• 제목/요약/키워드: conventional oxide method

검색결과 321건 처리시간 0.021초

소결온도에 따른 0.7Ba(Mg,Ta)O$_3$-0.3Ba(Co,Nb)O$_3$세라믹스 마이크로파 유전특성에 관한연구 (Microwave Dielectric Properties of 0.7Ba(Mg,Ta)O$_3$-0.3Ba(Co,Nb)O$_3$Ceramics with Sintering Temperature)

  • 이문기;김남영;이영희
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제50권3호
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    • pp.110-114
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    • 2001
  • $0.7Ba(Mg{\frac}_{1}{3}Ta{\frac}_{1}{3})O_3-0.3Ba({\frac}_{1}{3}Nb{\frac}_{1}{3})O_3ceramics$ were prepared by the conventional mixed oxide method. The ceramics were sintered at the temperature of $1500{\sim}1575[^{\circ}C]$ for 5 hours in air. The microwave dielectric properties of the specimens were investigated with sintering temperature. The 0.7BMT-0.3BCN ceramics showed typical XRD patterns of the complex perovskite structure. Dielectric constant and quality factor were increased with increasing the sintering temperature. In the case of the specimens sintered at $1575[^{\circ}C]$ for 5 hours, dielectric constant, quality factor and temperature coefficient of resonant frequency were good values of 28,23545 at 10[㎓] and -1.2 $[ppm/^{\circ}C]$, respectively.

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$Pb(Mb_{1/3}Nb_{2/3})O_3$-$BaTiO<_3$-$CaZrO<_3$세라믹의 유전특성에 관한 연구 (A Study on the Dielectric Properties of the $Pb(Mb_{1/3}Nb_{2/3})O_3$-$BaTiO<_3$-$CaZrO<_3$Ceramics)

  • 김수하;배선기
    • E2M - 전기 전자와 첨단 소재
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    • 제10권10호
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    • pp.1041-1047
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    • 1997
  • In this paper the dielectric properties of (0.8-x)Pb(Mb$_{1}$3//Nb/2/3)O$_3$/BaTiO$_3$-CaZrO$_3$(x=0.1, 0.15, 0.2, 0.25) ceramics were investigated. Specimens were prepared by the conventional mixed oxide method and sintering temperature and time were 1000~115$0^{\circ}C$ 2hr, respectively. The structural and dielectric properties with variation of sintering temperature and composition were investigated. All the specimens sintered at 115$0^{\circ}C$ for 2hr showed the highest value of 1043. With increasing the contents of CZ and frequency dielectric constant was decreased and which was decreased with increasing temperature from 3$0^{\circ}C$ to 15$0^{\circ}C$.

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$SrTiO_3$ 첨가에 따른 $MgTiO_3$ 세라믹스의 마이크로파 유전특성 (Microwave Dielectric Properties of the $MgTiO_3$ Ceramics with $SrTiO_3$)

  • 배경인;박인길;배선기;이영희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2000년도 추계학술대회 논문집 학회본부 C
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    • pp.473-475
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    • 2000
  • The (1-x)$MgTiO_3-xSrTiO_3$$(x=0.03{\sim}0.04)$ ceramics were fabricated by conventional mixed oxide method. The structural properties and microwave dielectric properties were investigated by XRD, SEM and HP8757D network analyzer. In the $0.96MgTiO_3-0.04SrTiO_3$ ceramics, the perovskite structure $SrTiO_3$ and ilmenite structure $MgTiO_3$ phases were coexisted. The dielectric constant(${\varepsilon}_r$ and temperature coefficient of resonant frequency(${\tau}_f$) was increased with addition of $SrTiO_3$. In the case of $0.96MgTiO_3-0.04SrTiO_3$ ceramics sintered at $1325^{\circ}C$, the dielectric constant, quality factor and temperature coefficient of resonant frequency were 20.13, 7956(at 7.27GHz), +1.7568ppm/$^{\circ}C$, respectively.

