• 제목/요약/키워드: copper sulphide

검색결과 11건 처리시간 0.021초

구리, 니켈, 코발트 혼합용액으로부터 침전법에 의한 구리의 분리 (Precipitation of Cu as the sulphide from Sulphate solution containing Cu, Ni and Co)

  • 박경호;정선희;박진태;남철우;김홍인
    • 자원리싸이클링
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    • 제14권6호
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    • pp.16-20
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    • 2005
  • 구리, 니켈 그리고 코발트를 함유한 용액으로부터 구리를 선택적으로 분리하기 위하여 $Na_{2}S$를 첨가하여 구리를 CuS로 침전시키는 연구를 행하였다. 구리의 침전율은 용액의 pH가 높을수록, 첨가한 $Na_{2}S$의 양이 많을수록,농도가 낮을수록, 반응온도와 반응시간이 증가할수록 증가하였다. pH 1, $20\%\;Na_{2}S$ 첨가량이 구리의 3 당량비, 온도 $25^{\circ}C$ 그리고 반응시간 30분에서 구리의 침전율은 $94.1\%$이었으며 니켈과 코발트도 각각 $4.3\%$$4.5\%$가 침전되었다. 즉 일부 니켈과 코발트 이온이 같이 공침되기 때문에 정량적으로 구리만을 침전, 분리하는 것은 가능하지 않았다.

해저열수광상 개발동향과 우리나라의 대응방안 (Strategies for Development of Seafloor Polymetallic Sulphides in Consideration of International Progress)

  • 박성욱;양희철;정현수
    • 한국해양학회지:바다
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    • 제13권3호
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    • pp.271-279
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    • 2008
  • 해저열수광상은 황화물 미네랄이 해저의 열수작용을 통해 형성된 광상을 의미하며 특히, 구리, 납, 아연, 금, 은 등의 금속이 다량 포함되어 있다. 현재 해저열수광상 개발분야의 선두주자는 노틸러스사이다. 노틸러스사는 파푸아뉴기니, 피지, 통가, 솔로몬제도, 뉴질랜드 등 남서태평양 도서국에 약 37만 $km^2$에 달하는 탐사권을 보유 또는 신청해 놓은 상태이다. 넵튠사 역시 뉴질랜드, 파푸아뉴기니, 마이크로네시아에서 27만 $km^2$가 넘는 면적의 탐사권을 취득하였다. 이들 두 광업회사는 2010년 세계 최초로 해저열수광상의 상업생산을 목표로 적극적인 활동을 전개하고 있다. 주변국가인 중국과 일본은 전략광물의 안정적 공급을 위하여 해저열수광상 탐사활동을 적극적으로 수행하고 있는 실정이다. 중국의 경우 중국대양협회를 통해 전 지구 대양을 대상으로 심해저자원개발을 위한 국가연구개발사업을 수행하고 있다. 일본의 경우 자국의 EEZ를 중심으로 해저열수광상 조사사업을 수행하고 있다. 이러한 국제적인 해저열수광상 개발동향을 고려하여 우리나라의 해저열수광상 개발을 위한 전략방향을 소관부처의 일원화와 법제도 정비, 사업추진주체 결정, 정부의 적극적 예산지원, 해저열수광상 개발을 위한 중장기 계획수립 등의 측면에서 제안하였다.

Total value recovery in the copper smelting and refining operations

  • Kim Joe. Y.;Kong Bong S.
    • 한국지구물리탐사학회:학술대회논문집
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    • 한국지구물리탐사학회 2003년도 Proceedings of the international symposium on the fusion technology
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    • pp.590-597
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    • 2003
  • Processing and smelting of copper containing sulphide concentrates result in the accumulation of impurities into various process streams. All primary copper smelters and refineries around the world produce significant amounts of slag, dust, sludge, residues and others, which contain copper and precious metals. The recovery of these valuable metals is essential to the overall economics of the smelting process. Physical, chemical and mineralogical characterization of particular slag and Cottrell dusts from primary smelters and $Dor\'{e}$ furnace (TBRC) slag and Pressure Leached Anode slimes from a copper refinery have been carried out to understand the basic behind the recovery processes. Various process options have been evaluated and adapted for the treatment of slag from different smelting furnaces and Cottrell dusts as well as the intermediate products from copper refineries. Besides the hydro- or pyro-metallurgical treatments, the above mentioned physical separation options such as magnetic, gravity separation, flotation and precipitation flotation processes have been successfully identified and adapted as the possible process options to produce a Cu-rich or precious metal-rich concentrates for in-house recycling and other valued by-product for further treatment. The results of laboratory, pilot plant and production operations are presented, and incorporation of several alternative flowsheet is discussed in this paper.

