• Title/Summary/Keyword: contaminated water

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Removal of Malathion Residues from Fruits and Vegetables by Washing Processes (과일채소중 말라티온 잔류분(殘溜分)의 세척효과)

  • Shim, Aei-Ryun;Choi, Eon-Ho;Lee, Su-Rae
    • Korean Journal of Food Science and Technology
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    • v.16 no.4
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    • pp.418-422
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    • 1984
  • In order to determine the removal efficiency of pesticide residues in fruits and vegetables by washing processes, samples of lettuce, young Chinese radish, Chinese cabbage, green red pepper, strawberry and grape were artificially contaminated with malathion and washed according to the household practices. After three times washings with water, the remaining ratios of malathion residues in grape, green red pepper, strawberry, young Chinese radish, lettuce and Chinese cabbage were 9.7%, 25.2%, 28.0%, 29.7%, 38.9% and 57.5%, respectively. After washing with detergent solution followed by two times rinsing with water, the remaining ratios of malathion residues in the same food samples were 1.6%, 8.3%, 15.8%, 24.8%, 27.2% and 45.9%, respectively. The removal efficiency of malathion by detergent washing was significantly higher than the water washings only. The removal ratio of malathion residues was the highest in the first washing and the ratio fell greatly in the following washings. The removal efficiency was not quite different in the temperature range of $5-35^{\circ}C$ of the washing solution, but the efficiency at $100^{\circ}C$ was 2-3 times higher than other temperature ranges.

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The Contamination of Groundwater by Acid Mine Drainage in the Vicinity of the Hanchang Coal Mine and the Efficiency of the Passive Treatment System (산성광산배수에 의한 한창탄광 부근 지하수의 오염과 자연정화처리시설 효율에 관한 연구)

  • 지상우;김선준
    • Journal of Soil and Groundwater Environment
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    • v.8 no.2
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    • pp.9-18
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    • 2003
  • Sampling of waters from each stage of treatment system (Successive Alkalinity Producing System; SAPS), tailings seepage, and spring near the Hanchang coal mine of Kangwon Province were carried out seasonally and analyzed to evaluate the source and possible path of groundwater contamination by acid mine drainage (AM). Sulfur isotope compositions were measured to identify the origin of groundwater contaminations and the sulfate reduction processes in the SAPS. Low pH and high metal concentration of spring water indicates possibility of the groundwater contamination by AMD. Removal efficiency of acidity of the SAPS was 18.17 g/$\textrm{m}^2$/day on an average and the metal removal efficiency was almost 100%, which was higher than those of other treatment systems. However, no appreciable decrease of sulfur content and almost similar sulfur isotope compositions of water from each stage of the treatment system may suggest incomplete or very poor sulfate reduction by sulfate reducing bacteria. Chemical and sulfur isotope compositions showed that spring water was contaminated by seepage from mine tailings. And seepage of stonewall, a part of treatment system was affected by both tailings seepage and mine adit drainage. In this study site, the treatment system was constructed for the only AMD from mine adit not for tailings seepages, which resulted in the groundwater contamination from tailing seepages. Similar situation is expected in other abandoned coal mine areas.

Removal of Radioactive Ions from Contaminated Water by Ion Exchange Resin (오염된 물로부터 이온교환수지를 이용한 방사성이온 제거)

  • Shin, Do Hyoung;Ju, Ko Woon;Cheong, Seong Ihl;Rhim, Ji Won
    • Applied Chemistry for Engineering
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    • v.27 no.6
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    • pp.633-638
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    • 2016
  • In this study, we used three kinds of commercially available cation, anion, and mixed-ion exchange resins to separate radioactive ions from a polluted water containing Cs, I, and other radioactive ions. The experiment was conducted at a room temperature with a batch method, and a comparative analysis on the decontamination ability of each resin for the removal of Cs and I was performed by using different quantities of resins. The concentration was analyzed using ion chromatography and the ion exchange resin product from company D showed an overall high ion exchange ability. However, for most of the experiments when the amount of ion exchange resin was decreased, the decontamination ability of the resins against mass increased. When the mass of company D's cation exchange resin was small, the ion exchange ability against Cs and I ions were measured as 0.199 and 0.344 meq/g, respectively. When the mixed ion exchange resin was used, the ion exchange ability against I ions was measured as 0.33 meq/g. All in all, company D's ion exchange resins exhibited a relatively higher ion exchange ability particularly against I ions than that of other companies' exchange ions.

