• Title/Summary/Keyword: corrosion area

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Evaluation on the Characteristics of Stress Corrosion Cracking for the Weldment of HT-60 Steel under Applied Potentials (인가전위 하에서 HT-60강 용접부의 SCC특성 평가)

  • Na, Ui-Gyun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.5
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    • pp.896-903
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    • 2002
  • The susceptibility of SCC for the weldment and PWHT specimens of HT-60 steel was evaluated using a slow strain rate method under applied potential by means of the potentiostat in synthetic seawater. In case of the parent, anodic polarization voltage was inappropriate in elongating the time to failure(TTF). -0.8V corresponding to cathodic protection range is most effective in improving the SCC resistance against corrosive environment. In case of the weldment, the values of reduction of area(ROA) and TTF at -0.68V corresponding to cathodic polarization value were 45.2% and 715,809sec which were the largest and longest life among other applied potentials. Those were vise versa at -1.1V. In case of the PWHT specimens, TTF and ROA at -0.68V was longest and largest like the weldment. Besides, PWHT is effective in prolonging the time to failure of the welded off-shore structure due to softening of effect. Regardless of the weldment and PWHT specimen, as corrosion rate gets higher, TTF becomes shorter and deformation behaviour for the weldment and PWHT specimen at -1.1V was shown to be irregular. Finally, it was found that specimens showed brittle fracture at -1.1V, but more ductile fracture accompanying the micro-cracks at applied potential of -0.68V.

Enhancing the Reliability of Coating Flaw Detection for Pipes Buried in Soil Using a Multi-Electrode Detector (다전극 탐상을 통한 토중 매설배관 피복결함 탐상 정확도의 개선)

  • Kim, M.G.;Lim, B.T.;Kim, K.T.;Chang, H.Y.;Park, H.B.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.19 no.5
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    • pp.265-280
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    • 2020
  • External corrosion of buried pipes can be controlled using both coating and cathodic protection. However, deterioration of the coating can occur due to several reasons. The detection reliabilty of coating flaw detection methods is affected by interference such as metal objects connected to rectifiers and copper grids. When performing parallel direct current voltage gradient (DCVG) inspection, a sine wave form without potential reversal in voltage gradient appears in the area where the interference exists. However, this area may be not identified using existing methods. The objective of this study was to determine the effect of analyzing direction on the reliability of coating flaw detection of pipes buried in soil using a multi-electrode detector. DCVG on the buried pipe was measured along the buried pipe. This measurement parallel to the pipe was repeated. Measured data were analyzed for parallel, vertical, and diagonal directions. The reliability of coating flaw detection was improved by up to 46.4% compared to the conventional method.

Performance Evaluation of Repair Methods for RC structures by Accelerating Test in Combined Deterioration Chamber and Long-Term Field Exposure Test (복합열화촉진실험 및 장기현장폭로실험에 의한 RC구조물 보수공법의 보수성능평가)

  • Kwon Young-Jin;Kim Jae-Hwan;Han Byung-Chan;Jang Seung-Yup
    • Journal of the Korean Society for Railway
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    • v.9 no.4 s.35
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    • pp.349-356
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    • 2006
  • At present, the selecting system and analytic estimation criterion on repair materials and methods of the deteriorated RC structures have not yet been set up in domestic. Under these circumstances, deterioration such as shrinkage crack, corrosion of rebar has been often occurred after repair, and this finally results in too frequent repairs. In this study, three types of repair methods were experimentally investigated by the accelerating test in a combined deterioration chamber and long-term field exposure test. Three types of repair methods applied in this study belong to a group of polymer cement mortar, which is commonly used in repair works. According to the results of this study, durability of repair mortar layers and corrosion properties of recovered rebar could be investigated in short period by the accelerating test in a combined deterioration chamber, which can simulate the condition of repeated high-and-low temperature and repeated dry-and-wet environment, spraying chloride solution and emitting $CO_2$ gas. After 36 month long-term filed exposure test in the coastal area, harmful macro-cracks are observed in the polymer cement mortar layer of some repair methods. These crack are considered to result from drying shrinkage of polymer cement mortar. Also, after 36 month exposure, amount of corrosion area and weight loss of rebar are found to be different according to the types of repair methods.

