Polyquinonediimines (PQDI) which have stable structure on heat and contains mono-azobenzene in the side chain were synthesized by means of condensation polymerization under TiCl$_4$. The synthesized monomers and polymers were identified by FT-IR, $^1$H-NMR, and elementary analysis. Especially, PQDI was comfirmed by the double-bonding peak of >C=N appeared near 1625 $cm^{-1}$ / by means of FT-IR spectrum. PQDI containing mono-azobenzene group in both side chains wat not soluble in non-polar solvents at all but partially soluble in the polar solvents having small dielectric constant, and dissolved in the strong acid such as sulfuric acid and $CH_3$SO$_3$H. Molecular weight distribution of PQDI measured by GPC showed 1.74. It was confirmed through X-ray diffraction analysis that the polymer was partially crystalline at the low angle region, but amorphous after heat treatment at 1$25^{\circ}C$. The glass transition temperature (T$_{g}$ ) of synthesized polymer was measured as 1$25^{\circ}C$ by differential scanning calorimetry. The SHG value for $\chi$$^{(2)}$ after poling at 1$25^{\circ}C$ was 8.6 pm/V (λ=1.542 ${\mu}{\textrm}{m}$). The SHG value slowly decreased with time from the start but appeared temporal stability after 100 hours.
An analytical procedure for calculating the failure load of a V-shaped rock notch under two-dimensional stress conditions was developed based on the slip-line plastic analysis method. The key idea utilized in the development is the fact that the α-line, one of the slip-lines, extends from the rock notch surface to the horizontal surface outside the notch when the rock around the notch is in the plastic state, and that there exists an invariant which is constant along the α-line. Since the stress boundary condition of the horizontal surface outside the rock notch is known, it is possible to calculate the normal and shear stresses acting on the rock notch surface by solving the invariant equation. The notch failure load exerted by the wedge was calculated using the calculated stress components for the notch surface. Rock notch failure analysis was performed by applying the developed analytical procedure. The analysis results show that the failure load of the rock notch increases with exponential nonlinearity as the angle of the notch and the friction of the notch surface increase. The analytical procedure developed in this study is expected to have applications to the study of fracture initiation in rocks through wedge-shaped notch formation, calculation of bearing capacity of the rock foundation, and stability analysis of rock slopes and circular tunnels.
We performed a study to obtain kinematic data on the characteristics of spike serving techniques used by volleyball players, including other basic data that will be useful for in-field applications. We used three-dimensional videography to compare good tough serves and serve errors. The subjects were 3 left attackers whose spike serves were videographed (60 fileds/s). The three-dimensional coordinates were calculated using the direct linear transformation method and then analyzed using the Kwon 3D software program version 3.1. There was no difference in time elapsed. However, the vertical displacement of the center of body mass(CM) differed between the 2 types of serves: in successful serves, the CM tended to be lower, as did the maximum ball height at the time of hitting. Further, the higher the level of the hitting hand was at the moment of impact, the higher was the likelihood of scoring points. In good serves, the players tended to accelerate their CM movement just before jumping to hit the ball and descend rapidly at the moment of hitting. The hand speed along with ball velocity during the impact was proven to be higher in successful serves. Moreover, in successful serves, the shoulder angles increased to a greater extent while the elbow angles were maintained constant. This possibly resulted in faster and more precise serves. An important observation was that the angle of trunk inclination during the jump did not increase with the swing of the shoulders, muscle tendon complex.
Christian Metz, the precursor of cine-semiology, considered cinema as a language in the sense that it is a set of messages grounded in a given matter of expression, and a signifying practice characterized by specific codifications. According to Metz, film forms a structured network produced by the interweaving of cinematic codes, within which cinematic subcodes represent specific usages of the particular code. For Metz, cinematic language is a totality of cinematic codes and subcodes, and history of the cinema is the trace of the competition, incorporations and exclusions of the subcodes. He also suggested a filmic text is not just a list of codes in effect, but a process of constant displacement and deformation of codes. Following Metz' textual analysis methodology, I investigated the formal configuration of Hayao Miyazaki‘s animation, Spirited Away. It is interesting to trace the interweaving of cinematic codes in Spirited Away, i.e. codes of lighting, color, movement, and auteurism, across the animation. I focused on the first scene at the bridge to Yubaba's bathhouse, analyzing each cinematic code and its subcode applied. The first bridge scene is carefully constructed to stand out the confrontation of Chihiro (with Haku) and the bathhouse. The bathhouse is not just a building, it represents the powerful witch, Yubaba, yet to appear on the scene, and functions as an antipode to Chihiro. In each shot, every subcode within the codes of framing, direction, angle, color, lighting and movement is used to maximize the contrast between the dominant bathhouse and the feeble 10-year-old girl. In Spirited Away, the subcodes within each cinematic ode are constantly competing and displacing each other to augment the antithesis between the characters and develop the narrative. As Metz's argument that film constitutes a quasi-linguistic practice as a pluricodic medium, Spirited Away communicates with the spectators with the combination and displacement of these cinematic codes and subcodes.
