• Bulletin of the Korean Chemical Society
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• v.27 no.5
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• pp.733-738
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• 2006

Nucleophilic addition reactions of p-substitutedbenzylamines $(XC _6H_4CH _2NH _2)$ to $\alpha$-phenyl-$\beta$-thiophenyl-acrylonitriles ($YC _4SH _2CH=C(CN)C_6H_4$Y') have been studied in acetonitrile at 25.0, 30.0, and 35.0 ${^{\circ}C}$. The reactions take place in single step in which the $C_\beta$ -N bond formation and proton transfer to $C_\alpha$ of $\alpha$-phenyl-$\beta$-thiophenylacrylonitriles occur concurrently with four-membered cyclic transition structure. These mechanistic conclusions are drawn based on (i) the large negative $\rho$x and large positive $\rho$Y' values and also large magnitude of $\rho$X, (ii) the negative sign and large magnitude of the cross-interaction constants ($\rho$XY), (iii) the normal kinetic isotope effects ($k_H/k_D$ > 1.0), and (iv) relatively low $\Delta H ^\neq$ and large negative $\Delta S ^\neq$ values.

• Membrane and Water Treatment
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• v.4 no.3
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• pp.157-174
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• 2013

The present study is devoted to the validation of a new method for in line electrokinetic characterisation of deposits on membrane surfaces. This method is based upon simultaneous measurements of transversal streaming potential and permeates flux at constant pressure before and during the deposit formation. Dead-end filtration experiments were conducted with negative flat membranes forming a narrow slit channel, negative hollow fiber membranes and mono-dispersed suspensions of (negatively charged) polystyrene latex and (positively charged) melamine particles at various concentrations. It was observed that the overall streaming potential coefficient increased in absolute value with the deposited latex quantity, whereas it decreased and changed of sign during the filtration of melamine suspensions. By considering a resistance-in-series model, the streaming potential coefficient of the single deposit ($SP_d$) was deduced from the electrokinetic and hydraulic measurements. The independence of $SP_d$ with respect to growth kinetics validates the measurement method and the reliability of the proposed procedure for calculating $SP_d$. It was found that $SP_d$ levelled off much more quickly when filtration was performed through the slit channel. This different behaviour could result from a non-uniform distribution of the deposit thickness along the membrane given that the position of measuring electrodes is different between the two cells.

• 제어로봇시스템학회:학술대회논문집
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• 2005.06a
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• pp.2126-2131
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• 2005

Interactions of a humanoid with a human are important, when the humanoid is requested to provide people with human-friendly services in unknown or uncertain environment. Such interactions may require more complicated and human-like behaviors from the humanoid. In this work the arm motions of a human are discussed as the early stage of human motion imitation by a humanoid. A motion capture system is used to obtain human-friendly arm motions as references. However the captured motions may not be applied directly to the humanoid, since the differences in geometric or dynamics aspects as length, mass, degrees of freedom, and kinematics and dynamics capabilities exist between the humanoid and the human. To overcome this difficulty a method to adapt captured motions to a humanoid is developed. The geometric difference in the arm length is resolved by scaling the arm length of the humanoid with a constant. Using the scaled geometry of the humanoid the imitation of actor's arm motions is achieved by solving an inverse kinematics problem formulated using optimization. The errors between the captured trajectories of actor arms and the approximated trajectories of humanoid arms are minimized. Such dynamics capabilities of the joint motors as limits of joint position, velocity and acceleration are also imposed on the optimization problem. Two motions of one hand waiving and performing a statement in sign language are imitated by a humanoid through dynamics simulation.