Human Health Risk Assessment of Benzene from Industrial Complexes of Chungcheong and Jeonla Province (충청·전라지역 산업단지 주변지역에서의 벤젠 인체 위해성 평가)

  • Jang, Yong-Chul;Lee, Sungwoo;Shin, YongSeung;Kim, Heekap;Lee, Jonghyun
    • Journal of Environmental Impact Assessment
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    • v.20 no.4
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    • pp.497-507
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    • 2011
  • This research studied human health risk assessment of benzene from industrial complexes of Chungcheong Province (Seosan industrial complex) and Jeonla Province (Iksan industrial complex and Yeosoo industrial complex). The residents near the industrial complexes areas can be often exposed to volatile organic compounds (e.g., benzene, toluene, xylenes) through a number of exposure pathways, including inhalation of the organic pollutant via various environmental matrices (air, water and soil), contaminated water, and soil intake. Benzene is well known to be a common carcinogenic and toxic compound that is produced from industrial and oil refinery complexes. In this study, a number of samples from water, air, and soil were taken from the residential settings and public school zones located near the industrial complex sites. Based on the carcinogenic risk assessment, the risk estimates were slightly above $10{\times}10^{-6}$ at all three industrial sites. According to deterministic risk assessment, inhalation was the most important route. The distribution of benzene in the environment would be dependent on vapor pressure, and the physical property influencing the extent of the potential risks. Non-carcinogenic risk assessment of benzene shows that the values of Hazard Index(HI) were much lower than 1.0 at all industrial complexes. Therefore, benzene was not a cause of concern in terms of non-carcinogenic risk posed to the residents near the sites. When compared to probabilistic risk assessment, the CTE(central tendency exposure) cancer risk values of deterministic risk assessment were close to the mean values predicted by the probabilistic risk assessment. The RME(reasonable maximum exposure) values fell within the range of 95% to 99.9% estimated by the probabilistic risk assessment. Since the values of carcinogenic risk assessment were higher than $10{\times}10^{-6}$, further detailed monitoring and refined risk assessment for benzene may be warranted to estimate more reliable and potential inhalation risks to receptors near the industrial complexes.

The XPS and SEM Evaluation of Various Technique for Cleansing and Decontamination of The Rough Surface Titanium Implants (수종의 방법으로 임프란트 표면 처치후 표면의 형태 및 성분 변화 분석에 관한 연구)

