• 제목/요약/키워드: conversion coating

검색결과 214건 처리시간 0.028초

공압과 정전기력을 이용한 스프레이 박막 코팅 기술 개발 (Development of Spray Thin Film Coating Method using an Air Pressure and Electrostatic Force)

  • 김정수;김동수
    • 한국정밀공학회지
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    • 제30권6호
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    • pp.567-572
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    • 2013
  • In many electro-devices, the vacuum process is used as the manufacturing process. However, the vacuum process has a problem, it is difficult to apply to a continuous process such as a R2R(roll to roll) printing process. In this paper, we propose an ESD (electro static deposition) printing process has been used to apply an organic solar cell of thin film forming. ESD is a method of liquid atomization by electrical forces, an electrostatic atomizer sprays micro-drops from the solution injected into the capillary with electrostatic force generated by electric potential of about several tens kV. The organic solar cell based on a P3HT/PCBM active layer and a PEDOT:PSS electron blocking layer prepared from ESD method shows solar-to-electrical conversion efficiency of 1.42% at AM 1.5G 1sun light illumination, while 1.86% efficiency is observed when the ESD deposition of P3HT/PCBM is performed on a spin-coated PEDOT:PSS layer.

은나노 코팅이 면직물의 역학적 특성과 태에 미치는 영향 (Effect of Nano Silver Coating on the Mechanical Properties and Hand of Cotton Fabrics)

  • 강미정;권영아
    • 한국의류학회지
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    • 제33권8호
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    • pp.1273-1279
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    • 2009
  • This study examined the difference in the mechanical properties of cotton fabrics treated with nano silver. Nano silver powder, UV-absorber, and DMDHEU are applied to cotton fabrics. The reagents added in a finishing solution were Triton X-100 and $MgCl_2$ $6H_2O$. The mechanical properties of the fabrics were measured by KES-FB system. From these, the primary hand values were evaluated by the conversion equation (KN-202-DS). The results of this study are summarized as follows. The fabric tensile properties and bending properties are increased by the application of nano silver, DMDHEU, and UV-absorber mixed. The values of tensile properties in the warp direction were significantly lower than those in the weft direction. However, the values of bending properties in the warp direction were higher than those in the weft direction. The differences in the values of compression parameters by nano silver coating were unnoticeable. However, the compression energy and resilience of compression in each fabric was increased by DMDHEU treatment. The SMD values of cotton fabrics are decreased by nano silver, DMDHEU, and UV-absorber mixed treatment.

Pack-cementation 방법에 의해서 탄화규소로 도포된 탄소/탄소 복합재의 산화거동 (Oxidation Behavior of SiC Coated Carbon/carbon Composite by Pack-cementation Method)

  • 김정일;박인서;주혁종
    • Composites Research
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    • 제13권2호
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    • pp.22-29
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    • 2000
  • 탄소/탄소 복합재는 고온에서의 우수한 물성에도 불구하고, 산화에 대한 취약한 성질로 인하여 많은 분야에서 사용에 제약을 받고 있다. 그러므로 탄소/탄소 복합재의 산화안정성을 향상시키기 위해서 수많은 연구가 수행되어지고 있다. 본 연구에서는 고온에서 보다 개선된 물성과 높은 산화안정성을 부여하고, 타 도포물질과 비교해서 낮은 열팽창계수의 차이를 보이는 탄화규소를 Pack-Cementation 방법으로 4방향성 탄소/탄소 복합재에 도포하였다. 제작된 탄화규소로 도포된 탄소/탄소 복합재는 광학현미경의 관찰을 통하여 도포기구를 추정하였으며, 산화시험을 통하여 개선된 산화안정성을 조사하였다. 그리고 여러 시험을 종합 ·분석하여 도포공정의 최적의 반응조건을 연구하였다.