• Journal of The Korean Astronomical Society
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• v.47 no.3
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• pp.105-113
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• 2014

We apply differential affine velocity estimator (DAVE) to the Solar Dynamics Observatory (SDO)/Helioseismic and Magnetic Imager (HMI) 12-min line-of-sight magnetograms, and separately calculate the injected magnetic helicity for the leading and the following polarities of nine emerging bipolar active regions (ARs). Comparing magnetic helicity flux of the leading polarity with the following polarity, we find that six ARs studied in this paper have the following polarity that injected more magnetic helicity flux than that of the leading polarity. We also measure the mean area of each polarity in all the nine ARs, and find that the compact polarity tend to possess more magnetic helicity flux than the fragmented one. Our results confirm the previous studies on asymmetry of magnetic helicity that emerging bipolar ARs have a polarity preference in injecting magnetic helicity. Based on the changes of unsigned magnetic flux, we divide the emergence process into two evolutionary stages: (1) an increasing stage before the peak flux and (2) a constant or decreasing stage after the peak flux. Obvious changes on magnetic helicity flux can be seen during transition from one stage to another. Seven ARs have one or both polarity that changed the sign of magnetic helicity flux. Additionally, the prevailing polarity of the two ARs, which injects more magnetic helicity, changes form the following polarity to the leading one.

• Journal of Korea Foundry Society
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• v.8 no.4
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• pp.437-445
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• 1988

The effect of interlamellar spacing on microstructural stability at high temperature was studied for unidirectionally solidified ternary $Ni\;/\;Ni_3Al-Ni_3$ Nb and binary $Ni-Ni_3Nb$ eutectic composite. The interlamellar spacing of both alloy systems were varied with the growth rate according to $"{\lambda}^2R=constant"$ relationship. As a result of isothermal heat treatments at high temperature it was considered that coarsening of lamellar structure was due to concentration gradient between the tip with a relatively small radius of curvature and the side of the thick lamellae with a larger radius of the opposite sign. Fault density was increased as the interlamellar spacing decreased. Therefore it is also considered that the higher coarsening rate of the specimen with the smaller interlamellar spacing was due to higher fault density. And the diference of coarsening rate between $Ni\;/\;Ni_3Al-Ni_3Nb$ and $Ni-Ni_3Nb$ eutectic composites was not observed when the interlamellar spacing was similar in size. This means that the presence of ${\gamma}'$ in ${\gamma}\;/\;{\gamma}'\;-{\delta}$ eutectic had no b arrier effect to diffusion through the ${\gamma}$ matrix.

• Bulletin of the Korean Chemical Society
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• v.32 no.7
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• pp.2339-2344
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• 2011

Kinetic studies for the reactions of O,O-dimethyl Z-S-aryl phosphorothioates with X-pyridines have been carried out in dimethyl sulfoxide at 85.0 $^{\circ}C$. The Hammett and Br$\"{o}$nsted plots for substituent X variations in the nucleophiles are biphasic concave upwards with a break point at X = H, while those for substituent Z variations in the leaving groups are linear. The negative sign of the cross-interaction constant (${\rho}_{XZ}$) implies that the reaction proceeds through a concerted mechanism for both the strongly and weakly basic pyridines. The magnitude of ${\rho}_{XZ}$ (= -0.35) for the strongly basic pyridines is greater than that (${\rho}_{XZ}$ = -0.15) for the weakly basic pyridines, indicating a change of the nucleophilic attacking direction from frontside for the strongly basic pyridines to backside for the weakly basic pyridines. The early transition state is proposed on the basis of the absence of positive deviations from both the Hammett and Br$\"{o}$nsted plots for the strong ${\pi}$-acceptor, X = 4-Ac, and small values of ${\rho}_{XZ}$ and ${\beta}_X$.

• Bulletin of the Korean Chemical Society
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• v.32 no.12
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• pp.4304-4308
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• 2011

Kinetic studies of the reactions of O,O-dimethyl Z-S-aryl phosphorothioates with X-benzylamines have been carried out in dimethyl sulfoxide at $85.0^{\circ}C$. The Hammett (log $k_2$ vs ${\sigma}_X$) and Br$\ddot{o}$nsted [log $k_2$ vs $pK_a$(X)] plots for substituent X variations in the nucleophiles are discrete with a break region between 4-Me and H, while the Hammett plots (log $k_2$ vs ${\sigma}_Z$) for substituent Z variations in the leaving groups are linear. The sign of the cross-interaction constant (${\rho}_{XZ}$) is positive for both the strongly and weakly basic nucleophiles. Greater magnitude of ${\rho}_{XZ}$ (= 2.54) value is observed with the weakly basic nucleophiles compared to with the strongly basic nucleophiles (${\rho}_{XZ}$ = 0.17). The deuterium kinetic isotope effects ($k_H/k_D$) involving deuterated benzylamines [$XC_6H_4CH_2ND_2$] are primary normal ($k_H/k_D$ > 1). The proposed mechanism is a stepwise with a rate-limiting leaving group expulsion from the intermediate involving a frontside nucleophilic attack with a hydrogen bonded, four-center-type transition state for both the strongly and weakly basic nucleophiles.

