• Title/Summary/Keyword: corrosion modeling

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Thermodynamic Modelling of Blast Furnace Slag Blended Cement Composites (고로슬래그가 치환된 시멘트복합체의 열역학적 모델링)

  • Yang, Young-Tak;Cha, Soo-Won
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.4
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    • pp.488-495
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    • 2017
  • In this study, we conducted the kinetic hydration modeling of OPC and the final product according to the substitution ratio of GGBS by using the geochemical code, GEMS, in order to calculate the thermodynamic equilibrium. The thermodynamic data was used by GEMS's 3rd party database, Cemdata18, and the cement hydration model, the Parrot & Killoh model was applied to simulate the hydration process. In OPC modeling, ion concentration of pore solution and hydration products by mass and volume were observed according to time. In the GGBS modeling, as the substitution rate increases, the amount of C-S-H, which contributes the long-term strength, increases, but the amount of Portlandite decreases, which leads to carbonation and steel corrosion. Therefore, it is necessary to establish prevention of some deterioration.

Temperature distribution behaviors of GFRP honeycomb hollow section sandwich panels

  • Kong, B.;Cai, C.S.;Pan, F.
    • Structural Engineering and Mechanics
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    • v.47 no.5
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    • pp.623-641
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    • 2013
  • The fiber-reinforced polymer (FRP) composite panel, with the benefits of light weight, high strength, good corrosion resistance, and long-term durability, has been considered as one of the prosperous alternatives for structural retrofits and replacements. Although with these advantages, a further application of FRPs in bridge engineering may be restricted, and that is partly due to some unsatisfied thermal performance observed in recent studies. In this regard, Kansas Department of Transportation (DOT) conducted a field monitoring program on a bridge with glass FRP (GFRP) honeycomb hollow section sandwich panels. The temperatures of the panel surfaces and ambient air were measured from December 2002 to July 2004. In this paper, the temperature distributing behaviors of the panels are firstly demonstrated and discussed based on the field measurements. Then, a numerical modeling procedure of temperature fields is developed and verified. This model is capable of predicting the temperature distributions with the local environmental conditions and material's thermal properties. Finally, a parametric study is employed to examine the sensitivities of several temperature influencing factors, including the hollow section configurations, environmental conditions, and material properties.

Chemical Equilibrium Modeling for Magnetite-Packed Crevice Chemistry in a Nuclear Steam Generator

  • Bahn, Chi-Bum;Rhee, In-Hyoung;Hwang, Il-Soon;Park, Byung-Gi
    • Bulletin of the Korean Chemical Society
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    • v.26 no.11
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    • pp.1783-1789
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    • 2005
  • Modeling of a steam generator crevice in a nuclear power system needs to take into account both thermalhydraulic and chemical phenomena. As a first step towards developing a reliable model, a chemical equilibrium model was developed to predict chemical speciation in a magnetite-packed crevice by adopting the “tableau” method. The model was benchmarked with the available experimental data and the maximum deviation did not exceed two orders of magnitude. The developed model was applied to predict the chemical speciation in a magnetite-packed crevice. It was predicted that caustic environment was developed by the concentration of NaOH and the dissolution of magnetite. The model indicated that the dominant aqueous species of iron in the caustic crevice was $FeO_2\;^-$. The increase of electrochemical corrosion potential observed in the experiment was rationalized by the decrease of dissolved hydrogen concentration due to a boiling process. It was predicted that under the deaerated condition magnetite was oxidized to hematite.

