• Title/Summary/Keyword: conventional oxide method

Search Result 321, Processing Time 0.038 seconds

Structural Properties of BMCT Ceramics with Sintering Temperature (소결온도에 따른 BMCT 세라믹스의 구조적 특성)

  • Lee, Moon-Kee;Lim, Sung-Su;Kim, Kang;Chung, Jang-Ho;Park, In-Gil;Lee, Young-Hie
    • Proceedings of the KIEE Conference
    • /
    • 2001.07c
    • /
    • pp.1421-1423
    • /
    • 2001
  • $Ba(Mg_{1-x}Co_x)TaO_3$[BMCT] ceramics were prepared by the conventional mixed oxide method. The ceramics were sintered at the temperature of 1525 $\sim$ 1625$^{\circ}C$ for 5hr. in air. The crystal structure of BMCT ceramics was investigated by the XRD. The microstructure of the specimens were observed by SEM. The structural properties of BMCT specimens were investigated as a function of composition and sintering temperature. All BMCT ceramics sintered over 1575$^{\circ}C$ were showed a polycrystalline complex perovskite structure without second phases and any unreacted materials. The density of BMCT (90/10) specimen sintered at 1575$^{\circ}C$ was 7.75g/$cm^2$. As the Co contents decreased, the ordering parameter of B-site in BMCT increased. The ordering parameter of BMCT(90/10) specimen sintered at 1575$^{\circ}C$ was 0.98.

  • PDF

The structural properties of (Ba,Sr)(Nb,Ti)$O_3$ ceramics with sintering temperature (소결온도에 따른 (Ba,Sr)(Nb,Ti)$O_3$ 세라믹스의 구조적 특성)

  • Park, Bo-Geun;Kim, Ji-Heon;Lee, Moon-Kee;Ryu, Ki-Won;Lee, Young-Hie
    • Proceedings of the KIEE Conference
    • /
    • 2001.07c
    • /
    • pp.1411-1413
    • /
    • 2001
  • The $(Ba_{0.5}Sr_{0.5})(Nb_{0.5}Ti_{0.5})O_3$ [BSNT] ceramics were prepared by conventional mixed oxide method. The structural properties of the BSNT ceramics with sintering temperature were investigated by XRD, SEM, EDS. Increasing the sintering temperature, diffraction intensity of the BST(110) peak was increased. The average grain size of BSNT ceramics were increased with sintering temperature. In the case of BSNT ceramics sintered at 1550$^{\circ}C$, the grain was uniform and the pore was not existed. Increasing the sintering temperature from 1400$^{\circ}C$ to 1500$^{\circ}C$, the amount of Nb and Sr were decreased. The density of BSNT ceramics sintered at 1550$^{\circ}C$ was $1.125g/cm^2$.

  • PDF

Microwave Dielectric Properties of the 0.96$MgTiO_3$-0.04$BaTiO_3$ Ceramics with Sintering Temperature (소결온도에 따른 0.96$MgTiO_3$-0.04$BaTiO_3$ 세라믹스의 마이크로파 유전특성)

  • Choi, Eui-Sun;Lee, Sang-Chul;Lee, Sung-Gap;Bae, Seon-Gi;Lee, Young-Hie
    • Proceedings of the KIEE Conference
    • /
    • 2001.07c
    • /
    • pp.1408-1410
    • /
    • 2001
  • The 0.96$MgTiO_3$-0.04$BaTiO_3$ ceramics were prepared by the conventional mixed oxide method. The structural properties were investigated with sintering temperature and composition ratio by XRD, SEM and EDS. According to the X-ray diffraction patterns of the 0.96$MgTiO_3$-0.04$BaTiO_3$ ceramics, the hexagonal $BaMg_6Ti_6O_{19}$ and ilmenite $MgTiO_3$ structures were coexisted. In the case of the 0.96$MgTiO_3$-0.04$BaTiO_3$ ceramics sintered at 1325$^{\circ}C$, dielectric constant, quality factor and temperature coefficient of resonant frequency were 23.95, 70,200, -55.8ppm/$^{\circ}C$, respectively.