  • Kim, Sun-bong;Yim, Sung-Bin;Chung, Chin-Hyung
    • Journal of Periodontal and Implant Science
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    • v.31 no.4
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    • pp.749-763
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    • 2001
  • Osseointegrated titanium implants have become an integral therapy for the replacement of teeth lost. For dental implant materials, titanium, hydroxyapatite and alumina oxide have been used, which of them, titanium implants are in wide use today. Titanium is known for its high corrosion resistance and biocompatability, because of the high stability of oxide layer mainly consists of $TiO_2$. With the development of peri-implantitis, the implant surface is changed in surface topography and element composition. None of the treatments for cleaning and detoxification of implant surface is efficient to remove surface contamination from contaminated titanium implants to such extent that the original surface elemental composition. In this sights, the purpose of this study was to evaluate rough surface titanium implants by means of scanning electron microscopy(SEM) and X-ray photoelectron spectroscopy(XPS) with respect to surface appearance and surface elemental composition. Moreover, it was also the aim to get the base for treatments of peri-implantitis. For the SEM and XPS study, rough surface titanium models were fabricated for control group. Six experimental groups were evaluated: 1) long-time room exposure, 2 ) air-powder abrasive cleaning for 1min, 3) burnishing in citric acid(pH1) for 1min, 4) burnishing in citric acid for 3min, 5) burnishing in tetracycline for 1min, 6) burnishing in tetracycline for 3min. All experimental treatments were followed by 1min of rinsing with distilled water. The results were as follows: 1. SEM observations of all experimental groups showed that any changes in surface topography were not detected when compared with control group. (750 X magnification) 2. XPS analysis showed that in all experimental groups, titanium and oxygen were increased and carbon was decreased, when compared with control group. 3. XPS analysis showed that the level of titanium, oxygen and carbon in the experimental group 3(citric acid treatment for 1min, followed by 1min of distilled water irrigation) reached to the level of control group. 4. XPS analysis showed that significant differences were not detected between the experimental group 1 and the other experimental groups except of experimental group 3. The Ti. level of experimental group 2, airpowder abrasive treatment for lmin followed by 1min of saline irrigation, was lower than the Ti. level of tetracycline treated groups, experimental group 5 and 6. From the result of this study, it may be concluded that the 1min of citric acid treatment followed by same time of rinsing with distilled water gave the best results from elemental points of view, and can be used safely to treat peri-implantitis.

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Perchlorate Removal by River Microorganisms in Industrial Complexes (산업단지지역 하천 미생물에 의한 퍼클로레이트 제거)

  • Jo, Kang-Ick;Ahn, Yeonghee
    • Korean Chemical Engineering Research
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    • v.52 no.1
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    • pp.92-97
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    • 2014
  • Perchlorate ($ClO_4^-$) is an emerging contaminant of soil/groundwater and surface water. $ClO_4^-$ has been shown to inhibit iodide uptake into the thyroid gland and cause a reduction in thyroid hormone production. $ClO_4^-$ is highly soluble and very stable in water. Biodegradation by $ClO_4^-$-reducing bacteria (PRB) is considered the most important factor in natural attenuation of $ClO_4^-$. Rivers in an industrial complex have potential to be contaminated with $ClO_4^-$ discharged from point or non-point sources. In this study, water samples were taken from the rivers running through the Gumi industrial complexes and used for batch test to analyze $ClO_4^-$-degradation potential of river microorganisms. The results of 83-h batch culture showed that $ClO_4^-$-removal efficiency of all samples was 0.77% or less without addition of an external electron ($e^-$) donor. However $ClO_4^-$-removal efficiency was higher when an $e^-$ donor (acetate, thiosulfate, $S^0$, or $F^0$) was added into the batch culture, showing up to 100% removal efficiency. The removal efficiency was various depending on type of $e^-$ donor and site of sampling. When acetate was used as an $e^-$ donor, the highest $ClO_4^-$-removal efficiency was observed among the $e^-$ donors used in this study, suggesting that activity of heterotrophic PRB was dominant. The results of this study provide basic information on natural attenuation of $ClO_4^-$ by river microorganisms. The information can be useful to prepare a strategy to enhance efficiency of $ClO_4^-$ biodegradation for in situ bioremediation.

A Study on Hygienic Control of contact lens Storage case (콘택트렌즈의 저장 케이스의 위생관리에 관한 연구)

