• Title/Summary/Keyword: corrosion area

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Effect of Area Ratio on Galvanic Corrosion Between Metallic Materials and GECM in 3.5% NaCl Solution (3.5% NaCl 수용액 중에서의 금속과 GECM의 갈바닉 부식에 미치는 면적비의 영향)

  • Kim, Y.S.;Lim, H.K.;Sohn, Y.I.;Yoo, Y.R.;Chang, H.Y.
    • Corrosion Science and Technology
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    • v.9 no.1
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    • pp.39-47
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    • 2010
  • Galvanic coupling between GECM(graphite epoxy composite material) and metallic materials can facilitate corrosion of metals and alloys because GECM is noble and electrically conductive. Galvanic corrosion is affected by many factors including metallic materials, area ratio, surface condition, and corrosivity. This work aims to evaluate the effect of area ratio on galvanic corrosion between GECM and several metals. In the case of glavanic coupling of carbon steel and Al to GECM, corrosion rate increased with increasing area ratio. Corrosion rate of sensitized STS 316S stainless steel decreased a little at an area ratio 1:1 but increased at an area ratio 30:1. It is considered to be due to that area ratio affects galvanic corrosion more in less corrosion resistant alloys. However, in case of STS 316 and Ti, galvanic coupling reduces corrosion rate by the formation of passive film.

The Effects of pH on the Corrosion Characteristics in Dissimilar Friction Welded Zone of IN713LC-SCM440 (IN713LC-SCM440 이종재 마찰용접부의 부식특성에 미치는 pH의 영향)

  • JO SANG-KEUN;KONG YU-SIK;KIM YOUNG-DAE
    • Journal of Ocean Engineering and Technology
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    • v.19 no.2 s.63
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    • pp.53-59
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    • 2005
  • The effect of pH on the corrosion characteristics in the dissimilar friction welded zone of IN713LC-SCM440 in the loaded torsional stress was studied. The corrosion experiment was performed for 120 hours on the specimens with five steps of pH. The surface corrosion pattern of the SCM440 area showed global corrosion and narrow pitting, which was caused by galvanic corrosion between friction welded IN713LC and SCM440, but corrosion did not proceeded from the IN713LC area. The average relative electrode potential gradually tends to decrease with the elapse of the immersion time in the acidity area. The average corrosion current also gradually tend to decrease The corrosion rate showed a larger value when the average relative electrode potential was higher and the average relative current was lower. The corrosion rate showed a larger value when the average relative electrode potential was higher in the acidity area, and it showed large when the average relative electrode potential was lower in the alkalinity area.

Elastic local buckling behaviour of corroded cold-formed steel columns

  • Nie Biao;Xu Shanhua;Hu WeiCheng;Chen HuaPeng;Li AnBang;Zhang ZongXing
    • Steel and Composite Structures
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    • v.48 no.1
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    • pp.27-41
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    • 2023
  • Under the long-term effect of corrosive environment, many cold-formed steel (CFS) structures have serious corrosion problems. Corrosion leads to the change of surface morphology and the loss of section thickness, which results in the change of instability mode and failure mechanism of CFS structure. This paper mainly investigates the elastic local buckling behavior of corroded CFS columns. The surface morphology scanning test was carried out for eight CFS columns accelerated corrosion by the outdoor periodic spray test. The thin shell finite element (FE) eigen-buckling analysis was also carried out to reveal the influence of corrosion surface characteristics, corrosion depth, corrosion location and corrosion area on the elastic local buckling behaviour of the plates with four simply supported edges. The accuracy of the proposed formulas for calculating the elastic local buckling stress of the corroded plates and columns was assessed through extensive parameter studies. The results indicated that for the plates considering corrosion surface characteristics, the maximum deformation area of local buckling was located at the plates with the minimum average section area. For the plates with localized corrosion, the main buckling shape of the plates changed from one half-wave to two half-wave with the increase in corrosion area length. The elastic local buckling stress decreased gradually with the increase in corrosion area width and length. In addition, the elastic local buckling stress decreased slowly when corrosion area thickness was relatively large, and then tends to accelerate with the reduction in corrosion area thickness. The distance from the corrosion area to the transverse and longitudinal centerline of the plate had little effect on the elastic local buckling stress. Finally, the calculation formula of the elastic local buckling stress of the corroded plates and CFS columns was proposed.