• Journal of the Korean Ceramic Society
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• v.23 no.1
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• pp.44-50
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• 1986

Si-ZnO n-n heterojunction diodes were prespared by r.f diode sputtering of the sintered ZnO target on n-type Si single crystal wafers and their structures and electrical properties were studied. The films were grown orientedly with the c-axis of crystallites perpendicular to the substrate surface at low r.f. powder and grown to polycrystalline films with random orientation at high r. f. powder. The crystallite size increased with the increasing substrate temperture The oriented texture films only were used to prepare the photovoltaic diodes and these didoes showed the photovoltaic effect veing positive of the ZnO side for the photons in the wavelength range of 380-1450nm. The sign reversal of phootovoltage which is the property os isotype heterojunction was not observed because of the degeneration of the ZnO films. The diode showed the forward rectification when it was biased with the ZnO side positive. The current-voltage characteristics exhibited the thermal-current type relationship J∝exp(qV/nkT) with n=1.23 at the low forward bias voltage and the tunnelling-current type relationship J∝exp($\alpha$V) where $\alpha$ was constant independent of temperature at the high forward bias voltage. The crystallite size of ZnO films were influenced largely on the photovoltaic properties of diodes ; The diodes with the films of the larger crystallites showed the poor photovoltaic properties. This reason may be cosidered that the ZnO films with the large crystallites could not grow to the electrically continuous films because the thickness of films was so thin in this experiment.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.14 no.8
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• pp.617-625
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• 2002

In this study, effects of refrigerant and oil charges on the performance of a refrigeration system simulating an automobile air conditioner have been experimentally investigated using R134a and PAG oil. Measurements were taken in a breadboard type refrigeration test unit with a compressor used for a commercial automobile air-conditioner under a set of condition imposed upon normally to automobile air conditioners. Both the COP and capacity decreased rapidly as the oil charge increased because of the decrease in vapor pressure of the circulating refrigerant/oil mixture. The excess oil left in the evaporator also caused heat transfer degradation resulting in a decrease in capacity and in turn COP. It was found that there is an optimum refrigerant charge at which the COP becomes the maximum. Below this optimum charge, both the capacity and COP increased as the refrigerant charge increased and above the optimum charge, both of them remained almost constant. Hence, the COP seems to be the most important factor in determining the optimum refrigerant charge. When the system was undercharged, the refrigerant at the condenser exit lost subcooling and showed a sign of poor miscibility.

• ETRI Journal
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• v.33 no.5
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• pp.695-703
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• 2011

The number of adders and critical paths in a multiplier block of a multiple constant multiplication based implementation of a finite impulse response (FIR) filter can be minimized through common subexpression elimination (CSE) techniques. A two-bit common subexpression (CS) can be located recursively in a noncanonic sign digit (CSD) representation of the filter coefficients. An efficient algorithm is presented in this paper to improve the elimination of a CS from the multiplier block of an FIR filter so that it can be realized with fewer adders and low logical depth as compared to the existing CSE methods in the literature. Vinod and others claimed the highest reduction in the number of logical operators (LOs) without increasing the logic depth (LD) requirement. Using the design examples given by Vinod and others, we compare the average reduction in LOs and LDs achieved by our algorithm. Our algorithm shows average LO improvements of 30.8%, 5.5%, and 22.5% with a comparative LD requirement over that of Vinod and others for three design examples. Improvement increases as the filter order increases, and for the highest filter order and lowest coefficient width, the LO improvements are 70.3%, 75.3%, and 72.2% for the three design examples.