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MINERAL PROCESSING and COPPER EXRACTIVE METALLURGY Complete Metal Recovery

  • Kim, J.Y.
    • 한국자원리싸이클링학회:학술대회논문집
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    • 한국자원리싸이클링학회 2003년도 추계정기총회 및 국제심포지엄
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    • pp.22-34
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    • 2003
  • Processing and smelting of copper containing sulphide concentrates result in the accumulation of impurities into various process streams. All primary copper smelters and refineries around the world produce significant amounts of slag, dust, sludge, residues and others, which contain copper and precious metals. The recovery of these valuable metals is essential to the overall economics of the smelting process. Physical, chemical and mineralogical characterization of particular slag and Cottrell dusts from primary smelters and Dore furnace (TBRC) slag and Pressure Leached Anode slimes from a copper refinery have been carried out to understand the basic behind the recovery processes. Various process options have been evaluated and adapted for the treatment of slag from different smelting furnaces and Cottrell dusts as well as the intermediate products from copper refineries. Besides the hydro- or pyre-metallurgical treatments, the above mentioned physical separation options such as magnetic, gravity separation, flotation and precipitation flotation processes have been successfully identified and adapted as the possible process options to produce a Cu-rich or precious metal-rich concentrates for in-house recycling and other valued by-product for further treatment. The results of laboratory, pilot plant and production operations are presented, and incorporation of several alternative flowsheet is discussed in this paper.

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옥천지향사대(沃川地向斜帶)의 진화(進化)와 광화작용(鑛化作用) (Evolution and Mineralizations in the Ockcheon Geosynclinal Zone)

  • 윤석규
    • 자원환경지질
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    • 제4권2호
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    • pp.77-90
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    • 1971
  • About four hundred deposits of iron, talc, fluorite, tungsten, molybdenum, lead, zinc and other polymetallic mineral deposits were plotted on the Ore Distribution Map of the Ockcheon Geosynclinal Area. These mineral deposits plotted on the map can be divided into the several metallogenic zones by the consideration of their geologic background including the sedimentary and tectonic cycles and the igneous activities in the geosynclinal evolution, as follows: a. Chungju iron and talc zones. b. Cheong-san copper bearing iron sulphide zone c. Kumsan-Muju fluorite-polymetallic zones. d. Cheong-an Puyong and Ein Suckseong gold zone e. Hwang-gan Seolcheon and Sangju gold zones. Chungju iron zone originated in the iron bed in the Kemyongsan Series corresponding to the Pre-Ockcheon Cycle of evolution history. In early period of the Ockcheon Cycle, Hyangsanri quartzite and Munjuri phyllitic formation corresponding to the lower terrigenous sequence were not mineralized while the next sequence of the Samsungsan basic igneous-metamorphic formation and the Changri limestone formation were mineralized by the copper bearing iron sulphide and the fluorite-polymetallic deposits respectively. Two generations of the gold zones are recognized. The earlier generation distributes directionaly in the outside of the Ockcheon sedimentary belt was followed by the earlier grantitic invasion of Jurasic in age, while the later generation scatters at random which was related to the nondirectional Cretaceous granitic intrusion of the Post-Ockcheon Cycle. Conclusively speaking, it was disclosed that the endogenic mineralization in the Ockcheon geosyn clinal zone was not conspicuous in its inner sedimentary belt except its limestone area but in its outer peripheral granitic or gneissic zones, and the related igneous activities occured in the Post-Ockcheon Cycle of evolution history.

