• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.190.1-190.1
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• 2016

One of the most serious problems faced by billions of people today is the availability of fresh water. According to statistics, 15% of the world's total output of dye products is discharged into the environment as dye wastewater, which seriously pollutes groundwater resources. For the treatment of chemically and biologically contaminated water the advanced oxidation processes (AOPs) shows the promising action. The main advantage with AOPs is the ability to degrade the organic pollutants to $CO_2$ and $H_2O$. For this degradation process the AOPs generation of powerful and non-selective radicals that may oxidize majority of the organic pollutants present in the water body. To generate the various reactive chemical species such as radicals (${\bullet}OH$, ${\bullet}H$, ${\bullet}O$, ${\bullet}HO_2$) and molecular species ($H_2O_2$, $H_2$, $O_2$) in large amount in water, we have used the atmospheric pressure plasma. Among the reactive and non-reactive species, the hydroxyl radical (${\bullet}OH$) plays important role due to its higher oxidation potential (E0: 2.8 V). Therefore, in this work we have checked the degradation of various dyes such as methyl orange, methylene blue and congo red using different type of atmospheric pressure plasma sources (Indirect jet and direct jet). To check the degradation we have used the UV-visible spectroscopy, HPLC and LC-MS spectroscopy. Further, to estimate role of ${\bullet}OH$ on the degradation of dyes we have studied the molecular dynamic simulation.

• Journal of Environmental Health Sciences
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• v.22 no.1
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• pp.45-50
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• 1996

The application of HACCP system, which was adopted by Codex Alimentarius Committee for the safe meat and poultry production, is one of the urgent task for competing in the world trade markets. But there have been no useful analytical studies to identify the causes of contamination in the poultry meat processing plants in Korea. This study was conducted to investigate the potential hazards during the operations by the microbiological examination for the poultry meat processing plant (20,000 birds capacity a day) located in Kangwon province. In spite of air contamination of work places, it may not directly affect the surface contamination of poultry meats. But the risk of Campylobacter jejuni/coli contamination was high. The number of total count was decreased about ten times, but remarkable changes of microbial contamination could not be recognized in each procedure during the operations. The washing water was already contaminated as much as $10^{3-6}CFU/ml$ in SPC before the operations. It means that to keep water tanks hygienic is a primary step to prevent the occurrences of microbial contamination. The overflow and recirculation of water in scalding, washing, and chilling was aslo an important factor for a hygienic control. Based on this study, the followings could be regarded as an important factors for hygenic control in the poultry slaughtering plants on a small scale. The temperature of water used for scalding should be constantly maintained on a required temperature, and the overflow rate of 1~1.5 liter per bird. The carcass surface and the body cavity should be washed thoroughly and the cross-contamination due to facilities, workers, and tools should be prevented. The chilling water sholud be maintained under 5$\circ$C of temperature with ice and overflow, and residual chlorine level of 50 ppm.

• Journal of Soil and Groundwater Environment
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• v.20 no.6
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• pp.62-72
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• 2015

This study investigates the in-situ implementation of bio-regenerated iron mineral catalyst to remove explosive compounds in ground water at a military shooting range in operation. A bio-regenerated iron mineral catalyst was synthesized using lepidocrocite (iron-bearing soil mineral), iron-reducing bacteria Shewanella putrefaciens CN32, and electron mediator (riboflavin) in the culture medium. This catalyst was then injected periodically in the ground to build a redox active zone acting like permeable reactive barrier through injection wells constructed at a live fire military shooting range. Ground water and core soils were sampled periodically for analysis of explosive compounds, mainly RDX and its metabolites, along with toxicity analysis and REDOX potential measurement. Results suggested that a redox active zone was formed in the subsurface in which contaminated ground water flows through. Concentration of RDX as well as toxicity (% inhibition) of ground water decreased in the downstream compared to those in the upstream while concentration of RDX reduction products increased in the downstream.

