• 제목/요약/키워드: contaminated water

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원위치 토양세척 공정의 효율향상을 위한 세제선정과 운전기법 (Selection of Surfactant and Operation Scheme for Improved Efficiency of In-situ Soil Flushing Process)

  • 손봉호;임봉수;어성욱;이병호
    • 한국물환경학회지
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    • 제22권5호
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    • pp.824-830
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    • 2006
  • Several tests were conducted to optimize the design parameters of ln-situ soil flushing processes for diesel contaminated soil. According to the batch extraction test for three anionic surfactants evaluation, Calgonit limiting bubble occurrence was selected for its higher oil cleaning efficiency. After optimum surfactant selection, there were many sets of column flushing test. Over 70% of BTEX was removed in this surfactant dose with 400% of soil volume. In the case of no surfactant addition flushing in column, so called "blank flushing test", BTEX removal rate was 64%. But when we reused the effluent for the cleaning solution, the removal rate was decreased to 46.9%. This result showed reabsorption of oil occurred on the soil. With the addition of Calgonit solution to the diesel contaminated column, BTEX was removed up to 98.9% during the first flushing and 99.4% for the second recirculation flushing. In microcosm tests, diesel contaminated soils were cleaned by both surfactant flushing and biological activities. In anoxic condition, nitrate was used as an electron acceptor while the surfactant and the oil were used an electron donor. BTEX removal efficiency could be achieved up to 80% by biological degradation.

중금속 오염 폐광산 주변토양의 세정 (Soil Washing of Abandoned Mine Soils Contaminated by Heavy Metals)

  • 이준호;남권철;박갑성
    • 한국물환경학회지
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    • 제22권5호
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    • pp.871-878
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    • 2006
  • Batch experiments were performed to evaluate the applicability of soil washing for heavy metal contaminated soils at Nacdong and Hamchang abandoned mines. The texture of the Nacdong soil was sandy loam. Nacdong abandoned mine soil was almost neutral (pH=6.5). Contaminations of As, Cd, Pb and Zn for Nacdong mine soils were 12,900 mg/kg, 29 mg/kg, 696 mg/kg and 276 mg/kg, respectively. Hamchang abandoned mine soils were acidic (pH=2.6) and the soil texture was loam. The contaminations of As, Cd, Pb and Zn for Hamchang abandoned mine soils were 6,410 mg/kg, 291 mg/kg, 1,300 mg/kg and 1,110 mg/kg, respectively. For the Nacdong abandoned mine soils, oxalic acid was found to be the most effective soil washing extracter for As and Pb while citric acid was the most effective extracter for Cd. For the Hamchang abandoned mine soils, oxalic acid showed the highest extraction efficiencies for As and Pb, whilst citric acid presented the best soil washing efficiencie for Cd. Oxalic acid and EDTA were found to be the most effective soil washing extracter for the Hamchang abandoned mine contaminated soils.

미생물 오염 용수 관개에 의한 작물의 오염 위험성 (Irrigation with Microbial-Contaminated Water and Risk of Crop Contamination)

  • 최연식;송인홍;권순국
    • 한국농공학회논문집
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    • 제49권2호
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    • pp.87-97
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    • 2007
  • The aim of this study was to compare crop contamination between two irrigation methods using microbial-contaminated water. The effect of relative humidity on microbial survival of the three indicator microorganisms was also investigated. Escherichia coli ATCC 25922, Clostridium perfringens ATCC 3624, and coliphage PRD1 were applied to irrigation water to grow cantaloupe, lettuce, and bell pepper. Half of the sixteen plots were subsurface drip irrigated (SDI) and the other half were furrow irrigated (FI). Two relative humidity levels were controlled at 15-65 % and 55-80 % for the dry and humid condition experiments, respectively. Samples of produce, surface soil, and subsurface soil at a depth of 10 cm were collected over a two-week period following the application of the study microorganisms. Overall, greater contamination of both produce and soil occurred in the FI plots. For the SDI plots, preferential water paths and resulting water appearance on the seed beds seemed to be responsible for produce contamination. Relative humidity levels did not appear to affect microbial survival in soil. PRD 1 showed lower inactivation rates than 5. coli in both dry and humid conditions. C. perfringens did not experience significant inactivation over the experimental period, suggesting this microorganism can be an effective indicator of fecal contamination.

