• Bulletin of the Korean Chemical Society
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• v.33 no.5
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• pp.1653-1658
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• 2012

A new anthracene-containing conjugated molecule was synthesized through the Sonogashira coupling and reduction reactions. 1-Ethynyl-4-hexylbenzene was coupled to 2,6-bis((4-hexylphenyl) ethynyl)anthracene-9,10-dione through a reduction reaction to generate 2,6,9,10-tetrakis((4-hexylphenyl)ethynyl) anthracene. The semiconducting properties were evaluated in an organic thin film transistor (OTFT) and a single-crystal field-effect transistor (SC-FET). The OTFT showed a mobility of around 0.13 $cm^2\;V^{-1}\;s^{-1}$ ($I_{ON}/I_{OFF}$ > $10^6$), whereas the SC-FET showed a mobility of 1.00-1.35 $cm^2\;V^{-1}\;s^{-1}$, which is much higher than that of the OTFT. Owing to the high photoluminescence quantum yield of 2,6,9,10-tetrakis((4-hexylphenyl)ethynyl) anthracene, we could observe a significant increase in drain current under irradiation with visible light (${\lambda}$ = 538 nm, 12.5 ${\mu}W/cm^2$).

• Korean Chemical Engineering Research
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• v.53 no.5
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• pp.638-645
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• 2015

Vanadium redox flow batteries (VRFBs) have been investigated for their potential utility as large energy storage systems due to their advantageous performances in terms of long cycle life, high energy efficiency, low cost, and flexible design. Carbon materials are typically used as electrodes in redox reactions and as a liquid electrolyte support. The activities, surface areas, and surface morphologies of porous carbon materials must be optimized to increase the redox flow battery performance. Here, to reduce the resistance in VRFBs, surface-modified carbon felt electrodes were fabricated, and their structural, morphological, and chemical properties were characterized. The surface-modified carbon felt electrode improved the cycling energy efficiencies in the VRFBs, from 65% to 73%, due to the improved wettability with electrolyte. From the results of impedances analysis with proposed fitting model, the electrolyte-coupled polarization in VRFB dramatically decreased upon modification of carbon felt electrode surface. It is also demonstrated that the compressibility of carbon felt electrodes was important to the VRFB polarization, which are concerned with mass transfer polarization. The impedance analysis will be helpful for obtaining better and longer-lived VRFB performances.

• Structural Engineering and Mechanics
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• v.73 no.3
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• pp.319-330
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• 2020

This paper investigates the free vibrations of cylindrical shells made of time-dependent materials for different viscoelastic models under various boundary conditions. During the extraction of equations, the displacement field is estimated through the first-order shear deformation theory taking into account the transverse normal strain effect. The constitutive equations follow Hooke's Law, and the kinematic relations are linear. The assumption of axisymmetric is included in the problem. The governing equations of thick viscoelastic cylindrical shell are determined for Maxwell, Kelvin-Voigt and the first and second types of Zener's models based on Hamilton's principle. The motion equations involve four coupled partial differential equations and an analytical method based on the elementary theory of differential equations is used for its solution. Relying on the results, the natural frequencies and mode shapes of viscoelastic shells are identified. Conducting a parametric study, we examine the effects of geometric and mechanical properties and boundary conditions, as well as the effect of transverse normal strain on natural frequencies. The results in this paper are compared against the results obtained from the finite elements analysis. The results suggest that solutions achieved from the two methods are ideally consistent in a special range.

• Journal of the Korean Institute of Telematics and Electronics
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• v.14 no.1
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• pp.15-22
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• 1977

We have obtained a violet-sensitive photocell as a part of the developing project on such type of solar cell. The photocell has the structure of SnO2-SiO2-Si MOS coupled on Si n-p homojuction. It is not relevant to use as a solar cell because of its small photovoltaic power(0.25V, 150$mutextrm{A}$), however, since the spectral response of the cell is shifted toward the violet band region and its switching speed is fairly high in comparison with those of the Si p-n homojunction type solar cell, it is expected that we will be able to find mere novel utilities than the ordinary silicon photocell.

• Coupled systems mechanics
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• v.5 no.3
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• pp.269-283
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• 2016

A two new high-order shear deformation theory for bending analysis is presented for a simply supported, functionally graded plate with porosities resting on an elastic foundation. This porosities may possibly occur inside the functionally graded materials (FGMs) during their fabrication, while material properties varying to a simple power-law distribution along the thickness direction. Unlike other theories, there are only four unknown functions involved, as compared to five in other shear deformation theories. The theories presented are variationally consistent and strongly similar to the classical plate theory in many aspects. It does not require the shear correction factor, and gives rise to the transverse shear stress variation so that the transverse shear stresses vary parabolically across the thickness to satisfy free surface conditions for the shear stress. It is established that the volume fraction of porosity significantly affect the mechanical behavior of thick function ally graded plates. The validity of the two new theories is shown by comparing the present results with other higher-order theories. The influence of material parameter, the volume fraction of porosity and the thickness ratio on the behavior mechanical P-FGM plate are represented by numerical examples.