• Journal of the Korean Society of Environmental Restoration Technology
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• v.11 no.2
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• pp.40-54
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• 2008

Small and large dams are installed in the course of a stream for maintaining the water level of the stream or obtaining agricultural water. Currently about 18,000 of them are installed in Korea to supply water. However, the environmental problems of small dams are well known : the interruption of stream eco-corridors, deterioration of water quality in the upper reaches of the small dam, changes in the habitats of riparian organisms, damages to the stream scenery. In a very few of these small dams artificial eco-corridors like fishways are installed, but the number is very minimal.Accordingly, to efficiently restore stream eco-corridors by removing these small dams, it will be necessary to closely examine physical impacts, such as changes in the riverbed and changes in the shape of the stream caused by the removal, chemical impacts, such as changes in water quality, and transport and accumulation of contaminated sediments and biological impacts, such as changes in the habitats of organisms, and develop related technologies in advance, and have these technologies verified through demonstration application in the sites. In this study, we analyzed the physical, chemical and ecological impacts of the removal of the above-mentioned small dams, and conducted a research on the demonstration small dam removal project for a spot investigation. As a result, the small dam removal will restore the eco-corridor, there by improving the habitat of fishes and crustaceans. The number of major underwater organisms inhabiting the Gokreungcheon, such as Korean spotted sleepers, Chinese minnows, Microphysogobio yaluensis, Abbottina rivularis, stone morokos, striped shinners, long-nosed barbels, and Chinese mitten crabs, is expected to increase, and the food chain in the ecosystem will improve so that species diversity will improve as well.

• Journal of Korean Society on Water Environment
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• v.23 no.5
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• pp.581-590
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• 2007

A float-type weir has been proposed for the control of algal blooms in some of eutrophic reservoirs recently. It is known as a costly and ecologically sound method, but there is little understanding about the sustainability of this low-cost technology for reservoirs that are located in monsoon climate areas where large flood events during the summer cause high water surface fluctuations. The objective of this study was to assess the effectiveness of a skimmer weir aimed at controlling algal blooms in the lacustrine zone and near the drinking water withdrawal structures of Daecheong Reservoir under various hydrodynamic flow conditions. The effect of weir on the control of algal blooms was simulated using a laterally averaged two-dimensional hydrodynamic and eutrophication model that can accommodate vertical displacement of the weir following the water surface fluctuations. Numerical simulations were performed for two different hydrological conditions, 2001 and 2004 for representing drought year and normal year, respectively. The results showed that the weir is very effective method to control algal blooms in the reservoir by curtailing the transport of phosphorus and algae from contaminated inflow to the downstream lacustrine epilimnion during the draught year. However, large flood events occurred in 2004 transported nutrients and algae built upstream of the weir into the downstream euphotic zone by strong entrainments.

• Journal of Korean Society of Water and Wastewater
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• v.26 no.1
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• pp.149-157
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• 2012

Experiments for As(V) removal using synthesized $Ca{\cdot}Al$-monosulfate was performed from the water contaminated with arsenate. Monosulfate is known as LDHs (Layered Double Hydroxides) which is one of the anionic clay minerals. Monosulfate was synthesized mixing $C_3A$ (tricalcium aluminate), gypsum (calcium sulfate), and water with an intercalation method. The product form the synthesis was characterized by FE-SEM, WDXRF, PXRD, and FT-IR. Experiments with different doses of monosulfate were carried out for kinetic. As a result of experiment, the concentration of As(V) was reduced from 0.67 mM to 0.19 mM (0.67mM of monosulfate) and 0.178 mM (1.34 mM of monosulfate). The concentration of sulfate was increased with As(V) decrease. The result of PXRD showed that the d-spacing of inter layer ($d_{003}$ peak) was shifted from 8.927 ${\AA}$ to 8.095 ${\AA}$ because the sulfate in the inter layer of monosulfate was exchanged arsenate with water molecules bonded. From the FT-IR results, a new single band (800 cm-1) was observed after the reaction of monosulfate and As(V). The arsenic removal can be regarded as anion exchange mechanism that is one of the characteristics of LDHs from the results of PXRD and FT-IR analysis.

• Journal of Environmental Health Sciences
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• v.38 no.1
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• pp.73-81
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• 2012

Objectives: With the goal of quantifying the risk of children contracting gastroenteritis while playing at interactive waterscape facilities and evaluating the adequacy of current water quality regulations, risk assessment was performed with Escherichia coli as pathogen. Methods: Abundances of E. coli in the waters of interactive water features in South Korea were acquired from survey reports. A gamma distribution describing the volume of water swallowed by children during swimming activities was adopted. Exposure rate and risk were calculated by Monte Carlo simulation and dose-response models for various pathogenic E. coli. Results: E. coli was detected in 25 out of 40 facilities, with range of ~1,600 CFU/100 ml. The abundance fitted an exponential distribution. Simulated exposures ranged ${\sim}1.9{\times}10^{10}$ CFU, varying greater along E. coli abundance than the volume of water. Risk of children being infected by enterohemorrhagic E. coli was high, with range of ~0.85. When E. coli abundance was <200 CFU/100 ml, which is the current government threshold, the risk decreased to <0.43. Although the guideline successfully reduced the risk of adults being infected by a less virulent E. coli strains (<0.03), the risk for children could not be quantified due to lack of dose-response models for those pathogens for children. Conclusions: Under the current guideline, children are at risk of being infected if water is contaminated with by enterohemorrhagic E. coli. For other E. coli strains, the risk appears to be considerably less. The result warrants need for developing dose-response models for children for each pathogenic E. coli strain.

