• Title/Summary/Keyword: core particle

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Making Hygiene Paper by Surface Modification Method of the Functional Particle (기능성 미립자의 표면개질방법에 의한 위생지 제조)

  • Cho, Jun-Hyung;Kim, Yeon-Oh;Kim, Won-Duck
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.40 no.2
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    • pp.29-36
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    • 2008
  • In order to give pulp surfaces anti-bacterial functionality and photo-catalytic deodorant ability, functional pulps was made using a surface modification method with Ag nano-colloidal solution and $TiO_2$ filler. Hygiene paper was made with the specially modified pulp, and anti-bacterial and deodorant tests were carried out. The Ag nano-colloidal solution was coated on the surface of the pulp using the high pressurized gas phase squirt through the spray nozzle mounted on the hybridization system. The surface modified functional pulp was hybridized with the optimum ratio of $TiO_2$(fine particle) to pulp(core particle) under the condition of $6,000{\sim}10,000$ rpm for $3{\sim}7$ minutes in the system. The anti-bacterial functionality of the hygiene paper was confirmed by the halo test in which the formation of the clear zone around the hygiene paper sample was observed. The inhibition growth test using MIC bioscreen C showed the inhibition growth effect of the bacteria as the reaction time was increased. The photo-catalytic effect measurement of the $TiO_2$ for 4 hours of the reaction showed $50{\sim}60%$ of decomposition rate, reaching over 60% for 5 hours of the reaction.

Influence of Dangling Bonds on Nanotribological Properties of Alpha-beam Irradiated Graphene

  • Hwang, Jinheui;Kim, Jong Hoon;Kwon, Sangku;Hwang, C.C.;Wu, Junqiao;Park, Jeong Young
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.265-265
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    • 2013
  • We have investigated the influences of dangling bonds generated by alpha particle irradiation on friction and adhesion properties of graphene. Single layer of graphene grown with chemical vapor deposition on copper foil was irradiated by the alpha beam with the average energy of 3.04 MeV and the irradiation dosing between $1{\times}10^{14}$ and $1{\times}10^{15}$/$cm^3$. Raman spectroscopic showed that the ${\pi}$ electron states below Fermi level arises and the $I_D$/$I_G$ increases as increasing the dosing of alpha particle irradiation. The core level X-ray photoelectron (XPS) revealed that these defects represent the creation of various carbon-related defects and dangling bond. The nanoscale tribological properties were investigated with atomic force microscopy in ultrahigh vacuum. The friction appeared to increase remarkably as increasing the amount of dosing, indicating that the dangling bonds on graphene layers enhances the energy dissipations in friction. This trend can be explained by the additional channel of energy dissipation by dangling bond or O- and H- terminated clusters created by alpha particle irradiation.

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Preparation and Evaluation of Sustained Release Aspirin Microcapsules Using Eudragit $RS^{\circledR}$ Polymer (Eudragit $RS^{\circledR}$를 이용한 지속 방출형 아스피린 마이크로캅셀의 제조 및 평가)

  • Chun, In-Koo;Shin, Dong-Won
    • YAKHAK HOEJI
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    • v.32 no.1
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    • pp.26-39
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    • 1988
  • Eudragit $RS^{\circledR}$ polymer was used as a wall material for the microencapsulation of aspirin by a phase separation method from chloroform-cyclohexane system with 5% polyisobutylene (PIB) in cyclohexane, and microcapsules obtained were evaluated by particle size analysis, scanning electron microscopy (SEM), drug release and drug stability test. With PIB as a coacervation inducing agent, smooth and tight microcapsules with less aggregation were obtained. Below 1 : 0.3 core-wall ratio, it was possible to coat individual particle. Variation of production conditions showed that increasing the proportion of wall material, particle size and wall thickness of microcapsules and the concentration of paraffin wax in cyclohexane as a sealant sustained drug release rates effectively. SEM confirmed that larger microcapsules after drug release did not rupture into smaller particles but contained a few small pores on the surface. Aspirin release from Eudragit $RS^{\circledR}$ coated microcapsules was independent of the pH of medium, and the mechanism of drug release from non-sealed and sealed microcapsules appeared to fit Higuchi matrix model kinetics. Aspirin in the mixture of aspirin microcapsules and sodium bicarbonate was by far more stable than that in the mixture of pure aspirin and sodium bicarbonate.