  • PDF

Structural and Microwave Dielectric Properties of BMT-BCN Ceramics (BMT-BCN 세라믹의 구조 및 마이크로파 유전특성)

  • Lee, Moon-Kee;Park, In-Gil;Ryu, Ki-Won;Lee, Young-Hie
    • Proceedings of the KIEE Conference
    • /
    • 1998.07d
    • /
    • pp.1453-1455
    • /
    • 1998
  • $Ba(Mg,Ta)O_3-Ba(Co,Nb)O_3$ ceramics were prepared by the conventional mixed oxide method. The ceramics were sintered at the temperature of 1500-$1575^{\circ}C$ for 5[hr.] in air. The crystal structure was investigated by the XRD. The microstructure of the ceramics were observed by SEM. The microwave properties of dielectric resonators were investigated as a function of composition and sintering temperature. $Ba(Mg,Ta)O_3-Ba(Co,Nb)O_3$ ceramics have a structure of complex perovskite type, and have peaks of (101),(102),(201),(202) and (212). In the case of the $0.7Ba(Mg,Ta)O_3-0.3Ba(Co,Nb)O_3$ ceramic resonator, dielectric constant, quality factor and temperature coefficient of resonant frequency(TCRF, ${\tau}_l$) were a good value of 26.5, 11.500 at 10[GHz] and -1.3[ppm/$^{\circ}C$] from $25^{\circ}C$ to $60^{\circ}C$, respectively.

  • PDF

Electrical properties of NKN-0.94BNT-0.06BT ceramics (NKN-0.94BNT-0.06BT 세라믹스의 전기적특성)

  • Lee, Young-Hie;Nam, Sung-Pill;Lee, Sung-Gap;Bae, Seon-Gi;Lee, Seung-Hwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2010.06a
    • /
    • pp.298-298
    • /
    • 2010
  • In this study, both structural, dielectric properties of the NKN-0.94BNT-0.06BT ceramics were investigated. All samples of the NKN-0.94BNT-0.06BT ceramics were fabricated by conventional mixed oxide method with Pt electrodes. We report the improved electrical properties in the perovskite structure composed of the NKN, BNT and the BT ceramics. We investigated the effects of NKN, BT on the structural and electrical properties of the NKN-0.94BNT-0.06BT ceramics. The dielectric and structural properties of the NKN-0.94BNT-0.06BT ceramics were superior to those of single composition NKN, NKN-BNT and those values for the NKN-0.94BNT-0.06BT ceramics were 1455, 0.025 and $29.04{\mu}C/cm^2$.

  • PDF

Solution Processed Single Walled Carbon Nanotubes Transparent Conducting Films (투명전도막을 위한 용해 처리된 단일막 탄소나노튜브)

  • Manivannan, S.;Jeong, Il-Ok;Ryu, Je-Hwang;Jang, Jin;Park, Kyu-Chang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2008.11a
    • /
    • pp.45-45
    • /
    • 2008
  • In recent years, new materials and technology has been developed using single-walled carbon nanotubes (SWCNTs) as an alternative to indium tin oxide (ITO) to fulfil the requirements towards novel technological drive. These technologies offer products having a broad range of conductivity, excellent transparency, neutral color tone, good adhesion, abrasion resistance as well as mechanical robustness. In addition, SWCNTs can be solution processed to replace the sophisticated vacuum techniques at high temperatures. In the present work, transparent conducting films were fabricated from the purified SWCNTs. Dispersion of purified SWCNTs was accomplished in 1,2-dichlorobenzene without using surfactants or polymers following ultrasonic process. We achieved coating of nanotubes film on poly ether suiphone (PES) for an average sheet resistance ~110 ${\Omega}/{\Box}$ of optical transmittance 80% at 550 nm. Conventional spin coating method was followed to fabricate films from the purified and dispersed nanotubes solution. The results will be presented.

  • PDF

Mid-infrared Continuous-wave Optical Parametric Oscillator with a Fan-out Grating MgO:PPLN Operating Up to 5.3 ㎛

  • Bae, In-Ho;Yoo, Jae-Keun;Lim, Sun Do;Kim, Seung Kwan;Lee, Dong-Hoon
    • Current Optics and Photonics
    • /
    • v.3 no.6
    • /
    • pp.577-582
    • /
    • 2019
  • We report on a continuous-wave (cw) optical parametric oscillator (OPO) optimized for mid-infrared emission above 5.0 ㎛. The OPO is based on a magnesium-oxide-doped periodically poled LiNbO3(MgO:PPLN) crystal with a fan-out grating design. A linear two-mirror cavity resonating both at the pump and signal wavelengths is stabilized to the pump laser by using the modified Pound-Drever-Hall (PDH) method. The idler wavelength is continuously tunable from 4.7 ㎛ up to 5.3 ㎛ by varying the poling period of the fan-out grating crystal. Pumped by a diode-pumped solid state (DPSS) laser with a power of 1.1 W at 1064 nm, the maximum idler output power is measured to be 5.3 mW at 4.8 ㎛. The output power above 5.0 ㎛ is reduced to the hundreds of ㎼ level due to increased absorption in the crystal, but is stable and strong enough to be measured with a conventional detector.