Change in Water Contact Angle of Carbon Contaminated TiO2 Surfaces by High-energy Electron Beam

  • Kim, Kwang-Dae;Tai, Wei Sheng;Kim, Young-Dok;Cho, Sang-Jin;Bae, In-Seob;Boo, Jin-Hyo;Lee, Byung-Cheol;Yang, Ki-Ho;Pack, Ok-Kyung
    • Bulletin of the Korean Chemical Society
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    • 제30권5호
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    • pp.1067-1070
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    • 2009
  • We studied change in water contact angle on $TiO_2$ surfaces upon high-energy electron-beam treatment. Depending on conditions of e-beam exposures, surface OH-content could be increased or decreased. In contrast, water contact angle continuously decreased with increasing e-beam exposure and energy, i.e. change in the water contact angle cannot be rationalized in terms of the overall change in the surfacestructure of carbon-contaminated $TiO_2$. In the C 1s spectra, we found that the C-O and C=O contents gradually increased with increasing e-beam energy, suggesting that the change in the surface structure of carbon layers can be important for understanding of the wettability change. Our results imply that the degree of oxidation of carbon impurity layers on oxide surfaces should be considered, in order to fully understand the change in the oxide surface wettability.

생체지표를 이용한 지하수 오염의 건강 영향 평가: 일개 지역을 중심으로 (Health Effects of Exposure to Oil-contaminated Water Using Biological Markers: Focusing on G Village near the Area of Daecheon Beach)

  • 오두남;임경춘;박승미
    • Journal of Korean Biological Nursing Science
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    • 제15권2호
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    • pp.74-81
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    • 2013
  • Purpose: This study was conducted to explore the health effects of exposure to oil-contaminated water in G village near the area of Daecheon beach on which air force had test fired. Methods: Eighty residents consented and were divided into three groups; 33 residents(drinking well water and still living there), 23 residents(drinking well water but do not live there any more), and 24 residents(did not drink well water but live there now: control group). Data were collected from August to September, 2010 from the survey questionnaires, general health examination, specific functional test, and biological marker tests. Results: Current residents showed higher levels of body mass index, blood pressure, and fasting blood glucose that are related to adult diseases. 64 participants received specific test for cancer. Only one person had esophageal cancer. Perchloroethylene was not found in the Urine Samples. Current residents showed a higher level of 8-hydroxydeoxyguanosine, an indicator of oxidative damage, and there was a statistically significant difference after correcting the confounding variables. Conclusion: We need education programs for managing the risk factors that are related to adult diseases in people who are now living in this village. We also need to expand further studies for investigating oxidative damage indicators.

다중 환경추적자를 이용한 제주도 지하수 유동 및 수질 특성 분석

  • 고동찬;김용재
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2004년도 임시총회 및 추계학술발표회
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    • pp.138-141
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    • 2004
  • The environmental tracers tritium/helium-3 (3H/3He) and chlorofluorocarbons (CFCs) were investigated in ground water from Jeju Island, Korea, a basaltic volcanic island. The apparent 3H/3He and CFC-12 ages were in relatively good agreement in samples with low concentrations of terrigenic He. Ground water mixing was evaluated by comparing 3H and CFC-12 concentrations with mixing models, which distinguished old water with negligible 3H and CFC-12, young water with piston flow, and binary mixtures of the two end members. The ground water CFC-12 age is much older in water from wells completed in confined zones of the hydro-volcanic Seoguipo formation in coastal areas than in water from the basaltic aquifer. Comparison of major element concentrations in ground water with the CFC-12 age shows that nitrate contamination processes contribute more solutes in young water than are derived from water-rock interactions in non-contaminated old water. Chemical evolution of ground water resulting from silicate weathering in basaltic rocks reaches the zeolite-smectite phase boundary. The calcite saturation state of ground water increased with the CFC-12 apparent (piston flow) age. In agricultural areas, the temporal trend of nitrate concentration in ground water was consistent with the known history of chemical fertilizer use on Jeju Island, but the response of nitrate concentration in ground water to nitrogen inputs follows an approximate 10-year delay. Based on mass balance calculations, it was estimated that about 40% of the nitrogen applied by fertilizers reached the water table and contaminated ground water resources when the fertilizer use was at the highest level.

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청주시 지하수의 인자분석 (An Factor Analysis of Groundwater in Chongju City)

  • 남기창
    • 환경위생공학
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    • 제18권4호
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    • pp.6-14
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    • 2003
  • A spring water quality was depend on the aquifer soil status. However, water quality was rapidly contaminated by artificial affects. In the contaminate components, the heavy metals were significantly important because the heavy metals influence the plants and the animals. But, it is difficult to find out how the heavy metal can affect in the water quality. According to the group analysis and the factor analysis, water quality management was advanced. The experimental area was divided into three region and six factor. The six factor could not define the overall water quality, however this method were one of the useful methods.

