• Title/Summary/Keyword: correlated parameters

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Diffusion of CO2 Molecules in Polyethylene Terephthalate/Polylactide Blends Estimated by Molecular Dynamics Simulations

  • Liao, Li-Qiong;Fu, Yi-Zheng;Liang, Xiao-Yan;Mei, Lin-Yu;Liu, Ya-Qing
    • Bulletin of the Korean Chemical Society
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    • v.34 no.3
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    • pp.753-758
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    • 2013
  • Molecular dynamics (MD) simulations have been used to study the diffusion behavior of small gas molecules ($CO_2$) in polyethylene terephthalate (PET)/polylactide (PLA) blends. The Flory-Huggins interaction parameters (${\chi}$) determined from the cohesive energy densities are smaller than the critical value of Flory-Huggins interaction parameters (${\chi}_{critical}$), and that indicates the good compatibility of PET/PLA blends. The diffusion coefficients of $CO_2$ are determined via MD simulations at 298 K. That the order of diffusion coefficients is correlated with the availably fractional free volume (FFV) of $CO_2$ in the PET/PLA blends means that the FFV plays a vital role in the diffusion behavior of $CO_2$ molecules in PET/PLA blends. The slopes of the log (MSD) as a function of log (t) are close to unity over the entire composition range of PET/PLA blends, which confirmes the feasibility of MD approach reaches the normal diffusion regime of $CO_2$ in PET/PLA blends.

Adsorption of Pb(II) Ions from Aqueous Solution Using Activated Carbon Prepared from Areca Catechu Shell: Kinetic, Isotherm and Thermodynamic Studies

  • Muslim, A.;Aprilia, S.;Suha, T.A.;Fitri, Z.
    • Journal of the Korean Chemical Society
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    • v.61 no.3
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    • pp.89-96
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    • 2017
  • This study proposed adsorption of Pb(II) ions from aqueous solution using activated carbon prepared from areca catechu shell (ACS AC) using Timphan Method. The effects of independent variables on adsorption kinetic and isotherm have been investigated by conducting experiments in batch mode at neutral pH. The structural characterization of adsorbent was done by FT-IR and SEM analysis. The Pb(II) adsorption was correlated very well with the pseudo second-order kinetic (PSOKM) and Langmuir isotherm models (LIM). Increasing NaOH mass for activation and adsorption temperature increased weakly all the parameters of adsorption kinetic and isotherm. The Pb(II) ions adsorption capacity of the ACS AC at 27 and $45^{\circ}C$ was 50.51 and 55.25 mg/g, respectively. Thermodynamic parameters were determined, and the results confirmed the Pb(II) ions adsorption should be endothermic and spontaneous process, and both physical and chemical adsorption should be taken place.

Comparison of 3-D structures of Halo CMEs using cone models

  • Na, Hyeon-Ock;Moon, Y.J.;Jang, Soo-Jeong;Lee, Kyoung-Sun
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.1
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    • pp.95.1-95.1
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    • 2012
  • Halo coronal mass ejections (HCMEs) are major cause of geomagnetic storms and their three dimensional structures are important for space weather. In this study, we compare three cone models: an elliptical cone model, an ice-cream cone model, and an asymmetric cone model. These models allow us to determine the three dimensional parameters of HCMEs such as radial speed, angular width, and the angle (${\gamma}$) between sky plane and cone axis. We compare these parameters obtained from three models using 62 well-observed HCMEs from 2001 to 2002. Then we obtain the root mean square error (RMS error) between maximum measured projection speeds and their calculated projection speeds from the cone models. As a result, we find that the radial speeds obtained from the models are well correlated with one another (R > 0.84). The correlation coefficients between angular widths are less than 0.53 and those between ${\gamma}$ values are less than 0.47, which are much smaller than expected. The reason may be due to different assumptions and methods. The RMS errors of the elliptical cone model, the ice-cream cone model, and the asymmetric cone model are 213 km/s, 254 km/s, and 267 km/s, respectively. Finally, we discuss their strengths and weaknesses in terms of space weather application.