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구리, 니켈, 코발트, 철 혼합용액(混合溶液)으로부터 구리의 제거(除去) (Removal of Copper from the Solution Containing Copper, Nickel, Cobalt and Iron)

  • 박경호;남철우;김현호
    • 자원리싸이클링
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    • 제22권6호
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    • pp.48-54
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    • 2013
  • 니켈, 코발트와 철의 혼합용액에 미량 함유되어 있는 구리 (399 ppm 구리, 208 ppm 철, 15.3 g/L 니켈, 2.1 g/L 코발트)를 분리, 제거를 위한 방법들을 검토하였다. 중화침전법의 경우 용액의 pH가 7.0 에서 구리는 철과 함께 전부 수산화물로 침전, 제거되었으나 니켈과 코발트의 일부도 함께 침전되었다. 황화침전법의 경우 1.25% 농도의 $Na_2S$를 구리의 2당량비 첨가하고 용액의 pH가 1.0인 경우 구리가 99.7% 제거 되었다. TP207 양이온 흡착제를 사용한 이온교환수지법은 평형 pH 2.0 에서 구리만이 선택적으로 흡착되었으며 탈착용액으로는 5% 황산이 적당하였다.

광양금광상(光陽金鑛床), 고흥동광상(高興銅鑛床)의 광상생성(鑛床生成)과 암석학적(岩石學的) 연구(硏究) (Metallogenesis and Petrology of the Gwangyang Gold Deposits and Goheung Copper Deposits)

  • 박영석;신병우
    • 자원환경지질
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    • 제17권2호
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    • pp.91-100
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    • 1984
  • The Gwangyang gold deposits geologically consist of granitic gneiss, metatectic gneiss and porphyroblastic gneiss which correspond to Jirisan gneiss complex. The formations of Gyeongsang system lies unconformably on these gneisses and are intruded by diorite, porphyritic andesite and Bulgugsa granites. Goheung districts are composed of quartz schist, andesitic rock, tuff and granite. The Gwangyang gold deposits are gold bearing fissure filling veins. The vein thickness varies from 15cm to 40cm and they consist of 7-10 layers in parallel. The Goheung copper deposits are sulphide bearing quartz veln which filled the fracture in andesitic rock and biotite granite. The contact zone of these rocks is partially altered. The mineral paragenesis of the Gwangyang and Goheung districts is pyrite, arsenopyrite, pyrrhotite, chalcopyrite, sphalerite, galena, sericite, quartz and calcite. The variation trends of FMA and A'KF triangular diagrams and the differentiation index (norm, Q + Or + Ab) versus oxides diagrams is similar to the Gyeonsang basin igneous rocks. From the trace element analysis of 10 samples of country rocks, wall rocks and veins, the distribution of copper and lead contents display a correlative distribution pattern in relation to gold and silver. Homogenization temperature of fluid inclusions range from $200^{\circ}C$ to $270^{\circ}C$ in quartz from the Gwangyang gold vein and the size of fluid inclusion range from 0.01mm to 0.04mm. The fluid inclusions are mainly one or two phase and the filling degree of the inclusions varies from 85 to 95.

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함안군북지구(咸安郡北地區)의 지질(地質)과 동광상(銅鑛床) (Geology and Ore Deposits in the Haman-Kunbuk Copper District)