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하이솔리드 아크릴/우레아 도료의 제조와 도막물성 연구 (Preparation and Physical Properties of High-Solids Acrylic/Urea Coatings)

  • 정충호;김성래;박형진;김명수;박홍수;박신자
    • 한국응용과학기술학회지
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    • 제19권4호
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    • pp.311-319
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    • 2002
  • Environmental friendly acrylic/urea high-solid paint(MUHC) were prepared through the curing reaction of acrylics resin(EBHC) containing 70wt% of solids content and butylated urea curing agent. The synthesis of EBHC Was done at $150^{\circ}C$ for 6 hours, and the results were obtained as follows : $M_{n}=1830{\sim}2190$, $M_{w}$ $3290{\sim}4000$, $M_{w}/M_{n}$=1.80{\sim}1.83$ viscosity=$110{\sim}352$ cps, and conversion=$82{\sim}92$%. After the film was coated with MUHC, the various physical properties were measured. They showed that enhancement of the coating properties such as adhesion, flexibility, abrasion resistance, impact resistance, and water resistance could be expected through introdl1cing caprolactone acrylate component in acrylics resin for the high-solids content acrylics/urea coatings.

REBCO 초전도 박막제조를 위한 Fluorine-free MOD 전구체 용액 개발 (Development of Fluorine-free MOD Precursor Solution for fabricating REBCO Superconducting Films)

  • 김병주;임선원;김호진;홍계원;이희균
    • Progress in Superconductivity
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    • 제7권2호
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    • pp.152-157
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    • 2006
  • New precursor solution with dichloroacetic acid (DCA) was developed for fabricating high $J_c$ REBCO film. DCA based-precursor solution was coated on $LaAlO_3$(001) substrate by dip coating method. Processing parameters such as oxygen partial pressure, water vapor, ramping rate and pyrolysis temperature were controlled in order to obtain a good epitaxial film. The film with thickness of 0.5 micrometer was obtained by single coating and no crack was observed at calcined films. Oxygen partial pressure was controlled in the range of $100{\sim}1,000$ ppm and conversion heat treatment was carried out at the temperature range of $705-765^{\circ}C$. A critical transition temperature ($T_c$) of 90 K and a critical transport current density ($J_c$) of $>0.5\;MA/cm^2$ (77 K and self-field) were obtained for the GdBCO film. It is thought that fluorine-free MOD solution using DCA is promising precursor solution for fabricating high quality REBCO films.

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산화물박막 증착에 의한 금속 메쉬전극 구조 광전기화학셀의 효율 개선에 관한 연구 (Efficiency Improvement of Metal-Mesh Electrode Type Photoelectrochemical Cells by Oxides Layer Coatings)

  • 한치환;박선희;성열문
    • 전기학회논문지
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    • 제60권3호
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    • pp.584-587
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    • 2011
  • In this work, the $TiO_2$ and $SnO_2$ thin films as blocking layers were coated directly onto the metal-mesh electrode surface to prevent unnecessary inflow of back-transfer electrons from the electrolyte ($I^-/I_3^-$) to the metal-mesh electrode. The DSCs were fabricated with working electrode of SUS mesh coated with blocking $TiO_2$ and $SnO_2$ layers, dye-attached mesoporous $TiO_2$ film, gel electrolyte and counter electrode of Pt-deposited F:$SnO_2$. From the experimental result, it was ascertained that the efficiency of metal electrode coated with $TiO_2$ by Dip-coating was superior to that of metal electrode coated with $SnO_2$ by Dip-coating and screen printing with the results of experiments. The photo-current conversion efficiency of the cell obtained from optimum fabrication condition was 3% ($V_{oc}$=0.61V, $J_{sc}$=11.64 mA/$cm^2$, ff=0.64) under AM1.5, 100 mW/$cm^2$ illumination.

나노분말 첨가에 따른 YBCO 초전도 박막의 미셀구조 및 초전도 특성변화 연구 (Effect of nano-sized powder addition on the microstructure and superconducting properties of the YBCO thin film.)

  • 박진아;김병주;임선원;안지현;김호진;홍계원;이희균
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2005년도 제36회 하계학술대회 논문집 C
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    • pp.1998-2000
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    • 2005
  • The effects of the addition of nanocrystalline Y2O3 powder on the microstructure and superconducting properties have been investigated in YBCO films prepared by TFA-MOD process. Precursor solution doped with extra $Y_2O_3$ Powder was prepared by adding $Y_2O_3$ powder into a stoichiometic precursor solution with a cation ratio of Y:Ba:Cu=1:2:3. Coating solutions with and without $Y_2O_3$ doping were coated on $LaAlO_3(100)$ single crystal by a dip coating method, cacination and conversion heat treatments were performed at the controlled atmosphere containing water vapor Current carry capacity(Jc) of YBCO film was enhanced about 50% by $Y_2O_3$ doping. It is thought that the enhancement of Jc is due to the better connectivity of YBCO grains and/or the flux pinning by the presence of nanocrystalline $Y_2O_3$ Particles embedded in YBCO grains.

