• Title/Summary/Keyword: conversion phosphors

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Analysis of Color Uniformity of White LED Lens Packages for Direct-lit LCD Backlight Applications

  • Joo, Byung-Yun;Ko, Jae-Hyeon
    • Journal of the Optical Society of Korea
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    • v.17 no.6
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    • pp.506-512
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    • 2013
  • Recently, the color separation issue of wide-spreading white LEDs has attracted attention due to their wide applicability as light sources in direct-lit LCD backlights. These wide-spreading LED packages usually consist of LED chips, a color-conversion phosphor layer, and a light-shaping lens. The technical aspect of this color issue was related to a method for balancing the yellow spectral component emitting from phosphors with respect to the blue one from the LED chip as a function of viewing angle. In this study, we suggested an approach for carrying out quantitative analysis for the color separation problem occurring in wide-spreading LED packages by optical simulation. In addition, the effect of an internal scattering layer on the color uniformity was investigated, which may be considered as a potential solution for this problem.

The Relative and Absolute Speed of Radiographic Screen-Film Systems (증감지(增感紙)-필름계(系)의 상대감도(相對感度)와 절대감도(絶對感度)에 관한 실험(實驗))

  • Huh, Joon;Lee, In-Ja
    • Journal of radiological science and technology
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    • v.16 no.1
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    • pp.67-80
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    • 1993
  • Recently, a large number of new screen-film systems have become available for use in diagnostic radiology. These new screens are made of materials generally known as rare-earth phosphors which have high x-ray absorption and high x-ray to light conversion efficiency compared to calcium tungstate phosphors. The major advantage of these new systesms is reduction of patient exposure due to their high speed or high sensitivity. However, a system with excessively high speed can result in a significant degradation of radiographic image quality. Therefore, th speed is important parameters for users of these system. Our aim of in this was to determine accurately and precisely the absolute speed and relative speeds of both new and conventional screen-film system. We determined the absolute speed in condition of BRH phantom beam qulity and the relative speed were measured by a split-screen technique in condition of BRH and ANSI phantom beam qulity. The absolute and the relative speed were determined for 8 kinds of screen-4 kinds of film in regular system and 7 kinds of screen-7 kinds of film in ortho system. In this study we could know the New Rx, T-MAT G has the highest film speed, also know Green system's stndard deviation of relative speed larger than blue system. It was realized that there were no relationship between the absolute speed and the blue system. It was realized that there were no relationship between the absolute speed and the relative speed in ortho or regular system.

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Upconversion Photoluminescence Properties of PbMoO4:Er3+/Yb3+ Phosphors Synthesized by Microwave Sol-Gel Method

  • Lim, Chang Sung
    • Korean Journal of Materials Research
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    • v.25 no.9
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    • pp.480-486
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    • 2015
  • $Pb_{1-x}MoO_4:Er^{3+}/Yb^{3+}$ phosphors with various doping concentrations of $Er^{3+}$ and $Yb^{3+}$ ($x=Er^{3+}+Yb^{3+}$, $Er^{3+}=0.05$, 0.1, 0.2, and $Yb^{3+}=0.2$, 0.45) are successfully synthesized using a microwave sol-gel method, and the up-conversion photoluminescence properties are investigated. Well-crystallized particles, which are formed after heat treatment at $900^{\circ}C$ for 16 h, exhibit a fine and homogeneous morphology with particle sizes of $2-5{\mu}m$. Under excitation at 980 nm, the $Pb_{0.7}MoO_4:Er_{0.1}Yb_{0.2}$ and $Pb_{0.5}MoO_4:Er_{0.05}Yb_{0.45}$ particles exhibit a strong 525 nm emission band, a weak 550 nm emission band in the green region, and a very weak 655 nm emission band in the red region. The Raman spectra of the doped particles indicate the presence of strong peaks at higher and lower frequencies induced by the disordered structures of $Pb_{1-x}MoO_4$ through the incorporation of the $Er^{3+}$ and $Yb^{3+}$ ions into the crystal lattice, which results in the unit cell shrinkage accompanying the new phase formation of the $MoO_{4-x}$ group.

