• Polymer(Korea)
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• v.32 no.5
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• pp.470-477
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• 2008

Core shell binder of organic/organic pair that has two different properties within a particle were prepared by a step emulsion polymerization of methacrylate (MMA), styrene (St), ethyl acrylate (EA), butyl acrylate (BA), and 2-HEMA by using an water soluble initiator(APS) in the presence of an anionic surfactant (SDBS). Unwoven tensile strength of the core shell binder after processing and measuring the PSt/PMMA/2-HEM core shell with the binder is a value represents the highest was $10.75\;kg_f$/2.5cm, elongation measurements PEA/PBA core shell binder showed the highest value was 120.00%. In conclusion, using the core shell binders were able to control the mechanical properties such as tensile strength and elongation.

• 한국정보디스플레이학회:학술대회논문집
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• 2005.07b
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• pp.1495-1498
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• 2005

Due to an efficient red emission, $Eu^{+3}$ ions have doped in various host materials. Eu-doped $LaPO_4/LaPO_4$ core/shell nanophosphor which emits red light in visible range, was synthesized by using a solution system. The mean size of the nanoparticle observed by TEM was about 7-8 nm. In this core/shell system, the thickness of $LaPO_4$ shell was optimized on the basis of relative PL emission intensity. In addition, the luminescent properties of $LaPO_4:Eu/LaPO_4$ core/shell particle have been compared with Eu-doped $LaPO_4$ bulk particle and nanoparticle.

• Journal of Adhesion and Interface
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• v.4 no.1
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• pp.35-42
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• 2003

Polystyrene nanocapsules containing octadecane as a core material were prepared by miniemulsion polymerization. The morphology and size of the nanocapsules were measured with varying the surfactant concentration, content of initiator, core/shell ratio and content of comonomer. The morphologies of the prepared nanoparticles were examined by a scanning electron microscope, a transmission electron microscope and the core material was confirmed by a differential scanning calorimeter. The particles below 70 nm in diameter were formed at a high surfactant concentration. The size of the nanoparticles was not significantly affected by the initiator content. With increasing the core/shell ratio and polar comonomer content, the particle size and its distribution were increased.

• Steel and Composite Structures
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• v.45 no.5
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• pp.767-774
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• 2022

A geometrically nonlinear stability analysis of sandwich annular plates with cellular core and particle-reinforced composite layers has been performed in the present research. The particles are powders of graphene oxide (GOP) which act as nanoscale filler of epoxy matrix. To this regard, Halpin-Tsai micromechanical scheme has been used to define the material properties of the layers. A square shaped core has been considered for which the material properties have been defined based on the relative density concept. Large deflection theory of thin shells has been selected to develop the complete formulation of sandwich plate. The geometrically nonlinear stability analysis of sandwich annular plates has been carried out by indicating that the buckling load is dependent on particle amount, thickness of layer and core relative density.

• Nuclear Engineering and Technology
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• v.45 no.3
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• pp.323-334
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• 2013

During a hypothetical core-disruptive accident (CDA) in a sodium-cooled fast reactor (SFR), degraded core materials can form roughly conically-shaped debris beds over the core-support structure and/or in the lower inlet plenum of the reactor vessel from rapid quenching and fragmentation of the core material pool. However, coolant boiling may ultimately lead to leveling of the debris bed, which is crucial to the relocation of the molten core and heat-removal capability of the debris bed. To clarify the mechanisms underlying this self-leveling behavior, a large number of experiments were performed within a variety of conditions in recent years, under the constructive collaboration between the Japan Atomic Energy Agency (JAEA) and Kyushu University (Japan). The present contribution synthesizes and gives detailed comparative analyses of those experiments. Effects of various experimental parameters that may have potential influence on the leveling process, such as boiling mode, particle size, particle density, particle shape, bubbling rate, water depth and column geometry, were investigated, thus giving a large palette of favorable data for the better understanding of CDAs, and improved verifications of computer models developed in advanced fast reactor safety analysis codes.

• Applied Chemistry for Engineering
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• v.18 no.5
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• pp.444-448
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• 2007

The effects of intra-particle composition on the adhesive properties and water dispersity of acrylic emulsion type pressure sensitive adhesives (PSAs) were investigated. In the case of PSA having uniform intra-particle composition, the higher holding strength made the water dispersity lower. By changing the intra-particle composition in hard core/soft shell type, however, it was possible to get PSAs showing both high holding strength and water dispersity. When the weight ratio of MAA/AA is 4/1, high holding strength, but low initial tack and very low water dispersity were observed in both cases of higher contents of (AA+MAA) in core and shell area. When the weight ratio of MAA/AA is 1/4, however, higher water dispersity and lower holding strength were indicated in the case of higher contents of (AA+MAA) in shell area.