  • Shin, Jae Hyun
    • Journal of Korean Ophthalmic Optics Society
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    • v.5 no.2
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    • pp.33-42
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    • 2000
  • This study was conducted for 356 customers coming to N optometrist office in Masan city in order to evaluate practice of hygienic control of contact lens storage cases. The results were as follows: 1) For disinfection of contact lens storage case, students used wetting saline solution(42.6%), exclusive wetting solution(23.0%) and 21(11.5%) of them didn't practice disinfection. Others besides students used wetting saline solution(29.1%), boiling water(27.3%) and 42(25.5%) of them didn't practice disinfection(P<0.01). 2) For storage case washing solution, 18(85.7%) out of 21 people who belong to high economic class used wetting saline solution, 3(14.3%) used exclusive wetting solution, 141(48.0%) out of 294 people who belong to middle economic class used wetting saline solution, 129(43.9%) used exclusive solution(P<0.01). 3) For wetting solution of storage case, 132(74.6%) out of 177 students used exclusive wetting solution and the rest(25.4%) used wetting saline solution, 102(64.2%) out of 159 others besides students used exclusive wetting solution, 51(32.1%) used wetting saline solution and 6(3.8%) used sold water and city water(P<0.05). 4) 66(94.3%) out of 70 contact lens storage cases were contaminated by bacteria and Serratia marcescens was isolated in 33(47.1%) out of 70 contact lens storage cases.

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Characteristic of Permeability with the Sand, Calcium Bentonite and Solidifier Mixtures according to Selective Reaction of TCE (트리클로로에틸렌(TCE) 선택적 반응에 따른 모래, 칼슘-벤토나이트 및 겔화제 혼합차수물의 투수 특성)

  • Yun, Seong Yeol;Choi, Jeong Woo;Oh, Minah;Lee, Jai-Young
    • Journal of the Korean Geosynthetics Society
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    • v.19 no.1
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    • pp.25-33
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    • 2020
  • To improvement the swelling characteristics of the existing cutoff wall against the moisture, the permeability of the sand, calcium bentonite and solidifier mixture according to the contact with trichloroethylene (TCE) was evaluated. Characteristics analysis and the permeability test of the research materials were performed. The permeability was decreased as the mixing ratio of the calcium bentonite was increased and it was increased as the mixing ratio of the solidifier was increased. In conclusion, when mixing 15% of calcium bentonite and more than 30% of solidifier, the permeability coefficient in the underground water movement was analyzed as more than α × 10-4 cm/sec showing that it does not block the underground water movement. In addition, as the permeability coefficient of mixtures after TCE reaction was analyzed as less than α ×10-7 cm/sec, it satisfied the condition of blocking layer (less than 1.0 × 10-6 cm/sec). Therefore, the calcium bentonite and solidifier can be utilized as barrier that showing the characteristic of percolation ability conversion in soil and underground water contaminated with TCE.

Pollution Characteristics of Water and Sediments for contaminated Agricultural Reservoirs (오염된 농업용저수지에서의 수질 및 퇴적물의 오염 특성)

