 GHz diplexer for domestic Ku-band satellite transponder have the return loss of 25 dB, insertion loss of 0.3 dB in passband, and below-50 dB of stopband characteristics (T$_{x}$ : f$_{o}{\pm}$250 MHz, R$_{x}$ : f$_{o}{\pm}$220 MHz) at room temperature.

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Simulation and Modelling of the Write/Erase Kinetics and the Retention Time of Single Electron Memory at Room Temperature

  • Boubaker, Aimen;Sghaier, Nabil;Souifi, Abdelkader;Kalboussi, Adel
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.10 no.2
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    • pp.143-151
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    • 2010
  • In this work, we propose a single electron memory 'SEM' design which consist of two key blocs: A memory bloc, with a voltage source $V_{Mem}$, a pure capacitor connected to a tunnel junction through a metallic memory node coupled to the second bloc which is a Single Electron Transistor "SET" through a coupling capacitance. The "SET" detects the potential variation of the memory node by the injection of electrons one by one in which the drainsource current is presented during the memory charge and discharge phases. We verify the design of the SET/SEM cell by the SIMON tool. Finally, we have developed a MAPLE code to predict the retention time and nonvolatility of various SEM structures with a wide operating temperature range.

Nature of the Interfacial Regions in the Antiferromagnetically-coupled Fe/Si Multilayered Films

  • Moon, J.C.;Y.V. Kudryavtsev;J.Y.Rhee;Kim, K.W.;Lee, Y.P.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.174-174
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    • 2000
  • A strong antiferromagnetic coupling in Fe/Si multilayered films (MLF) had been recently discovered and much consideration has been given to whether the coupling in the Fe/Si MLF system has the same origin as the metal/metal MLF. Nevertheless, the nature of the interfacial ron silicide is still controversial. On one hand, a metal/ semiconductor structure was suggested with a narrow band-gap semiconducting $\varepsilon$-FeSi spacer that mediates the coupling. However, some features show that the nature of coupling can be well understood in terms of the conventional metal/metal multilayered system. It is well known that both magneto-optical (MO) and optical properties of a metal depend strongly on their electronic structure that is also correlated with the atomic and chemical ordering. In this study, the nature of the interfacial regions is the Fe/Si multilayers has been investigated by the experimental and computer-simulated MO and optical spectroscopies. The Fe/Si MLF were prepared by rf-sputtering onto glass substrates at room temperature with the number of repetition N=50. The thickness of Fe sublayer was fixed at 3.0nm while the Si sublayer thickness was varied from 1.0 to 2.0 nm. The topmost layer of all the Fe/Si MLF is Fe. In order to carry out the computer simulations, the information on the MO and optical parameters of the materials that may constitute a real multilayered structure should be known in advance. For this purpose, we also prepared Fe, Si, FeSi2 and FeSi samples. The structural characterization of Fe/Si MLF was performed by low- and high -angle x-ray diffraction with a Cu-K$\alpha$ radiation and by transmission electron microscopy. A bulk $\varepsilon$-FeSi was also investigated. The MO and optical properties were measured at room temperature in the 1.0-4.7 eV energy range. The theoretical simulations of MO and optical properties for the Fe/Si MLF were performed by solving exactly a multireflection problem using the scattering matrix approach assuming various stoichiometries of a nonmagnetic spacer separating the antiferromagnetically coupled Fe layers. The simulated spectra of a model structure of FeSi2 or $\varepsilon$-FeSi as the spacer turned out to fail in explaining the experimental spectra of the Fe/Si MLF in both intensity and shape. Thus, the decisive disagreement between experimental and simulated MO and optical properties ruled out the hypothesis of FeSi2 and $\varepsilon$-FeSi as the nonmagnetic spacer. By supposing the spontaneous formation of a metallic ζ-FeSi, a reasonable agreement between experimental and simulated MO and optical spectra was obtained.