Area Effect on Galvanic Corrosion of Condenser Materials with Titanium Tubes in Nuclear Power Plants (Titanium 전열관을 사용하는 원전 복수기 재료의 Galvanic Corrosion에 미치는 면적의 영향)

  • Hwang, Seong-Sik;Kim, Joung-Soo;Kim, Uh-Chul
    • Nuclear Engineering and Technology
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    • v.25 no.4
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    • pp.507-514
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    • 1993
  • Titanium tubes have recently been used in condensers of nuclear power plants since titanium has very good corrosion resistance to seawater. However, when it is connected to Cu alloys as tube sheet materials and these Cu alloys are connected to carbon steels as water box materials, it makes significant galvanic corrosion on connected materials. It is expected from electrochemical tests that the corrosion rate of carbon steel will increase when it is galvanically coupled with Ti or Cu in sea water and the corrosion rate of Cu will increase when it is coupled with Ti, if this couple is exposed to sea water for a long time. It is also expected that the surface area ratios, R$_1$(surface area of carbon steel/surface area of Ti) and R$_2$(surface area of carbon steel/surface area of Cu) are very important for the galvanic corrosion of carbon steel and that these should not be kept to low values in order to minimize the galvanic corrosion on the carbon steel of the water box. Immersed galvanic corrosion tests show that the corrosion rate of carbon steel is 4.4 mpy when the ratio of surface area of Fe/ surface area of Al Brass is 1 while it is 570 mpy when this ratio is 10$^{-2}$ . The galvanic corrosion rate of this carbon steel is increased from 4.4 mpy to 13 mpy at this area ratio, 1, when this connected galvanic specimen is galvanically coupled with a Ti tube. This can be rationalized by the combined effects of R$_1$ and R$_2$ on the polarization curve.

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The study on the protection method from corrosion by the sealant injection on the unpainted weathering steel top flange outer surface of box girder (도장이 필요없는 내후성강 박스거더 상부 플랜지외부면 방식제 주입을 통한 방식공법 연구)

  • Song, Chang-Young
    • Corrosion Science and Technology
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    • v.13 no.4
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    • pp.139-144
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    • 2014
  • In corrosion-sensitive area of exsisting unpainted weathering steel bridge with closed box girder structure. there are some serious local corrosion problems because of rain water or dew water which can not be solved by conventional maintenance method. These problems must be technically controled because of the influence on the safety of bridge. This study is the first stage of developing the economic corrosion control manual for these local corrosion problems. Through the injecting experiment of tar sealant into the crevice of mock-up equipment, it was proofed that the corrosive sealant can be useful to corrosion control at crevice of corrosion sensitive area.

Galvanic Corrosion of AZ31 Mg Alloy Contacting with Copper

  • Phuong, Nguyen Van;Moon, Sungmo
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.151.1-151.1
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    • 2017
  • This work studied the corrosion behavior of AZ31 Mg alloy galvanically coupled with Cu during immersion in 0.1 and 0.5 M NaCl solutions by in-situ observation and galvanic corrosion current measurement using a zero resistance ammeter. The corrosion behavior of AZ31 Mg alloy was also studied by salt spray test. The average galvanic corrosion density during 2 h immersion in 0.1 NaCl solution was found to decrease as an exponential function with increasing the surface area ratios between AZ31:Cu or with increasing the distance between AZ31 and Cu. The corrosion of electrodeposited Cu on AZ31 Mg alloy was concentrated at the area next to Cu (about 5 mm for immersion test and 2 mm for salt spray test) and pitting corrosion was accelerated at the area beyond the severely corroded area by the galvanic coupling effect.