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소결온도에 따른 $0.98MgTiO_3-0.02BaTiO_3$ 세라믹스의 마이크로파 유전특성 (Microwave Dielectric Properties of the $0.98MgTiO_3-0.02BaTiO_3$ Ceramics with Sintering Temperature)

  • 최의선;이문기;이성갑;배선기;이영희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 춘계학술대회 논문집 유기절연재료 전자세라믹 방전플라즈마 연구회
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    • pp.123-126
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    • 2001
  • The $0.98MgTiO_3-0.02BaTiO_3$ ceramics were prepared by the conventional mixed oxide method. The structural properties were investigated with sintering temperature and composition ratio by XRD, SEM and EDS. According to the X-ray diffraction patterns of the $0.98MgTiO_3-0.02BaTiO_3$ ceramics, the hexagonal $BaMg_6Ti_6O_{19}$ and ilmenite $MgTiO_3$ structures were coexisted. The dielectric constant$({\varepsilin}_r)$ and quality factor$(Q{\times}f_r)$ were decreased with increasing the sintering temperature in the range of $1275^{\circ}C{\sim}1350^{\circ}C$. In the case of the $0.98MgTiO_3-0.02BaTiO_3$ ceramics sintered at $1275^{\circ}C$, dielectric constant, quality factor and temperature coefficient of resonant frequency were 20.27, 76,845, $-46.6ppm/^{\circ}C$, respectively.

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소결온도에 따른 $BaTiO_3+Nb_2O_5$ 세라믹스 구조적 특성 (The Structural properties of $BaTiO_3+Nb_2O_5$ ceramics with sintering temperature)

  • 이상철;김지헌;김강;류기원;이영희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 춘계학술대회 논문집 유기절연재료 전자세라믹 방전플라즈마 연구회
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    • pp.127-130
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    • 2001
  • The $BaTiO_3+xNb_2O_5$(x=6, 8, 10wt%) ceramics were prepared by conventional mixed oxide method. The structural properties of the $BaTiO_3+Nb_2O_5$ ceramics with the sintering temperature and addition of $Nb_2O_5$ were investigated by XRD and SEM. Increasing the sintering temperature, the $2{\theta}$ value of BT(110) peak was shifted to the lower degree and intensity of the $Ba_6Ti_2Nb_8O_{30}$ (133) peak was increased. Increasing the addition of $Nb_2O_5$, the intensity of $BaTiNb_4O_{13}$ (201) peak was decreased and $Ba_6Ti_2Nb_8O_{30}$ (133) peak was increased. The grain size of the $BaTiO_3+Nb_2O_5$ ceramics sintered at $1500^{\circ}C$ were almost uniform.

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Carbon nanotubes synthesis using diffusion and premixed flame methods: a review

  • Mittal, Garima;Dhand, Vivek;Rhee, Kyong Yop;Kim, Hyeon-Ju;Jung, Dong Ho
    • Carbon letters
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    • 제16권1호
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    • pp.1-10
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    • 2015
  • In recent years, flame synthesis has absorbed a great deal of attention as a combustion method for the production of metal oxide nanoparticles, carbon nanotubes, and other related carbon nanostructures, over the existing conventional methods. Flame synthesis is an energy-efficient, scalable, cost-effective, rapid and continuous process, where flame provides the necessary chemical species for the nucleation of carbon structures (feed stock or precursor) and the energy for the production of carbon nanostructures. The production yield can be optimized by altering various parameters such as fuel profile, equivalence ratio, catalyst chemistry and structure, burner configuration and residence time. In the present report, diffusion and premixed flame synthesis methods are reviewed to develop a better understanding of factors affecting the morphology, positioning, purity, uniformity and scalability for the development of carbon nanotubes along with their correlated carbonaceous derivative nanostructures.

BMCT 세라믹스의 마이크로파 유전특성 (The Microwave Dielectric Properties of BMCT Ceramics)

  • 이문기;최의선;류기원;이영희
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제51권8호
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    • pp.335-339
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    • 2002
  • Ba(Mgl-xCox)TaO3[BMCT] ceramics were prepared by the conventional mixed oxide method. The ceramics were sintered at the temperature of 1525~$1625^{\circ}C$ for 5hr. in air. The crystal structure of BMCT ceramics was investigated by the XRD. The microstructure of the specimens were observed by SEM. The Microwave dielectric properties of BMCT specimens were investigated as a function of composition and sintering temperature. All BMCT ceramics sintered over 1575$^{\circ}C$ were showed a polycrystalline complex perovskite structure. The density of BMCT (90/10) specimen sintered at $1575^{\circ}C$ was 7.75g/㎤. As the Co contents decreased, the ordering parameter of B-site in BMCT increased. In the case of the BMCT(90/10) ceramics sintered at $1575^{\circ}C$ for 5 hours, dielectric constant, quality factor and temperature coefficient of resonant frequency for microwave dielectrics application were a good value o( 25, 17, 845 at 10㎓ and +2.4 ppm/${\circ}$, respectively.

