• Journal of Surface Science and Engineering
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• v.29 no.6
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• pp.739-744
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• 1996

Lanthanide diphthalocyanines have interesting properties on electrochemical and chemical redox reactions. It is however, difficult to use because of thier short device life. Plasma-polymerization attends to improvement thier device life. Yb-diphthalocyanine ($YbPc_2$) polymer film was deposited in a parallel plate electrodes-type RF plasma reactor. $YbPc_2$ was sublimed into the argon plasma, and polymer film was obtained on a substrate. Radio frequency was constant of 13.56MHz. Pressure of argon gas, sublimation rate of $YbPc_2$ and RF power were variable parameters depending on film quality. Surface of polymer films include a lot of sub-micron order lumps. It was indicated that size of lumps depends on polymerization degree controled by parameters. Size of lumps and polymerization degree are increased with RF power. However, by the high RF power over 40W, polymerization degree is decreased with RF power and surface of film is rough. In condition of RF power is high, polymerization will compete with etching of film. We obtained good films for electrochromic display with RF power of 20W, argon gas pressure of 8.0 Pa and sublimationrate of $1.2 \times 10$ mol/min, and good films for gas sensor with RF power of 30W, argon gas pressure of 10.6Pa and sublimation rate of $1.2 \times 10$ mol/min.

• KEPCO Journal on Electric Power and Energy
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• v.6 no.2
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• pp.123-127
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• 2020

KEPCO has installed Frequency Regulation ESS (FR ESS) of 376 MW since 2015. Frequency Regulation is ancillary service to support stabilizing system frequency, which is divided into governor free and automatic generation control. KEPCO operates FR ESS as governor free application and leads FR ESS market with capability of diverse demonstration and operation experiences. To expand FR ESS role during transient states of power system, KEPCO has extended operating time of charging and discharging. KEPCO has also changed speed droop lower than before to improve contribution on frequency compensation, and acquired much experiences of differentiating bad cells from others. Based on these technologies and know-hows, KEPCO Research Institutes received request of feasibility study and technical cooperation for overseas FR ESS business. This paper suggests the simple and practical method for making technological feasibility study of FR ESS.

• Journal of Power Electronics
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• v.16 no.6
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• pp.2202-2211
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• 2016

In certain applications, such as IPT-based EV charger (IPTEC), any variation in alignment and distance between pickup and charger primary leads to a change in leakage and magnetic impedance magnitudes. The power transmission capacity is not always at the maximum level because of these variations. This study proposes a new low-cost tracking method that achieves the Maximum Inductive Power Transmission Capacity (MIPTC). Furthermore, in the proposed method, the exchange of information between load and source is not required. For an application such as IPTEC, the load detected by the IPTEC varies continuously with time because of the change in state of the charge. This load variation causes a significant variation in IPT resonant circuit voltage gain. However, the optimized charging output voltage should be kept constant. From the analysis of the behavior of the IPT circuit at different working frequencies and load conditions, a MIPTC operation point that is independent of load condition can be identified. Finally, the experimental results of a developed prototype IPT circuit test show the performance of the proposed method.

• The Transactions of the Korean Institute of Electrical Engineers B
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• v.54 no.12
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• pp.609-615
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• 2005

A 30kW electrical power conversion system is developed for a variable speed wind turbine. In the wind energy conversion system(WECS) a synchronous generator with field current excitation converts the mechanical energy into electrical energy. As the voltage and the frequency of the generator output vary according to the wind speed, a 6-bridge diode rectifier and a PWM boost chopper is utilized as an ac-dc converter maintaining the constant dc-link voltage with only single switch control. An input current control algorithm for maximum power generation during the variable speed operation is proposed without any usage of speed sensor. Grid connection type PWM inverter converts dc input power to ac output currents into the grid. The active power to the grid is controlled by q-axis current and the reactive power is controlled by d-axis current with appropriate decoupling. The phase angle of utility voltage is detected using software PLL(Phased Locked Loop) in d-q synchronous reference frame. Experimental results from the test of 30kW prototype wind turbine system show that the generator power can be controlled effectively during the variable speed operation without any speed sensor.

• The Transactions of the Korean Institute of Power Electronics
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• v.6 no.5
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• pp.377-385
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• 2001

The mixed gas of Hydrogen and Oxygen is gained from water electrolysis reaction. It has constant volume ratio 2 : 1 Hydrogen and Oxygen, and it is used as a source of thermal energy by combustion reaction. This gas has better characteristics in the field of economy, efficiency of energy, and environmental intimacy than acetylene gas and LPG used for gas welding machine. So several studies of this gas are actively in progress nowadays. The object of this study is the optimization of power condition in the side of electricity for the Hydrogen-Oxygen gas generator, Firstly chemical analysis of electrolysis is conducted, and the relation of electrical energy and chemical energy is quantitatively investigated through Faraday's laws of electrolysis. After that, pulse power supply is designed for basic experiment which could be applied to the analysis of Hydrogen-Oxygen gas generator. In the basis of above steps, comparison and analysis of Hydrogen-Oxygen gas generator was conducted as variable frequency using pulse Power supply.