Characteristics of Cavitation-Erosion Damage with Amplitude in Seawater of 5052-O Al Alloy for Ship (선박용 5052-O 알루미늄 합금의 해수 내 진폭 변수에 따른 캐비테이션-침식 손상 특성)

  • Yang, Ye-Jin;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.19 no.5
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    • pp.239-249
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    • 2020
  • The characteristics of cavitation-erosion damage with changes in the amplitude of 5052-O aluminum alloy for ships were investigated in a seawater environment. In the cavitation-erosion experiment, the cavitation environment was created using a vibration-generating device with a piezo-electric effect. The amplitudes of 5 ㎛, 10 ㎛, and 30 ㎛ were created by changing the geometric shape of the cavitation horn. The resistance characteristics of cavitation-erosion damage were evaluated by weight loss and pitting area. The damaged surface was analyzed using scanning electron microscopy (SEM) and 3D optical microscopy. As the amplitude increased, the amount of damage and the area of the damaged surface increased, and the damage was concentrated at the center and edge of the specimen. The pit was created after the initial incubation period with increasing experimental time, and then the pits were merged to grow and propagate into craters, and eventually, the surface was detached and damaged. The cavitation-erosion damage after 30 minutes with amplitude of 10 ㎛ and 30 ㎛ was 1.48 and 2.21 times compared to 5 ㎛, respectively.

Characterization of Phosphorus Removal in Wastewater Using Iron Precipitation Reactor (철 석출장치에 의한 폐수 중의 인 제거 특성)

  • Cho Il-Hyoung;Zoh Kyung-Duk;An Sang-Woo;Chang Soon-Woong;Kim Young-Kyu
    • Journal of Environmental Health Sciences
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    • v.32 no.1 s.88
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    • pp.89-95
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    • 2006
  • This study was conducted to improve an effect of phosphorus removal using FNR(Ferrous Nutrient Removal) process which had iron precipitation reactor and to analyze the iron corrosion. For simultaneous removal of phosphorus, iron electrolysis was combined with oxic tank. In this study, The removal efficiency of phosphorus increased with an increase voltage in iron precipitation reactor. The distance of 15mm between the two iron bed in each tests influence the concentration of remaining phosphorus most. The extensive surface area of iron bed is the more removes the phosphorus. In this test the $400\;cm^2$ of surface area was proved to be the most removal efficient.

Design and Synthesis of Multi Functional Noble Metal Based Ternary Nitride Thin Film Resistors

  • Kwack, Won-Sub;Choi, Hyun-Jin;Lee, Woo-Jae;Jang, Seung-Il;Kwon, Se-Hun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.93-93
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    • 2013
  • In recent years, multifunctional ternary nitride thin films have received extenstive attention due to its versatility in many applications. In particular, noble metal based ternary nitride thin films showed a promising properties in the application of Multifunctional heating resistor films because its good electrical properties and excellent resistance against oxidation and corrosion. In this study, we prepared multifunctional noble metal based ternary nitride thin films by atomic layer deposition (ALD) and plasma-enhanced ALD (PEALD) method. ALD and PEALD techniques were used due to their inherent merits such as a precise composition control and large area uniformity, which is very attractive for preparing multicomponent thin films on large area substrate. Here, we will demonstrate the design concept of multifunctional noble metal based ternary thin films. And, the relationship between microstructural evolution and electrical resistivity in noble metal based ternary thin films will be systemically presented. The useful properties of noble metal based ternary thin films including anti-corrosion and anti-oxidation will be discussed in terms of hybrid functionality.

