• Analytical Science and Technology
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• v.28 no.3
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• pp.182-186
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• 2015

In this study, the porous CuO/MnO₂ catalyst was prepared through the co-precipitation process from an aqueous solution of potassium permanganate (KMnO₄), manganese(II) acetate (Mn(CH₃COO)₂·4H₂O) and copper(II) acetate (Cu(CH₃COO)₂·H₂O). The phase change in MnO₂ was analyzed according to the reaction molar ratio of KMnO₄ to Mn(CH₃COO)₂. The reaction mole ratio of KMnO₄ to Mn(CH₃COO)₂·4H₂O was varied at 0.3:1, 0.6:1, and 1:1. The aqueous solution of Cu(CH₃COO)₂ was injected into a mixed solution of KMnO₄ and Mn(CH₃COO)₂ to 10~75 wt% relative to MnO₂. The Cu ion co-precipitates as CuO with MnO₂ in a highly dispersed state on MnO₂. The physicochemical property of the prepared CuO/MnO₂ was analyzed by using the TGA, DSC, XRD, SEM, and BET. The different phase types of MnO₂ were prepared according to the reaction mole ratio of KMnO₄ to Mn(CH₃COO)₂·4H₂O. The results confirmed that the porous CuO/MnO₂ catalyst with γ-phase MnO₂ was produced in the reaction mole ratio of KMnO₄ to Mn(CH₃COO)₂ as 0.6:1 at room temperature.

• Journal of the Korean Association of Geographic Information Studies
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• v.21 no.4
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• pp.50-63
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• 2018

The rapid urbanization had led to a distortion of natural hydrological cycle system. The change in hydrological cycle structure is causing streamflow depletion, changing the existing use tendency of water resources. To manage such phenomena, a streamflow depletion impact assessment technology to forecast depletion is required. For performing such technology, it is indispensable to build GIS-based spatial data as fundamental data, but there is a shortage of related research. Therefore, this study was conducted to use the use of GIS-based time series spatial data for streamflow depletion assessment. For this study, GIS data over decades of changes on a national scale were constructed, targeting 6 streamflow depletion impact factors (weather, soil depth, forest density, road network, groundwater usage and landuse) and the data were used as the basic data for the operation of continuous hydrologic model. Focusing on these impact factors, the causes for streamflow depletion were analyzed depending on time series. Then, using distributed continuous hydrologic model based DrySAT, annual runoff of each streamflow depletion impact factor was measured and depletion assessment was conducted. As a result, the default value of annual runoff was measured at 977.9mm under the given weather condition without considering other factors. When considering the decrease in soil depth, the increase in forest density, road development, and groundwater usage, along with the change in land use and development, and annual runoff were measured at 1,003.5mm, 942.1mm, 961.9mm, 915.5mm, and 1003.7mm, respectively. The results showed that the major causes of the streaflow depletion were lowered soil depth to decrease the infiltration volume and surface runoff thereby decreasing streamflow; the increased forest density to decrease surface runoff; the increased road network to decrease the sub-surface flow; the increased groundwater use from undiscriminated development to decrease the baseflow; increased impervious areas to increase surface runoff. Also, each standard watershed depending on the grade of depletion was indicated, based on the definition of streamflow depletion and the range of grade. Considering the weather, the decrease in soil depth, the increase in forest density, road development, and groundwater usage, and the change in land use and development, the grade of depletion were 2.1, 2.2, 2.5, 2.3, 2.8, 2.2, respectively. Among the five streamflow depletion impact factors except rainfall condition, the change in groundwater usage showed the biggest influence on depletion, followed by the change in forest density, road construction, land use, and soil depth. In conclusion, it is anticipated that a national streamflow depletion assessment system to be develop in the future would provide customized depletion management and prevention plans based on the system assessment results regarding future data changes of the six streamflow depletion impact factors and the prospect of depletion progress.

• Economic and Environmental Geology
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• v.50 no.6
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• pp.477-486
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• 2017