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Effects of Torsional Stress on the Corrosion Characteristics in the Rotor Assembly of Marine Diesel Engine Supercharger (선박용 디젤엔진 과급기 로터 접합체의 부식특성에 미치는 비틀림응력의 영향)

  • Jo, S.K.;Kong, Y.S.;Kim, Y.D.
    • Journal of Power System Engineering
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    • v.9 no.1
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    • pp.50-56
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    • 2005
  • The corrosion experiment was performed for 120 hours on the specimens in the natural seawater tank with four steps of the loaded torsional stress. The surface corrosion pattern of SCM440 area was showed global corrosion and narrow pitting, that was cause by galvanic corrosion between friction welded IN713LC and SCM440. But corrosion does not proceeded from IN713LC area. Initially, the average relative electrode potential and corrosion current were decreased suddenly, by and large, it was stabilized gradually tend to decreasing with the elapse of the immersion time. The corrosion rate was decreased by increasing the load stress, but 200 MPa specimen was showed most large value.

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Evaluation of Corrosion Properties of Several Metals in Waters for Reference Standard on Corrosion Rate - I. Andong Area (부식속도에 대한 참조 표준 작성을 위한 수환경에 따른 각종 금속의 부식특성 평가 - I. 안동지역)

  • Shim, G.T.;Kwon, Y.H.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.8 no.6
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    • pp.238-242
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    • 2009
  • Corrosion of metallic materials occurs by the reaction with corrosive environment. In general, corrosive environments are classified as atmospheric, marine, soil etc. and regardless of any corrosive environments, reduction of thickness and cracking and degradation are induced by corrosion. Among several corrosive environments, knowing the atmospheric corrosiveness of a region, city, or country is considered of ultimate importance for major industrialists and investors who require knowledge of the corrosive impact of the atmosphere on everyday materials such as carbon steel, weathering steel, zinc, copper, and aluminium. This is why the atmospheric corrosiveness map is needed. This paper dealt with corrosion properties between several waters in the region and carbon steel, weathering steel, galvanized steel, pure copper, and pure aluminium at the representative rural area of Korea - Andong.

Atmospheric corrosion rate and corrosivity categories of industrial metals in Asan area (아산지역에서 산업재료의 대기부식속도 측정)

  • Kim, Jin-Hyung;Lee, Jong-Kwon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.10
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    • pp.4653-4657
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    • 2013
  • The atmospheric corrosion rate were measured in Asan area for four years according to ISO 9224. The tested metals chosen as the most frequently used in industry, aluminum were copper, carbon steel, weathgering steel, and galvanized steel. The assessed corrosivity categories was 3 in average. The corrosivity categories of asan area was higher than typical rural area and even urban area, whereas it slightly lower than marine area. The results were discussed, specially as the regional climatic characteristics.

An experimental study on corrosion properties of reinforcing steel under environment of complex deterioration (표면피복종류에 따른 복합열화환경하의 철근콘크리트 부식특성에 관한 실험적 연구)

  • 조봉석;김영덕;윤종기;김재환;김용로;김무한
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.86-89
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    • 2003
  • It is recognized that reinforcement corrosion is the main distress behind the present concern regarding concrete durability. In this study, to confirm corrosion of reinforced concrete affected by thickness of cover, kinds of surface coating, measured electric potential, ratio of corrosion area, weight reduction, corrosion velocity of steel bar under environment of complex deterioration. The results showed that an increase in age also increases corrosion of steel bar. Ratio of corrosion area is largely related to ratio of weight reduction. as well, corrosion of steel bar by thickness of cover is superior to l0mm thick than 20mm thick. It showed that an increase in thickness of cover prevent steel bar from deteriorating. The results of this study showed that corrosion velocity was affected by thickness of cover, kinds of surface coating. data on the development of corrosion velocity made with none, organic B, organic A, inorganic B, and inorganic A is shown.

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