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고특성 REBCO 초전도 박막 제조를 위한 새로운 MOD 전구 용액 제조 (New MOD solution for the preparation of high $J_c$ REBCO superconducting films)

  • 김병주;홍계원;이희균
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2005년도 제36회 하계학술대회 논문집 C
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    • pp.2001-2003
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    • 2005
  • Various organic acid were used in order to prepare new metalorganic deposition solution for high quality $REBa_2Cu_3O_{7-{\delta}}$ (RE=Y, Eu, Gd) films. Prepared fluorine free MO precursor solution was coated on single crystal (001) $LaAlO_3$ (LAO) by dip coating method. Processing parameters such as oxygen partial pressure, water vapor, ramping rate and pyrolysis temperature etc havebeen controlled in order to make high $J_c$ films with a good epitaxial relationship with substrate. 0.5 micron-thick film was obtained by single coating and no crack appeared after calcination. Oxygen partial pressure was varied in the range of $100{\sim}1,000 ppm$ and conversion heat treatment was carried out at the temperature of $725{\sim}765^{\circ}C$. A critical transition temperature $(T_{c0})$ of 90K and a critical transport current density $(J_c)$ of $>0.5MA/cm^2$ (77K and self-field) were demonstrated for the YBCO film on (001) oriented LAO substrates with a thickness of 0.5 micron. $I_c$ was determined by utilizing a transport measurement. SEM and XRD investigations confirmed that films were grown epitaxially onto the LAO single crystal substrate. It is thought that fluorine free new MOD solutionis promising for high quality REBCO films.

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정전분무법을 이용한 염료감응형 태양전지의 $TiO_2$ 박막 특성에 관한 연구 (A Study on the Characteristics of $TiO_2$ thin Film in Dye-sensitized Solar Cells using Electrospray Method)

  • 김희제;이정기;홍지태;김호성;이동길;허국성;안태풍;장진주
    • 전기학회논문지
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    • 제58권11호
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    • pp.2223-2228
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    • 2009
  • Dye sensitized solar cells(DSCs) have been very economical and easy method to convert solar energy to electricity. DSC can reach low costs in future outdoor power applications. However, to commercialize the DSC, there are still many shortages to overcome such a low efficiency in a large size DSC. In this study, DSCs were fabricated by an electrospray coating method for the $TiO_2$ thin film. They were compared with DSCs prepared by conventional coating methods. We conducted an experiment to obtain the optimized parameters of voltage, flow rate, incident angle and distance in the electrospray method. After we fabricated $TiO_2$ film using that way, we investigated the characteristics of DSC through I-V Curve, SEM and EIS. This novel method shows stable performance with an energy conversion efficiency of 3.44 % under 1 sun illumination (AM 1, $P_{in}$ of $100\;mW/cm^2$).

Evaluation of the Performance of an Organic Thin Film Solar Cell Prepared Using the Active Layer of Poly[[9-(1-octylnonyl)-9H-carbazole-2.7-diyl]-2.5-thiophenediyl-2.1.3-benzothiadiazole-4.7-Diyl-2.5-thiophenediyl]/[6,6]-Phenyl C71 Butyric Acid Methyl Ester Composite Thin Film

  • Ochiai, Shizuyasu;Uchiyama, Masaki;Kannappan, Santhakumar;Jayaraman, Ramajothi;Shin, Paik-Kyun
    • Transactions on Electrical and Electronic Materials
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    • 제13권1호
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    • pp.43-46
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    • 2012
  • Organic solar cell devices were fabricated using poly[9-(1-octylnonyl)-9H-carbazole-2.7-diyl]-2.5-thiophenediyl-2.1.3-benzothiadiazole-4.7-diyl-2.5-thiophenediyl] PCDTBT/ [6,6]-phenyl $C_{71}$ butyric acid methyl ester (PC71BM) active layer deposited by spin coating. Moreover, the relationship between solar cell performance and buffer layer thickness was investigated by spin coating speed and AFM imaging of the buffer layer surface. The performance of the organic solar cell with spin-coated active layer was then evaluated, and the power conversion efficiency of the solar cell was determined to be > 5%.