• Title/Summary/Keyword: contact effect

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Acid green-25 removal from wastewater by anion exchange membrane: Adsorption kinetic and thermodynamic studies

  • Khan, Muhammad Imran;Ansari, Tariq Mahmood;Zafar, Shagufta;Buzdar, Abdul Rehman;Khan, Muhammad Ali;Mumtaz, Fatima;Prapamonthon, Prasert;Akhtar, Mehwish
    • Membrane and Water Treatment
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    • v.9 no.2
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    • pp.79-85
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    • 2018
  • In this work, batch adsorption of anionic dye acid green-25 (AG-25) from aqueous solution has been carried out at room temperature using anion exchange membrane (DF-120B) as a noval adsorbent. The effect of various experimental parameters such as contact time, membrane dosage, ionic strength and temperature on the adsorption of dye were investigated. Kinetic models namely pseudo-first-order, pseudo-second-order, Elovich, liquid film diffusion, Bangham and modified freundlich models were employed to evaluate the experimental data. Parameters like adsorption capacities, rate constant and related correlation coefficients for every model are calculated and discussed. It showed that adsorption of AG-25 onto DF-120B followed pseudo-first-order rate expression. Thermodynamic study indicates that adsorption of AG-25 onto DF-120B is an exothermic and spontaneous process.

Structure-soil-structure interaction in a group of buildings using 3D nonlinear analyses

  • Sharifi, Behroozeh;Nouri, Gholamreza;Ghanbari, Ali
    • Earthquakes and Structures
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    • v.18 no.6
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    • pp.667-675
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    • 2020
  • The current study compares the effect of structure-soil-structure interaction (SSSI) on the dynamic responses of adjacent buildings and isolated structures including soil-structure interaction (SSI) with the responses of fixed-base structures. Structural responses such as the relative acceleration, displacement, drift and shear force were considered under earthquake ground motion excitation. For this purpose, 5-, 10- and 15-story structures with 2-bay moment resisting frames resting on shallow foundations were modeled as a group of buildings in soft soil media. Viscous lateral boundaries and interface elements were applied to the soil model to simulate semi-infinite soil media, frictional contact and probable slip under seismic excitation. The direct method was employed for fully nonlinear time-history dynamic analysis in OpenSees using 3D finite element soil-structure models with different building positions. The results showed that the responses of the grouped structures were strongly influenced by the adjacent structures. The responses were as much as 4 times greater for drift and 2.3 times greater for shear force than the responses of fixed-base models.

Ion Beam-based Surface Modification of Polyimide Films for Adhesion Improvement with Deposited Metal Layer

  • Cho, Hwang-Woo;Jung, Chan-Hee;Hwang, In-Tae;Choi, Jae-Hak;Nho, Young-Chang
    • Journal of Radiation Industry
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    • v.4 no.4
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    • pp.335-339
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    • 2010
  • In this study, the surface of polyimide (PI) films was modified using ion implantation to enhance its adhesion to a deposited copper (Cu) layer. The surfaces of the PI films were implanted with 150 keV $Xe^+$ ions at fluences varying from $1{\times}10^{14}$ to $1{\time}10^{16}ions\;cm^{-2}$. The Cu layers were then deposited on the implanted PI. The surface properties of the implanted PI film were investigated based on the contact angle measurements, Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), and atomic force microscopy (AFM). Furthermore, the adhesive strength between the deposited Cu layer and PI film was estimated through a scratch test using a nanoindenter. As a result, the surface environment of the PI film was changed by the ion implantation, which could have a significant effect on the adhesion between the deposited Cu layer and the PI.

Fabrication and Evaluation of Polyelectrolyte Complexes of Dextran Derivatives for Drug Coating of Coronary Stents