• Journal of Mushroom
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• v.1 no.1
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• pp.28-33
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• 2003

Pseudomonas tolaasii causing brown blotch disease was detected by PCR from water samples collected from the oyster mushroom cultivation farms to find the contamination level of the pathogen in water. Sixteen water samples (28.1%) contain less than 1,000 cfu, 31 samples (54.4%) contain 1,001-10,000 cfu, 6 samples (10.5%) contain 10,001-100,000 cfu, and 4 samples (7%) contain of bacteria per milliliter. P. tolaasii-specific DNA band was amplified in 3 samples (5.3%) by nested-PCR and in 20 samples (35.1%) by immunocapture (IC)-nested PCR respectively. These results suggest that IC-nested-PCR was much more sensitive than nested-PCR in detection of P. tolaasii and a quite few waters using for oyster mushroom cultivation were contaminated with P. tolaasii.

• Journal of Environmental Impact Assessment
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• v.18 no.6
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• pp.461-467
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• 2009

This paper provides two case studies of environmental impacts with socio-economic values. The first case is on flood protection levees conducted from 2003 to 2004 in Phu Tan district, An Giang province. The impacts were found by comparing full flood protection levees area (FFPL) to non-full flood protection levees area (NFFPL). Participatory Rural Appraisal (PRA) tools per each group of rich, middle, and poor people were used to list the impacts. Then, major impacts were selected by ranking and interviewing 60 households per site, and assessed by Cost Benefit Analysis (CBA) in rice production from 1996 to 2002 between two areas. The tested research indicated moving system of NFFPL to that of FFPL lost about 11 million VND/ha/year. The second case is on impacts of Penaeid shrimp farming conducted in Duyen Hai District, Tra Vinh Province in 2004-2005. Ninety households and 12 local officials were interviewed. Four PRAs were conducted and 36 water samples were taken inside and outside shrimp pond to measure values of DO, COD, Fe total, TSS, N-$NO_3{^-}$, N-$NH_4{^+}$, P-$PO{_4}^{3-}$, and Chlorophyll-a. Research results showed only 36.7% of the households got profit from shrimp farming. Highest financial efficiency was 0.72 for the semi-intensive system. Tested water indicators showed surface water quality did not match Vietnamese standard for surface water in coastal area (TCVN 5943-1995) and in rain. The water was very muddy and contaminated by organic aluminum. Summarily, the impacts were clarified more obviously via adding socio-economic values to assessment. Importantly, the values were transformed to household's income which is an indicator for policy-makers to consider the impacts obviously. Besides, data of different group of people impacted are cases contributing to consideration of the impacts in an appropriate social level.

• Journal of the Korean Chemical Society
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• v.13 no.4
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• pp.401-407
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• 1969

The results of water analysis for 10 stations in the main Naktong and 11 stations in the tributaries from March to December 1968 are as follows: The water quality of the Naktong River Basin is generally the frist class of water, especially the tributaries, Hwang river, Nam river, Milyang river, Naesongchun, Hoechun, Wichun and Panbyunchun were dissolved in less than 100 mg/l as the amount of the total ion of the main component. In comparison with river discharge, the amount of the total ion of the main component is decreased in June and July, because of the river discharge is increased in those periods. According to the measurement of the conductivity and the hardness, the better water quality is distinguished by the following order: lower part of river (Namji), middle part of river (Waegwan), upper part of river (Yean). The conductivity of Kumho river, Tongchon is higher than the middle part of the main river and Nam river, Chongam is smaller than lower part of the main rivller. The variation of the amount of the total ion of main component in the basin is mainly effected by $HCO_3^-, SO_4^{-2}, Cl^-, Ca^{+2}$. The relationship between $[K^+]\;and\;[C^l-]\;and\;[Na^+]\;and\;[Cl^-]\;are\;[K^+]=0.04\;[Cl^-]+1.7\;mg/l,\;[Na^+]=0.06\;[Cl^-]$ mg/l .The main river was much contaminated by Kumho river and C.O.D. at Gang-chung, Kumho river in June was recorder over the standard about 7 times.