• KEPCO Journal on Electric Power and Energy
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• v.5 no.2
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• pp.83-92
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• 2019

Spontaneous combustion propensity of various coals of carbonization grade as a pulverized fuel of coal-fired power plant has been tested from an initial temperature of $25^{\circ}C$ to $600^{\circ}C$ by heating in an oven with air to analyze the self-oxidation starting temperature. These tests produce CPT (Cross Point Temperature), IT (Ignition temperature), and CPS (Cross Point Slope) calculated as the slope of time taken for a rapid exothermic oxidation reaction at CPT base. CPS shows a carbonization rank dependence whereby wood pellet has the highest propensity to spontaneous combustion of $20.995^{\circ}C/min$. A sub-bituminous KIDECO coal shows a CPS value of $15.370^{\circ}C/min$, whereas pet coke has the highest carbonization rank at $2.950^{\circ}C/min$. The nature of this trend is most likely attributable to a concentration of volatile matter and oxygen functional groups of coal surface that governs the available component for oxidation, as well as surface area of fuel char, and constant pressure molar heat.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.24 no.3
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• pp.310-315
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• 2013

This paper presents a two-port time-domain reflectometry(TDR) measurement technique for extracting the complex propagation constant of a cross-linked polyethylene(XLPE) cable. For the extraction, a short pulse transmitted through the cable is measured in the time domain and analyzed in the frequency domain. The propagation constant of a 22.9 kV XLPE cable with a conductor area of 325 $mm^2$ is extracted up to a frequency of approximately 2.14 GHz. The $S_{21}$ measured using a network analyzer and the two-port TDR technique are compared for verification. As a result compared with previous TDR method, the upper possible frequency limit for extracting the propagation constant increases and the measurement error decreases.

• Bulletin of the Korean Chemical Society
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• v.26 no.12
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• pp.2007-2016
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• 2005

An artificial neural network (ANN) is successfully presented for prediction acidity constant (pKa) of various benzoic acids and phenols with diverse chemical structures using a nonlinear quantitative structure-property relationship. A three-layered feed forward ANN with back-propagation of error was generated using six molecular descriptors appearing in the multi-parameter linear regression (MLR) model. The polarizability term $(\pi_1)$, most positive charge of acidic hydrogen atom $(q^+)$, molecular weight (MW), most negative charge of the acidic oxygen atom $(q^-)$, the hydrogen-bond accepting ability $(\epsilon_B)$ and partial charge weighted topological electronic (PCWTE) descriptors are inputs and its output is pKa. It was found that properly selected and trained neural network with 205 compounds could fairly represent dependence of the acidity constant on molecular descriptors. For evaluation of the predictive power of the generated ANN, an optimized network was applied for prediction pKa values of 37 compounds in the prediction set, which were not used in the optimization procedure. Squared correlation coefficient $(R^2)$ and root mean square error (RMSE) of 0.9147 and 0.9388 for prediction set by the MLR model should be compared with the values of 0.9939 and 0.2575 by the ANN model. These improvements are due to the fact that acidity constant of benzoic acids and phenols in water shows nonlinear correlations with the molecular descriptors.

• Journal of Korean Society on Water Environment
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• v.24 no.3
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• pp.311-316
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• 2008

This study aimed to obtain equilibrium concentration on adsorption removal of ammonia nitrogen by activated carbon, to express the adsorption characteristics following Freundlich isotherm and also, based on the value obtained, to investigate the relationship between physical characteristics of activated carbon and dynamics of ammonia nitrogen removal by obtaining rate constant and effective pore diffusivity. The results summarized from this study are as follows. It was noted that powdered activated carbon showed better adsorption ability than granular activated carbon. The value of constant (f) of Freundlich isotherm of powered activated carbon was $4.6{\times}10^{-8}$ which is bigger than that of granular activated carbon. The adsorption rate constant on ammonia nitrogen of powered activated carbon with high porosity and low effective diameter was highest as 0.416 hr-1 and the effective pore diffusivity ($D_e$) was lowest as $1.17{\times}10^{-6}cm^2/hr$, and the value of ammonia nitrogen adsorption rate constant of granular activated carbon was $0.149{\sim}0.195hr^{-1}$. It was revealed that, with the same amount of dosage, the adsorptive power of activated carbon with lower effective diameter and bigger porosity was better and its rate constant was also high. With a little adsorbent dosage of 2 g, there was no difference removal ability of ammonia nitrogen as change of adsorption properties.

• Journal of Korean Society on Water Environment
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• v.26 no.3
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• pp.491-496
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• 2010

This study aimed to obtain equilibrium concentration on adsorption removal of phosphorus by activated carbon, to express the adsorption characteristics following Freundlich isotherm and also, based on the value obtained, to investigate the relationship between physical properties of activated carbon and dynamics of phosphorus removal by obtaining rate constant and effective pore diffusivity. The results summarized from this study are as follows. Phosphorus adsorption equilibrium reaching time of powdered activated carbon was reduced as the dosage of activated carbon increases, while granular activated carbon despite increased dosage did not have influence on adsorption equilibrium reaching times of phosphorus as well, taking more than 10 hours. It was also noted that powdered activated carbon showed better adsorption ability than granular activated carbon. The value of constant (f) of Freundlich isotherm of powered activated carbon on phosphorus was 4.26 which is bigger than those of granular activated carbon. The adsorption rate constant on phosphorus of powered activated carbon with low effective diameter and iodine number was highest as $8.888hr^{-1}$ and the effective pore diffusivity ($D_e$) was lowest as $2.45{\times}10^{-5}cm^2/hr$, and the value of phosphorus adsorption rate constant of granular activated carbon was $0.174{\sim}0.372hr^{-1}$, It was revealed that, with the same amount of dosage, the adsorptive power of activated carbon with lower effective diameter was better and its rate constant was also high.