• Journal of the Korean institute of surface engineering
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• v.48 no.6
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• pp.354-359
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• 2015

Stainless steel has poor corrosion resistance in marine environment due to the breakdown of a passive film caused by chloride. It suffers electrochemical corrosion like pitting corrosion, crevice corrosion, and stress corrosion crack (SCC) in marine environment. In general, it indicates that the passive film of $Al_2O_3$ has better corrosion resistance than that of $Cr_2O_3$ in seawater. This paper investigated the damage behavior 304 stainless steel and hot-dip aluminized 304 stainless steel in seawater solution. Various electrochemical experiments were carried out including potential measurement, potentiodynaimic experiment, Tafel analysis and galvanostatic experiment. As a result of anodic polarization experiment, higher pitting damage depth was indicated at 304 stainless steel than hot-dip aluminized 304 stainless steel. In addition, relatively higher corrosion current density was shown at hot-dip aluminized stainless steel as a result of Tafel analysis.

• Journal of the Korean Society for Heat Treatment
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• v.19 no.2
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• pp.90-95
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• 2006

Nitriding or carburizing of carbon steels results in good mechanical properties such as high surface hardness and wear resistance but it has no affection on the corrosion resistance. Corrosion properties of nitriding and carburizing steels could be deteriorated. So, recently, there have been great demand for oxi-nitriding to enhance both mechanical properties and corrosion resistance. In this study, the corrosion resistance of carbon steel, S35C, and free cutting steel, SUM222, are prepared by vacuum nitriding and vacuum post-oxidation were compared with those treated by nitriding. After vacuum post-oxidation, $5{\mu}m$ oxide layer was formed on the nitride layer with $20{\sim}30{\mu}m$ depth. Potentio-dynamic polarization curve in corrosion test showed that the corrosion potential after post oxidation was increased from 200 mV to 800 mV in S35C and from 600 mV to 1200 mV in SUM222. SEM analyses showed that pores was increased and surface roughness became rougher with post oxidation. However, the formation of $Fe_3O_4$ resulted in the enhanced corrosion resistance of steels.

• Corrosion Science and Technology
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• v.20 no.2
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• pp.94-104
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• 2021

Atmospheric corrosion severity associated with aircraft parking environment was studied using metallic specimens, and temperature and humidity sensors installed at each aircraft operating base. Data were analyzed after a year of exposure. Silver was used to measure chloride deposition by integrating X-ray photoelectron spectroscopy depth profiles. Carbon steel was utilized to determine the corrosion rate by measuring the weight loss. The time of wetness was determined using temperature and humidity sensor data. Analysis of variance followed by Tukey's "honestly significant difference" test indicated that atmospheric environment inside the shelter varied significantly from that of unsheltered parking environment. The corrosion rate of unsheltered area also varies with the roof. Hierarchical clustering analysis of the measured data was used to classify air bases into groups with similar atmospheric corrosion. Bases where aircraft park at a shelter can be grouped together regardless of geographical location. Unsheltered bases located inland can also be grouped together with sheltered bases as long as the aircraft are parked under the roof. Environmental severity index was estimated using collected data and validated using the measured corrosion rate.

• Advances in concrete construction
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• v.7 no.1
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• pp.11-22
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• 2019

A comprehensive assessing approach for durability of reinforced concrete structures dealing with the corrosion process of rebar subjected to the attack of aggressive agent from environment was proposed in this paper. Corrosion of rebar was suggested in the form of combination of global corrosion and pitting. Firstly, for the purposed of considering the influence of rebar's radius, a type of Plane Corrosion Model (PCM) based on uniform corrosion of rebar was introduced. By means of FE simulation approach, global corrosion process of rebar regarding PCM and LCM (Linear Corrosion Model) was regressed and compared according to the data from Laboratoire $Mat{\acute{e}}riaux$ et $Durabilit{\acute{e}}$ des Constructions (LMDC). Secondly, pitting factor model of rebar in general descend law with corrosion degree was introduced in terms of existing experimental data. Finally, with the comprehensive numerical simulation, the durability of an existing arch bridge was studied in depth in deterministic way, including diffusion process and sectional strength of typical cross section of arch, crossbeam and deck slab. Evolution of structural capacity considering life-cycle rehabilitation strategy indicated the degradation law of durability of reinforced arch bridges.

• Corrosion Science and Technology
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• v.20 no.6
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• pp.391-402
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• 2021

In this investigation, the electrochemical characteristics of superaustenitic and general austenitic stainless steels were compared by conducting potentiodynamic polarization experiment with varying temperatures in natural seawater solution. From the result of the potentiodynamic polarization experiment, the corrosion rate of UNS S31603 was found to be 17 times faster than that of UNS N08367 under the most severe corrosion conditions. The relationship between the corrosion rate by maximum damage depth and the corrosion rate by the corrosion current density was expressed as α value for each stainless steel. The α value of UNS S31603 under all temperature conditions was higher than that of UNS N08367 under similar conditions. This means that UNS S31603 is more prone to localized corrosion than UNS N08367. UNS S31603 expressed pitting type damages under all temperature conditions as shown by SEM analysis results. The pitting damage rapidly grew at the relatively poor grain boundaries. Damage on UNS N08367 was not clearly represented at 30 ℃ and 60 ℃, and slight intergranular corrosion damage was observed on the entire surface at 90 ℃.