Modeling of a Confinement Effect in Laser Shock Peening on Titanium Alloy (티타늄 합금에 대한 레이저 쇼크 피닝에서 컨파인먼트에 따른 피닝 효과 모델링)

  • Lee, Wooram;Kim, Joohan
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.22 no.4
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    • pp.680-685
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    • 2013
  • In this study, the effect of laser shock peening on a titanium alloy was modeled using different confinements. Both liquid and solid confinement could be applied to laser shock peening, and solid confinement provided a dry laser shock peening process, which has the advantage of a corrosion-free effect. When a different confinement was applied to laser shock peening, a different peening effect would be expected. In our study, the peening effect was numerically modeled and simulated. The main effect of different confinements was a change in the impedances required to confine a shock wave from a plasma. The impedances were assumed with respect to different materials. Johnson-Cook's plastic deformation modeling was applied to the simulation. The strains and residual stresses were calculated to evaluate the confinement effects. When solid confinement was used, the residual stress increased by 60-85%, compared to the case of liquid confinement. However, the depth of the residual stress was slightly deeper. The simulated results could be applied to estimate the peening effect when a different confinement was used in the laser shock peening process.

Modeling of chloride diffusion in a hydrating concrete incorporating silica fume

  • Wang, Xiao-Yong;Park, Ki-Bong;Lee, Han-Seung
    • Computers and Concrete
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    • v.10 no.5
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    • pp.523-539
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    • 2012
  • Silica fume has long been used as a mineral admixture to improve the durability and produce high strength and high performance concrete. And in marine and coastal environments, penetration of chloride ions is one of the main mechanisms causing concrete reinforcement corrosion. In this paper, we proposed a numerical procedure to predict the chloride diffusion in a hydrating silica fume blended concrete. This numerical procedure includes two parts: a hydration model and a chloride diffusion model. The hydration model starts with mix proportions of silica fume blended concrete and considers Portland cement hydration and silica fume reaction respectively. By using the hydration model, the evolution of properties of silica fume blended concrete is predicted as a function of curing age and these properties are adopted as input parameters for the chloride penetration model. Furthermore, based on the modeling of physicochemical processes of diffusion of chloride ion into concrete, the chloride distribution in silica fume blended concrete is evaluated. The prediction results agree well with experiment results of chloride ion concentrations in the hydrating concrete incorporating silica fume.

Model-Based Prediction of Pulsed Eddy Current Testing Signals from Stratified Conductive Structures

  • Zhang, Jian-Hai;Song, Sung-Jin;Kim, Woong-Ji;Kim, Hak-Joon;Chung, Jong-Duk
    • Journal of the Korean Society for Nondestructive Testing
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    • v.31 no.6
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    • pp.609-615
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    • 2011
  • Excitation and propagation of electromagnetic field of a cylindrical coil above an arbitrary number of conductive plates for pulsed eddy current testing(PECT) are very complex problems due to their complicated physical properties. In this paper, analytical modeling of PECT is established by Fourier series based on truncated region eigenfunction expansion(TREE) method for a single air-cored coil above stratified conductive structures(SCS) to investigate their integrity. From the presented expression of PECT, the coil impedance due to SCS is calculated based on analytical approach using the generalized reflection coefficient in series form. Then the multilayered structures manufactured by non-ferromagnetic (STS301L) and ferromagnetic materials (SS400) are investigated by the developed PECT model. Good prediction of analytical model of PECT not only contributes to the development of an efficient solver but also can be applied to optimize the conditions of experimental setup in PECT.

Rotordynamic Analysis of a Dual-Spool Turbofan Engine with Focus on Blade Defect Events (블레이드 손상에 따른 이축식 터보팬 엔진의 동적 안정성 해석)