Drying grain with conventional artificial drying methods requires great quantities of petroleum fuels. Depletion of fossil fuel increases the need of the utilization of solar energy as an alternative to petroluem fuels for drying grain , an energy intensive agricultural operation. Many techniques for the utilization of solar energy in grain drying have been developed, however, there are many problems in adopting solar energy as an energy sources for drying grain. Futhermore, very little research has been done on solar grain drying in Korea. This study was conducted to evaluate the availability of solar energy for drying of rough rice in Chuncheon, Suweon, and Jinju areas based on 50year meteorological data, and to analyze experimentally the performance of a solar air collector for dying grain, and to find the effects of solar heated air compared to unheated air on the rate of drying and energy consumption required for drying of rough rice. The results of this study was may be summarized as follows ; 1. Monthly average daily total radiation on a horizontal surface in October was 260.6 ly/day for Chuncheon, 240.3 ly/day for Suweon , and 253.4 ly/day for Jinju area, respectively. 2. the ratio of monthly average daily diffuse radiation to daily total radiation on a horizontal surface was approximately 0.41 for Chuncheon, 0.45 for Suweon, and 0.44 for Jinju area, respectively. 3. Although the statistical distribution curves of daily total radiation for the three locations were not identical , the differences among them were not large and may be neglected for many practical purposes. 4. I was estimated that the optimum tilting angle of the collector in October was approximately 46 degrees for Chuncheon and Suweon and 45 degrees for Jinju. 5. The ratio of the total radiation on a optimum tilting plane to that on a horizontal plane was estimated to be 1.36 for Chuncheon, 1.31 for Suweon, and 1.27 for Jinju , respectively. 6. The collection efficiency of the solar air collector ranged from 47. 8 to 51. 5 percent at the air flow rates of 251. 1-372.96 $m^3$/hr. High efficiency remained nearly , constant during the best sunshine hours, 10 a.m. to 2 p.m. and decreased during other hours. More energy was collected as the air flow rate incresed. 7. The average temperature rise in the drying air from the solar collector for the test period varied from $6.5^\circC$ to $21.8^\circC$ above the ambient air temperature. 8. Solar-dried rough rice averaged 13.7 percent moisture (w.b.) after 130 hours of drying with the air flow rate of 1. 64 ccm/$m^3$, and rough rice dried with natural air averaged 15.1 percent moisture (w.b.) after 325 hours of drying with the same air flow rate. 9. Energy saving of 2.4 kwh per $m^3$ percentage point of moisture removed was obtained from solar heated air drYing. The solar bin used 53.3 percent less energy per percentage point of moisture removed than the natural air bin.
Journal of the Korean Society of Marine Environment & Safety
/
v.22
no.7
/
pp.884-891
/
2016
A secondary injection system in a diesel engine has benefits: it can be controlled independently without interrupting engine control, it can be adapted to various layouts for exhaust systems, and it pose no reductant dilution problems compared to post injection systems in the combustion chamber or other supplemental reductant injections. In a secondary injection system, the efficiency of the catalyst depends on the method of reducing the supply. The reductant needs to be maintained and optimized with constant pressure, the positions and angles of injector is a very important factor. The concentration and amount of reductant can be changed by adjusting secondary injection conditions. However, secondary injection is highly dependent upon the type of injector, injection pressure, atomization, spray technology, etc. Therefore, it is necessary to establish injection conditions the spray characteristics must be well-understood, such as spray penetration, sauter mean diameter, spray angle, injection quantity, etc. Uniform distribution of the reductant corresponding to the maximum NOx reduction in the DeNOx catalyst system must also assured. With this goal in mind, the spray characteristics and impingement plate types of a secondary injector were analyzed using visualization and digital image processing techniques.
