• Title/Summary/Keyword: corrosion protection performance

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A Study on the Standardization of Performance Test Method for CP Rectifier in Korea (국내 전기방식용 정류기의 성능평가 시험 방법에 대한 표준화 연구)

  • Bae, Jeong-Hyo;Ha, Tae-Hyun;Lee, Hyun-Goo;Kim, Dae-Kyeong;Lee, Ji-In
    • Proceedings of the KIEE Conference
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    • 2002.11d
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    • pp.253-256
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    • 2002
  • Generally, the owners of the facilities adopt CP(Cathodic Protection) Systems to protect the corrosion accidents previously. The developed countries have secured the standard of CP systems through the various researches and consolidation of the rules. So in the first stage. I had been studied the international standards; JSCE, NACE Standard, ASTM, DNV, Australian Standard etc. and standardized the CP systems about items performance. specifications and so on. In this thesis, I have been studying the results of standardization of performance test methods of CP rectifier to apply in Korea.

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Corrosion Protection of Rebars Using High Durability Polymer Cementitious Materials for Environmental Load Reduction (환경부하저감형 고내구성 폴리머 시멘트계 재료를 이용한 철근 부식저감기술)

  • Kim, Wan-Ki;Chung, Seung-Jin
    • KIEAE Journal
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    • v.10 no.5
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    • pp.131-137
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    • 2010
  • The building industry must aim at high-durability and sustainability. A holistic life cycle based approach is recommended to reduce the environmental load. In recent years, technical innovations in the construction industry have advanced to a great extent, and caused the active research and development of high-performance and multifunctional construction materials. Nowadays, various polymer powders have been commercialized to manufacture construction materials in the form of prepackaged-type products, which have rapidly been developed for lack of skilled workmen in construction sites. Recently, terpolymer powders of improved quality have been developed and commercialized as cement modifiers. And, hydrocalumite is a material that can adsorb the chloride ions (Cl-) causing the corrosion of reinforcing bars and liberate the nitrite ions (NO2-) inhibiting the corrosion in reinforced concrete, and can provide a self-corrosion inhibition function to the reinforced concrete. The purpose of this study is to ascertain the self-corrosion inhibition function of polymer-modified mortars using redispersible powders with hydrocalumite. Polymer-modified mortars using VA/E/MMA and VAE redispersible powders are prepared with various calumite contents and polymer-binder ratios, and tested for chloride ion penetration depth, corrosion inhibition. As a result, regardless of the polymer-binder ratio, the replacement of ordinary portland cement with hydrocalumite has a marked effect on the corrosion-inhibiting property of the polymer-modified mortars. Anti-corrosion effect of polymer-modified mortars using VA/E/MMA terpolymer powder with hydrocalumite is higher than that of VAE copolymer powder.

Design of an Active Shaft Grounding System for the Elimination of Alternating Electromagnetic Field in Vessel (선체 교류 전자장 제거를 위한 능동 축 접지 시스템 설계)

  • Kim, Tae-kue;Ahn, Ho-kyun;Yoon, Tae-sung;Park, Seung-kyu;Kwak, Gun-pyong
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.19 no.6
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    • pp.1515-1524
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    • 2015
  • Recently, for the purpose of preventing the corrosion of a vessel, the electrical corrosion protection device that prevents the corrosions of the hull and the propeller is widely used. However, the electrical corrosion protection method artificially emits the current into the seawater around the hull using the power supply in order to make the hull and propeller be in the state of not being corrosion, so that electromagnetic field is generated outside the hull by the current emitted into the seawater. In this paper, the static and alternating constituents of the electromagnetic field generated in underwater outside the hull are analyzed and a countermeasure is investigated to reduce the strength of the electromagnetic field. In conventional shaft grounding system, the shaft potential is maintained above at least 100mV and the alternating current component constitutes more than 10% of the total current. However, in this paper, a control system was designed in order that the alternating current component and the shaft potential which generate electromagnetic field are maintained within 1% and 2mV respectively, and the performance was verified by simulation.

