• Journal of the Korean Applied Science and Technology
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• v.12 no.2
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• pp.145-150
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• 1995

The Kinetics velocity for hydrolysis reaction of vanillylidene imine derivatives has been measured by ultra-violet ray spectrophotometer in 20wt% $dioxane-H_2O$ at $25^{\circ}C$. It was measured the reaction rate Constant of vanillylidene imine derivatives that can be applied widely following to pH-change at $25^{\circ}C$. Final products that hydrolyzed the vanillylidene imine certified in vanillin and aniline derivative, and the effect of substitution radical that has affected on hydrolysis reaction was largely promoted to reaction rate by electron attrating group in acidity and electron donoring group in basic. From the results of rate constant to hydrolysis reaction, substituent radical effect and final products. It has certified the hydrolysis reaction mechanism of vanillylidene imine derivatives.

• 한국전산유체공학회:학술대회논문집
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• 2007.10a
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• pp.272-276
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• 2007

In this paper, we researched a parametric study in flow control system using louver with numerical method. Generally, for the large fans with constant rotational speed, the louver can be used to control the flow rate. The opening and closing of louver can make a some change of flow properties generated by a large fan. To develope the relation between the opening angle of louver and flow rate(or pressure difference), we simulated the flow past the modelled louver installed in a virtual wind tunnel. For the various angles, the mean flow properties are investigated and parameterized with a given boundary condition. The research result can be used directly to design the flow control system of large constant-speed fans, which are often applied to petrolic refinery system.

• Proceedings of the SAREK Conference
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• 2009.06a
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• pp.242-247
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• 2009

The present study has been conducted to reduce the cold air drying rate. According to the cold air drying method, the quality-excellent product could be made and there would be little change of color, taste and smell. As compared with the hot air drying, the cold air drying equipment has the superior dehumidification in a constant drying zone. However, in a falling drying zone that equipment is not energy-efficient because the drying period could be longer by the dehumidificated.

• Journal of Korean Society on Water Environment
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• v.24 no.3
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• pp.311-316
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• 2008

This study aimed to obtain equilibrium concentration on adsorption removal of ammonia nitrogen by activated carbon, to express the adsorption characteristics following Freundlich isotherm and also, based on the value obtained, to investigate the relationship between physical characteristics of activated carbon and dynamics of ammonia nitrogen removal by obtaining rate constant and effective pore diffusivity. The results summarized from this study are as follows. It was noted that powdered activated carbon showed better adsorption ability than granular activated carbon. The value of constant (f) of Freundlich isotherm of powered activated carbon was $4.6{\times}10^{-8}$ which is bigger than that of granular activated carbon. The adsorption rate constant on ammonia nitrogen of powered activated carbon with high porosity and low effective diameter was highest as 0.416 hr-1 and the effective pore diffusivity ($D_e$) was lowest as $1.17{\times}10^{-6}cm^2/hr$, and the value of ammonia nitrogen adsorption rate constant of granular activated carbon was $0.149{\sim}0.195hr^{-1}$. It was revealed that, with the same amount of dosage, the adsorptive power of activated carbon with lower effective diameter and bigger porosity was better and its rate constant was also high. With a little adsorbent dosage of 2 g, there was no difference removal ability of ammonia nitrogen as change of adsorption properties.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.66 no.1
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• pp.203-210
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• 2017

In this paper, we propose a electrical/mechanical method to effectively diagnose the local deterioration of a 10m long power shielded twist pair cable defined by the American Wire Gauge (AWG) 14 specification using electrical/mechanical methods. The rapid deterioration of the cable proceeded by using the heating furnace, which is based on the Arrhenius equations proceeds from 0 to 35 years with the deteriorated equivalent model. In this paper, we introduce a method to diagnose the characteristics of locally deteriorated cable by using $S_{21}$ phase and frequency change rate measured by vector network analyzer which is the electrical diagnostic method. The measured $S_{21}$ phase and rate of change of frequency show a constant correlation with the number of years of locally deteriorated cable, thus it can be useful for diagnosing deteriorated cables. The change of modulus due to deterioration was measured by a modulus measuring device, which is defined by the ratio of deformation from the force externally applied to the cable, and the rate of modulus change also shows a constant correlation with the number of years of locally deteriorated cable. Finally, By combining the advantages of electrical/mechanical diagnostic methods, we can efficiently diagnose the local deterioration in the power shielded cable.