Improved Power Conversion Efficiency of Dye-Sensitized Solar Cells Assisted with phosphor materials Scattering layer

  • Lee, Yong-Min;Choi, Hyun Ji;Kim, Dong In;Lee, Yul Hee;Yu, Jung-Hoon;Kim, Jee Yun;Seo, Hyeon Jin;Hwang, Ki-Hwan;Nam, Sang Hun;Boo, Jin-Hyo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.408.2-409
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    • 2016
  • Theoretically, the dye-sensitized solar cells (DSSCs) are high efficiency solar cells. However DSSCs have low power conversion efficiency (PCE) than silicon based solar cells. In this study, we use the phosphor materials, such as $Y_2O_3:Eu$ (Red), $Zn_2SiO_4:Mn$ (Green), $BaMgAl_{14}O_{23}:Eu$ (Blue), to enhance the PCE of DSSCs. Three phosphors were prepared and used as an effective scattering layer on the transparent $TiO_2$ with doctor blade method. We confirmed that the three scattering layers improve the PCE and Jsc due to the light harvesting enhancement via increased the scattering and absorbance in visible range. Under the sun illumination AM 1.5 conditions, the PCE of the mesoporous $TiO_2$ based DSSCs is 5.18 %. The PCE of the DSSCs with Y2O3:Eu, $Zn_2SiO_4:Mn$ and $BaMgAl_{14}O_{23}:Eu$ as scattering layer were enhanced to 5.66 %, 5.72% and 5.82%, respectably. In order to compare the optical properties change, DSSCs were measured by EQE, reflectance and PCE. At the same time, FE-SEM and XRD were used to confirm the structural changes of each layer.

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Optical Properties as Process Condition of Color Conversion Lens Using Low-softening Point Glass for White LED (백색 LED용 저 연화점 유리를 이용한 색 변환 렌즈의 제조 조건에 따른 광 특성)

  • Chae, Yoo-Jin;Lee, Mi-Jai;Hwang, Jong-Hee;Lim, Tae-Young;Kim, Jin-Ho;Jeong, Hee-Suk;Lee, Young-Sik;Kim, Deug-Joong
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.454-459
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    • 2013
  • Recently, remote phosphors have been reported for application to white LEDs to provide enhanced phosphor efficiency compared with conventional phosphor-based white LEDs. In this study, a remote phosphor was produced by coating via screen printing on a glass substrate with different numbers of phosphor coating. The paste consists of phosphor, lowest softening glass frits, and organic binders. The remote phosphor could be well controlled by varying the phosphor content rated paste. After mounting the remote phosphor on top of a blue LED chip, CCT, CRI, and luminance efficiency were measured and values of 5300 K, 62, and 117 lm/W were respectively obtained in the 80 wt% phosphor with 3 coating layers sintered at $800^{\circ}C$.

Growth and Excretion of Nitrogen and Phosphorus of Israeli Strain of Carp(Cyprinus carpio) Fed a Low Pollution Diets (저오염 사료의 급여에 의한 잉어의 성장과 질소 및 인 배설량)