  • Kim, Sitae;Jung, Kihyun;Lee, Junho;Park, Kihyun;Yang, Kwangjin
    • Tribology and Lubricants
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    • v.36 no.2
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    • pp.105-115
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    • 2020
  • This paper presents a numerical study on the rotordynamic analysis of a dual-spool turbofan engine in the context of blade defect events. The blades of an axial-type aeroengine are typically well aligned during the compressor and turbine stages. However, they are sometimes exposed to damage, partially or entirely, for several operational reasons, such as cracks due to foreign objects, burns from the combustion gas, and corrosion due to oxygen in the air. Herein, we designed a dual-spool rotor using the commercial 3D modeling software CATIA to simulate blade defects in the turbofan engine. We utilized the rotordynamic parameters to create two finite element Euler-Bernoulli beam models connected by means of an inter-rotor bearing. We then applied the unbalanced forces induced by the mass eccentricities of the blades to the following selected scenarios: 1) fully balanced, 2) crack in the low-pressure compressor (LPC) and high pressure compressor (HPC), 3) burn on the high-pressure turbine (HPT) and low pressure compressor, 4) corrosion of the LPC, and 5) corrosion of the HPC. Additionally, we obtained the transient and steady-state responses of the overall rotor nodes using the Runge-Kutta numerical integration method, and employed model reduction techniques such as component mode synthesis to enhance the computational efficiency of the process. The simulation results indicate that the high-vibration status of the rotor commences beyond 10,000 rpm, which is identified as the first critical speed of the lower speed rotor. Moreover, we monitored the unbalanced stages near the inter-rotor bearing, which prominently influences the overall rotordynamic status, and the corrosion of the HPC to prevent further instability. The high-speed range operation (>13,000 rpm) coupled with HPC/HPT blade defects possibly presents a rotor-case contact problem that can lead to catastrophic failure.

Modeling of the lifetime prediction of a 12-V automotive lead-acid battery (차량용 납축전지의 수명 예측 모델링)

  • Kim, Sung Tae;Lee, Jeongbin;Kim, Ui Seong;Shin, Chee Burm
    • Journal of Energy Engineering
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    • v.22 no.4
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    • pp.338-346
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    • 2013
  • The conventional lead acid battery is optimized for cranking performance of engine. Recently electric devices and fuel economy technologies of battery have influenced more deep cycle of dynamic behavior of battery. I also causes to reduce battery life-time. This study proposed that aging battery model is focused for increasing of battery durability. The stress factors of battery aging consist of discharge rate, charging time, full charging time and temperature. This paper considers the electrochemical kinetics, the ionic species conservation, and electrode porosity. For prediction of battery life cycle we consider battery model containing strong impacts, corrosion of positive grid and shedding. Finally, we validated that modeling results were compared with the accelerated thermal measurement data.

Simulation of chloride penetration into concrete structures subjected to both cyclic flexural loads and tidal effects

  • Mien, Tran Van;Stitmannaithum, Boonchai;Nawa, Toyoharu
    • Computers and Concrete
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    • v.6 no.5
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    • pp.421-435
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    • 2009
  • Chloride induced corrosion is a concern that governs the durability of concrete structures in marine environments, especially in tidal environments. During the service lives of concrete structures, internal cracks in the concrete cover may appear due to imposed loads, accelerating chloride penetration because of the simultaneous action of environmental and service structural loads. This paper investigated the effects of cyclic flexural loads on chloride diffusion characteristics of plain concretes, and proposed a model to predict the chloride penetration into plain concretes subjected to both tidal environments and different cyclic flexural load levels. Further, a new experiment was performed to verify the model. Results of the model using Finite Difference Method (FDM) showed that the durability of concretes in tidal environments was reduced as cyclic flexural load levels, SR, increased, and the modeling results fitted well with the experimental results.

Basic Study on Combustion Characteristics of Coaxial Premixed Burner with the Addition of $Al_2O_3$ Particles (산화 알루미나 입자 첨가에 따른 동축류 예혼합 연소기의 연소 특성 기초연구)

  • Park, Seung-Il;Kim, Go-Tae;Kim, Nam-Il
    • Journal of the Korean Society of Combustion
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    • v.16 no.1
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    • pp.58-65
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    • 2011
  • Thermal spray technology has been used in many industrial application. Especially, thermal spray coating have been employed with the purposes of achieving better resistances in abrasion, heat and corrosion. In the previous studies on the thermal spray coating, thermal spray characteristics from the perspective of combustion engineering have not been investigated sufficiently, while the material characteristics of the coated substrates have been investigated widely. In this study, the effect of spray particles on the flame behavior was experimentally investigated. The amount of the injected particles was measured using the light scattering method and the temperature of the particles was estimated using a two-color method. Various flame-spray interactions were observed and it was found that the high temperature zone near the flame is elongated by particles density. Based on these results, the applicability of the light scattering method and the two-color method was discussed.