In this study, we analyze precise seabed geomorphology and conditions for comparing the nearshore areas of the Dongdo(East Island) and the Seodo(West Island) using detailed bathymetry data and seafloor backscattering images, in Dokdo, the East Sea. We have been obtained the detailed bathymetry data and the seafloor backscattering data. The survey range is about $250m{\times}250m$ including land of islets to the nearshore areas of the southern part of the Dongdo and the Seodo. As a result of bathymetry survey, the southern area of the Dongdo(~50 m) is deeper than the Seodo(~30 m) in the water depth. The survey areas are consist of extended bedrocks from land of the Dongdo and the Seodo. The underwater rock region of the Seodo is larger than the Dongdo. In spite of similar extended rocks features from islets, there are some distinctive seabed characteristics between the southern nearshore areas of the Dongdo and the Seodo. The Talus-shaped seafloor environment formed by gravel and underwater rocks originating from the land of the Dongdo is up to about 15 m depth. And the boundary line of between extended bedrocks and seabottom is unclear in the southern nearshore of the Dongdo. On the other hand, the southern coast of the Seodo is characterized by relatively large scale underwater rocks and evenly distributed sediments, which clearly distinguish the boundary of between extended bedrocks and seafloor. This is because the tuff layers exposed to the coastal cliffs of the Dongdo are weak against weathering and erosion. It is considered that there are more influences of the clastic sediments carried from the land of the Dongdo compared with the Seodo. Particularly, the land of the Dongdo has been undergoing construction activities. And also a highly unstable ground such as faults, joints and cracks appears in the Dongdo. In previous study, there are dissimilar features of the massive tuff breccia formations of the Dongdo and the Seodo. These conditions are thought to have influenced the different seabed characteristics in the southern nearshore areas of the Dongdo and the Seodo.

• Journal of the Korean Society for Railway
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• v.17 no.3
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• pp.193-200
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• 2014

In this study, fatigue tests on existing continuous welded rail (CWR) on a concrete track were carried out. Based on the test results, a S-N curve expressing the remaining life of the CWR at a fracture probability of 50% was obtained using weighted probit analysis suitable for small-sample fatigue data sets. As rails had different histories in terms of accumulated passing tonnage, the test data were corrected to average out the accumulated passing tonnage. The remaining service life for the CWR on the concrete track in an urban railway was estimated using the prediction equation for the bending stress of rail developed in the past to estimate rail base bending stress and taking the surface irregularities into consideration. Estimating the remaining service life of the CWR in an urban railway showed that the rail replacement period could be extended over 200MGT. In addition, comparing the concrete track to the ballast track, the fatigue life of rail was analyzed as approximately 300MGT higher than. Therefore, the rail replacement criteria needs to distinguish between the ballast track and the concrete track, and not the criteria needs to be changed as a target for the maintenance, although it is necessary to remove longitudinal rail surface irregularities at welds by grinding.

• Geotechnical Engineering
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• v.12 no.3
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• pp.127-148
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• 1996

Recently, foundations of heavy structures such as bridge abutments have been built on slopes or near the crest of slopes at an increasing rate. Because the bearing capacity of such foundations is considerably lower than the bearing capacity of the same soil on a level ground, deep footings such as piles and caissons are often used. However, the costs of such methods are generally very high. One of the new techniques to overcome the problem is to place reinforcing members such as geosynthetics or metal strips horizontally at some depths beneath the footings. Rational methods of analysis to predict the bearing capacity of footings in reinforced slopes are therefore needed. This paper proposes an analytical method for estimating the increase in bearing capacity gained from the included horizontal strips or ties of tensile reinforcing in the foundation soil below the footing built near the crest of a slope. A failure mechanism, including the concept of'wide slab effect', adopted in the present study for analyzing the bearing capacity of foundations in reinforced slopes, is established through the observed model test behaviors described by Binquet SE Lee and Huang et al, and the Boussinesq solutions. The analytical results are then compared with the experimental data described in the paper by Huang et al. Also in order to properly evaluate the soil reinforcement interaction, typical pullout test values of the apparent friction coefficient, which usually vary with depths owing to both the increase of the shearing volume and the increase in local stress caused by soil dilatancy, are analyzed and related functionally. Furthermore, analytical parametric studies are carried out to investigate the effect and significance of various pertinent parameters associated with design of reinforced slope foundations. Keywords : Bearing capacity, Reinforced slope, Slab effect, Friction coefficient.

• Journal of the Korea Concrete Institute
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• v.21 no.3
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• pp.283-290
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• 2009

Differently from fly ash, the bottom ash produced from thermoelectric power plant has been treated as an industrial waste matter, and almost reclaimed a tract from the sea. If this waste material is applicable to foam concrete as an aggregate owing to its light-weight, however, it may be worthy of environmental preservation by recycling of waste material as well as reducing self-weight of high-rising structure and horizontal forces and deformations of retaining wall subject to soil pressure. This study has an objective of evaluating the effects of application of bottom ash on the mechanical properties of foam concrete. Thus, the ratio of bottom ash to cement was selected as a variable for experiment and the effect was measured in terms of unit weight of concrete, air content, water-cement ratio and compressive strength. It can be observed from experiments that the application ratios have different effects on the material parameters considered in this experiment, thus major relationships between application ratio and each material parameter were finally introduced. The result of this study can be applied to decide a mix design proportion of foam concrete while bottom ash is used as an aggregate of the concrete.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.2
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• pp.193-201
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• 2000