  • Jang, Eun-Jae;Lee, So-Youn;Bae, In-Ho;Park, Dae Sung;Jeong, Myung Ho;Park, Jun-Kyu
    • Applied Chemistry for Engineering
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    • v.30 no.5
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    • pp.586-590
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    • 2019
  • The aim of this study was to fabricate a dextran polyelectrolyte multi-layer on a bare metal stent (BMS) and to evaluate bio-physical properties of the layer. Diethylaminoethyl-dextran (DEAE-D) as a polycation and dextran sulfate (DS) as a polyanion were successively coated on the bare metal stent by a well-known layer-by-layer procedure. The morphology of the stent surface and its cell adhesion were studied after each coating step by scanning electron microscopy. The stent showed more blotched and slightly rougher morphology after dextran-DS coating. The contact angle of the DEAE-DS group ($39.5{\pm}0.15^{\circ}$) was significantly higher than that of the BMS group ($45.16{\pm}0.08^{\circ}$), indicating the improvement of hydrophilic. The SMC proliferation inhibition in the DEAE-DS-coated stent group ($20.9{\pm}0.04%$) was stronger than that in the control group ($21.7{\pm}0.10%$ in DS-coated group only). The DEAE-DS coating is desired for stent coating materials with biocompatibility and anti-restenosis effect.

Smart PZT-interface for wireless impedance-based prestress-loss monitoring in tendon-anchorage connection

  • Nguyen, Khac-Duy;Kim, Jeong-Tae
    • Smart Structures and Systems
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    • v.9 no.6
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    • pp.489-504
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    • 2012
  • For the safety of prestressed structures such as cable-stayed bridges and prestressed concrete bridges, it is very important to ensure the prestress force of cable or tendon. The loss of prestress force could significantly reduce load carrying capacity of the structure and even result in structural collapse. The objective of this study is to present a smart PZT-interface for wireless impedance-based prestress-loss monitoring in tendon-anchorage connection. Firstly, a smart PZT-interface is newly designed for sensitively monitoring of electro-mechanical impedance changes in tendon-anchorage subsystem. To analyze the effect of prestress force, an analytical model of tendon-anchorage is described regarding to the relationship between prestress force and structural parameters of the anchorage contact region. Based on the analytical model, an impedance-based method for monitoring of prestress-loss is conducted using the impedance-sensitive PZT-interface. Secondly, wireless impedance sensor node working on Imote2 platforms, which is interacted with the smart PZT-interface, is outlined. Finally, experiment on a lab-scale tendon-anchorage of a prestressed concrete girder is conducted to evaluate the performance of the smart PZT-interface along with the wireless impedance sensor node on prestress-loss detection. Frequency shift and cross correlation deviation of impedance signature are utilized to estimate impedance variation due to prestress-loss.

Two-dimensional numerical investigation of the effects of multiple sequential earthquake excitations on ancient multi-drum columns

  • Papaloizou, Loizos;Polycarpou, Panayiotis;Komodromos, Petros;Hatzigeorgiou, George D.;Beskos, Dimitri E.
    • Earthquakes and Structures
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    • v.10 no.3
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    • pp.495-521
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    • 2016
  • Ancient monuments of Greek and Roman classical architecture usually consist of multi-drum columns that are constructed of stone blocks placed on top of each other. Several research studies deal with the seismic behaviour of such structures, since earthquakes are common causes of destruction of such monuments. This paper investigates the effect of multiple earthquakes on the seismic performance of multi-drum columns, through numerical simulations and parametric analyses. The Discrete Element Method and an appropriate contact model have been implemented in a specially developed software application that is able to efficiently perform the necessary simulations in two dimensions. Specifically, various strong ground excitations are used in series for the computation of the collective final deformation of multi-drum columns. In order to calculate this cumulative deformation for a series of ground motions, the individual deformation of the column for each excitation is computed and then used as initial conditions for the next earthquake excitation. Various multi-drum columns with different dimensions are also considered in the analyses in order to examine how the geometric characteristics of columns can affect their seismic sequence behaviour, in combination with the excitation frequency content.

Critical heat flux measurement experiment to improve safety of copper nano-particle coated heat exchanger (구리나노입자가 코팅된 열교환기의 안전성 향상을 위한 임계 열유속 측정실험)

  • Mo, Yong-Hyun;Kim, Nam-Jin;Jeon, Yong-Han;Lee, Deok-Soo
    • Journal of the Korea Safety Management & Science
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    • v.19 no.4
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    • pp.317-322
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    • 2017
  • When the heat flux on the heating surface following changing heat condition in the boiling heat transfer system exceeds critical heat flux, the critical heat flux phenomenon is going over to immediately the film boiling area and then it is occurred the physical destruction phenomenon of various heat transfer systems. In order to maximize the safe operation and performance of the heat transfer system, it is essential to improve the CHF(Critical Heat Flux) of the system. Therefore, we have analysis the effect of improving CHF and characteristics of heat transfer following the nanoparticle coating thickness. As the results, copper nanocoating time are increased to CHF, and in case of nano-coatings are increased spray-deposited coating times more than in the fure water; copper nanopowder is increased up to 6.40%. The boiling heat transfer coefficients of the pure water are increased up to 5.79% respectively. Also, the contact angle is decreased and surface roughness is increased when nano-coating time is increasingly going up.