Evaluation of Corrosivity of Antifreeze for Automobiles Containing Non-amine Type Corrosion Inhibitors for Copper (Non-amine계 부식방지제를 포함하는 자동차용 부동액의 구리 부식성 평가)

  • Soh, Soon-Young;Chun, Yong-Jin;Park, In-Ha;Han, Sang-Mi;Jang, Hee-Jin
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.2
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    • pp.619-626
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    • 2020
  • The development of new antifreeze mixtures containing non-amine-type corrosion inhibitors, which considers environmental protection, has become a major issue. In this study, four non-amine-type corrosion inhibitors were synthesized and used to produce five kinds of new antifreeze for automobiles to evaluate the rate of copper corrosion. The effects were evaluated by the weight change, surface observation, roughness measurement, and measurement of copper elution in the solution. The amount of copper eluted measured by ICP from Sample 4 was small, and the elution rate was prolonged. Sample 4 showed the best anti-corrosion performance owing to a corrosion suppression effect by passivating copper because the metal surface was smooth after the test, and the corrosion product layer was formed evenly on the surface as small local corrosion was observed. The major corrosion inhibitor added to Sample 4 was 1-aminomethyl(N',N'-di(2-hydroxyethyl)benzotrazole, which contained a certain amount in Sample 5 to show relatively high local corrosion but passivation in progress. Therefore, among the four corrosion inhibitors, 1-aminomethyl(N',N'-di(2-hydroxyethyl)benzotrazole had the highest corrosion inhibitory effect. This corrosion inhibitor prevents corrosion by promoting the passivation of copper on the antifreeze.

Preparation and application of silica-based coatings for corrosion protection of marine structures (해양구조물용 silica 기반 내해수성 코팅제의 제조 및 응용)

  • Lee, Byeong Woo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.31 no.3
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    • pp.137-142
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    • 2021
  • In this study, the development of the room temperature curable silica-based coating compositions for anticorrosive and antifouling performance in marine environments was carried out. The marine (plant) structures with many exposed parts are operated in harsh marine environments such as strong ultraviolet rays, extreme temperature differences and salt water corrosion. Organic paints that are easily degraded under these environments and easily eroded by physical stimuli such as waves can not play a role properly. Dense ceramic coatings on marine structures provide careful protections even in saltwater environments due to their high hardness and rust resistance. Therefore, in the case of ceramic coatings, their use and application range in marine structures can be greatly improved due to their functional advantages. In the present study, silica-based coating compositions based on colloidal silica with silane coupling agents, curing salts, and ceramic fillers were developed, and their applications as protective coatings for corrosion protection and fouling prevention in seawater were also studied.

Effect of Repeated Wet/Dry Cycles of Salt Solution on Flexural Performance of Steel Fiber Reinforced Concrete (반복적 염수침지가 강섬유 혼입 콘크리트의 휨성능에 미치는 영향)

  • Kim, Ji-Hyun;Choi, Yu-Jin;Chung, Chul-Woo
    • Journal of the Korea Institute of Building Construction
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    • v.22 no.6
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    • pp.553-564
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    • 2022
  • Concrete is a representative composite material that shows excellent performance in the construction field. However, it is a brittle and nonhomogeneous material and exhibits weak behavior against bending and tensile forces. To compensate for such weakens, fiber reinforcement has been utilized, and steel fiber has been recognized as one of the best material for such purpose. However, steel fiber can seriously affect the durability of concrete exposed to the marine environment due to the corrosion caused by chlorine ions. This study intended to evaluate the mechanical performance of steel fiber reinforce concrete during and after repeated wet/dry cycles in salt solution. According to the experimental results, there was no reduction in the relative dynamic modulus of concrete during the repeated wet/dry cycles in salt solution for 37 weeks. Flexural strength was not decreased after completion of repeated wet/dry cycles in salt solution. There was no sign of corrosion in steel fibers after visual observation of fractured surface. However, the flexural toughness was decreased, and this is because about half of the concrete specimen showed failure before reaching the maximum displacement of 3 mm. Although repeated wet/dry cycles in salt solution did not cause cracks in concrete through corrosion of steel fibers, specific attention is required because it can reduce flexural toughness of steel fiber reinforced concrete.

Development of Prediction Model of Chloride Diffusion Coefficient using Machine Learning (기계학습을 이용한 염화물 확산계수 예측모델 개발)

  • Kim, Hyun-Su
    • Journal of Korean Association for Spatial Structures
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    • v.23 no.3
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    • pp.87-94
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    • 2023
  • Chloride is one of the most common threats to reinforced concrete (RC) durability. Alkaline environment of concrete makes a passive layer on the surface of reinforcement bars that prevents the bar from corrosion. However, when the chloride concentration amount at the reinforcement bar reaches a certain level, deterioration of the passive protection layer occurs, causing corrosion and ultimately reducing the structure's safety and durability. Therefore, understanding the chloride diffusion and its prediction are important to evaluate the safety and durability of RC structure. In this study, the chloride diffusion coefficient is predicted by machine learning techniques. Various machine learning techniques such as multiple linear regression, decision tree, random forest, support vector machine, artificial neural networks, extreme gradient boosting annd k-nearest neighbor were used and accuracy of there models were compared. In order to evaluate the accuracy, root mean square error (RMSE), mean square error (MSE), mean absolute error (MAE) and coefficient of determination (R2) were used as prediction performance indices. The k-fold cross-validation procedure was used to estimate the performance of machine learning models when making predictions on data not used during training. Grid search was applied to hyperparameter optimization. It has been shown from numerical simulation that ensemble learning methods such as random forest and extreme gradient boosting successfully predicted the chloride diffusion coefficient and artificial neural networks also provided accurate result.