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Suggestion and Evaluation of a Multi-Regression Linear Model for Creep Life Prediction of Alloy 617 (Alloy 617의 장시간 크리프 수명 예측을 위한 다중회귀 선형 모델의 제안 및 평가)

  • Yin, Song-Nan;Kim, Woo-Gon;Jung, Ik-Hee;Kim, Yong-Wan
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.33 no.4
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    • pp.366-372
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    • 2009
  • Creep life prediction has been commonly used by a time-temperature parameter (TTP) which is correlated to an applied stress and temperature, such as Larson-Miller (LM), Orr-Sherby-Dorn (OSD), Manson-Haferd (MH) and Manson-Succop (MS) parameters. A stress-temperature linear model (STLM) based on Arrhenius, Dorn and Monkman-Grant equations was newly proposed through a mathematical procedure. For this model, the logarithm time to rupture was linearly dependent on both an applied stress and temperature. The model parameters were properly determined by using a technique of maximum likelihood estimation of a statistical method, and this model was applied to the creep data of Alloy 617. From the results, it is found that the STLM results showed better agreement than the Eno’s model and the LM parameter ones. Especially, the STLM revealed a good estimation in predicting the long-term creep life of Alloy 617.

Application of Sediment Physical Properties to Paleoclimatic Interpretation: Preliminary Results in the Ulleung Basin, the East Sea

  • Kim, Gil-Young;Kim, Dae-Choul;Keene, Jock;Kim, Jeong-Chang
    • Journal of the korean society of oceanography
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    • v.34 no.4
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    • pp.207-213
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    • 1999
  • Sediment physical properties (compressional wave velocity, grain density, dry bulk density, and wet bulk density) are correlated to the paleoenvironmental parameters (coarse fraction, oxygen isotope, and planktonic foraminifera fragmentation) to reveal the possible interrelationship in the latest Quaternary sediments of the Ulleung Basin, the East Sea of Korea. Laboratory determinations of physical properties and paleoenvironmental parameters have been conducted on four piston core sediments. There are slight differences in the physical properties between glacial and interglacial period sediment sections. This is due to the large fraction of coarse grains of volcanic and terrigenous sediments relative to carbonate sediments. However, dry bulk density as an indicator of carbonate abundance in pelagic environment shows higher values at the lower part of cores, reflecting deeper CCD in the glacial period. Changes in velocity also relatively parallel to those in sediment coarse fraction, number of planktonic foraminifera, and wet bulk density. Therefore, we suggest that high-resolution physical properties may be used as a valuable tool for paleoenvironmental interpretation in the Ulleung Basin.

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Distributional Ecology Of Planktonic Diatoms In The Strait Of Georgia, B. C.

  • Shim, Jae Hyung
    • 한국해양학회지
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    • v.12 no.1
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    • pp.13-32
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    • 1977
  • In order to determine the distributional ecology, and to investigate factors influencing these features, the diatom communities in plankton at depths of one, twenty-five, fifty, and seventy five meters in the area were studied and measured over a fifteen month of period. Measurements of environmental factors including temperature and salinity and algal nutrients such as phosphate, silicate, nitrate, and ammonia were also made at the same depths and locations. The results indicate that the size of diatom communities and the species population changes were heavily dependent upon to season and location parameters as well as nutrient concentrations and hydrographic factors. Major factors influencing population distributions varied with principal species responsible for dominant species and species sucession. Two distinct distributional patterns in total diatom crop were observed in the study area. Maximum standing crop observed during spring and/or summer were related to the concentration of nutrients available at the onset of the spring bloom on a large scale. On a small scale, however, the distributions of total diatom standing crops were significantly correlated with both season/location factors and with hydrographic parameters as well. Vertical stratification of diatoms was observed only in the presence of the thermocline in the water column. Within the study area there was some seasonal consistancy in the composition of the species groups. However, some species association in these environments may vary with the change of season.