소결온도에 따른 0.8Ba($Zn_{1/3}Ta_{2/3})O_3$-0.2Ba($Co_{1/3}Nb_{2/3})O_3$ 세라믹스의 구조적 특성 (The Structural Properties of The Structural Properties of 0.8Ba($Zn_{1/3}Ta_{2/3})O_3$-0.2Ba($Co_{1/3}Nb_{2/3})O_3$ Ceramics with Sintering Temperature)

  • 배경인;이문기;임성수;김강;류기원;이영희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2000년도 하계학술대회 논문집 C
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    • pp.1667-1669
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    • 2000
  • The 0.8Ba($Zn_{1/3}Ta_{2/3})O_3$-0.2Ba($Co_{1/3}Nb_{2/3})O_3$ ceramics were prepared by conventional mixed oxide method. The structural properties of the 0.8BZT-0.2BCN ceramics with the sintering temperature were investigated by XRD and SEM. The 0.8BZT-0.2BCN ceramics had a superstructure reflection plane of (100), (200). Increasing the sintering temperature. the ordering parameter of B-site atoms were increased. The lattice constant of 0.8BZT-0.2BCN ceramics was 3.97${\AA}$. Increasing the sintering temperature, the average gram sizes were increased. In the case of the 0.8BZT-0.2BCN ceramics sintered at 1500$^{\circ}C$, the average grain size and bulk density were 1.56${\mu}m$, 6.93$g/cm^3$, respectively.

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소결온도에 따른 ${Ba_5}{B_4}{O_15}$ (B=Ta,Nb) 세라믹스의 구조 및 마이크로파 유전특성 (Structural and Microwave Dielectric Properties of the ${Ba_5}{B_4}{O_15}$ (B=Ta,Nb) Ceramics with Sintering Temperature)

  • 이승준;이성갑;배선기;이영희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2006년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.20-21
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    • 2006
  • In this study, structural and microwave dielectric properties of the ${Ba_5}{B_4}{O_{15}}$ (B=Ta, Nb} cation-deficient perovskite ceramics with sintering temperature were investigated. All sample of the ${Ba_5}{B_4}{O_{15}}$ (B=Ta, Nb) ceramics prepared by conventional mixed oxide method and sintered at $1325^{\circ}C{\sim}1575^{\circ}C$. The bulk density and dielectric constant of the ${Ba_5}{Ta_4}{O_{15}}$ ceramics were increased continuously with increasing of sintering temperature. And the bulk density and dielectric constant of the ${Ba_5}{Nb_4}{O_{15}}$ ceramics was increased in $1375^{\circ}C{\sim}1400^{\circ}C$ but decerased in $1425^{\circ}C$. In the case of ${Ba_5}{Ta_4}{O_{15}}$ ceramics sintered at $1475^{\circ}C$ and ${Ba_5}{Nb_4}{O_{15}}$ ceramics sintered at $1400^{\circ}C$, The dielectric constant and quality factor, and temperature coefficient of the resonant frequency (TCRF) were 25.15, 53,105 GHz, $-3.06\;ppm/^{\circ}C$ and, 39.55, 28,052 GHz, $5.7\;ppm/^{\circ}C$ respectively.

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제한요소를 고려한 가스터빈-가압형 SOFC 하이브리드 시스템의 성능특성 해석 (Analysis of Performance Characteristics of Gas Turbine-Pressurized SOFC Hybrid Systems Considering Limiting Design Factors)

  • 양원준;김동섭;김재환
    • 설비공학논문집
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    • 제16권11호
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    • pp.1013-1020
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    • 2004
  • The hybrid system of gas turbine and fuel cell is expected to produce electricity more efficiently than conventional methods, especially in small power applications such as distributed generation. The solid oxide fuel cell (SOFC) is currently the most promising fuel cell for the hybrid system. To realize the conceptual advantages resulting from the hybridization of gas turbine and fuel cell, optimized construction of the whole system must be the most important. In this study, parametric design analyses for pressurized GT/SOFC systems have been peformed considering probable practical limiting design factors such as turbine inlet temperature, fuel cell operating temperature, temperature rise in the fuel cell and soon. Analyzed systems include various configurations depending on fuel reforming type and fuel supply method.