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Prototype-based Classifier with Feature Selection and Its Design with Particle Swarm Optimization: Analysis and Comparative Studies

  • Park, Byoung-Jun;Oh, Sung-Kwun
    • Journal of Electrical Engineering and Technology
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    • v.7 no.2
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    • pp.245-254
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    • 2012
  • In this study, we introduce a prototype-based classifier with feature selection that dwells upon the usage of a biologically inspired optimization technique of Particle Swarm Optimization (PSO). The design comprises two main phases. In the first phase, PSO selects P % of patterns to be treated as prototypes of c classes. During the second phase, the PSO is instrumental in the formation of a core set of features that constitute a collection of the most meaningful and highly discriminative coordinates of the original feature space. The proposed scheme of feature selection is developed in the wrapper mode with the performance evaluated with the aid of the nearest prototype classifier. The study offers a complete algorithmic framework and demonstrates the effectiveness (quality of solution) and efficiency (computing cost) of the approach when applied to a collection of selected data sets. We also include a comparative study which involves the usage of genetic algorithms (GAs). Numerical experiments show that a suitable selection of prototypes and a substantial reduction of the feature space could be accomplished and the classifier formed in this manner becomes characterized by low classification error. In addition, the advantage of the PSO is quantified in detail by running a number of experiments using Machine Learning datasets.

AN EXPERIMENTAL STUDY OF THE EFFECT OF ALUMINA AND ZIRCONIA ON MECHANICAL PROPERTIES OF DENTAL CORE PORCELAIN (Alumina와 zirconia가 치과용 코아 도재의 물리적 성질에 미치는 영향에 관한 실험적 연구)

  • Shin Hyeon-Soo;Lee Sang-Jin;Lee Keun-Woo
    • The Journal of Korean Academy of Prosthodontics
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    • v.31 no.3
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    • pp.317-349
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    • 1993
  • This study investigated the effect of filler particle size and weight% on mechanical properties of dental core porcelain. In alumina, variation in particle size and weight% and in zirconia, variation in weight%, all specimens were tested three-point bending strength, transmittance, thermal expansion coefficient, porosity and shrinkage and observed with SEM and analysed with X-ray diffractometer. In order to develop shrink-free porcelain, after firing alumina only, glass wasinfiltrated. And aluminum was added to alumina with the expanding character of aluminum oxidize into alumina, and was followed by second firing of glass infiltration procedure. Then mechanical properties were observed. The results of this study were obtained as follows. 1. The bending strength of zirconia was higher than that of alumina, and $5{\mu}m$ alumina had highest strength in variation of particle size of alumina. Except for $5{\mu}m$ alumina, increased with weight%, bending strength increased up to 80% and decreased at 90%. In case of glass infiltration, bending strength was slight higher than 80% and 90% of $5{\mu}m$ alumina. 2. Transmittance increased with increase of shrinkage, decrease of porosity, and with increase of filler size and had no direct correlation with weight%. 3. Thermal expansion coefficient of alumina group was $7.42\sim8.64\times10^{-6}/^{\circ}C$ and that of zirconia group was $9.83\sim12.11\times10^{-6}/^{\circ}C$ and the latter was higher than the former. 4. In x-ray diffraction analysis, alumina group and zirconia group increased $Al_2O_3$ peak and $t-ZrO_2$ peak with increase of weight%. The second phase(cristobalite peak) was observed in zirconia 40% group. 5. Porosity of zirconia was lower than that of alumina and $5{\mu}m$ alumina group had many pores with SEM. In case of low filler content, fracture occurred in glass and high filler content, in glass and filler. In case of aluminum addition to alumina, small oxidised aluminum was observed. 6. Zirconia group had high shrinkage than alumina group, and mixed group of alumina group had high shrinkage. In case of glass infiltration, shrinkage decreased and aluminum addition to alumina group was almost shrink-free.

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Biocompatible Dispersion Methods for Carbon Black

  • Kim, Hwa;Park, Kwangsik;Lee, Moo-Yeol
    • Toxicological Research
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    • v.28 no.4
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    • pp.209-216
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    • 2012
  • The biological activity of particles is largely dependent on their size in biological systems. Dispersion in the aqueous phase has been both a critical impediment to and a prerequisite for particle studies. Carbon black has been used as a surrogate to investigate the biological effects of carbonaceous particles. Here, biocompatible methods were established to disperse carbon black into ultrafine and fine particles which are generally distinguished by the small size of 100 nm. Carbon black with a distinct particle size, N330 and N990 were suspended in blood plasma, cell culture media, Krebs-Ringer's solution (KR), or physiological salt solution (PSS). Large clumps were observed in all dispersion preparations; however, sonication improved dispersion - averaged particle sizes for N330 and N990 were $85.0{\pm}42.9$ and $112.4{\pm}67.9$ nm, respectively, in plasma; the corresponding sizes in culture media were $84.8{\pm}38.4$ and $164.1{\pm}77.8$ nm. However, sonication was not enough to disperse N330 less than 100 nm in either KR or PSS. Application of Tween 80 along with sonication reduced the size of N330 to less than 100 nm, and dispersed N990 larger than 100 nm ($73.6{\pm}28.8$ and $80.1{\pm}30.0$ nm for N330 and $349.5{\pm}161.8$ and $399.8{\pm}181.1$ nm for N990 in KR and PSS, respectively). In contrast, 1,2-dipalmitoyl-sn-glycero-3-phosphocholine (DPPC) exhibited little effect. Electron microscopy confirmed the typical aciniform structure of the carbon arrays; however, zeta potential measurement failed to explain the dispersibility of carbon black. The methods established in this study could disperse carbon black into ultrafine and fine particles, and may serve as a useful model for the study of particle toxicity, particularly size-related effects.