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Characteristics in Paintability of Advanced High Strength Steels

  • Park, Ha Sun
    • Corrosion Science and Technology
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    • v.6 no.3
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    • pp.83-89
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    • 2007
  • It is expected that advanced high strength steels (AHSS) would be widely used for vehicles with better performance in automotive industries. One of distinctive features of AHSS is the high value of carbon equivalent (Ceq), which results in the different properties in formability, weldability and paintability from those of common grade of steel sheets. There is an exponential relation between Ceq and electric resistance, which seems also to have correlation with the thickness of electric deposition (ED) coat. Higher value of Ceq of AHSS lower the thickness of ED coat of AHSS. Some elements of AHSS such as silicon, if it is concentrated on the surface, affect negatively the formation of phosphates. In this case, silicon itself doesn't affect the phosphate, but its oxide does. This phenomenon is shown dramatically in the welding area. Arc welding or laser welding melts the base material. In the process of cooling of AHSS melt, the oxides of Si and Mn are easily concentrated on the surface of boundary between welded and non‐welded area because Si and Mn could be oxidized easier than Fe. More oxide on surface results in poor phosphating and ED coating. This is more distinctive in AHSS than in mild steel. General results on paintability of AHSS would be reported, being compared to those of mild steel.

A multiscale numerical simulation approach for chloride diffusion and rebar corrosion with compensation model

  • Tu, Xi;Li, Zhengliang;Chen, Airong;Pan, Zichao
    • Computers and Concrete
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    • v.21 no.4
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    • pp.471-484
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    • 2018
  • Refined analysis depicting mass transportation and physicochemical reaction and reasonable computing load with acceptable DOFs are the two major challenges of numerical simulation for concrete durability. Mesoscopic numerical simulation for chloride diffusion considering binder, aggregate and interfacial transition zone is unable to be expended to the full structure due to huge number of DOFs. In this paper, a multiscale approach of combining both mesoscopic model including full-graded aggregate and equivalent macroscopic model was introduced. An equivalent conversion of chloride content at the Interfacial Transition Layer (ITL) connecting both models was considered. Feasibility and relative error were discussed by analytical deduction and numerical simulation. Case study clearly showed that larger analysis model in multiscale model expanded the diffusion space of chloride ion and decreased chloride content in front of rebar. Difference for single-scale simulation and multiscale approach was observed. Finally, this paper addressed some worth-noting conclusions about the chloride distribution and rebar corrosion regarding the configuration of rebar placement, rebar diameter, concrete cover and exposure period.

A Stress Analysis of Feeedwater Heater Shell in Nuclear Power Plant (원전 급수가열기 동체 응력 해석)

  • Song, Seok-Yoon;Kim, Hyung-Nam
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.11 no.1
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    • pp.1-11
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    • 2015
  • Feedwater Heaters are important components in a nuclear power plant. As the age of heater increases, the maintenance cost required for continuous operation also increases. Most heaters have the carbon steel shells, tube support plates and flow baffles. The carbon steel is susceptible to flow-accelerated corrosion. This is especially true if the flow has a two-phase mixture of steam and condensate. The wall thinning around the wet steam entrance area of the shell is inevitable during some long term operation. The structural integrity of the feedwater heater shell affects the safe operation of the nuclear power plant. Therefore, it is needed for the thinned shell to be repaired. The maintenance method for preventing failure of the shell should be determined by investigating various factors including the stress distribution of thinned area. The stress analysis of the shell including the steam entrance region is studied in this paper. The results of thinned shell is compared with that of intact shell.

Evaluation of STS 430 and STS 444 for SOFC Interconnect Applications

  • Kim, S.H.;Huh, J.Y.;Jun, J.H.;Kim, D.H.;Jun, J.H.
    • Corrosion Science and Technology
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    • v.6 no.1
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    • pp.1-6
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    • 2007
  • Ferritic stainless steels for the SOFC interconnect applications are required to possess not only a good oxidation resistance, but also a high electrical conductivity of the oxide scale that forms during exposure at the SOFC operating environment. In order to understand the effects of alloying elements on the oxidation behavior of ferritic stainless steels and on the electrical properties of oxide scales, two kinds of commercial ferritic stainless steels, STS 430 and STS 444, were investigated by performing isothermal oxidations at $800^{\circ}C$ in a wet air containing 3% $H_{2}O$. The results showed that STS 444 was superior to STS 430 in both of the oxidation resistance and the area specific resistance. Although STS 444 contained a less amount of Mn for the $(Mn,Cr)_{3}O_{4}$ spinel formation than STS 430, the minor alloying elements of Al and Mo in STS 444, which were accumulated in the base metal region adjacent the scale, were suggested to reduce the scale growth rate and to enhance the scale adherence to the base metal.