• 열처리공학회지
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• 제36권3호
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• pp.153-160
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• 2023

The use of biogas is an industrially necessary means to achieve resource circulation. However, since biogas obtained from waste frequently causes corrosion in pipes, it is important to elucidate corrosion mechanisms of the pipes used for biogas transportation. Recently, corrosion failure occurred in a pipe which supplied for the biogas at the speed of 12.5 m/s. Pinholes and pits were found in a straight line along the seamline of the pipe. By using corrosion-damaged samples, residual thickness, microstructure, and composition of oxide film and inclusion were examined to analyze the cause of the failure. It was revealed that the thickness reduction of biogas pipe was ~0.11 mm per year. A thin sulfuric acid film was formed on the surface of the interior of a pipe due to moisture and hydrogen sulfide contained in a biogas. Near the seamline, microstructure was heterogeneous and manganese sulfide (MnS) was found. Pits were generated by micro-galvanic corrosion between the manganese sulfide and the matrix in the interior of the pipe along the seamline. In addition, microcracks formed along the grain boundaries beneath the pits revealed that hydrogen-induced cracking (HIC) also contributed to accelerating the pitting corrosion.

• Advances in concrete construction
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• 제6권6호
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• pp.645-658
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• 2018

Despite being one of the most abundantly used construction materials because of its exceptional properties, concrete is susceptible to deterioration and damage due to various factors particularly corrosion, improper loading, poor workmanship and design discrepancies, and as a result concrete structures require retrofitting and strengthening. In recent times, Fiber Reinforced Polymer (FRP) composites have substituted the conventional techniques of retrofitting and strengthening of damaged concrete. Most of the research studies related to concrete strengthening using FRP have been performed on undamaged test specimens. This contribution presents the results of an experimental study in which concrete specimens were damaged by mechanical loading and elevated temperature in laboratory prior to application of Carbon Fiber Reinforced Polymer (CFRP) sheets for strengthening. The test specimens prepared using concrete of target compressive strength of 28 MPa at 28 days were subjected to compressive and splitting tensile testing up to failure and the intact pieces of the failed specimens were collected for the purpose of repair. In order to induce damage as a result of elevated temperature, the concrete cylinders were subjected to $400^{\circ}C$ and $800^{\circ}C$ temperature for two hours duration. Concrete cylinders damaged under compressive and split tensile loads were re-cast using concrete and rich cement-sand mortar, respectively and then strengthened using CFRP wrap. Concrete cylinders damaged due to elevated temperature were also strengthened using CFRP wrap. Re-cast and strengthened concrete cylinders were tested in compression and splitting tension. The obtained results revealed that re-casting of specimens damaged by mechanical loadings using concrete & mortar, and then strengthened by single layer CFRP wrap exhibited strength even higher than their original values. In case of specimens damaged by elevated temperature, the results indicated that concrete strength is significantly dropped and strengthening using CFRP wrap made it possible to not only recover the lost strength but also resulted in concrete strength greater than the original value.

• Smart Structures and Systems
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• 제29권1호
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• pp.17-28
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• 2022

The cable component of cable-stayed bridges is gradually impacted by weather conditions, vehicle loads, and material corrosion. The stayed cable is a critical load-carrying part that closely affects the operational stability of a cable-stayed bridge. Damaged cables might lead to the bridge collapse due to their tension capacity reduction. Thus, it is necessary to develop structural health monitoring (SHM) techniques that accurately identify damaged cables. In this work, a combinational identification method of three efficient techniques, including statistical analysis, clustering, and neural network models, is proposed to detect the damaged cable in a cable-stayed bridge. The measured dataset from the bridge was initially preprocessed to remove the outlier channels. Then, the theory and application of each technique for damage detection were introduced. In general, the statistical approach extracts the parameters representing the damage within time series, and the clustering approach identifies the outliers from the data signals as damaged members, while the deep learning approach uses the nonlinear data dependencies in SHM for the training model. The performance of these approaches in classifying the damaged cable was assessed, and the combinational identification method was obtained using the voting ensemble. Finally, the combination method was compared with an existing outlier detection algorithm, support vector machines (SVM). The results demonstrate that the proposed method is robust and provides higher accuracy for the damaged cable detection in the cable-stayed bridge.

