• 자원리싸이클링
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• 제18권4호
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• pp.44-51
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• 2009

양극과 철근과의 사이에 이온의 흐름이 원활하도록 전도성이 우수한 탄소리본전극과 표면코팅을 실기한 후 무공해, 반영구적인 무한태양전기를 전류로 공급한 전기방식에 의한 콘크리트 중의 철근 부식 방지 효과를 알아보기 위하여 복극량, 철근의 복극전위 및 부식속도를 측정하였다. 실험결과 방식을 실시한 모든 대상 시험체가 NACE의 복극량 기준 100 mV 기준을 만족하였으며, 방식을 실시한 경우 복극전위와 부식속도가 안정적인 범위에 있음을 알 수 있었다.

• 한국마린엔지니어링학회:학술대회논문집
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• 한국마린엔지니어링학회 2002년도 춘계학술대회논문집
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• pp.135-139
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• 2002

Most of all the mechanical devices are becoming more high-speed and high-power as well as their used condition being more polluted. So, it is necessary for these devices to equip cooling system to overcome that kind of severe using condition. In this study, corrosion test was carried out in distilled and tap water for the investigation on the corrosion characteristics of Al-alloy that is using as material for radiator.

• Corrosion Science and Technology
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• 제17권6호
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• pp.292-300
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• 2018

The modeling of 3D finite elements based on CAD data has been used to detect sites of corrosion defects in buried pipes. The results generated sophisticated profiles of electrolytic potential and vectors of current distributions on the earth surface. To identify the location of defects in buried pipes, the current distribution on the earth surface was projected to a plane of incidence that was identical to the pipe locations. The locations of minimum electrolytic potential value were found. The results show adequate match between the locations of real and expected defects based on modeling. In addition, the defect size can be calculated by integrating the current density curve. The results show that the defect sizes were $0.74m^2$ and $0.69m^2$, respectively. This technology may represent a breakthrough in the detection of indirect damage in various cases involving multiple defects in size and shape, complex/cross pipe systems, multiple anodes and stray current.

• 한국해양공학회지
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• 제25권2호
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• pp.85-91
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• 2011

Many protection methods such as surface coating, electric protection, or other methods have been applied to the numerous steel structures widely used in continental and marine areas to control their corrosion, which is done from an economic point of view. Most of these steel structures are primarily protected by coating methods. However, some steel piles under seawater are protected by the electric protection method, that is, either using an impressed current or a sacrificial anode method. Furthermore, environmental contamination may cause a severely corrosive environment, which, in turn, causes the accelerated corrosion of steel structures. Subsequently, coated steel structures could deteriorate more rapidly than the designed lifetime because of the acid rain caused by air pollution, etc. Therefore, a coating of marine paint exposed to seawater, that is, underwater hardening painting, is increasingly required to be fast drying as well as highly corrosion resistant. In this study, five types of underwater hardening paints were prepared with different resin series and additives. Their corrosion and water resistances were investigated using electrochemical methods such as corrosion potential, polarization curves, impedance and cyclic voltammogram measurements, etc. Even though it is generally accepted that the corrosion resistance of bare steel tends to increase with a shift of the corrosion potential in the noble direction, the corrosion resistance of a sample with a coating exhibited a relatively better tendency when it had a lower corrosion potential in this study. The corrosion current density was also decreased with a decrease in the diffusion limiting current density, which may mean that there is some relationship between corrosion and water resistance. The S sample of the ceramic resin series showed the relatively best corrosion and water resistance among those of samples, while the worst corrosion and water resistance were observed for the R sample of the epoxy resin series. The corrosion and water resistance of those samples tended to deteriorate with an increase in the immersion days, and their corrosion and water resistances were considered to be apparently improved by the types of resin and additives.

• Corrosion Science and Technology
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• 제23권1호
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• pp.1-10
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• 2024

Oil well casing leak is caused by contact of casing outer surface with formation electrolyte. It is usually associated with an aquifer with a high salt content or absence of a cement ring behind the casing. The only way to reduce external casing corrosion is through cathodic protection. Through cathodic polarization of casing structure, electron content in crystal lattice and electron density will increase, leading to a potential shift towards the cathodic region. At Tatneft enterprises, cathodic protection is carried out according to cluster and individual schemes. The main criterion for cathodic protection is the size of protective current. For a casing, the protective current is considered sufficient if measurements with a two-contact probe show that the electric current directed to the casing has eliminated all anode sites. To determine the value of required protective current, all methods are considered in this work. In addition, an analysis of all methods used to determine the minimum protective current of the casing is provided. Results show that the method of measuring potential drop along casing is one of the most reliable methods for determining the value of protective current.

• 해양환경안전학회:학술대회논문집
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• 해양환경안전학회 2005년도 춘계학술발표회
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• pp.161-165
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• 2005

Recently, it is on the increase interest for Al alloy with new material for ship application to substitute for FRP ship. The reason is thatAl alloy ship has beneficial characteristics such as high sea speed, increase of loadage and easy to recycle compared with FRP ship. In this paper, mechanical and electrochemical properties are investigated by slow strain rate test experiment in various applied potential condition. These results will provide as reference data to design ship by deciding optimum protection potential regard to hydrogen embrittlement and stress corrosion cracking. In general, Al and Al alloys are not corroded with forming film which has the corrosion resistance property in neutral solution. However, it was observed that formation and destruction of passive film by $Cl^-$ ion in sea water environment. At comparison of current density after 1200 sec in potentiostatic experiment, the current density in the potential range of -0.68 $\~$-1.5 V is shown low value. The low current density means protection potential range. Elongation in applied potential of 0 V was high. However, the corrosion protection application in this condition is impossible potential because the toughness is low value by decreasing strength by active dissolution reaction at parallel part of specimen. The film composed with $CaCO_3$ and $Mg(OH)_2$ has a corrosion resistance property. However, the uniform electrodeposition coating at below -1.6 V potential is not formed since the time to form the uniform electrodeposition coating is short. Therefore, it is concluded that mechanical property is poor because effect by hydrogen gas generation is larger than that of electrodeposition coating. It is concluded that the optimum protection potential range from comparison of_maxim urn tensile strength, elongation and time to fracture is -1.3$\~$0.7 V (SSCE).

