• Title/Summary/Keyword: corrosion area

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Evaluation of Corrosion Resistance and Weldability for the Butt Welding Zone of Hot Rolled Clad Steel Plates (열간압연 클래드강의 맞대기용접부 내식성 및 용접성 평가)

  • Park, Jae-Won;Lee, Chul-Ku
    • Journal of Welding and Joining
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    • v.31 no.5
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    • pp.47-53
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    • 2013
  • We have investigated the traits of clad metals in hot-rolled clad steel plates, including the sensitization and mechanical properties of STS 316 steel plate and carbon steel (A516), under various specific circumstances regarding post heat treatment, multilayered welds, and thick or repeated welds for repair. For evaluations, sectioned weldments and external surfaces were investigated to reveal the degree of sensitization by micro vickers hardness, tensile, and etching tests the results were compared with those of EPR tests. The clad steel plates were butt-welded using FCAW and SAW with the time of heat treatment as the variable, a that was conducted at $625^{\circ}C$, for 80, 160, 320, 640, and 1280 min. Then, the change in corrosion resistance was evaluated in these specimens. With carbon steel (A516), as the heat treatment time increased, the annealing effect caused the tensile strength to decrease. The micro-hardness gradually increased and decreased after 640 min. The elongation and contraction of the area also increased gradually. The oxalic acid etch test and EPR test on STS316 and the clad metal showed STEP structure and no sensitization. From the test results on multi-layered and repair welds, it could be concluded that there is no effect on the corrosion resistance of clad metals. The purpose of this study was to suggest some considerations for developing on-site techniques to evaluate the sensitization of stainless steels.

AN ELECTROCHEMICAL STUDY ON THE OXIDATION' AND REDUCTION OF DENTAL AMALGAM (치과용 아말감의 산화환원에 관한 전기화학적 연구)

  • Yi, In-Bog;Lee, Myong-Jong
    • Restorative Dentistry and Endodontics
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    • v.18 no.2
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    • pp.431-445
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    • 1993
  • The purpose of this study was to observe corrosion characteristics of six dental amalgams and was to analyse corrosion products electrochemically. After each amalgam alloy and Hg was triturated as the direction of the manufacturer by using mechanical amalgamator, the triturated mass was inserted into the cylinderical metal mold ($12{\times}10mm$) and was condensed with 160kg/$cm^2$ by using the hydrolic press. The specimen was removed from the mold and was stored at room temperature for 1 week, and was polished with amalgam polishing kit. The anodic and cathodic polarization curve was obtained by using cyclic voltammetric method with 3-electrode potentiostat in saline for each amalgam and Ag, Sn, Cu plate specimen at $37{\pm}0.5^{\circ}C$. The potential sweep range was -1.7V~0. 4V(vs SCE) in working electrode and scan rate was 50mV/s and the exposed surface area of each specimen to the electrolytic solution was $0.79cm^2$. The results were as follows. 1. In anodic-cathodic polarization curve of amalgam specimens, two anodic current rising areas and two cathodic current peaks were obtained at the low Cu amalgam(CF, CS) specimen and three anodic current rising areas and three cathodic current peaks were obtained at the high Cu amalgam (TY, DS, HV) specimen. 2. As this compared with the anodic and cathodic current peak potentials of Sn, Cu and Ag specimen, the first cathodic current peak I c was caused by the reduction of divalent tin salt, second cathodic current peak IIIc results from the reduction of quadravalent tin salt, and third cathodic current peak me results from the reduction of copper salt. 3. As reverse potential sweeping was done repeatedly, anodic current was decreased slightly in all amalgam specimens.