• Advances in materials Research
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• v.11 no.1
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• pp.41-57
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• 2022

This paper is focused on delamination analysis of a multilayered inhomogeneous viscoelastic beam subjected to linear creep under constant applied stress. The viscoelastic model that is used to treat the creep consists of consecutively connected units. Each unit consists of one spring and two dashpots. The number of units in the model is arbitrary. The modulus of elasticity of the spring in each unit changes with time. Besides, the modulii of elasticity and the coefficients of viscosity change continuously along the thickness, width and length in each layer since the material is continuously inhomogeneous in each layer of the beam. A time-dependent solution to the strain energy release rate for the delamination is derived. A time-dependent solution to the J-integral is derived too. A parametric analysis of the strain energy release rate is carried-out by applying the solution derived. The influence of various factors such as creep, material inhomogeneity, the change of the modulii of elasticity with time and the number of units in the viscoelastic model on the strain energy release rate are clarified.

• Asian Journal of Atmospheric Environment
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• v.2 no.2
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• pp.116-124
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• 2008

In this study, the Tier 2 method recommended by the Intergovernmental Panel on Climate Change (IPCC) was used to predict the methane generation rate at two landfill sites, designated as Y and C for purposes of this study, in South Korea. Factors such as the average annual waste disposal, methane emissions ($L_0$) and methane gas generation rate constant (k) were estimated by analyses of waste and the historical data for the landfills. The value of k was estimated by field experiments and then the changes in the methane generation rate were predicted through the year 2050, based on the value of k. The Y landfill site, which was in operation until the year 2008, will generate a total of 17, 198.7 tons by the end of 2018, according to our estimations. At the C landfill site, which will not be closed until the end of 2011, the amount of methane gas generated in 2011 will be 3,316 tons and the total amount of gas generated by 2029 will be 61,200 tons. The total production rate of methane gas at the C landfill is higher than that of the Y landfill. This indicates that the capacity of a landfill site affects the production rate of methane gas. However, the interrelation between the generation rate of methane and the value of k is weak. In addition, the generation of methane gas does not cease even when the operations at a landfill site come to a close and the methane gas production rate is at its highest at end of the operating life of a landfill site.

• Journal of Astronomy and Space Sciences
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• v.1 no.1
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• pp.23-34
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• 1984

A bubble trapped in the liquid manifold of INTELSAT IV F-7 spacecraft caused a mass imbalance between the System 1 propellant tanks and a wobble half angle of 0.38 degree to 0.48 degree. A maneuver on May 14, 1980 passed the bubble through the axial jet and allowed propellant to redistribute. A 0.2 rpm change in sin rate was observed with an exponential decay time constant of 6 minutes. In this paper, moment of inertia, tank geometry and hydrodynamic models are derived to match the observed spin rate data. The values of the total mass of propellant considered were 16, 19 and 20 kgs with corresponding mass imbalances of 14.3, 15 and 15.1 Kgs, respectively. The result shows excellent agreement with observed spin rate data but it was necessary to assume a greater mass of hydrazine in the tanks than propellant accounting indicated.

• Journal of Korean Society for Atmospheric Environment
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• v.28 no.5
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• pp.518-526
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• 2012

The objective of this research was to develop fugitive emission models of HFC-134a (Hydrofluorocarbon-134a) at the operation and disposal stages of passenger cars. It is essential to estimate the emission of HFC-134a from mobile air conditioner (MAC) due to its high Global Warming Potential (GWP) and extensive use as a refrigerant in MAC. The first-order emission model was introduced and the emission rate constant was assumed to be unvaried with time. A commercial recovery station of refrigerants was used to recover the HFC-134a from the MAC. Average emission rate constant and annual emission rate during the operation period of vehicle are estimated to be $0.0538{\pm}0.0092$ (n=21) $yr^{-1}$ and $5.2{\pm}0.6%$, respectively within a confidence interval of 95%. According to the model results, about 50% of HFC-134a would be emitted from the MAC during the 10 years operation of passenger cars. On the other hand, average remaining portion of HFC-134a in the MACs of scrap cars is $58.2{\pm}4.8%$ (n=50) within a confidence interval of 95%, suggesting that over 40% of the initially charged amount could be released fugitively after disposal provided that the HFC-134a would not be properly treated or recycled.

• Journal of Soil and Groundwater Environment
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• v.8 no.1
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• pp.48-56
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• 2003

A geophysical conductivity logging technique has been adopted to determine hydraulic constants using a simplified physical model that depicts the borehole condition. An experiment has been made by monitoring the conductivity change within the model hole using borehole environment water and incoming-outgoing water of different salinity, under the state of constant flow rate by maintaining balance between inflow and outflow. Conductivity variation features were observed that depended on flow rate, salinity contrasts between fluid within the hole and incoming-outgoing fluid, and density contrasts between fluid conductivity within the hole and incoming fluid. The results of the experiment show the uniform change of fluid conductivity within the hole with time, a fairly good correlation between the flow rate and the conductivity change rate. The geophysical conductivity logging technique can be an efficient tool for determining hydraulic constants if the model equation is verified by henceforward experiments.