  • Lee, Jin Kyung;Choi, Sun Hwa;Lee, Seong Houn
    • Proceedings of the Korea Water Resources Association Conference
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    • 2016.05a
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    • pp.500-500
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    • 2016
  • 전국의 농업용 저수지 중 장기간 높은 유기물 및 영양염의 농도로 인해 부영양화가 우려되는 71개 저수지에 대하여 수질오염 및 퇴적물오염 특성을 분석하였다. 수질오염 특성 분석 결과, 평균농도가 COD 11.7 mg/L, TOC 6.8 mg/L, TN 1.844 mg/L, TP 0.101 mg/L, SS 18.1 mg/L, Chl-a 57.3 mg/$m^3$ 로 분석되었다. 조사 대상 저수지 71개 지구 중 COD 46.3 %, TN 84.4 %, Chl-a 63.7 %가 농업용수 수질기준 초과 저수지로 조사되었다. 또한 연구 대상지구의 주요 오염원으로 생활계오염원 31개 저수지의 COD 11.1 mg/L이며, 축산계오염원 40개 저수지의 COD 12.2 mg/L로 나타났다. 각 항목의 수질 결과에 대한 평균 오염도를 분석한 결과, 축산계 오염원이 생활계 오염원 저수지보다 부유물질(SS)을 제외하고 모든 항목에서 오염도가 높게 나타났다. 그러나 TN, TP는 오염원에 따라 크게 차이를 보이지는 않았으며, 축산계 오염원 저수지의 수질 오염도는 모든 항목에서 농업용수 수질기준을 초과하였다. 장기적인 수질오염 저수지에 대하여 퇴적물의 오염 특성을 조사하였으며, 퇴적물오염으로 인한 수질오염 영향관계를 조사 분석하였다. 퇴적물 오염 특성 분석 결과, 강열감량 10.5 %, 총질소 3,480 mg/kg, 총인 1,299 mg/kg으로 오염 수준이 전체적으로 높게 조사되었다. 생활계오염원 31개 저수지의 강열감량 9.8 %, 총질소 2,711 mg/kg, 총인 1,178 mg/kg이며, 축산계오염원 40개 저수지의 강열감량 11.1 %, 총질소 4,076 mg/kg, 총인 1,393 mg/kg로 나타났다. 수질 중 COD, TOC, TN, TP, SS, Chl-a의 오염도와 퇴적물중 강열감량, 총질소, 총인의 각 항목간 상관관계를 분석한 결과, 퇴적물 내 다른 항목에 비해 SS를 제외하고 총인이 모든 수질 항목과 정(+)의 상관관계를 나타내었다. 특히 퇴적물 중 총인과 수질의 TP가 가장 높은 상관성을 나타내는 것으로 조사되었는데, 이는 퇴적물 내 총인이 수질오염에 가장 많은 영향을 줄 수 있으며, 상호작용이 있음을 의미한다고 하겠다. 또한 수질의 TP 오염도에 따라 부영양화 및 조류의 활성화가 크게 영향을 받는다는 기존의 연구결과에 의하면 퇴적물 내 총인의 오염도가 부영양화와 조류 번식에 영향을 크게 미칠 것이라 판단된다.

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Distribution Status, Habitat Characteristics and Extinction Threat Evaluation of the Endangered Species, Brachymystax lenok tsinlingensis (Pisces: Salmonidae) (멸종위기어류 열목어 Brachymystax lenok tsinlingensis (Pisces: Salmonidae)의 분포현황과 서식지 특징, 멸종위협 평가)

  • Ko, Myeong-Hun;Choi, Kwang-Seek;Han, Mee-Sook
    • Korean Journal of Ichthyology
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    • v.33 no.2
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    • pp.74-83
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    • 2021
  • Distribution status, habitat characteristics, and extinction threat evaluation of the endangered species, Brachymystax lenok tsinlingensis were investigated in 2015 and 2019. Historical distribution reports of B. l. tsinlingensis were divided into before 1990, 1997~2006, 2000~2011, and 2010~2019. Among the 150 sampling sites investigated during the study period, number of individuals of B. l. tsinlingensis were collected 542 individuals from 67 sites. The streams inhabited of B. l. tsinlingensis were Naerincheon (11 stations), Odaecheon (11 stations), Bukcheon (10 stations), Bangtaecheon (8 stations), Songjeongricheon (4 stations), Suipcheon (3 stations), Inbukcheon (3 stations), Hyeondongcheon (3 stations) etc. The main habitat of B. l. tsinlingensis was upstream of the river with a high altitude of more than 400 m, 4~20 m water flow width, 1~2 m water depth, and high ratio (70~80%) boulder bottoms. The main reasons for the decline in population size were assumed as river works, construction of reservoirs and bridges, discharge of contaminated water into the river, the inflow of summer vacationers, and weir. Compared to our results there exists evidence that states a 20.7% reduction in occupancy within 10 years, in a small appearance range (7,732 km2) and occupancy area (268 km2), number of disconnected locations (15 locations), and a decline in habitat quality. Therefore, B. l. tsinlingensis is now considered as Near Threatened (NT) based on the results (Near meets VU A2acd, B1b(i,ii,iii)+B2b(i,ii,iii)) of IUCN Red List categories and criteria.