Dielectric and Piezoelectric Properties of (Ba0.85Ca0.15)(Ti0.9Zr0.1)O3 Ceramics as a Function of Sintering Temperature (소결온도 변화에 따른 (Ba0.85Ca0.15)(Ti0.9Zr0.1)O3 세라믹스의 유전 및 압전 특성)

  • Lee, Kab-Soo;Yoo, Ju-Hyun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.27 no.1
    • /
    • pp.22-26
    • /
    • 2014
  • $(Ba_{0.85}Ca_{0.15})(Ti_{0.9}Zr_{0.1})O_3$ + 0.04 wt% $CeO_2$ lead-free ceramics were prepared by conventional oxide-mixed method and the effect of sintering temperature on microstructure, dielectric and piezoelectric properties were investigated. Improved piezoelectric properties have been observed at $1,400^{\circ}C$ sintering temperature which show the optimal electrical properties, $k_p{\sim}0.412$, $d_{33}{\sim}316pC/N$, $Q_m{\sim}144$, ${\varepsilon}_r{\sim}3,345$ and $T_c{\sim}85^{\circ}C$. These results show that the sintering temperature plays an important role in piezoelectric properties.

Development of the dielectric ceramics with low loss for microwave applications (고주파 응용을 위한 저손실 유전체 세라믹스의 개발)

  • Kim, Jae-Sik;Choi, Eui-Sun;Ryu, Ki-Won;Lee, Young-Hie
    • Proceedings of the KIEE Conference
    • /
    • 2008.07a
    • /
    • pp.1250-1251
    • /
    • 2008
  • In this study, the dielectric ceramics with low loss were investigated for high frequency application. All sample of the $Ba_5M_4O_{15}$ (M=Ta, Nb) ceramics were prepared by the conventional mixed oxide method and sintered at $1325{\sim}1575^{\circ}C$. The bulk density and dielectric constant of the $Ba_5Ta_4O_{15}$ ceramics were increased continuously with increasing of sintering temperature. The quality factor was increased in the sintering temperature of $1375{\sim}1475^{\circ}C$ but decreased at the temperature above 1475$^{\circ}C$. In the case of $Ba_5Nb_4O_{15}$ ceramics, the bulk density, dielectric constant and quality factor were increased with sintering temperature but decreased above temperature of 1400$^{\circ}C$. The dielectric constant, quality factor and temperature coefficient of the resonant frequency (TCRF) of the $Ba_5Ta_4O_{15}$ and $Ba_5Nb_4O_{15}$ ceramics, sintered at 1475$^{\circ}C$ and 1400$^{\circ}C$, were 25.15, 53105 GHz, -3.06 ppm/$^{\circ}C$ and 39.55, 28052 GHz, 5.7 ppm/$^{\circ}C$, respectively.

  • PDF

Fabrication of ZnO and CuO Nanostructures on Cellulose Papers

  • Nagaraju, Goli;Ko, Yeong Hwan;Yu, Jae Su
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2014.02a
    • /
    • pp.315.1-315.1
    • /
    • 2014
  • The use of cellulose papers has recently attracted much attention in various device applications owing to their natural advantageous properties of earth's abundance, bio-friendly, large-scale production, and flexibility. Conventional metal oxides with novel structures of nanorods, nanospindles, nanowires and nanobelts are being developed for emerging electronic and chemical sensing applications. In this work, both ZnO (n-type) nanorod arrays (NRAs) and CuO (p-type) nanospindles (NSs) were synthesized on cellulose papers and the p-n junction property was investigated using the electrode of indium tin oxide coated polyethylene terephthalate film. To synthesize ZnO and CuO nanostructures on cellulose paper, a simple and facile hydrothermal method was utilized. First, the CuO NSs were synthesized on cellulose paper by a simple soaking process, yielding the well adhered CuO NSs on cellulose paper. After that, the ZnO NRAs were grown on CuO NSs/cellulose paper via a facile hydrothermal route. The as-grown ZnO/CuO NSs on cellulose paper exhibited good crystalline and optical properties. The fabricated p-n junction device showed the I-V characteristics with a rectifying behaviour.

  • PDF