Hydrated Lime Roasting of Precious Metal Ores with A Cyclone Reactor

  • Cho, Chong S.
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1997.06a
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    • pp.53-60
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    • 1997
  • The roasting of pyrite with a cyclone reactor have been studied in terms of investigating the reaction behavior of pyrite. The development of a fundamental model for pyrite oxidation and lime sulfation in a vertical cyclone reactor. The model assumes a chemical control shrinking core behavior for the pyrite and a fluid film control shrinking core behavior for the lime. The oxygen and sulphur dioxide concentrations and the energy balance for the gas, pyrite and lime particles are solved. The model was solved and characterized numerically. Experiments have been performed to study the influence of reaction parameters such as reactor temperatures, pyrite particle sizes, air flow rates, feeding rates, and mixing ratio of pyrite and lime. The oxidation and sulfation products were characterized chemically and physically.

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Kinetic study of high-temperature removal of $H_2S$ by Ca-based sorbents (황화수소 제거를 위한 칼슘계 고온탈황제의 황화반응속도에 관한 연구)

  • 김영식;전지환
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 1998.04a
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    • pp.144-153
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    • 1998
  • Sorbents of calcined limestone and oyster particles having a diameter of about 0.63mm were exposed to simulate fuel gases containing 5000ppmv H2S for temperatures ranging from 600 to 800C in a TGA. The reaction between CaO and H2S proceds via an unreacted shrinking core mechanism. The sulfidation rate is likely to be controlled primarily by countercurrent diffusion through the product layer of calcium sulfide(CaS) formed. The kinetics of the sorption of H2S by CaO is sensitive to the reaction temperature and particle size, and the reaction rate of oyster was faster than the calcined limestone.

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Preparation of FeAl nanopowders by Plasma Arc Discharge Process (플라즈마 아크방전(PAD)법으로 제조된 FeAl 나노분말 특성)

  • Park Woo-Young;Youn Cheol-Su;Yu Ji-Hun;Oh Young-Woo;Choi Chul-Jin
    • Journal of Powder Materials
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    • v.11 no.6 s.47
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    • pp.522-527
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    • 2004
  • Nano sized FeAl intermetallic particles were successfully synthesized by plasma arc discharge pro-cess. The synthesized powders shouted core-shell structures with the particle size of 10-20 nm. The core was metallic FeAl and shell was composed of amorphous $AI_{2}O_{3}\;and\;a\;little\;amount\;of\;metallic\;Fe_{3}O_{4}.$ Because of the difference of Fe and Al vapor pressure during synthesis, the Al contents in the nanoparticles depended on the Al contents of master alloy.

PIV Measurements of the Pressure Driven Flow Inside a T-Shaped Microchannel (T형 마이크로채널 내부 압력구동 유동의 PIV 계측)

  • Choi Jayho;Lee In-Seop
    • Proceedings of the KSME Conference
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    • 2002.08a
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    • pp.423-426
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    • 2002
  • A custom micro-PIV optics assembly has been used to measure the flow field inside a T-shaped microchannel. The micro-PIV system consists of microscope objectives of various magnifications, a dichroic cube, and an 8-bit CCD camera. Fluorescent particles of diameters 620nm have been used with a Nd:YAG laser and color filters. A programmable syringe pump with Teflon tubings were used to inject particle-seeded distilled water into the channel at flow rates of $420,\;40,\;60{\mu}L/hr$. The microchannels are fabricated with PDMS with a silicon mold, then $O_2-ion$ bonded onto a slide glass. Results show differences in flow characteristics and resolution according to fluid injection rates, and magnifications, respectively. The results show PIV results with vector-to-vector distances of $2{\mu}m$ with 32 pixel-square interrogation windows at $50{\%}$ overlap.

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