Effect of HF and Plasma Treated Glass Surface on Vapor Phase-Polymerized Poly(3,4-ethylenedioxythiophene) Thin Film : Part II

  • Lee, Joonwoo;Kim, Sungsoo
    • Journal of Integrative Natural Science
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    • v.6 no.4
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    • pp.215-219
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    • 2013
  • In this study, in order to investigate how consecutive treatments of glass surface with HF acid and water vapor/Ar plasma affect the quality of 3-aminopropyltriethoxysilane self-assembled monolayer (APS-SAM), poly(3,4-ethylenedioxythiophene) (PEDOT) thin films were vapor phase-polymerized immediately after spin coating of FeCl3 and poly-urethane diol-mixed oxidant solution on the monolayer surfaces prepared at various treatment conditions. For the film characterization, various poweful tools were used, e.g., FE-SEM, an optical microscope, four point probe, and a contact angle analyzer. The characterization revealed that a well prepared APS-SAM on a glass surface treated with water vapor/Ar plasma is very useful for uniform coating of FeCl3 and DUDO mixed oxidant solution, regardless of HF treatment. On the other hand, a bare glass surface without APS-SAM but treated with HF and water vapor/Ar plasma generally led to a very poor oxidant film. As a result, PEDOT films vapor phase-polymerized on APS-SAM surfaces are far superior to those on bare glass surfaces in the quality and electrical characteristics aspects.

Surface Modification of Functional Titanium Oxide to Improve Corrosion Resistance (내식성 향상을 위한 기능성 타이타늄 표면 개질)

  • Park, Youngju;Jeong, Chanyoung
    • Corrosion Science and Technology
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    • v.20 no.5
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    • pp.256-265
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    • 2021
  • Titanium is applied in various industries due to its valuable properties and abundant reserves. Generally, if a highly uniform oxide structure and a high-density oxide film is formed on the surface through anodization treatment, the utility value such as color appearance and corrosion inhibition efficiency is further increased. The objective of this study was to determine improvement of water-repellent property by controlling titanium oxide parameters such as pore size and inter-pore distance to improve corrosion resistance. Oxide film structures of different shapes were prepared by controlling the anodization processing time and voltage. These oxide structures were then analyzed using a Field Emission Scanning Electron Microscope (FE-SEM). Afterwards, a Self-Assembled Monolayer (SAM) coating was performed for the oxide structure. The contact angle was measured to determine the relationship between the shape of the oxide film and the water-repellency. The smaller the solid fraction of the surface, the higher the water-repellent effect. The surface with excellent hydrophobic properties showed improved corrosion resistance. Such water-repellent surface has various applications. It is not only useful for corrosion prevention, but also useful for self-cleaning. In addition, a hydrophobic titanium may open up a new world of biomaterials to remove bacteria from the surface.

Effect of Organizational Culture on Corporate Social Welfare Activities

  • JEONG, Young Joo;CHOI, Moon Kyung
    • East Asian Journal of Business Economics (EAJBE)
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    • v.9 no.4
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    • pp.43-54
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    • 2021
  • Purpose - Stakeholders play a vital part in the company's CSR activities and they are part of the company's achievement and affect the company's achievement or business objectives. This study aims to add insight into the already existing knowledge how the organizational culture can promote corporate social welfare activities. Research design, Data, and methodology - The current authors obtained text data for the possible practical suggestions which might be used for the creation of coding method. That implies that the present author investigated only trustable textual sources to provide for the possible solutions such as peer-revied sources and published book. Result - Research results indicated that organizational culture promotes corporate social welfare activities by making people know their values and understand how they come about. Not every community knows what its members want and how to achieve its needs. Sometimes, a community can obtain the values and principles of an organization and incorporate them into community values. Conclusion - Executive leadership and customers are part of society. Any strategy that influences their operation and works ethic influences the contact of the community. This research found methods vital in setting up an excellent culture that enhances profitability and the corporate social welfare activities through motivation and communication.