• Nuclear Engineering and Technology
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• v.53 no.3
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• pp.752-762
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• 2021

The Smoothed Particle Hydrodynamics is one of the most widely used mesh-free numerical method for thermo-fluid dynamics. Due to its Lagrangian nature and simplicity, it is recently gaining popularity in simulating complex physics with large deformations. In this study, the 3D single/two-phase numerical simulations are performed on the Liquid Metal Reactor (LMR) centralized sloshing benchmark experiment using the SPH parallelized using a GPU. In order to capture multi-phase flows with a large density ratio more effectively, the original SPH density and continuity equations are re-formulated in terms of the normalized-density. Based upon this approach, maximum sloshing height and arrival time in various experimental cases are calculated by using both single-phase and multi-phase SPH framework and the results are compared with the benchmark results. Overall, the results of SPH simulations show excellent agreement with all the benchmark experiments both in qualitative and quantitative manners. According to the sensitivity study of the particle-size, the prediction accuracy is gradually increasing with decreasing the particle-size leading to a higher resolution. In addition, it is found that the multi-phase SPH model considering both liquid and air provides a better prediction on the experimental results and the reality.

• Elastomers and Composites
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• v.38 no.4
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• pp.303-315
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• 2003

Inorganic/organic composite particles were also synthesized by changing an initiator an it's concentration, concentration of an adsorbed surfactant, reaction temperature, and agitation speed in the presence of $CaCO_3$ adsorbed SDBS. The polymerization conditions were optimized according to the conversion of the core-shell composite particles. In the inorganic/organic core-shell composite particle polymerization, $CaCO_3$ absorbed surfactant SDBS of 0.5 wt % was prepared first and then core $CaCO_3$ was encapsulated by sequential emulsion polymerization using MMA, concentration of APS $3.16{\times}10^{-3}mol/L$ to minimize the formation of new PMMA particle during MMA shell polymerization. The structure characterization of the inorganic/organic core-shell particles was verified by measuring the decomposition degree of $CaCO_3$ using HCl solution. It was found that $CaCO_3$ was encapsulated by shell PMMA due to having excellent dispersion in the epoxy resin, smooth surface distinctly from spindle shape, and broad particle distribution after the capsulation.

• Journal of the Korean Wood Science and Technology
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• v.23 no.4
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• pp.74-84
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• 1995

Eight types of thin composite panels were manufactured by press-lam and mat-forming process applied to optimum manufacturing condition, studied in former first research by author (1995). They were tested and compared with control boards on dimensional stability, internal bond strength, tensile strength, Screw withdrawal strength, and bending properties. These thin composite panels manufactured by mat-forming process were generally superior to those by press-lam in dimensional stability and mechanical properties. In the dimensional stability and mechanical properties of thin composite panels manufactured by mat-forming process, the thin composite panels (A and E type) composed of particle or sawdust core and veneer face with polyethylene film, were as good as those of common plywood (control board). Internal bond strength showed highest value in the thin composite panel(D type) which composed of particle core and polypropylene screen face with polyethylene film. The thin composite panels(G and H type) composed of sawdust or particle core and polypropylene screen face with polyethylene film by press-lam and mat-forming process, showed most highest value in dimensional stability and water absorption.

• Macromolecular Research
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• v.16 no.4
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• pp.329-336
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• 2008

Core/shell ($\pm$)PS/(-)silica nanocomposite particles were synthesized by dispersion polymerization using an amphoteric initiator, 2,2'-azobis [N-(2-carboxyethyl)-2,2-methylpropionamidine] ($HOOC(CH_2)_2HN$(HN=) $C(CH_3)_2CN$=NC $(CH_3)_2C$(=NH)NH $(CH_2)_2COOH$), VA-057. Negatively charged (-6.9 mV) silica was used as the stabilizer. The effects of silica addition time and silica and initiator concentrations were investigated in terms of polymerization kinetics, ultimate particle morphology, and size/size distribution. Uniform hybrid microspheres with a well-defined, core-shell structure were obtained at the following conditions: silica content = 10-15 wt% to styrene, VA-057 content=above 2 wt% to styrene and silica addition time=0 min after initiation. The delay in silica addition time retarded the polymerization kinetics and broadened the particle size distribution. The rate of polymerization was strongly affected by the silica content: it increased up to 15 wt% silica but then decreased with further increase in silica content. However, the particle size was only marginally influenced by the silica content. The zeta potential of the composite particles slightly decreased with increasing silica content. With increasing VA-057 concentration, the PS microspheres were entirely coated with silica sol above 1.0 wt% initiator.