• 한국환경보건학회지
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• 제36권3호
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• pp.236-246
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• 2010

In preparative anti-corrosive coating experiments, polyaniline was obtained by reacting an oxidizing agent with the monomer aniline. Further, the primer coating was prepared using a variety of widely-used materials such as urethane resin. For the top coating, epoxy resin and acrylic urethane resin were used. Characteristics of the coatings were assessed according to KS and ASTM specifications, and the structure of the polyaniline was characterized using FT-IR and TGA. For analysis of anti-corrosive properties in salt-spray experiments, measurements of the oxidation state of iron and surface atomic analysis were conducted using XPS and SEM-EDX. Unlike general anti-corrosive coatings which exhibit anti-corrosive effects only as a primer coating, the anti-corrosive coatings using polyaniline as the anti-corrosive pigment showed a marked synergistic effect with the top coatings. In other words, the top coatings not only produce a fine view effect, but also increase, through interaction with the primer coatings, the resistance to diffusion of corrosive factors from the external environment. It was also found that, unlike the heavy metal oxide-forming layer of the passive barrier alone, the polyaniline anti-corrosive pigment oxidized iron at the interface with the iron substrate to form a passive barrier in the oxidic layer, and itself formed a potential barrier layer with anti-corrosive factors from the external environment. Although the passive layer was damaged, the damaged area did not become completely oxidized iron; on the contrary, it showed a tendency to reduction. This can be interpreted such that a passive layer is formed again on the damaged area, and that at the same time there is a tendency to self-healing.

• 박물관보존과학
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• 제11권
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• pp.9-16
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• 2010

국립춘천박물관은 고려 철제석가여래좌상의 부식방지와 상설전시 활용을 위하여 보존처리를 실시하였다. 처리 전 유물의 상태는 부식으로 인한 표면 박락현상이 관찰되었고 가부좌의 오른편 둔부에서 다리부분까지 결손되어 정상적인 전시가 불가능 하였다. 따라서 표면의 이물질을 제거하고 강화·보호 위한 강화처리 작업이 진행되었다. 강화처리 진행에 앞서 국내·외 연구 자료를 바탕으로 micro crystalline wax계를 선정하여 기초 실험을 실시하였다. 그 결과 (주)동남유화의 wax(in xylene) 5wt%가 백화현상과 표면 색상변화가 적으며 작업에 편리성이 높아 강화제로 선택하여 부식을 억제하였다. 결손부분의 복원은 내부 지지대 제작과 함께 epoxy계 수지를 이용하여 탈착이 가능한 복원을 실시하여 전시 효용성을 높였다.

• 한국안전학회지
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• 제29권6호
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• pp.87-93
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• 2014

In this study, the reinforced concrete rahmen bridge damaged by the chloride attack was investigated. According to the investigation, the degraded concretes on cantilever kerb and end part were intensively observed. Thus, the chloride content test and half-cell method were performed to evaluate the degraded parts. As a result, the contents of chloride on degraded parts were C and D grade. On the other hand, the half-cell potential values of rebar in degraded concrete were measured with the minor corrosion. This rebar corrosion is expected to progressing. Chloride content D grade is due to expansion pressure by corrosion of rebar and freeze-thaw by permeate water, could see progresses rapidly degradation. In order to prevent chloride attack to concrete deck caused by deicing salts, corresponding to the chloride critical concentration must maintain grade b or at least grade c. Chloride condition evaluation standard apply to evaluation of marine structure chloride attack with chloride attack by deicing salts.

• Computers and Concrete
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• 제6권6호
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• pp.473-490
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• 2009

This paper presents a new methodology to evaluate the load carrying capacity of deteriorated non-slender concrete bridge pier columns by construction of the full P-M interaction diagrams. The proposed method incorporates the actual material properties of deteriorated columns, and accounts for amount of corrosion and exposed corroded bar length, concrete loss, loss of concrete confinement and strength due to stirrup deterioration, bond failure, and type of stresses in the corroded reinforcement. The developed structural model and the damaged material models are integrated in a spreadsheet for evaluating the load carrying capacity for different deterioration stages and/or corrosion amounts. Available experimental and analytical data for the effects of corrosion on short columns subject to axial loads combined with moments (eccentricity induced) are used to verify the accuracy of proposed model. It was observed that, for the limited available experimental data, the proposed model is conservative and is capable of predicting the load carrying capacity of deteriorated reinforced concrete columns with reasonable accuracy. The proposed analytical method will improve the understanding of effects of deterioration on structural members, and allow engineers to qualitatively assess load carrying capacity of deteriorated reinforced concrete bridge pier columns.