Partitioning of hydrophobic organic compounds (HOCs) to a biosurfactant, hydroxypropyl-${\beta}$-cyclodextrin (HPCD), was conducted to evaluate the feasibility of using HPCD to remove HOCs from soil/groundwater. HOC partitioning to HPCD was very fast, with over 95% of the complexation occurring within 10 min. Some influence of solution chemistry and HOC concentration on HOC-HPCD complex formation coefficients was observed. HPCD sorption on soil as quantified by both a fluorescence technique and total organic carbon measurements was negligible, indicating no significant affinity of HPCD for the solid phase. Although the HOC solubilization capability of HPCD was lower than that of synthetic surfactants such as SDS and Tween 80, HPCD can be effective in removing sorbed HOCs from a model subsurface environment, primarily because of its negligible sorption to the solid phase (i.e., all the HPCD added facilitates HOC elution). However, in contrast with conventional surfactants, HPCD becomes relatively less effective for HOC partitioning with increasing HOC size and hydrophobicity. Therefore, comparisons between HPCD and synthetic surfactants for enhanced remediation applications must consider the specific HOC(s) present and the potential for surfactant material losses to the solid phase, as well as other more generally recognized considerations such as material costs and potential toxicological effects.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.33 no.1
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• pp.363-375
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• 2013

Today, a shortage of the skilled operator has been intensified gradually and the necessity of an earthwork in extreme environment operators are difficult to access is increasing for the purpose of resource development and new living space creation. For this reason, an effort to develop an unmanned excavation robot for fully automated earthwork system is continuing globally. In Korea, a research consortium called 'Intelligent Excavation System' has been formed since 2006 as a part of Construction Technology Innovation Program of Ministry of Land, Transport and Maritime Affairs of Korea. Among detailed technologies of the Task Planning System is one of the core technologies of IES, this paper explains research and development process of the Local Area Design Module, which provides informatization unit to create automated excavators' work command information at operation level such as location, range, target, and sequence for excavation work. Designing of Local Area should be considered various influential factors such as excavator's specification, working mechanism, heuristics, and structural stability to create work plan guaranteed safety and effectiveness. For this research, conceptual and detail design of the Local Area is performed for analyzing design element and variable, and quantization method of design specification corresponding with heuristics and structural safety is generated. Finally, module is developed through constructed algorithm and developed module is verified.

• Journal of the Korean Association of Geographic Information Studies
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• v.14 no.1
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• pp.94-106
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• 2011

The muddy water occurrence possibility of reservoir were analyzed by considering GIS based soil erosion model, sediment delivery ratio and effective reservoir capacity. For the purpose, the weakness factors for the establishment of countermeasures of basin were analyzed by evaluating input factors of RUSLE model based on spatial data such as DEM, soil map, landcover map and so on. The potential of soil erosion was estimated considering highland upland. The sediment yields of Chungju-Dam and Soyanggang-Dam showed the highest result in sediment yield using sediment delivery ratio with considering basin area. The sediment concentration of Imha-Dam and Chungju-Dam showed the highest value as 0.791 $kg/m^3/yr$ and 0.526 $kg/m^3/yr$ respectively in sediment concentration with considering effective reservoir capacity. Especially, sediment yield of Imha-Dam was about 2.36 times lower than Soyanggang-Dam, but the sediment concentration was 1.90 times higher preferably, because the effective reservoir capacity of Imha-Dam was about 4.48 times lower. This study calculated sediment concentration using the 10 years mean rainfall event and could consider the aspects of soil, terrain, landcover, cultivation condition and effective reservoir capacity of each basin effectively through the results. Therefore, these quantitative sediment concentration data could be used to estimate the potential of high density turbid water for reservoir and applied with effective tools for the management of reservoir.

• Korean Journal of Environment and Ecology
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• v.22 no.6
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• pp.658-665
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• 2008

One of the characteristics of fluvial river channel with sand bed-material is the existence of movable sand bars not occupied with vegetation. However, sand bars at the Hahoe's reach of the Nakdong River showing a double-meandering channel has been changed into expanding vegetation area. Moreover, sand material, in recent years, has stopped moving to downstream in channel and the number and area of bare bars which did not occupied by vegetation have been decreased. In order to find out the mechanism, we carried out the channel characteristics surveys such as hydro-geomorphologic, soil physio-chemical and vegetation surveys were conducted twice on autumn season in 2005,2006. The results so far achieved showed that the reduced discharge of transported sediment and duration of dry season might be critical factors for the spread of luxuriant vegetation. The vegetation area was significantly expanded by floods exceeding the subsequent dominant flow discharge. Furthermore, the expansion of vegetation area was highly correlated with the supply of organic matter, nutrients and alteration of soil texture by sediment deposition during the flooding event.