• Journal of Korean Society for Atmospheric Environment
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• v.20 no.5
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• pp.663-670
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• 2004

The catalytic oxidation of benzene, toluene and xylene over a spent industrial catalyst (Pd-based) was investigated in a fixed bed flow reactor system. According to the priming condition, the properties of a spent Pd-based catalyst were characterized by XRD(X-ray diffraction). BET(Brunauer-Emmett-Teller) and ICP(Inductively coupled plasma). When air was used as a primer, optimum priming temperature was found to be 200$^{\circ}C$, and the catalytic activity decreased as the priming temperature increased. When a spent Pd-based catalyst primed with air at 200$^{\circ}C$ was re-treated with hydrogen at 200$^{\circ}C$, 300$^{\circ}C$ or 400$^{\circ}C$, respectively, the catalytic activity increased and thermal effect were negligible. $HNO_3$ aqueous solution priming resulted in slight decrease of the catalytic activity, with little effects on $HNO_3$ concentrations. The activity of a spent Pd-based catalyst with respect to VOC molecule was observed to follow sequence: xylene> toluene> benzene. Benzene. toluene and xylene could be removed to almost 100% by a spent Pd-based catalyst primed with hydrogen.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• v.y2005m4
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• pp.183-188
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• 2005

This study targets to investigate thermal wave transfer in a droplet strongly coupled with acoustic pressure and its effects on combustion response. The one-dimensional vaporization model uses SRK equation of state and flash calculation method to obtain more accurate thermophysical properties and compute vapor-liquid equilibrium. Calculations of an n-pentane droplet exposed into a perturbing nitrogen gas is carried out in terms of different ambient gas pressures and wave frequencies. The thermal wave is transferred more effectively at lower frequencies, which results in the decrease in the amplitude of the response.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2009.06a
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• pp.126-126
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• 2009

Noninvasive plasma diagnostic technique is introduced to analyze and characterize HICP (Helmholtz Inductively Coupled Plasma) source during the plasma etching process. The HICP reactor generates plasma mainly through RF source power at 13.56MHz RF power and RF bias power of 12.56MHz is applied to the cathode to independently control ion density and ion energy. For noninvasive sensors, the RF sensor and the OES (Optical emission spectroscopy) were employed since it is possible to obtain both physical and chemical properties of the reactor with plasma etching. The plasma impedance and optical spectra were observed while altering process parameters such as pressure, gas flow, source and bias power during the poly silicon etching process. In this experiment, we have found that data measured from these noninvasive sensors can be correlated to etch results. In this paper, we discuss the relationship between process parameters and the measurement data from RF sensor and OES such as plasma impedance and optical spectra and using these relationships to analyze and characterize H-ICP source.

• Korean Journal of Optics and Photonics
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• v.8 no.4
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• pp.260-266
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• 1997

Holographic optical elements for polarization separation (HPS) are fabricated in a dichromated gelatin(DCG) thin film of 7${\mu}{\textrm}{m}$ thickness. The polarization properties of HPS is characterized by measuring diffraction efficiency with several physical parameters like exposure time, incident angle and read-out polarization angles. The experimental data are compared with theoretical results based on Kogelnik's coupled wave theory, which shows good agreement. It is also found that the HPS element has a very high extinction ratio of polarization over 500:1 for S and P polarizations, respectively, with He-Ne laser wavelength. We also propose an optical switch optical interconnects by using HPS elements.

• Journal of Ocean Engineering and Technology
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• v.31 no.6
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• pp.397-404
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• 2017

In this study, an anchor dragging simulation was performed using the CEL method to design a rock-berm, which is a protection method for submarine cables. In order to simulate an anchor drag, preliminary simulations were first performed to determine the initial anchor penetration depth, anchor drag velocity, drag angle, and distance between the anchor and rock-berm. Based on the preceding simulation results, a safe rock-berm design for protecting the submarine cables was simulated to calculate the anchor penetration depth by the anchor dragging. As a result, the penetration depth of the anchor was found to be shallower in a hard seabed, and the penetration depth was deeper in a soft seabed, the height of the rock-berm was determined according to the physical properties of the seabed.