• 대한조선학회논문집
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• 제33권2호
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• pp.96-110
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• 1996

노후선박은 부식, 피로균열 등의 구조손상을 입고 있으며, 구조손상이 심각하면 중대한 해난사고를 초래할 위험성이 높다. 선각붕괴에 의한 선박의 침몰사고를 미연에 방지하기 위하여는 구조손상에 기인된 각종 불확실성을 고려한 노후선박의 최종강도 신뢰성을 평가할 필요가 있다. 본 논문에서는 부식에 의한 선체구조부재의 판두께 감소효과를 고려하여 선체구조의 최종강도를 기준으로한 신뢰성 평가기법을 제시하였다. 이를 위해 선체구조의 부식 속도모델을 선급에서 제시하는 데이타를 바탕으로 설정하고, 부식효과를 고려한 신뢰성 한계상태방정식을 도출하였으며, 최종강도 신뢰성은 SORM (second-order reliability method)을 적용하여 계산하였다. 본 기법을 이중선체 유조선에 적용하여 선령의 증가에 따른 단면계수 및 최종강도 신뢰성의 감소특성을 고찰하였다.

• 한국전산구조공학회:학술대회논문집
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• 한국전산구조공학회 2007년도 정기 학술대회 논문집
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• pp.3-17
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• 2007

This paper provides an introduction to life-span simulation and numerical approach to support the performance design processes of reinforced concrete structures. An integrated computational system is proposed for life-span simulation of reinforced concrete. Conservation of moisture, carbon dioxide, oxygen, chloride, calcium and momentum is solved with hydration, carbonation, corrosion, ion dissolution. damage evolution and their thermodynamic/mechanical equilibrium. Coupled analysis of mass transport and damage mechanics associated with steel corrosion is presented for structural performance assessment of reinforced concrete. Multi-scale modeling of micro-pore formation and transport phenomena of moisture and ions are mutually linked for predicting the corrosion of reinforcement and volumetric changes. The interaction of crack propagation with corroded gel migration can also be simulated. Two finite element codes. multi-chemo physical simulation code (DuCOM) and nonlinear dynamic code of structural reinforced concrete (COM3) were combined together to form the integrated simulation system. This computational system was verified by the laboratory scale and large scale experiments of damaged reinforced concrete members under static loads, and has been applied to safety and serviceability assessment of existing structures. Based on the damage details predicted by the nonlinear finite element analytical system, the life-span-cost of RC structures including the original construction costs and the repairing costs for possible damage during the service life can be evaluated for design purpose.

• 전력전자학회논문지
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• 제26권2호
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• pp.90-95
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• 2021

In contrast to AC grounding systems, the ground electrode in DC systems continuously maintains positive or negative polarity. Ground electrodes with (+) polarity proceeds by oxidation reaction. Thus, the DC current should flow opposite to the polarity of the leakage current flowing through the (+) ground electrode by using a compensation electrode, and the current flowing through the (+) ground electrode can be 0A. However, according to protecting the (+) ground electrode, the compensation electrode corrodes and gets damaged. Thus, the (+) ground electrode must be protected from corrosion, and the service life of the compensation electrode must be extended. As an alternative, the average value of the current flowing through the compensation electrode should be equal with the value of the leakage current flowing through the (+) ground electrode by using the square waveform. Throughout the experiment, the degree of corrosion on the compensation electrode is analyzed by the frequency of the compensation electrode for a certain time. In the experiment, the frequencies of the square waveform are considered for 0.1, 1, 10, 20, 50, 100 Hz, and 1 kHz. Through experiments and analysis, the optimal frequency for reducing the electrolytic damage of the (+) electrode and compensation electrode in an LVDC grounding environment is determined.