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A Study on the Development of Prediction System for Pipe Wall Thinning Caused by Liquid Droplet Impingement Erosion (액적충돌침식으로 인한 배관감육 예측체계 구축에 관한 연구)

  • Kim, Kyung-Hoon;Cho, Yun-Su;Hwang, Kyeong-Mo
    • Corrosion Science and Technology
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    • v.12 no.3
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    • pp.125-131
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    • 2013
  • The most common pipe wall thinning degradation mechanisms that can occur in the steam and feedwater systems are FAC (Flow Acceleration Corrosion), cavitation, flashing, and LDIE (Liquid Droplet Impingement Erosion). Among those degradation mechanisms, FAC has been investigated by many laboratories and industries. Cavitation and flashing are also protected on the piping design phase. LDIE has mainly investigated in aviation industry and turbine blade manufactures. On the other hand, LDIE has been little studied in NPP (Nuclear Power Plant) industry. This paper presents the development of prediction system for pipe wall thinning caused by LDIE in terms of erosion rate based on air-water ratio and material. Experiment is conducted in 3 cases of air-water ratio 0.79, 1.00, and 1.72 using the three types of the materials of A106B, SS400, and A6061. The main control parameter is the air-water ratio which is defined as the volumetric ratio of water to air (0.79, 1.00, 1.72). The experiments were performed for 15 days, and the surface morphology and hardness of the materials were examined for every 5 days. Since the spraying velocity (v) of liquid droplets and their contact area ($A_c$) on specimens are changed according to the air-water ratio, we analyzed the behavior of LDIE for the materials. Finally, the prediction equations(i.e. erosion rate) for LDIE of the materials were determined in the range of the air-water ratio from 0 to 2%.

Development and Application of Dry Process Caisson for Maintenance of Submerged Barber Structure

  • Lee, Joong-Woo;Lee, Seung-Chul;Oh, Dong-Hoon;Kwak, Seung-Kyu;Lee, Jeong-Su
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2006.10a
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    • pp.105-114
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    • 2006
  • Together with the trend of enhancement in domestic industrial development and economic progress due to import and export, the demand for construction of the roads, bridges, especially port facilities, and several coastal protection and ocean structures is increasing rapidly. MOMAF of Korean Government is driving construction of 9 new ports and renovation of the existing fishery ports. Among these structures most of bridge base, wharves, dolphins, quays, and jetties are being newly built of steel or concrete pile. As the base, supporting bulkheads, and piles are underwater after construction, it is difficult to figure out the status of structures and not enough to get maintenance and strengthen the structures. Every year, moreover, these works suck the government budget due to higher incomplete maintenance expense for protection from corrosions of structures and increased underwater construction period. for the purpose of cutting down the government budget, it is necessary to extend the life cycle of the existing structures. We developed a new method for maintenance of submerged structures near the waterline by allowing dry work environment with the floating caisson. The method shows easy to move around the working area and handle. It also showed not only a significant reduction of maintenance expenses and time for anti-corrosion work but also better protection. This will be a milestone to reduce the maintenance and construction expenses for the shore and water structures.

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A Study of Weldability for Pure Titanium by Nd:YAG Laser(III) - Weld Properties of Edge Welding - (순티타늄판의 Nd:YAG 레이저 용접성에 관한 연구(III) - 에지 용접 특성 -)