• Corrosion Science and Technology
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• v.21 no.4
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• pp.282-289
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• 2022

Aluminum 1000 series alloy, a pure aluminum with excellent workability and weldability, is mainly used in the ship field. Aluminum alloy can combine with oxygen in the atmosphere and form a natural oxide film with high corrosion resistance. However, its corrosion resistance and durability are decreased when it is exposed to a harsh environment for a long period of time. For solving this problem, a porous oxide film can be formed on the surface using an anodizing treatment method, a typical surface technique among various methods. In this study, aluminum 1050 alloy was anodized for 2 minutes, 6 minutes, and 10 minutes. The structure and shape of the oxide film were then analyzed to determine the corrosion resistance according to the thickness of the oxide film that changed depending on working condition using 15 wt% NaCl. After it was immersed in NaCl solution for 1, 5, and 10 days, corrosion damage was observed. Results confirmed that the thickness of the oxide film increased as the anodization time became longer. The depth of surface damage due to corrosion became deeper when the film was immersed in the 15 wt% NaCl solution for a longer period of time.

• Corrosion Science and Technology
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• v.22 no.4
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• pp.252-256
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• 2023

The galvanostatic polarization technique was used to accelerate corrosion in high chromium cast iron (HCCI) immersed in a simulated slurry solution of 0.1 mol dm^-3 H₂SO₄, 0.05 mol dm^-3 HCl, and 10 wt% SiC. The HCCI contained 27 wt% of Cr and 2.8 wt% of C, and its microstructure mainly comprised austenitic and carbide phases. A two-electrode system using a dense carbon rod and the HCCI sample was employed for the galvanostatic polarization by applying an anodic current for 24 hours. The corrosion rate increased upon applying the anodic current, but the increase was not significant, particularly for current densities higher than 10 µA cm^-2. Following polarization, the corrosion morphology revealed that the anodic current accelerated surface corrosion in the HCCI; however while the depth of the corroded area increased, the increase was not substantial. The propagation behavior of the anodic current and its impact on corrosion were further discussed.

• Corrosion Science and Technology
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• v.6 no.3
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• pp.103-111
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• 2007

The effect of stress factors on the growing process of stress corrosion cracking (SCC) of the sensitized 18-8 stainless steel in high temperature water was investigated using equations of crack growth rate derived from applying electric circuits to SCC corrosion paths. Three kinds of cross sections have to be considered when electric circuit is constructed using total current. The first is ion flow passage area, $S_{sol}$, of solution in crack, the second is total dissolving surface area, $S_{dis}$, of metal on electrode of crack tip and the third is dissolving cross section, $S_{met}$, of metal on grain boundary or in base metal or in welding metal. Stress may affect each area. $S_{sol}$ may depend on applied stress, $\sigma_{\infty}$, related with crack depth. $S_{dis}$ is expressed using a factor of $\varepsilon(K)$ and may depend on stress intensity factor, K only. SCC crack growth rate is ordinarily estimated using a variable of K only as stress factor. However it may be expected that SCC crack growth rate depends on both applied stress $\sigma_{\infty}$ and K or both crack depth and K from this consideration.$\varepsilon(K)$ is expressed as ${\varepsilon}(K)=h_2{\cdot}K^2+h_3{\cdot}K^3$ when $h_{2}$ and $h_{3}$ are coefficients. Also, relationships between SCC crack growth rate, da/dt and K were simulated and compared with the literature data of JBWR-VIP-04, NRC NUREG-0313 Rev.2 and SKIFS Draft. It was pointed out in CT test that the difference of distance between a point of application of force and the end of starter notch (starting point of fatigue crack) may be important to estimate SCC crack growth rate. An anode dissolution current density was quantitatively evaluated using a derived equation.

• Journal of the Korean Society of Hazard Mitigation
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• v.8 no.6
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• pp.47-52
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• 2008

Deicer has been generally used for prevention of a road freezing in winter, and the usage amount is increasing every year. However, deicer may induce the decrease of bond strength, surface scaling, and environmental pollution. In this study, the field test was performed to investigate the deterioration of concrete road structures used for 17 years. And, the corrosion resistance characteristics were compared for the existing deicer and eco-friendly deicer. According to the field test results, the penetration depth of limit chloride amount was about 40mm, and the average concentration of chloride was $3.45kg/m^3$ at the surface of structures. On the contrary, the carbonation depth was slight. The penetration depth of eco-friendly deicer was less than the existing deicer, and the corrosion resistance of eco-friendly deicer was higher.

• Journal of the Korean Society for Heat Treatment
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• v.22 no.5
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• pp.298-306
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• 2009

Gas nitriding and post oxidation were performed on stainless steels and SACM 645 steel. With increasing gas nitriding time, the increasing rate of nitrided layer was most rapid on SACM 645 steel and the nitriding depth of nitrided layer was most narrow on STS 304 steel among three steels. Corrosion resistance was increased with post oxidation on stainless steels and with increasing time the effect of corrosion resistance was decreased to compare with relatively short gas nitriding time. An improvement effect of corrosion resistance was consisted of predominantly on austenitic stainless steel by post oxidation after gas nitriding among three steels and it was relatively less influenced on martensitic stainless steel.