  • 김정대;이종윤;김광석;이승복;최낙중;김응오
    • Journal of Aquaculture
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    • v.11 no.1
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    • pp.39-48
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    • 1998
  • Growth performance and excretions of nitrogen (N) and phosphorus (P) were investigated with carp (Cyprinus carpio) with carp (Cyprinus carpio) grower fed a low pollution diets (A and B) and commercial ones (Com-1 and Com-2). A recirculated rearing system (Exp. I) and a floating net cage system (Exp. II) were employed for two feeding trials in which fish having an initial body weight of 152g and 193g were fed for 41 an 39 days, respectively. The highest weight gain, daily growth rate and protein efficiency ratio were found (P<0.05) in fish fed diet A containing 10% fish meal and 2% monocalcium phosphate (MCP) for both experiments. They also showed the lowest feed conversion ratio and daily feeding ration among treatments. Fish fed diet B containing 10% fish meal, 5% fish protein concentrate and 1% MCP showed weight gain and FCR more improved (P<0.05) than those fed commercial diets. In all groups, whole body cmpositions were not greatly different among treatment, and protein and P contents in final fish ranged from 14.3 to 15.6% and from 0.39 to 0.48%, respectively. Fish fed diet A excreted the least N which were 38.3 in Exp. I and 39.6g/kg gain in Exp. II. However, the values found in fish fed two commercial diets amounted to 59.1 and 58.9g, respectively. A significant decrease in P excretion was also found in fish groups fed diets A and B. In Exp. I, a reduction of 53.4% was shown in fish fed diet A, compared to the averaged value (18.5g P/kg gain) of two commercial groups. In Exp. II conducted using the floating net cages, fish fed diet B excreted the least P (8.6g/kg gain) among the treatment, which was followed by fish fed diet A, showing 48.6% reduction compared to the average value (18.5g/kg gain) for fish fed two commercial diets. The present results clearly showed that N and P excretions from fish culture could be significantly reduced by using the low pollution diet.

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Luminescence Properties of White LED with Different CdSe nanoparticles Phosphor Layer (CdSe 나노입자 형광층 구조에 따른 백색 LED 발광 특성 연구)

  • Chung, Won-Keun;Yu, Hong-Jeong;Park, Sun-Hee;Chun, Byung-Hee;Kim, Sung-Hyun
    • Korean Chemical Engineering Research
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    • v.49 no.3
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    • pp.320-324
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    • 2011
  • TOPO/TOP capped CdSe nanoparticles were synthesized via thermal-solvent method. The 540 nm green and 620 nm red emitting CdSe nanoparticles were obtained by controlling the reaction time and temperature. Phosphor conversion white LED was produced combining a 460 nm emitting InGaN LED chip as an excitation source with 540 and 620 nm CdSe nanoparticles as phosphors. The single or double phosphor layer was fabricated by mixing with epoxy, and investigated the effects on the luminous properties of the white LED. The single phosphor layer white LED showed 5.78 lm/W with CIE of (0.36, 0.45) in reddish white, and the double phosphor layer white LED showed 7.28 lm/W with that of (0.32, 0.34) in pure white at 20 mA. When the 400 nm near-UV LED was applied to optical pumping source, the luminous efficiency of white LED was enhanced to 8.76 lm/W.

Upconversion luminescence from poly-crystalline Yb3+, Er3+ co-doped NaGd(MoO4)2 by simple solid state method (Er3+, Yb3+ 이온이 동시 도핑된 NaGd(MoO4)2의 업컨버젼 분석)

  • Kang, Suk Hyun;Kang, Hyo Sang;Lee, Hee Ae;Shim, Kwang Bo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.26 no.4
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    • pp.159-163
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    • 2016
  • Up-conversion (UC) luminescence properties of polycrystalline $Er^{3+}/Yb^{3+}$ doped $NaGd(MoO_4)_2$ phosphors synthesized by a simple solid-state reaction method were investigated in detail. Used to 980 nm excitation (InfraRed area), $Er^{3+}/Yb^{3+}$ co-doped $NaGd(MoO_4)_2$ exhibited very weak red emissions near 650 and 670 nm, and very strong green UC emissions at 540 and 550 nm corresponding to the infra 4f transitions of $Er^{3+}(^4F_{9/2},\;^2H_{11/2},\;^4S_{3/2}){\rightarrow}Er^{3+}(^4I_{15/2})$. The optimum doping concentration of $Er^{3+}$, $Yb^{3+}$ for highest emission intensity was determined by XRD and PL analysis. The $Er^{3+}/Yb^{3+}$ (10.0/10.0 mol%) co-doped $NaGd(MoO_4)_2$ phosphor sample exhibited very strong shiny green emission. A possible UC mechanism for $Er^{3+}/Yb^{3+}$ co-doped $NaGd(MoO_4)_2$ depending on the pump power dependence was discussed.