  • Kim, Jong-Do;Kil, Byung-Lea;Kwak, Myung-Sub;Song, Moo-Keun
    • Journal of Welding and Joining
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    • v.27 no.6
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    • pp.74-79
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    • 2009
  • Titanium and titanium alloy can be reproduced immediately even if oxide films($TiO_2$) break apart in sea water. Therefore, since titanium demonstrates large specific strength and outstanding resistance to stress corrosion cracking, crevice corrosion, pitting and microbiologically influenced corrosion in sea water environment, it has been widely applied to heat exchanger for ships. In particular, with excellent elongation, pure titanium may be deemed as optimal material for production of heat exchanger plate which is used with wrinkles formed for efficient heat exchange. Conventional plate type heat exchanger prevented leakage of liquid through insertion of gasket between plates and mechanical tightening by bolts and nuts, but in high temperature and high pressure environment, gasket deterioration and leakage occur, so heat exchanger for LPG re-liquefaction device etc do not use gasket but weld heat exchanger plate for use. On the other hand, since welded plate cannot be separated, it is important to obtain high quality reliable welds. In addition, for better workability and production performance, lasers that can obtain weldment with large aspect ratio and demonstrate fast welding speed even in atmospheric condition not in vacuum condition are used in producing products. So far, 1st report and 2nd report compared and analyzed embrittlement degrees by bead colors of weldment through quantitative analysis of oxygen and nitrogen and measurement of hardness as fundamental experiment for the evaluation of titanium laser welding, and evaluated the welding performance and mechanical properties of butt welding. This study welded specimens in various conditions by using laser and GTA welding machine to apply edge welding to heat exchanger, and evaluated the mechanical strength through tensile stress test. As a result of tensile test, laser weldment demonstrated tensile strength 4 times higher than GTA welds, and porosity could be controlled by increasing and decreasing slope of laser power at overlap area.

Investigating the Cause of Ash Deposition and Equipment Failure in Wood Chip-Fueled Cogeneration Plant (우드칩을 연료로 하는 열병합발전소의 회분 퇴적 및 설비 고장 원인 분석)

  • Min Ji Song;Woo Cheol Kim;Heesan Kim;Jung-Gu Kim;Soo Yeol Lee
    • Corrosion Science and Technology
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    • v.22 no.3
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    • pp.187-192
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    • 2023
  • The use of biomass is increasing as a response to the convention on climate change. In Korea, a method applied to replace fossil fuels is using wood chips in a cogeneration plant. To remove air pollutants generated by burning wood chips, a selective denitrification facility (Selective catalytic reduction, SCR) is installed downstream. However, problems such as ash deposition and descaling of the equipment surface have been reported. The cause is thought to be unreacted ammonia slip caused by ammonia ions injected into the reducing agent and metal corrosion caused by an acidic environment. Element analysis confirmed that ash contained alkali metals and sulfur that could cause catalyst poisoning, leading to an increase in the size of ash particle and deposition. Measurement of the size of ash deposited inside the facility confirmed that the size of ash deposited on the catalyst was approximately three times larger than the size of generally formed ash. Therefore, it was concluded that a reduction in pore area of the catalyst by ash deposition on the surface of the catalyst could lead to a problem of increasing differential pressure in a denitrification facility.

Effects of Plastic Deformation on Surface Properties and Microstructure of Alloy 690TT Steam Generator Tube (증기발생기 전열관 Alloy 690TT의 소성변형이 표면특성 및 미세조직에 미치는 영향)

  • Soon-Hyeok Jeon;Ji-Young Han;Hee-Sang Shim;Sung-Woo Kim
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.20 no.1
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    • pp.16-24
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    • 2024
  • Denting of steam generator (SG) tube is defined as the reduction in tube diameter due to the stresses exerted by the corrosion products formed on the outer diameter surface. This phenomenon is mostly observed in the crevices between SG tube and the top-of tubesheet or tube support plate. Despite the replacement of SG tube with Alloy 690, which has better corrosion resistance than Alloy 600, the denting of SG tube still remains a potential problem that could decrease the SG integrity. Deformation of SG tube by denting phenomenon can affect the surface properties and microstructure of SG tube. In this study, the effects of plastic deformation on surface properties and microstructure of Alloy 690 thermally treated (TT) tube was investigated by using the various analysis techniques. The plastic deformation of Alloy 690 increased the surface roughness and area. Many surface defects such as ripped surface and micro-cracks were observed on the deformed Alloy 690TT specimen. Based on the electron backscatter diffraction analysis, the dislocation density of deformed SG tube increased compared to non-deformed SG tube. In addition, the effects of changes in surface properties and microstructure of SG tube on general corrosion behavior were discussed.