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Calculation of Proton-Induced Reactions on Tellurium Isotopes Below 60 MeV for Medical Radioisotope Production

  • Kim, Doohwan;Jonghwa Chang;Yinlu Han
    • Nuclear Engineering and Technology
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    • v.32 no.4
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    • pp.361-371
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    • 2000
  • The 123Te(p,n)123I, 124Te(p,n)124I and 124Te(p,2n)123I reactions, among the many reaction channels opened, are the major reactions under consideration from a diagnostic purpose because reaction residuals as the gamma emitters are used for most radiophamaceutical applications involving radioiodine. Based on the available experimental data, the absorption cross sections and elastic scattering angular distributions of the proton-induced nuclear reaction on Te isotopes below 60 MeV are calculated using the optical model code APMNK. The transmission coefficients of neutron, proton, deuteron, trition and alpha particles are calculated by CUNF code and are fed into the GNASH code. By adjusting level density parameters and the pair correction values of some reaction channels, as well as the composite nucleus state density constants of the pre-equilibrium model, the production cross sections and energy-angle correlated spectra of the secondary light particles, as well as production cross sections and energy distributions of heavy recoils and gamma rays are calculated by the statistical plus pre-equilibrium model code GNASH. The calculated results are analysed and compared with the experimental data taken from the EXFOR. The optimized global optical model parameters give overall agreement with the experimental data over both the entire energy range and all tellurium isotopes.

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Catalytic Growth and Properties of Carbon Nanotubes from Fe-Mo/MgO by Chemical Vapor Deposition

  • Woo, Jong-Chang;Kim, Kyoung-Tae;Kim, Gwan-Ha;Kim, Jong-Sik;Kim, Jong-Gyu;Kim, Chang-Il
    • Transactions on Electrical and Electronic Materials
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    • v.8 no.5
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    • pp.206-210
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    • 2007
  • Carbon nanotubes(CNTs) are largely synthesized on Fe catalysts by catalytic chemical vapor deposition. The various shapes and compositions of these nanostructure CNTs were obtained by controlled parameters such as the reaction temperature, gas-mixing ratio. The influence of these parameters is investigated, together with observations of the produced materials after the purification processes. A diameter of CNTs, range from 2 to 10 nm, closely correlated with the size of the catalyst particle found attached to the tube end. The yield of CNTs was estimated to be 88.5 % and the purities of CNTs thus obtained were more than 80 %. The experimental results were documented with field emission scanning electron microscopy and raman spectroscopy and transmission electron microscopy, both before and after the purification.

Genetic Evaluation and Selection Response of Birth Weight and Weaning Weight in Indigenous Sabi Sheep

  • Assan, N.;Makuza, S.;Mhlanga, F.;Mabuku, O.
    • Asian-Australasian Journal of Animal Sciences
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    • v.15 no.12
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    • pp.1690-1694
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    • 2002
  • Genetic parameters were estimated for birth weight and weaning weight from three year (1991-1993) data totalling 1100 records of 25 rams to 205 ewes of Indigenous Sabi flock maintained at Grasslands Research Station in Zimbabwe. AIREML procedures were used fitting an Animal Model. The statistical model included the fixed effects of year of lambing, sex of lamb, birth type and the random effect of ewe. Weight of ewe when first joined with ram was included as a covariate. Direct heritability estimates of 0.27 and 0.38, and maternal heritability estimates of 0.24 and 0.09, were obtained for birth weight and weaning weight, respectively. The total heritability estimates were 0.69 and 0.77 for birth weight and weaning weight, respectively. Direct-aternal genetic correlations were high and positive. The corresponding genetic covariance estimates between direct and maternal effects were positive and low, 0.25 and 0.18 for birth weight and weaning weight, respectively. Responses to selection were 0.8 kg and 0.14 kg for birth weight and weaning weight, respectively. The estimated expected correlated response to selection for birth weight by directly selecting for weaning weight was 0.26. Direct heritabilities were moderate; as a result selection for any of these traits should be successful. Maternal heritabilities were low for weaning weight and should have less effect on selection response. Indirect selection can give lower response than direct selection.

Pattern Recognition for the Target Signal Using Acoustic Scattering Feature Parameter (표적신호 음향산란 특징파라미터를 이용한 패턴인식에 관한 연구)

  • 주재훈;신기철;김재수
    • The Journal of the Acoustical Society of Korea
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    • v.19 no.4
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    • pp.93-100
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    • 2000
  • Target signal feature parameters are very important to classify target by active sonar. Two highly correlated broad band pulses separated by time T have a time separation pitch(TSP) of 1/T Hz which is equal to the trough-to-trough or peak-to-peak spacing of its spectrum. In this study, TSP informations which represent feature of each target signal were effectively extracted by the FFT. The extracted TSP feature parameters were also applied to the pattern recognition algorithm to classify target and to analyze their properties.

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