• The Journal of Korean Academy of Prosthodontics
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• v.31 no.3
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• pp.423-446
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• 1993

Titanium and its alloys are finding increasing use in medical devices and dental implants. The strong selling point of titanium is its resistance to the highly corrosive body fluids in which an implant must survive. This corrosion resistance is due to a tenacious passive oxide or film which exists on the metal's surface and renders it passive. Potentiodynamic polarization measurement is one of the most commonly used electro-chemical methods that have been applied to measure corrosion rates. And the potentiodynamic polarization test supplies detailed information such as open circuit, rupture, and passivation potential. Furthermore, it indicates the passive range and sensitivity to pitting corrosion. This study was designed to compare the corrosion resistance of the commonly used dental implant materials such as CP Ti, Ti-6A1-4V, Co-Cr-Mo alloy, and 316L stainless steel. And the effects of galvanic couples between titanium and the dental alloys were assessed for their useful-ness-as. materials for superstructure. The working electrode is the specimen , the reference electrode is a saturated calomel electrode (SCE), and the counter electrode is made of carbon. In $N_2-saturated$ 0.9% NaCl solutions, the potential scanning was performed starting from -800mV (SCE) and the scan rate was 1 mV/sec. At least three different polarization measurements were carried out for each material on separate specimen. The galvanic corrosion measurements were conducted in the zero-shunt ammeter with an implant supraconstruction surface ratio of 1:1. The contact current density was recorded over a 24-hour period. The results were as follows : 1. In potential-time curve, all specimens became increasingly more noble after immersion in the test solution and reached between -70mV and 50mV (SCE) respectively after 12 hours. 2. The Ti and Ti alloy in the saline solution were most resistant to corrosion. They showed the typical passive behavior which was exhibited over the entire experimental range. Therefore no breakdown potentials were observed. 3. Comparing the rupture potentials, Ti and Ti alloy had the high(:st value (because their break-down potentials were not observed in this study potential range ) followed by Co-Cr-Mo alloy and stainless steel (316L). So , the corrosion resistance of titanium was cecellent, Co-Cr-Mo alloy slightly inferior and stainless steel (316L) much less. 4. The contact current density sinks faster than any other galvanic couple in the case of Ti/gold alloy. 5. Ag-Pd alloy coupled with Ti yielded high current density in the early stage. Furthermore, Ti became anodic. 6. Ti/Ni-Cr alloy showed a relatively high galvanic current and a tendency to increase.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.5
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• pp.559-568
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• 2019

Recently, the infrastructure of the marine environment has been increasing. Therefore, there has been increasing interest in increasing the durability of structures. The FRP Hybrid Bar with improved durability against corrosion was developed in recent years. On the other hand, studies that evaluate the corrosion resistance are insufficient. In this study, the corrosion resistance according to the type of rebar in concrete was assessed and analyzed. The experiment used steel bars and FRP Hybrid Bar. The corrosion test method was a galvanic current and half-cell potential method. The accelerated corrosion test was carried out by four levels (0%, 1.5%, 3%, and 6%) of chloride added to the concrete. The galvanic current measurements revealed no corrosion current in the FRP Hybrid Bar. The half-cell measurement also showed the corrosion resistance of the FRP Hybrid Bar. Therefore. FHB can be used as an alternative steel for structures where a marine environment and steel corrosion are predicted.

• Journal of Power System Engineering
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• v.5 no.3
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• pp.88-94
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• 2001

Stellite 12 alloy-powders were overlaid on 410 stainless steel valve seat using plasma transferred arc(PTA) process. Variation of the microstructure, hardness, wear and corrosion of overlaid deposit with current change was investigated. The deposit showed hypoeutectic microstructure, which was consisted of primary cobalt dendrite and networked $M_7C_3$ type eutectic carbides. As current increased, the amount of eutectic carbide decreased and its dendritic secondary arm spacing increased. Hardness of the deposit was decreased with increase of current. Stress relief heat treatment at $600^{\circ}C$ for two hours resulted in slight increase of hardness in the deposit and showed uniform hardness distribution in base metal without any hardened layer in HAZ. Specific wear decreased with increase of sliding distance. The deposit of high hardness with a lot of eutectic carbide showed relatively low specific wear. Initial corrosion current density of the deposit in 0.1N sulfuric acid was lower than those of 410 stainless steel, and showed a little variation with PTA current.

