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Hydrogen Supply to PEMFC for Unmanned Aero Vehicles Using Hydrolysis Reaction of NaBH4 (NaBH4 가수분해 반응에 의한 무인항공기용 PEMFC 수소공급)

  • Jung, Hyeon-Seong;Jo, Byung-Joo;Lee, Jung-Hoon;Lee, Han-Jong;Na, Il-Chai;Chu, Cheun-Ho;Park, Kwon-Pil
    • Korean Chemical Engineering Research
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    • v.54 no.1
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    • pp.11-15
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    • 2016
  • Proton Exchange Membrane Fuel Cells (PEMFC) instead of batteries is appropriate for long time flight of unmanned aero vehicles (UAV). In this work, $NaBH_4$ hydrolysis system supplying hydrogen to PEMFC was studied. In order to decrease weight of $NaBH_4$ hydrolysis system, enhancement of hydrogen yield, recovery of condensing water and maintenance of stable hydrogen yield were studied. The hydrogen yield of 3.4% was increased by controlling of hydrogen pressure in hydrolysis reactor. Condensing water formed during air cooling of hydrogen was recovered into storage tank of $NaBH_4$ solution. In this process the condensing water dissolved $NaBH_4$ powder and then addition of $NaBH_4$ solution decreased system weight of 14%. $NaBH_4$ hydrolysis system was stably operated with hydrogen yield of 96% by 2.0g Co-P-B catalyst for 10 hours at 2.0L/min hydrogen evolution rate.

Studies on Cryotop Vitrification Method for Simple Freezing of Hanwoo Embryos (한우 수정란의 간이 동결을 위한 유리화 동결법에 관한 연구)

  • Lee, Hae-Lee;Kim, Sang-Hun;Kim, Yong-Jun
    • Journal of Embryo Transfer
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    • v.29 no.1
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    • pp.13-19
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    • 2014
  • This study was carried out to study the survival rate of thawed Hanwoo embryos frozen by the slow-rate freezing or the cryotop vitrification method. Hanwoo cumulus-oocyte complexes were recovered from ovaries at a slaughter house, matured for 20~22 hours, fertilized with Hanwoo semen for 5~6 hours, and cultured for 7~9 days in $38.5^{\circ}C$, 5% $CO_2$ incubator. For freezing, Day 7~9 blastocysts were collected. Embryos for the slow-rate freezing were equilibrated in 1.8 M ethylene glycol (EG) with Dulbecco's phosphate-buffered saline (D-PBS). Programmable cell freezer was precooled down to $-7^{\circ}C$, and the straw was seeded during 8 minutes-holding time, and was cooled to $-35^{\circ}C$ at the cooling rate of $0.3^{\circ}C/min$, and then was plunged and stored in liquid nitrogen. Embryos for the cryotop vitrification were treated in TCM199 with 0.5 M sucrose, 16% EG, 16% dimethylsulfoxide (DMSO). Embryos were then loaded individually onto cryotop and plunged directly into liquid nitrogen. The survival rates of embryos frozen by these two freezing methods were evaluated at 12 to 24h post-thawing. The survival rates of frozen/thawed Hanwoo embryos by the cryotop vitrification method ($56.86{\pm}26.53%$) were slightly higher than those by the slow-rate freezing method ($55.07{\pm}26.43%$) with no significant difference. Using the cryotop vitrification and the slow-rate freezing of Hanwoo blastocysts on Day 7 following in-vitro fertilization (IVF) treatment, the survival rates of frozen/thawed Hanwoo embryos were $72.65{\pm}18.3%$ and $79.06{\pm}17.8%$, respectively. The survival rates by the cryotop vitrification were higher than those by the slow-rate freezing on both Day 8 and 9 with significantly higher survival rate on Day 9 (p<0.05). Using the cryotop vitrification and the slow-rate freezing of Hanwoo embryos to compare between three different blastocyst stages, the survival rates of the blastocyst stage embryos were $66.22{\pm}18.8%$ and $45.76{\pm}12.8%$, respectively with higher survival rate by the vitrification method (p<0.05). And the survival rate of expanded blastocysts was higher than those of early blastocysts and blastocysts in two freezing methods with significantly higher survival rate by the slow-rate freezing method (p<0.05).