The average ratio of the daily UV-B to total solar (75) irradiance at Busan (35.23$^{\circ}$N, 129.07$^{\circ}$E) in Korea is found as 0.11%. There is also a high exponential relationship between hourly UV-B and total solar irradiance: UV-B=exp (a$\times$(75-b))(R$^2$=0.93). The daily variation of total ozone is compared with the UV-B irradiance at Pohang (36.03$^{\circ}$N, 129.40$^{\circ}$E) in Korea using the Total Ozone Mapping Spectrometer (TOMS) data during the period of May to July in 2005. The total ozone (TO) has been maintained to a decreasing trend since 1979, which leading to a negative correlation with the ground-level UV-B irradiance doting the given period of cloudless day: UV-B=239.23-0.056 TO (R$^2$=0.52). The statistical predictions of daily total ozone are analyzed by using the data of the Brewer spectrophotometer and TOMS in East Asia including the Korean peninsula. The long-term monthly averages of total ozone using the multiplicative seasonal AutoRegressive Integrated Moving Average (ARIMA) model are used to predict the hourly mean UV-B irradiance by interpolating the daily mean total ozone far the predicting period. We also can predict the next day's total ozone by using regression models based on the present day's total ozone by TOMS and the next day's predicted maximum air temperature by the Meteorological Mesoscale Model 5 (MM5). These predicted and observed total ozone amounts are used to input data of the parameterization model (PM) of hourly UV-B irradiance. The PM of UV-B irradiance is based on the main parameters such as cloudiness, solar zenith angle, total ozone, opacity of aerosols, altitude, and surface albedo. The input data for the model requires daily total ozone, hourly amount and type of cloud, visibility and air pressure. To simplify cloud effects in the model, the constant cloud transmittance are used. For example, the correlation coefficient of the PM using these cloud transmissivities is shown high in more than 0.91 for cloudy days in Busan, and the relative mean bias error (RMBE) and the relative root mean square error (RRMSE) are less than 21% and 27%, respectively. In this study, the daily variations of calculated and predicted UV-B irradiance are presented in high correlation coefficients of more than 0.86 at each monitoring site of the Korean peninsula as well as East Asia. The RMBE is within 10% of the mean measured hourly irradiance, and the RRMSE is within 15% for hourly irradiance, respectively. Although errors are present in cloud amounts and total ozone, the results are still acceptable.
The resistance curves (R-curves) for 381 m crack extension of CLWL-DCB specimens had been determined. The average velocities of the crack extension measured with strain gages were 0.70 and 55 ㎜/sec. The measured rotation angle of the notch faces showed the existence of the singularity at least before 171 and 93 mm crack extensions for the 0.70 and 55 ㎜/sec crack velocities, respectively. The maximum slopes of the R-curves occurred between 25 and 89 ㎜ crack extensions for 0.70 ㎜/sec crack velocity and between 51 and 127 ㎜ crack extensions for 55 ㎜/sec crack velocity During the maximum slopes of the R-curves, the micro-crack localization can be expected, and faster crack velocity may form longer micro-cracking and micro-crack localizing zones. The fracture resistance of 0.70 ㎜/sec crack velocity reached a roughly constant maximum value of 143 N/m at 152 ㎜ crack extension, while that of 55 ㎜/sec crack velocity increased continuously to 245 N/m at 254 ㎜ crack extension and then decreased to the value of 0.70 ㎜/sec crack velocity. The R-curve of 55 ㎜/sec crack velocity was similar to that of the small size three-point bend test, and it showed that small size specimen or fast crack velocity could cause more brittle behavior.
Journal of the Korean Society of Marine Environment & Safety
/
v.20
no.4
/
pp.443-450
/
2014
In this study, we have discussed about the effect of hydrofoil arrangement and longitudinal moment characteristic on longitudinal motion stability of fully-submerged hydrofoil by the experiment of tandem hydrofoil model. First of all, tandem hydrofoil model that has canard wing arrangement has been made and characteristics of lift force and drag force by performing the lift force and drag force measuring experiment has also been estimated. Besides, tandem hydrofoil model's wing arrangement which has the initial stability and self stability of longitudinal motion has also been determined. In longitudinal stability experiment of tandem hydrofoil model, the motion characteristic of pitch and heave and the longitudinal stability of foil borne condition by variation of self stability of longitudinal moment and longitudinal distance are estimated. The result from the experiment and it's important conclusion can be described as below; Increase the self stability for longitudinal moment, the higher self stability for pitch motions in a constant pitch angles. By increasing the self stability for longitudinal moment, the range of fluctuation of pitch motion and heave motion for pitch angle also will change relatively small and longitudinal stability is excellent. Lastly, when the lift force of hydrofoil is remain constants, we can conclude that securing the enough self stability for longitudinal moment is essential for stable foil borne condition of tandem hydrofoil.
Although conventional seismic data processing is based on the assumption that the media are isotropic, the subsurface is often anisotropy in shale formation or carbonate with cracks and fractures. This paper presents the anisotropic parameter and seismic modeling in transversely isotropic media with a vertical symmetry axis using seismic physical modeling. The experiment was successfully carried out with VTI media, laminated bakelite material, using contact transducer of p and s-wave transmission. The variation of velocities with angle of incidence was clearly shown in anisotropic material. Comparing these velocities with the calculated phase velocities, the (P) and (S)-wave velocity observed in anisotropic material was a very good agreement with the calculated values. Anisotropic parameter ${\varepsilon}$, ${\delta}$, ${\gamma}$ was estimated by using Lame's constant calculated from the observed velocity. For the purpose of testing (S)-wave polarization, a birefringence experiment was carried out. The higher velocity was associated with the polarization parallel to the fracture, and the lower velocity was associated with the polarization perpendicular to the fracture.
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