• Corrosion Science and Technology
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• v.8 no.3
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• pp.93-102
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• 2009

The direct-current electroetching of high purity aluminum in hot aqueous-chloride solution produces a high density of micrometer-wide tunnels whose walls are made up of the {100} planes and penetrate aluminum in the <100> directions at rates of micrometer per second. In the process of the alternating-current pitting of aluminum, cathodic polarization plays an important role in the nucleation and growth of the pits during the subsequent polarization. The direct-current tunnel etching and alternating-current etching of aluminum are basically related to the formation of poorly crystallized or amorphous passive films. If the passive film forms on the wall, a natural misfit exists between the film and the aluminum substrate, which in turn gives rise to stress in both the film and the substrate. Even though the amorphous films do not have directed properties, their stresses are influenced by the substrate orientation. The films on elastically soft substrate are likely to be less stressed and more stable than those on elastically hard substrate. The hardest and softest planes of aluminum are the {111} and {100} planes, respectively. Therefore, the films on the {111} substrates are most likely to be attacked, and those on the {100} substrates are least likely to be attacked. For the tunnel etching, it follows that the tunnel walls tend to consist of the {100} planes. Meanwhile, the tunnel tip, where active corrosion takes place, tend to be made of four closely packed {111} planes in order to minimize the surface energy, which gives rise to the <100> tunnel etching.

• Journal of Advanced Marine Engineering and Technology
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• v.29 no.6
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• pp.654-661
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• 2005

Copper is a well known alloying element that is used to improve the resistance to general corrosion of stainless steel And also Cu cation have the anti-fouling effect to inhibit adhesion of the marine algae and shellfish to the surface of heat exchanger cooling pipe or outside wall of the ship, Therefore there are some anti-fouling methods such as anti-fouling Paint mixed with copper oxide or MGPS(Marine Growth Preventing System) by using Cu cation dissolved to the sea wather solution. Cu cation can be dissolved spontaneously by galvanic current due to Potential difference between Cu and cooling pipe of heat exchanger with Ti material, which may be one of the anti-fouling designs. In this study the effect of annealing heat treatment to galvanic current and Polarization behavior was investigated with a electrochemical points of view such as measurement of corrosion Potential, anodic polarization curve. cyclic voltammetric curve, galvanic current etc The grain size of the surface in annealed at $700^{\circ}C$ was the smallest than that of other annealing temperatures. and also the corrosion Potential showed more positive potential than other annealing temperatures. The galvanic current between Ti and Cu with annealed at $700^{\circ}C$ was the largest value in the case of static condition. However its value in the case of flow condition was the smallest than the other temperatures. Therefore in order to increase anti-fouling effect by Cu cation, the optimum annealing temperature in static condition of sea water is $700^{\circ}C$, however non- heat treated specimen in the case of flow condition may be desirable.

• Advances in materials Research
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• v.13 no.3
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• pp.153-160
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• 2024

This study investigates the application of alternating current (AC) and direct current (DC) anodization techniques on stainless steel 304L (SS304L) in an ethylene glycol and ammonium fluoride (NH4F) electrolyte solution to produce a nano-porous oxide layer. With limited research on AC anodizing of stainless steel, this study focuses on comparing AC and DC anodization in terms of current density versus time response, phase analysis using X-ray diffraction (XRD), and corrosion rate determined by linear polarization. Both AC and DC anodization were performed for 60 minutes at 50 V in an electrolyte solution containing 0.5% NH4F and 3% H₂O in ethylene glycol. The results show that AC anodization exhibited higher current density compared to DC anodization. XRD analysis revealed the presence of ferrite (α-Fe) and austenite (γ-Fe) phases in the as-received specimen, while both AC and DC anodized specimens exhibited only the γ-Fe phase. The corrosion rate of the AC-anodized specimen was measured at 0.00083 mm/year, lower than the corrosion rate of the DC-anodized specimen at 0.00197 mm/year. These findings indicate that AC anodization on stainless steel offers advantages in terms of higher current density, phase transformation, and lower corrosion rate compared to DC anodization. These results highlight the need for further investigation and exploration of AC anodization as a promising technique for enhancing the electrochemical properties of stainless steel.

