• Korean Journal of Materials Research
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• v.8 no.8
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• pp.685-692
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• 1998

Since a wet-seal area of Molten Carbonate Fuel Cell (MCFC) operated at $650^{\circ}C$ is exposed to severe environment, a life-time of MCFC is influenced by the corrosion resistance of separator. In order to improve corrosion resistance of 316L stainless steel used as separator material, AI- base alloy such as NiAI has been widely used as coat¬ing material on the wet-seal area. The purpose of this work is to develope a more protective coating material by adding yttrium on NiAI alloy. An immersion test and a polarization test were performed in molten carbonate salt at $650^{\circ}C$ to estimate corrosion resistance of the NiAI alloy and the NiAl/Y alloys with up to L5at% yttrium. NiAl/Y alloys showed better corrosion resistance than NiAI alloy. We found that more than 0.7 at% yttrium was required to improve the corrosion resistance of NiAI alloy in molten carbonate salt at $650^{\circ}C$.

• Corrosion Science and Technology
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• v.17 no.3
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• pp.109-115
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• 2018

Electrical Resistance Welding (ERW) on a longitudinal seam-welded pipe has been extensively used in oil and gas pipelines. It is well known that the weld zone commonly suffers from grooving corrosion in ERW pipes. In this paper, the grooving corrosion performances of API X65 grade non-sour service (steel-A) and API X70 grade sour gas resistant (steel-B) steel electrical resistance welding pipelines were evaluated. The microstructure of the bondline is composed of coarse polygonal ferrite grains and several elongated pearlites. The elongated pattern is mainly concentrated in the center of the welded area. The grooving corrosion test and electrochemical polarization test were conducted to study the corrosion behavior of the given materials. A V-shaped corrosion groove was found at the center of the fusion zone in both the steel-A and steel-B ERW pipes, as the corrosion rate of the bondlines is higher than that of the base metal. Furthermore, the higher volume fraction of pearlite at the bondline was responsible for the higher corrosion rate at the bondline of both types of steel.

• Structural Engineering and Mechanics
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• v.42 no.4
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• pp.531-549
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• 2012

Numerous oil tanker losses have been reported and one of the possible causes of such casualties is caused by the structural failure of aging ship hulls in rough weather. In aging ships, corrosion and fatigue cracks are the two most important factors affecting structural safety and integrity. This research is about effect on hull girder ultimate strength behavior of double hull oil tanker according to corrosion after Part I: stiffened panel. Based on corrosion data of Part I (time-dependent corrosion wastage model and CSR corrosion model), when progressing corrosion of fourtypes of double hull oil tankers (VLCC, Suezmax, Aframax, and Panamax), the ultimate strength behavior of hull girder is compared and analyzed. In case of the ultimate strength behavior of hull girder, when occurring corrosion, the result under vertical and horizontal bending moment is analyzed. The effect of time-dependent corrosion wastage on the ultimate hull girder strength as well as the area, section modulus, and moment of inertia are also studied. The result of this research will be useful data to evaluate ultimate hull girder strength of corroded double hull oil tanker.

• Journal of the Korea Institute of Building Construction
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• v.4 no.1
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• pp.119-126
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• 2004

Generally, reinforced concrete is one of the most commonly used structural materials and it prevents corrosion of steel bar by high pH of interior, But, as time elapsed, reinforced concrete structure become deteriorated by many of combined deterioration factors and environmental conditions. And, there are large number of deteriorate mechanism of the reinforced concrete structure and it acts complexly. It is recognized that steel bar corrosion is the main distress behind the present concern regarding concrete durability. In this study, to institute combined deterioration environments, established acceleration condition and cycle for combined deterioration environments has a resemblance to environments which are real structures placed. After that to confirm corrosion properties of reinforced concrete due to permeability with covering depth and types of surface cover under combined deterioration environments, measured carbonation velocity coefficients, chloride ion diffusion coefficients, water absorption coefficients, air permeability coefficients and electric potential, corrosion area ratio, weight reduction, corrosion velocity of steel bar. The results showed that an increase in age also decrease carbonation velocity coefficients, increase Chloride ion diffusion coefficients and increases water absorption coefficients. As well, an increase in age also increases corrosion of steel bar. Data on the development of corrosion velocity of steel bar with types of surface cover made with none, organic B, organic A, inorganic B, and inorganic A is shown. As well, permeability and corrosion velocity of steel bar with covering depth is superior to 10mm than 20mm. And it is confirmed permeability and corrosion properties of steel bar are closely related.

• The Journal of the Petrological Society of Korea
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• v.16 no.2 s.48
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• pp.47-58
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• 2007

This study examines the distribution of basement rocks in Gyochon-ri, Muan-eup, Muan-gun, Jeonnam where ground subsidence occurred in June 2005, and traces corrosion of limestone. Mica schist and rhyolite are distributed in the surface of the study area, but thick limestone layer with large and small caverns are distributed underground. A horizon of limestone with maximum width of 300 m and 4 km of length was found along the detour which is in the north of pound subsidence. Such identification of limestone presence would be very useful to predict potential ground subsidence. Limestone in this area was disturbed by fold and fault due to severe shearing deformation. Small caverns were frequently found in anticline part of folds formed in limestone layer. Schists with different thicknesses were intercalated in the limestone with shearing deformation and consist of sheet silicate minerals (chlorite and mica) and quartz. In sections of weathered specimen, it is shown that biotite of schist part was altered into chlorite and corrosion of calcite around the schist followed. This suggest that ground water permeated between intercalated sheet silicate minerals and corrosion of limestone began. And small caverns were generated where active corrosion occurred. This study suggests that because of many reasons (for instance, reclamation of the Bulmu reservior and excess pumping), cavern water level was lowered and cave sediments were removed, and it caused ground subsidence to occur.