• Journal of Advanced Marine Engineering and Technology
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• 제38권10호
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• pp.1206-1211
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• 2014

This study has been conducted to confirm the effect of sacrificial anode cathodic protection system for 90 days to protect corrosion on pier that is located in Korea. The cathodically protected structure was a slab and a pile cap. Before the construction of cathodic protection system, the macrography was carried out. As a result of the macrography, many corrosion traces were confirmed in this structure. The trace was mainly focused on joint and zones that concrete cover was eliminated. To apply the cathodic protection system, many onsite techniques have been adopted. In addition, to confirm the inner state of steel in concrete properly, a corrosion monitoring sensor (DMS-100, Conclinic Co. Ltd) has been applied. Test factors were corrosion & cathodic protection potential, 4 hour depolarization potential, resistivity and current density. After 90 days from the installation of cathodic protection system, it could confirm that proper corrosion protection effect was obtained by considering the result of tests.

• 수산해양교육연구
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• 제12권2호
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• pp.164-175
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• 2000

Port facilities and marine structures used in marine environment were encountered to corrosion damages because of the influence of Cl-. Generally, to protect these accidents, anti-corrosion paint and epoxy coating have been used. But they were still remained erosion-corrosion damage like impingement erosion, cavitation erosion and deposit attack. It is necessary to develope the new composite lining material in order to protective those corrosion damages. In this paper, polyester glass flake, vinylester glass flake lining and epoxy coating for SS400 were investigated by the electrochemical polarization test and the impingement-cavitation erosion test for corrosion behaviour under the sea water. The main results obtained are as follows ; 1) Epoxy coating appear potentiodynamic polarization behaviour, but polyester glass flake and vinylester glass flake lining do not appear potentiodynamic polarization behaviour. 2) Open circuit potential of polyester glass flake lining is more noble than that of epoxy coating and corrosion current density of polyester glass flake lining is less drained than that of epoxy coating in sea water. 3) Open circuit potential of vinylester glass flake lining is more noble than that of polyester glass flake lining and corrosion current density of vinylester glass flake lining is less drained than that of polyester glass flake lining in the sea water.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2008년도 추계학술대회 초록집
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• pp.34-35
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• 2008

We investigated the effects of Pt nano electrodeposits on the corrosion of carbon substrate in an acidic solution. The electrodes for experiments were prepared by electrodepositing Pt on carbon substrate in a solution of 5 mM $H_2PtCl_6$ and 0.5 M $H_2SO_4$ using pulse deposition technique. In cyclic voltammograms for the carbon electrodes with and without Pt nano electrodeposits, total anodic current including both currents from oxygen evolution reaction and carbon corrosion increased abruptly above a critical potential. In addition, the critical potential of the carbon electrodes with Pt nano electrodeposits was lower than that of bare carbon electrode. This phenomenon was more prominent at $75^{\circ}C$ than $25^{\circ}C$. In potentiostatic experiments, the current transients and the corresponding power spectral density increased with increasing the applied potential for the electrodes. Furthermore, the current transients for the carbon electrodes with Pt nano electrodeposits were much higher than those for the bare carbon substrate. This indicates that the corrosion of carbon substrate can be highly accelerated by Pt nano electrodeposits.

• Journal of Advanced Marine Engineering and Technology
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• 제30권1호
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• pp.157-168
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• 2006

Recently, interest in using Al alloys in ship construction instead of fiber-reinforced plastic (FRP) has increased because of the advantages of A) alloy ships over FRP ships, including high speed, increased load capacity. and ease of recycling. This paper investigated the mechanical and electrochemical properties of Al alloys in a slow strain rate test under various potential conditions. These results will provide reference data for ship design by determining the optimum protection potential regarding hydrogen embrittlement and stress corrosion cracking. In general, Al and Al alloys do not corrode on formation of a film that has resistance to corrosion in neutral solutions. In seawater, however, $Cl^-$ ions lead to the formation and destruction of a Passive film. In a potentiostatic experiment. the current density after 1200 sec in the Potential range of $-0.68\~-1.5\;V$ was low. This low current density indicates the protection potential range. Elongation at an applied potential of 0 V was high in this SSRT. However, corrosion protection under these conditions is impossible because the mechanical properties are worse owing to decreased strength resulting from the active dissolution reaction in parallel parts of the specimen. A film composed of $CaCO_3\;and\;Mg(OH)_2$ confers corrosion resistance. However, at potentials below -1.6 V forms non-uniform electrodeposition coating, since there is too little time to form a coating. Therefore, we concluded that the mechanical properties are poor because the effect of hydrogen gas generation exceeds that of electrodeposition. Comparison of the maximum tensile strength, elongation, and time to fracture indicated that the optimum protection potential range was from -1.45 to -0.9 V (SSCE).