• Journal of the Korean Applied Science and Technology
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• v.29 no.1
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• pp.88-94
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• 2012

In this study, the current-voltage curves for metals were measured using cyclic voltammetry. The relationship between the electrochemical properties and surface states of metals were investigated by Scanning Electron Microscope (SEM). In cyclic voltammetry, we used a 3-electrode system for the electrochemical measurements. The measurement was conducted at the condition that consists of the first reduction from the initial potential to -1350 mV, continuous oxidation to 1650 mV, and last reduction to the initial potential. The scan rates were 50, 100, 150 and 250 mV/s. The results show the C-V characteristics of metals to be for an irreversible process, which was caused by the oxidation current from cyclic voltammogram, when monoethanolamine (MEA) was used as a corrosion inhibitor. When we used MEA as a corrosion inhibitor, the diffusion coefficient was decreased as the concentration of electrolyte was increased. In the SEM images of copper, we observed an increase of surface corrosion at the increased electrolyte concentration. Addition of $1.0{\times}10^{-3}M$ corrosion inhibitor MEA reduced the effect of corrosion prevention due to the relatively large diffusion coefficient at the electrolyte concentration of 0.1N.

• Journal of Advanced Marine Engineering and Technology
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• v.24 no.5
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• pp.58-68
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• 2000

When SS400 steel was welded with low hydrogen type and ilmennite type welding, the effect of post-weld heat treatment(PWHT) was investigated with parameters such as micro vickers hardness, corrosion potential, polarization behaviors, galvanic current, Al anode generating current and Al anode weight loss etc. Hardness of each parts(HAZ, BM, WM) by PWHT in case of low hydrogen type and ilmennite type welding was lower than that of each parts by As-welded However hardness of WM area in case of low hydrogen type and ilmennite type welding was the highest among those three parts regardless of PWHT, Whereas in case of ilmennite type welding, WM area was the highest potential among these three parts on galvanic potential series with As-welded while BM area was the highest potential among these three parts by PWHT on the contrary. And in case of low hydrogen type welding, galvanic corrosion and micro cell corrosion of welding parts was decreased with PWHT. However, It was increased with PWHT in case of ilmennite type welding. Moreover Al anode generating current and anode weight loss in case of low hydrogen type was decreased by PWHT compared to As-wedled but, which was increased than that of As-welded in case of ilmennite type welding. Therefore, it is suggested that Corrosion resistance property in case of low hydrogen type welding is increased by PWHT. However its property was devreased with PWHT in case of ilmennite type welding.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.38 no.4
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• pp.265-270
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• 2002

Most of all the mechanical devices are becoming more high-speed and high-power as well as their used condition being more pollution with rapid development in industrial part. So, it is necessary for these devices to equip cooling system to overcome that kind of severe using condition. Industrial development and income increase causes rapid increase in using fossilenergy and it results in accelerating environmental pollution owing to the increasement in emission of air pollution substance. Specially, fresh water like stream and river water is acidified. Therefore, corrosion damage is accelerated in radiator for automobile that is using acidified water. So, in this study, corrosion test was carried out in distilled and tap water for the investigation on the corrosion behavior of Al-alloy that is using as material for radiator of automobile The main results obtained are as follows According to increase of temperature, open circuit potential is decreased in fresh water. And open circuit potential after deaeration is lower than that before deaeration. Corrosion current density in distilled water is less drained than that of tap water. And Corrosion current density after deaeration is less drained than that before deaeration.

• Proceedings of the Korea Concrete Institute Conference
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• 1999.10a
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• pp.675-678
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• 1999

Rebar corrosion in concrete containing both chloride ions and calcium nitrite inhibitors were investigated by the various electrochemical methods. Rebar corrosion was accelerated by applying the impressed current to the rebar in concrete. Effect of chloride content and inhibitors on rebar corrosion were evaluated. Accelerated corrosion technique is the method to measure the time to the initiation of cracks of reinforced concretes, by applying constant voltage between rebar and the stainless steel cathedes. The increase of concentration of chloride ions in concrete result in the increase in anodic currents and the reduction of time to crack. However addition of inhibitors did not improve corrosion resistance of rebar in concrete. Rebar corrosion in concrete with chloride ions and inhibitors was also analyzed by the immersed tests though the mesurement of corrosion potentials.