A Study on Residual Stress Reduction Effect of Cold Spray Coating to Improve Stress Corrosion Cracking of Stainless Steel 304L and 316L Welds (STS304L 및 STS316L 용접부의 응력 부식 균열 개선을 위한 저온 분사 코팅의 잔류 응력 감소 효과에 대한 연구)

  • Kwang Yong Park;Deog Nam Shim;Jong Moon Ha;Sang Dong Lee;Sung Woo Cho
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.19 no.2
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    • pp.102-108
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    • 2023
  • A Chloride-induced stress corrosion cracking (CISCC) of austenite stainless steel in dry cask storage system (DCSS) can occur with extending service time than originally designed. Cold spray coating (CSC) not only form a very dense microstructure that can protect from corrosive environments, but also can generate compressive stress on the surface. This characteristic of CSC process is very helpful to increase the resistance for CISCC. CSC with several powders, such as 304L, 316L and Ni can be optimized to form very dense coating layer. In addition, the impact energy generated as the CSC powder collides with the surface of base metal at a speed of Mach 2 or more can remove the residual tensile stress of welding area and serve the compress stress. CSC layers include no oxidation and no contamination with under 0.2% porosity, which is enough to protect from the penetration of corrosive chloride. Therefore, the CSC coating layer can be accompanied by a function that can be disconnected from the corrosive environment and an effect of improving the residual stress that causes CISCC, so the canister's CISCC resistance can be increased.

국립공원 월악산 지역의 지형관광자원에 대한 연구

  • 김종은
    • Journal of Applied Tourism Food and Beverage Management and Research
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    • v.13 no.2
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    • pp.207-221
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    • 2002
  • Wolaksan is a national park which has beautiful scenery with exposed rocks. The mountain is 1097 meters high and has 3 tops which are Jungang(the center), Arae(the lower part), Jjokduri. The highest point of the vertical cliff is 150m from the earth and the total circumferences of three tops is about 4km. These tops are easy to break by grains because they are from sedimentary rocks. Wolaksan is a bad mountain because the area is a Mosikjuk rocky area. However, the area around Wolaksan is thicky wooded and has many achievements and it makes good scenery. From top to southeastern, there are vertical cliff, The tops are originally from one but these are divided by partial weathering corrosion. The slide of path to Wolaksan is about 70。. The lower part of the mountain from Shinroksa to top has a gentle slope but there are a steep slope from the middle. Especially, the area has many rocks. The rocks of Wolaksan are almost granitic-gneiss or metamorphic rocks so it often fall down. Because of these fallen rocks, its valleys have great landscapes. The size of rock is less than 60cm. The landscapes of valleys such as Songgye, Dukju, Yonghwa are the main natural tourism resources.

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Estimation Method of Local Elastic-Plastic Strain at Thinning Area of Straight Pipe Under Tension Loading (인장하중을 받는 직선 배관 감육부의 국부 탄소성 변형률 평가 방법)

  • An Joong-Hyok;Kim Yun-Jae;Yoon Kee-Bong;Ma Young-Wha
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.30 no.5 s.248
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    • pp.533-542
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    • 2006
  • In order to assess the integrity of pipes with local thinning area, the plastic strain as well as the elastic strain at the root of thinned region are required particularly when fluctuating load is applied to the pipe. For estimating elastic-plastic strain at local wall thinning area in a straight pipe under tensile load, an estimation model with idealized fully circumferential constant depth wall thinning area is proposed. Based on the compatibility and equilibrium equations a nonlinear estimation equation, from which local elastic-plastic strain can be determined as a function of pipe/defect geometry, material and the applied strain was derived. Estimation results are compared with those from detailed elastic-plastic finite element analysis, which shows good agreements. Noting that practical wall thinning in nuclear piping has not only a circular shape but also a finite circumferential length, the proposed solution for the ideal geometry is extended based on two-dimensional and three-dimensional numerical analysis of pipes with circular wall thinning.