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Analysis of Acoustic Radiation Efficiency and Underwater Radiated Noise of Double Bottom-shaped Structure (이중저 형상 구조물의 음향방사효율과 수중방사소음 해석)

  • Choi, Sung-Won;Kim, Kook-Hyun;Cho, Dae-Seung;Suh, Kyu-Youl
    • Journal of the Society of Naval Architects of Korea
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    • v.49 no.2
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    • pp.158-163
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    • 2012
  • Recently, reducing underwater radiated noise (URN) of ships has become an environmental issue to protect marine wildlife. URN of ships can be predicted by various methods considering its generating mechanism and frequency ranges. For URN prediction due to ship structural vibration in low frequency range, the fluid-structure interaction analysis technique based on finite element and boundary element methods (FE/BEM) is regarded as an useful technique. In this paper, URN due to a double bottom-shaped structure vibration has been numerically investigated based on a coupled method of FE/BEM to enhance the prediction accuracy of URN due to the vibration of real ship engine room structure. Acoustic radiation efficiency and URN transfer function in case of vertical harmonic excitation on the top plate of double bottom structure have been evaluated. Using the results, the validity of an existing empirical formula for acoustic radiation efficiency estimation and a simple URN transfer function, which are usually adopted for URN assessment in initial design stage, is discussed.

Interfacial Properties of Antiferromagnetically-coupled Fe/Si Multilayeres Films

  • Kim, K.W.;Y.V.Kudryavtsev;J.Y.Rhee;J.Dubowik;Lee, Y.P.
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.168-168
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    • 1999
  • Recently, Fe/Si multilayered films (MLF) have been a focus of interest due to the strong antiferromagnetic (AF) coupling observed in such kind of MLF originates from the same nature as in the metal/metal MLF. In particular, a question of whether the spacer layer in the Fe/Si MLF is metallic or semiconducting is of interest. In spite of various experimental techniques envolved in the study, the chemical composition and the properties of the interfacial regions in the MLF exhibiting the AF coupling is still questionable. The nature of the AF coupling and the interfacial properties of Fe/Si MLF are investigated in this study. A series of Fe/Si MLF with a fixed nominal thickness of Fe(3nm) and a variable thickness of Sk(1.0-2.2nm) were deposited by RF-sputtering onto glass substrates at room temperature. The atomic structures and the actual sublayer thicknesses of the Fe/Si MLF are investigated by using x-ray diffraction. The magnetic-field dependence of the equatorial Kerr effect clearly shows an appearance of the AF coupling between Fe sublayers at tsi = 1.5 - 1.8 nm. the drastic discrepancies between the experimental magnetooptical (MO) and optical properties, and based on the assumption of sharp interfaces between Fe and Si sublayers leads to a conclusion that pure si is absent in the AF-coupled Fe/Si MLF. Introducing in the model nonmagnetic semiconducting FeSi alloy layers between Fe and Si sublayers or as spacer between pure Fe sublayers only slightly improves the agreement between model and experiment. A reasonable agreement between experimental and simulated MO spectra was reached with using the fitted optical properties for the spacer with a typical metallic type of behavior. The results of the magnetic properties measured by vibrating sample magnetometer and magnetic circular dichroism are also analyzed in connection with the MO and optical properties.

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Performance and analysis of wireless power charging system from room temperature to HTS magnet via strong resonance coupling method

  • Chung, Y.D.;Lee, C.Y.;Lee, S.Y.;Lee, T.W.;Kim, J.S.
    • Progress in Superconductivity and Cryogenics
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    • v.18 no.1
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    • pp.41-45
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    • 2016
  • The technology of supplying the electric power by wireless power transfer (WPT) is expected for the next generation power feeding system since it can supply the power to portable devices without any connectors through large air gap. As such a technology based on strongly coupled electromagnetic resonators is possible to deliver the large power and recharge them seamlessly; it has been considered as a noble option to wireless power charging system in the various power applications. Recently, various HTS wires have now been manufactured for demonstrations of transmission cables, motors, MAGLEV, and other electrical power components. However, since the HTS magnets have a lower index n value intrinsically, they are required to be charged from external power system through leads or internal power system. The portable area is limited as well as the cryogen system is bulkier. Thus, we proposed a novel design of wireless power charging system for superconducting HTS magnet (WPC4SM) based on resonance coupling method. As the novel system makes possible a wireless power charging using copper resonance coupled coils, it enables to portable charging conveniently in the superconducting applications. This paper presented the conceptual design and operating characteristics of WPC4SM using different shapes' copper resonance coil. The proposed system consists of four components; RF generator of 370 kHz, copper resonance coupling coils, impedance matching (IM) subsystem and HTS magnet including rectifier system.