  • 문정욱;김명환;이지헌;최충정
    • 자원환경지질
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    • 제3권2호
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    • pp.55-73
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    • 1970
  • The district investigated covers the central and southern portions of the Uiryong Quadrangle amounting to $40km^2$ in area and is bounded approximately by geographical coordinates of $128^{\circ}$ 28' $40^{{\prime}{\prime}}{\sim}128^{\circ}$ 24' 25"E in longitude and $35^{\circ}10{\prime}{\sim}35^{\circ}14^{\prime}06^{{\prime}{\prime}}N$ in latitude. The purpose of this investigation was to provide basic information in drawing up a comprehensive development plan of the copper ore deposits known to exist in the HamanKumbuk district with special emphasis given to the ascertainment of geological and paragenetic characteristics. The area consists chiefly of shale, sandy shale and chert, all belong to Kyongsang System of Cretaceous age. Intruded into these rocks are andesite, granodiorite, basic dikes, and acidic dikes. The mineralization which took place in the area, consists of mostly fissure-filling vein deposits, numbering several tens, with varying magnitudes. The fissures and shear zones created in rocks, such as chert and granodiorite, hosted the deposition of mineralizing vapors and/or hydrothermal solutions along their openings. The strike lengths of these veins vary from 50 to 600 meters in extension and 0.1 to 3 meters in width. Although the degree of fluctuation in width is great, it averages 0.3m. The stuctural patterns, which apparently affected the deposition of veins, are fissure patterns, trend NS to $N30^{\circ}W$, and steep-pitching tension fractures as well as normal fault pattern. Ore minerals associated with vein matters are primarily chalcopyrite and small amounts of scheelite, cobaltiferous arsenopyrite, and gold and silver intimately associated with sulphide minerals. Associated with these ore mineral are pyrite, pyrrhotite, magnetite, specularite and arsenopyrite. Gangue minerals noted are quartz, calcite, chlorite, tourmaline and hornblende. In terms of the compositions of associated minerals, the vein deposits in the district could be grouped under the following four categories: 1. Pyrrhoitite, Arsenopyrite, Gold and Silver Bearing Copper Vein (Type I) 2. Calcite-Scheelite-Copper Vein (Type II) 3. Magnetite-Pyrite-Copper Vein (Type III) 4. Tourmaline Copper Vein (Type IV) Of the four types, the first and the fourth are presently yielding relatively higher grades: of copper ores and concentrates. The estimated ore reserves total some 222,000 metric tons with the following breakdown in terms of metal contents: Name of Mines Au(g/t) Ag(g/t) Cu(%) Reserves(M/T) Kunbuk 15.92 78.69 6,074 60.498 Cheil Kunbuk - - 1.040 60,847 Haman - - 2.688 101,204 222,549 As rehabilitation of old workings and/or exploration of veins at depth proceed, additional estimation of ore reserves may become apparent and necessary. With regard to the problem of beneficiation and upgrading of low-grade ores in the district, it would be advisable to make decisions on location, treating capacity and mill flowsheet after sufficient amount of exploration is completed as suggested in the report.

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해외 금속자원에 대한 광상유형별 자료 분석을 통한 효과적인 자원개발 (The Optimal Resource Development for Analysing Data of Deposit Types' Ore Reserves of Oversea Metal Resource)

  • 유봉철;이종길;이길재;이현구
    • 자원환경지질
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    • 제41권6호
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    • pp.773-795
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    • 2008
  • 우리나라의 주요 수입 광종은 동광, 연-아연광, 철광, 망간광 및 몰리브덴광 등이다. 우리나라의 해외자원개발은 아시아 14개국 92개 사업, 미주 및 유럽지역 10개국 29개 사업 그리고 중동 및 아프리카 9개국 14개 사업이 있으며 주로 호주, 중국, 몽골 및 인도네시아에서 사업수가 높다. 호주, 인도네시아 및 중국의 사업은 대부분이 석탄이고 일부 망간, 철, 연-아연, 니켈, 구리, 금, 몰리브덴, 희유원소 및 우라늄 등이나 몽골은 금과 희유원소가 큰 부분을 차지한다. 금속자원에 대한 광상 유형별 대표적인 광상형은 조산 lode형 광상, VMS형 광상, 반암형 광상, SEDEX형 광상, MVT형 광상, IOCG형 광상 및 마그마성 Ni-Cu-PGE형 광상 등이 있으며 이들 유형별 광상들은 전세계적으로 도처에 분포하며 다른 유형별 광상보다 금속자원의 매장량이 높고 부산물인 미량 금속자원에 대한 품위도 높게 나타난다. 따라서 향후 해외광물자원의 탐사 및 개발에 있어 우선 각 국가별 매장량, 주요 광물자원의 생산량 및 지체구조와 함께 광상 유형별 등을 종합 검토하여 조사 및 탐사를 실시한다면, 해외자원개발의 투자 위험도가 감소될 뿐만 아니라 탐사대상지역에서 품위가 높은 광체를 확보할 수 있을 것이다.