A Perception of Beginning Earth Science Teachers on Porphyritic Texture (반상조직에 대한 초임 지구과학교사들의 인식)

  • Kim, Yong-Hwan;Chung, Duk-Ho;Cho, Kyu-Seong;Choi, Jin-A;Park, Kyeong-Jin
    • Journal of the Korean earth science society
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    • v.32 no.7
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    • pp.860-870
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    • 2011
  • This study is to explore the Pedagogical Content Knowledge of beginning earth science teachers about the porphyritic texture of igneous rocks, and to suggest the teaching device that can prevent a trial and error of students in earth science instruction. We developed an interview guideline concerned with basic perception on the porphyritic texture, formation condition and formation process of porphyritic rocks, teaching and learning on porphyritic rocks for it. And data was collected from 5 beginning earth science teachers (3 high schools, 2 middle schools) through a group discussion method. In result, despite the porphyritic texture can be found at hypabyssal rocks as well as volcano rocks and plutonic rocks, most beginning earth science teachers cognized that it could be found at hypabyssal rocks only by focusing the formation depth of hypabyssal rocks. Also, the formation of porphyritic texture should be considered the factors such as cooling rate, nucleation density, growth rate, growth time, etc. However they mainly reflected the formation temperature and growth rate as it's parameter. Participants have wrongly perceived that a phenocryst necessarily differs from a groundmass on chemical composition. And they are inclined to discriminate phenocryst from groundmass through their chemical differences, instead of grain size.

In-Vivo Heat Transfer Measurement using Proton Resonance Frequency Method of Magnetic Resonance Imaging (자기 공명영상 시스템의 수소원자 공명 주파수법을 이용한 생체 내 열 전달 관찰)

  • 조지연;조종운;이현용;신운재;은충기;문치웅
    • Journal of the Institute of Electronics Engineers of Korea SC
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    • v.40 no.3
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    • pp.172-180
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    • 2003
  • The purpose of this study is to observe the heat transfer process in in-vivo human muscle based on Proton Resonance Frequency(PRF) method in Magnetic Resonance Imaging(MRI). MRI was obtained to measure the temperature variation according to the heat transfer in phantom and in-vivo human calf muscle. A phantom(2% agarose gel) was used in this experiment. MR temperature measurement was compared with the direct temperature measurement using a T-type thermocouple. After heating agarose gel to more than 5$0^{\circ}C$ in boiling hot water, raw data were acquired every 3 minutes during one hour cooling period for a phantom case. For human study heat was forced to deliver into volunteer's calf muscle using hot pack. Reference data were once acquired before a hot pack emits heat and raw data were acquired every 2 minutes during 30minutes. Acquired raw data were reconstructed to phase-difference images with reference image to observe the temperature change. Phase-difference of the phantom was linearly proportional to the temperature change in the range of 34.2$^{\circ}C$ and 50.2$^{\circ}C$. Temperature resolution was 0.0457 radian /$^{\circ}C$(0.0038 ppm/$^{\circ}C$) in phantom case. In vivo-case, mean phase-difference in near region from the hot pack is smaller than that in far region. Different temperature distribution was observed in proportion to a distance from heat source.

The Marine Tourism Co-Development of the South-North Korea and Policy Support Devices (남북한 공동 해양관광개발의 방향과 정책지원 방안)

  • Sin, Dong-Ju
    • Korean Business Review
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    • v.23 no.1
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    • pp.87-106
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    • 2010
  • North Korea is hoping get more international aids and cooperations with facing serious difficulties in the domestic economies, but it is expected to be hard to induce foreign direct investments due to the lots of existing negative factors in the credibility, profitability, bad images, and so on. On the other hand, in South Korea, the demands of the places and facilities for the leisure & tourism have been skyrocketed with the fast economic growth during the last three decades, especially in marine tourism As the Korea peninsula is surrounded with sea in three sides, North and South Korea must utilize these area qualitatively and quantitatively for advance of entire cooperation. The cooperation through sea has some restraint factors. They may occur unexpected conflict and need enormous infrastructure investment for the further cooperation. In the other side, it has some advantages such as, it can avoid direct contact between both people for North government. Even though inter-Korean relationship is facing temporary cooling time recently, The marine tourism co-development of the South-North Korea is a potential and important factor for enhancement of the reconciliation and cooperation. Furthermore, it can achieve unification of two Koreas. This study reviews many factors and suggests marine policy Support devices for The marine tourism co-development between South-North Korea.