Effect of Retained Pre-construction Primer on the Corrosion Protection Properties of Epoxy Coatings

  • Lee, Chul-Hwan;Shin, Chil-Seok;Lee, Ho-Il;Chung, Mong-Kyu;Baek, Kwang-Ki
    • Corrosion Science and Technology
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    • v.6 no.5
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    • pp.219-226
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    • 2007
  • Pre-construction primer (PCP), or shopprimer, have been applied to steel plates to control temporary corrosion during ship fabrication. For surface preparation at ship block stage, in common shipyard practices, welding beads, burnt and rusted areas shall be blasted or power tool cleaned and the contamination such as zinc salt shall be removed with blasting or power tool. Whereas, the sound film of PCP needs not to be removed or roughened as the paint having good compatibility with PCP is used for the first coat. In many cases, however, full blasting or sweep blasting on the sound PCP treated block assemblies was requested. There still has been argument about the legitimacy of this practice, thus, it is critical to evaluate the quality of the coating system applied on the sound PCP retained condition, comparing with the one applied on the full blasted or sweep blasted condition. In this study, two different epoxy systems for water ballast tank were applied on the surfaces with sound PCP condition, full blasted condition, and sweep blasted condition. Coating performances such as durability, anti-corrosion, cathodic disbondment resistance were evaluated. The test results clearly indicated that the sound film of PCP needed not to be removed or roughened as the paint having good compatibility with PCP based on inorganic zinc silicate.

Effect of ALD-Al2O3 Passivation Layer on the Corrosion Properties of CrAlSiN Coatings (ALD-Al2O3 보호층이 적용된 CrAlSiN 코팅막의 내부식성 특성에 관한 연구)

  • Wan, Zhixin;Lee, Woo-Jae;Jang, Kyung Su;Choi, Hyun-Jin;Kwon, Se Hun
    • Journal of the Korean institute of surface engineering
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    • v.50 no.5
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    • pp.339-344
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    • 2017
  • Highly corrosion resistance performance of CrAlSiN coatings were obtained by applying ultrathin $Al_2O_3$ thin films using atomic layer deposition (ALD) method. CrAlSiN coatings were prepared on Cr adhesion layer/SUS304 substrates by a hybrid coating system of arc ion plating and high power impulse magnetron sputtering (HiPIMS) method. And, ultrathin $Al_2O_3$ passivation layer was deposited on the CrAlSiN/Cr adhesion layer/SUS304 sample to protect CrAlSiN coatings by encapsulating the whole surface defects of coating using ALD. Here, the high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) and energy dispersive X-ray spectrometry (EDX) analysis revealed that the ALD $Al_2O_3$ thin films uniformly covered the inner and outer surface of CrAlSiN coatings. Also, the potentiodynamic and potentiostatic polarization test revealed that the corrosion protection properties of CrAlSiN coatings/Cr/SUS304 sample was greatly improved by ALD encapsulation with 50 nm-thick $Al_2O_3$ thin films, which implies that ALD-$Al_2O_3$ passivation layer can be used as an effect barrier layer of corrosion.

Durability Performance Evaluation On Early-Aged Concrete with Rice Husk Ash and Silica Fume (Rice Husk Ash와 실리카퓸을 혼입한 초기재령 콘크리트의 내구성능 평가)

  • Saraswathy, Velu;Kwon, Seung-Jun
    • Journal of the Korea Concrete Institute
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    • v.27 no.4
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    • pp.343-351
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    • 2015
  • Currently, lots of researches have been performed for reducing cement usages due to increasing social/engineering problems caused by $CO_2$ emission. Supplementary cement materials like fly ash, slag, and silca fume are usually employed for cement replacement, and nowadays rice husk ash (RHA) is widely studied for enhancement of concrete performance as mineral admixture. In this paper, concrete samples with RHA and SF which is known for its engineering advantages are prepared and a resistance to chloride attack is evaluated in early-aged concrete. For the work, replacement ratios of 10~30% for RHA concrete and 2~8% for SF concrete are considered, and various durability tests such as density, void, sorptivity, current measurement, and chloride diffusion coefficient are performed including mechanical test like compressive and tensile strength. Replacement of RHA 10~15% shows better improvement of corrosion resistance and strength than that of SF 2~4% and normal concrete, which shows a strong applicability for utilization as construction materials.