막투과법에 의한 녹차음료의 카드뮴 및 납 제거효과 (Effect of Green Tea Beverage on the Removal of Cadmium and Lead by Membrane Filtration)

  • 최성인;이정희;이서래
    • 한국식품과학회지
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    • 제26권6호
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    • pp.740-744
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    • 1994
  • 본 연구는 녹차음료가 음용수나 식품에 오염된 중금속 (Pb, Cd)의 장내 흡수 억제효과가 있는지를 조사하기위해 장내 흡수 조건을 고려한 한외여과막을 이용한 in vitro 실험을 실시하였다. 납과 카드뮴이 수질기준의 10배 또는 100배로 오염된 음료수애서 단독오염의 경우 납은 녹차, 홍차에서 $50{\sim}70%$, 보리차에서 $30{\sim}40%$의 제거율을 보였으며 카드뮴은 녹차, 홍차에서 $30{\sim}40%$, 보리차에서 $10{\sim}20%$의 제거율을 나타냈다. 납과 카드뮴이 혼합오염된 경우는 단독오염보다 제거효과가 낮았는데 이는 다엽성분 및 여과막에 대한 두 금속원소의 흡착경합에 기인하는 것으로 생각된다. 다류 원료에서 음료틀 침출하는$70^{\circ}C$, 2분과 $95^{\circ}C$, 10분외 두 조건은 비슷한 중금속 제거율을 보였다. 녹차의 페놀성 물질인 tannic acid 와 gallicd acid도 비슷한 중금속 제거효과를 보였다.

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타액에 오염된 상아질에 대한 콤포머의 접합양상 (THE ADHESIVE PATTERNS OF COMPOMER TO SALIVA-CONTAMINATED DENTIN)

  • 조영곤;김병태;이석종
    • Restorative Dentistry and Endodontics
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    • 제25권4호
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    • pp.575-586
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    • 2000
  • In this study, adaptation of compomer to saliva contaminated dentin was evaluated with scanning electron microscope(SEM) and confocal laser scanning microscope(CLSM). For the SEM study, the occulusal surfaces of thirty two molar teeth were grounded to exposure dentin surfaces. The specimen were randomly assigned to control and three experimental groups with four samples in each group. In control group, Dyract and F-2000 compomer were bonded on the specimens according to the manufactures direction. Experimental groups were subdivided into three groups. They were contaminated with saliva on dentin surfaces ; Experimental group 1 : Saliva was dried with compressed air. Experimental group 2 : Saliva was rinsed with air-water spray and dried. Experimental group 3 : After polymerization of an adhesive, they were contaminated with saliva, and then saliva was rinsed with air-water spray and dried. Dyract and F-2000 compomer were bonded on saliva-treated dentin surfaces. The interfaces between dentin and compomer were observed with SEM. For the CLSM study, Class V cavities were prepared in buccal and ligual surfacess of thirty two molars. The specimens were divided into control and experimental groups. Class V cavities in experimental group were contaminated with saliva and those surfaces in each experimental groups received the same treatments as for the SEM study. Cavities were applied Prime & Bond 2.1 and F-2000 compomer primer/adhesive that were mixed with fluorescein, and then were filled with Dyract and F-2000 compomer. Specimens were embedded in transparent acrylic resin and sectioned buccolingual1y with diamond wheel saw, and then mounted on cover slide for CLSM study. The interface between cavity and compomer was observed by fluoresence imaging with a CLSM. The results were as follows : 1. In SEM exammination of Dyract group, control group, experimental group 2, 3 showed close adaptation to dentin and hybrid layer of $3{\sim}4{\mu}m$ diameter. Interfacial gap between compomer and dentin in experimental group 1 was wider than in control group. 2. In SEM examination of F-2000 group, adaptation to dentin of control group was closer than Dytact control group, but hybrid-like layer was not observed. Interfacial gap between compomer and dentin in experimental group 1 was wider than in Dyract experimental group 1. 3. In dissolution specimens of Dyract and F-2000 group, resin tags penetrated through dentinal tubules in control group and experimental group 1 and 3, but the penetration of resin tag was irregular and partial in experimental group 1. 4. In CLSM exammination of Dyract and F-2000 group, adhesive patterns of control and experimental groups showed same as in SEM. This result suggests the treatment methods, rinsing & drying, repeating all adhesive procedures, will produce good effect on adaptation of compomer to dentin if the dentin surface or polymerized adhesive is contaminated by saliva.

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