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Thermal-Hydraulic Research Review and Cooperation Outcome for Light Water Reactor Fuel (경수로핵연료 열수력 연구개발 분석 및 연산학 협력 성과)

  • In, Wang Kee;Shin, Chang Hwan;Lee, Chi Young;Lee, Chan;Chun, Tae Hyun;Oh, Dong Seok
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.40 no.12
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    • pp.815-824
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    • 2016
  • The fuel assembly for pressurized water reactor (PWR) consists of fuel rod bundle, spacer grid and bottom/top end fittings. The cooling water in high pressure and temperature is introduced in lower plenum of reactor core and directed to upper plenum through the subchannel which is formed between the fuel rods. The main thermal-hydraulic performance parameters for the PWR fuel are pressure drop and critical heat flux in normal operating condition, and quenching time in accident condition. The Korea Atomic Energy Research Institute (KAERI) has been developing an advanced PWR fuel, dual-cooled annular fuel and accident tolerant fuel for the enhancement of fuel performance and the localization. For the key thermal-hydraulic technology development of PWR fuel, the KAERI LWR fuel team has conducted the experiments for pressure drop, turbulent flow mixing and heat transfer, critical heat flux(CHF) and quenching. The computational fluid dynamics (CFD) analysis was also performed to predict flow and heat transfer in fuel assembly including the spent fuel assembly in dry cask for interim repository. In addition, the research cooperation with university and nuclear fuel company was also carried out to develop a basic thermal-hydraulic technology and the commercialization.

Numerical Simulation of CNTs Based Solid State Hydrogen Storage System (탄소나노튜브 기반의 고체수소저장시스템에 관한 전산해석)

  • Kim, Sang-Gon;HwangBo, Chi-Hyung;Yu, Chul Hee;Nahm, Kee-Suk;Im, Yeon-Ho
    • Korean Chemical Engineering Research
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    • v.49 no.5
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    • pp.644-651
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    • 2011
  • Storing hydrogen in solid state hydride is one of the best promising methods for the future hydrogen economy. The total performance of such systems depends on the rate at which the amount of mass and heat migration is supplied to solid hydride. Therefore, an accurate modeling of the heat and mass transfer is of prime importance in optimizing the design of such systems. In this work, Hydrogen storage in Pt-CNTs hydrogen reactor has been intensively investigated by solving 2 dimensional mathematical models. Using a CFD computer software, systematic studies have been performed to elucidate the effect of heat and mass transfer during hydrogen charging periods. It was revealed that the optimized design of hydrogen storage vessel can prevent the increase of system temperature and the charging time due to the convective cooling effects inside the vessels at even high charging pressure. Because none has reported the critical issues of heat and mass transfer for CNT based hydrogen storage system, this work can support the first insight of the optimal design for solid state hydrogen storage system based on CNT in the near future.

An Analysis on the Deep Geological Disposal Concepts Considering the Spent Fuel Length (사용후핵연료 길이에 따른 심지층 처분시스템 분석)

  • LEE, Jongyoul;KIM, Hyeona;LEE, Minsoo;CHOI, Heuijoo;KIM, Keonyoung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.13 no.3
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    • pp.201-209
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    • 2015
  • Currently, 23 nuclear power plants are in operation at Kori, Uljin, Younggwang and Wolsong site and a reference deep geological disposal system has been developed for the spent fuels generated by them. The reference spent fuel for this disposal system has 4.5wt% of initial enrichment, 55 GWd/MtU of burn-up, and 40 years of cooling time. In this paper, to improve disposal efficiency and economic feasibility, the characteristics of spent fuels from nuclear power plants, such as type and burn-up, were reviewed. A disposal canister concept for shorter length and relatively lower burn-up spent fuels than the reference spent fuels was developed. Based on this canister concept, thermal analyses were carried out and a deep geological disposal concept was proposed. Measures of disposal efficiency such as unit disposal area and disposal density were compared between this disposal system and the reference disposal system. Also, economic feasibility, such as the volume reduction of copper, cast iron, and bentonite, was analyzed and the results of these analyses showed that the disposal system proposed in this paper has an efficiency of at least 20%. These results could be used for establishing spent fuel management policy and designing practical disposal systems for spent fuels.