• Journal of Korean Society of Water and Wastewater
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• v.32 no.3
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• pp.235-242
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• 2018

Corrosion inhibitors including calcium hydroxide have been used to prevent corrosion in the pipes for tap water supply. The corrosion index (i.e., Langelier Index) differs by area and water quality. The corrosion indices of the areas studied differed by more than 2.0. The 'homogenized' calcium hydroxide was added to the treated water at the K water treatment plant, in order to increase the value of the corrosion index and the concentration of calcium. As the result, the concentration of calcium was increased while the turbidity and pH changed little. The corrosion rate of the tap water with the 'homogenized' calcium hydroxide could be slowed down pretty much. The results suggested that the technology of 'homogenization' of calcium hydroxide can applied to tap water and desalinated water to prevent corrosion in water pipes even in corrosive pipes.

• Corrosion Science and Technology
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• v.12 no.6
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• pp.280-287
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• 2013

Flow accelerated corrosion(FAC) of the carbon steel piping in pressurized water reactors(PWRs) has been major issue in nuclear industry. Severe accident at Surry Unit 2 in 1986 initiated the worldwide interest in this area. Major parameters influencing FAC are material composition, microstructure, water chemistry, and hydrodynamics. Qualitative behaviors of FAC have been well understood but quantitative data about FAC have not been published for proprietary reason. In order to minimize the FAC in PWRs, the optimal method is to control water chemistry factors. Chemistry factors influencing FAC such as pH, corrosion potential, and hydrazine contents were reviewed in this paper. FAC rate decreased with pH up to 10 because magnetite solubility decreased with pH. Corrosion potential is generally controlled dissolved oxygen (DO) and hydrazine in secondary water. DO increased corrosion potential. FAC rate decreased with DO by stabilizing magnetite at low DO concentration or by formation of hematite at high DO concentration. Even though hydrazine is generally used to remove DO, hydrazine itself thermally decomposed to ammonia, nitrogen, and hydrogen raising pH. Hydrazine could react with iron and increased FAC rate. Effect of hydrazine on FAC is rather complex and should be careful in FAC analysis. FAC could be managed by adequate combination of pH, corrosion potential, and hydrazine.

• The Journal of Korean Academy of Prosthodontics
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• v.39 no.4
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• pp.336-350
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• 2001

The purpose of this study was to investigate corrosion tendency and to compare corrosion resistance of three dental magnetic attachments and its keeper alloy by coercive, electrochemical method. By using petentiodynamic polarization technique, magnetic elements and its keeper alloy of Magfit EX600 system(MF, MFK), Dyna ES regular system(DN, DNK) and Shiner SR magnet system(SR, SRK) were corroded electrochemically in 0.9% NaCl electrolytic solution. Open-circuit potential and anodic polarization curve was measured with Potentiostat(model 273 EG&E) and polarization curve was created by current density per square area following scanning of increased series of voltage in the rate of 1.0mV per second. Before and after electrochemical corrosion, the surface roughness test was done. Thereafter the change of mean surface roughness value(Ra) and mean peak value(Rt) of surface roughness was compared one another. In order to observe the corroded surface of each specimen, metallurgical light microscopic(${\times}37.5$) and scanning electron microscopic view(SEM ${\times}100$) was taken and compared one another. Conclusion is followings. 1. All of six covering metal of dental magnetic attachments and its keeper alloy were corroded in various degree after electrochemical corrosion. 2. The corrosion resistance of which used in this experiment is the following in high order; DNK, MFK, DN, MF, SRK and SR. 3. Especially Shiner magnet system and its keeper alloy were more severely corroded after electrochemical corrosion and the change of Ra Rt value were more increased than others. 4 Metallurgical and scanning electron microscopic view showed the pitting corrosion tendency of all experimental alloy but DNK and SR. 5. Covering metal of magnet was more corroded than its keeper alloy.

• Corrosion Science and Technology
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• v.17 no.6
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• pp.287-291
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• 2018

In this study, corrosion behavior of a SA178-A alloy used in the boiler tube of a district heating system was investigated in different environments where it was exposed to pure water, district heating (DH) water, and filtered district heating (FDH) water. After the corrosion test, the surface morphology was examined for observation of the number of pitting sites and pitting area fraction, using a scanning electron microscope. The DH water and FDH water conditions resulted in a lower corrosion potential and pitting potential, and revealed a significantly higher corrosion rate than the pure water condition. The pitting sites in the DH water (pH 9.6) were approximately eighteen times larger than those in the pure water (pH 9.6). Compared to the DH water, the corrosion potential became more noble in the FDH water condition, where iron ions were reduced through filtration. However, the corrosion rate increased in the FDH water due to an increased concentration of chloride ions, which deteriorated the stability of passive film.

• Journal of Power System Engineering
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• v.19 no.5
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• pp.38-44
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• 2015

The cold-rolled steel sheet for automobile is liable to corrosion, and will be painting in a variety of ways for the anticorrosive. This paper was coated on cold rolled steel (SPCC and SPFC590) for automobiles using five kinds of organic/inorganic hybrid solution. This was evaluated corrosion resistance and so on by the salt spray. Corrosion area was less according to increasing of curing time in 2 types of steel plate with 5 types of the coating solution. No.1 solution was showed the best corrosion resistance regardless of the kinds of the steel sheet. It is judged that the melamin hardner had the role of bridge between $SiO_2$ polysilicate and urethan resin. Other properties were excellent in all solution.