A study on the development of simulation program for the small naturally aspirated four-stroke diesel engine (소형 4행정사이클 무과급 디이젤 기관의 성능 시뮤레이션 전산프로그램의 개발에 관한 연구)

  • 백태주;전효중
    • Journal of Advanced Marine Engineering and Technology
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    • v.8 no.1
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    • pp.17-36
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    • 1984
  • Since 1973, the competition on the development of fuel saving type internal combustion engines has become severe by the two times oil shock, and new type engines are reported every several months. Whenever these new type engines are developed, new designs are required and they will be offered in the market after performing the endurance test for a long time. But the engine market is faced with a heavy burden of finance, as the developing of a new engine requires tremendous expenses. For this reason, the computer simulation method has been lately developed to cope with it. The computer simulation method can be available to perform the reasonable research works by the theoretical analysis before carrying out practical experiments. With these processes, the developing expenses are cut down and the period of development is curtailed. The object of this study is the development of simulation computer program for the small naturally aspirated four-stroke diesel engine which is intended to product by the original design of our country. The process of simulation is firstly investigated for the ideal engine cycle, and secondly for the real engine cycle. In the ideal engine cycle, each step of the cycle is simulated by the energy balance according to the first law of thermodynamics, and then the engine performance is calculated. In the real cycle imulation program, the injection rate, the preparation rate and the combustion rate of fuel and the heat transfer through the wall of combustion chamber are considered. In this case, the injection rate is supposed as constant through the crank angle interval of injection and the combustion rate is calculated by the Whitehouse-Way equation and the heat transfer is calculated by the Annand's equation. The simulated values are compared with measured values of the YANMAR NS90(C) engine and Mitsubishi 4D30 engine, and the following conclusions are drawn. 1. The heat loss by the exhaust gas is well agree with each other in the lower load, but the measured value is greater than the calculated value in the higher load. The maximum error rate is about 15% in the full load. 2. The calculated quantity of heat transfer to the cooling water is greater than the measured value. The maximum error rate is about 11.8%. 3. The mean effective pressure, the fuel consumption, the power and the torque are well agree with each other. The maximum error is occurred in the fuel consumption, and its error rate is about 7%. From the above remarks, it may be concluded that the prediction of the engine performance is possibly by using the developed program, although the program needs to reform by adding the simulation of intake and exhaust process and assumping more reliable mechanical efficiency, volumetric efficiency, preparation rate and combustion rate.

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Thermal Process Evaluation and Simulation in a Pilot Scale Kimchi Pasteurizer (Pilot Scale 김치순간살균장치(瞬間殺菌裝置)에서의 살균효과분석(殺菌效果分析) 및 Simulation)

  • Gil, Gwang-Hoon;Kim, Kong-Hwan;Chun, Jae-Kun
    • Applied Biological Chemistry
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    • v.27 no.2
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    • pp.55-63
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    • 1984
  • Lethal effect on Chinese radish Kimchi was investigated by using a pilot scale Kimchi pasteurizer. A simulation model was presented so as to predict the change in viable cell concentration of the Kimchi during pasteurization. D values of microorganisms in the Kimchi were found to be 2.21, 1.62, 0.73, 0.39 and 0.21min at 60, 64, 70, 75 and $80^{\circ}C$, correspondingly, and thereby z value was $19^{\circ}C$. One cycle time required was 0.99min at flow rate of 4 l/min. The ratio of lethality in preheating section to total lethality was 0.3 and the ratio of lethality in holding, precooling and cooling sections to total lethality was 0.7. The experimental data were in good agreement with the values simulated by two model equations to which linear and exponential temperature profiles were applied at $65^{\circ}C\;and\;70^{\circ}C$ in holding section.

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