• Title/Summary/Keyword: conductive composites

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A Study on Adhesion of Mechanical Properties of Rubber by MgCl2 (투명 차폐 필름 구현을 위한 전도성 복합 바인더의 입자구조에 따른 성능 평가)

  • Park, Ji-won;Back, Jong-Ho;Lee, Tae-Hyung;Kim, Hyun-Joong
    • Journal of Adhesion and Interface
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    • v.18 no.2
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    • pp.59-67
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    • 2017
  • Recently, integration of parts is accelerating according to the growth of the smart mobile industry. The integration of these parts causes problems of interference phenomena between the parts, and the importance of electromagnetic wave shielding technology to solve this problem is highlighted. Electromagnetic wave shielding technology is implemented so as to reflect or absorb electromagnetic waves, and generally conductive materials are utilized for electromagnetic wave shielding. Transparent shielding technology is required according to recent industrial changes. In this research, we propose transparent the shielding film using imprint technology with conductive composite binder. Utilizing UV polymerized acrylic binder to produce a conductive composite binder. Spherical, plate and stacked silver particles were used for conductivity. The changes of the curing characteristics, conductivity and adhesion were observed according to the structural characteristics of the silver particles. The use of spherical particles was the most efficient in the curing process, and an additional curing system was required to complement the UV-shadowing structure. In the conductivity evaluation, the stacked structure showed excellent characteristics. The adhesion of spherical system was the best. It is evaluated as a result of irregularities on the surface. Ultimately, the patterned film using this showed excellent transparency characteristics.

A Study on Carbon Nano Materials as Conductive Oilers for Microwave Absorbers (전자파 흡수체를 위한 전도성 소재로서의 탄소나노소재의 특성에 대한 연구)

  • Lee, Sang-Kwan;Kim, Chun-Gon;Kim, Jin-Bong
    • Composites Research
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    • v.19 no.5
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    • pp.28-33
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    • 2006
  • In this paper, we have studied the complex permittivities and their influence on the design of microwave absorbers of E-glass fabric/epoxy composite laminates containing three different types of carbon-based nano conductive fillers such as carbon black (CB), carbon nano fiber (CNF) and multi-wall nano tube (MWNT). The measurements were performed fur permittivities at the frequency band of 0.5 GHz$\sim$18.0 GHz using a vector network analyzer with a 7 mm coaxial air line. The experimental results show that the complex permittivities of the composites depend strongly on the natures and concentrations of the conductive fillers. The real and imaginary parts of the complex permittivities of the composites were proportional to the filler concentrations. But, depending on the types of fillers and frequency band, the increasing rates of the real and imaginary parts with respect to the filler concentrations were all different. These different rates can have an effect on the thickness in designing the single layer microwave absorbers. The effect of the different rates at 10 GHz was examined by using Cole-Cole plot; the plot is composed of a single layer absorber solution line and measured permittivities from these three types of composites. Single layer absorbers of 3 different thicknesses using carbon nano materials were fabricated and the -10 dB band of absorbing performances were all about 3 GHz.

Fabrication and characterization of polymer-based carbon nanomaterial composites for thermal conductive adhesive application (열전도성 점착제 응용을 위한 고분자 기반 탄소나노소재 복합체 제조 및 특성 평가)

  • Lee, Byeong-Joo;Jo, Sung-Il;Yoon, Eun-Hye;Lee, Ae-Ri;Lee, Woo-Young;Heo, Sung-Gyu;Hwang, Jae-Sung;Jeong, Goo-Hwan
    • Journal of the Korean institute of surface engineering
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    • v.53 no.4
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    • pp.160-168
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    • 2020
  • A polymer-based carbon nanomaterial composite was fabricated and characterized for the application of a thermal conductive adhesive. Low-dimensional carbon nanomaterials with excellent thermal conductivity such as carbon nanotube (CNT) and graphene were selected as a filler in the composite. Thermal, electrical and adhesive properties of the composite were investigated with respect to the morphology and content of the low-dimensional carbon nanomaterials. As a result, the composite-based adhesive fabricated by the loading of surface-treated MWCNTs of 0.4 wt% showed uniform dispersion, moderate adhesion and effective heat dissipation properties. Finally, it was confirmed through the thermal image analysis of LED module that the temperature reduction of 10℃ was achieved using the fabricated composite adhesive with MWCNT-6A. Expecially, heat dissipation performance of the optimized composite adhesive was evident at the hot spot in the module compared to other samples mixed with graphene or different MWCNT loading ratios.

Comparison study between recovered carbon black and commercial carbon black filled epoxy conductive materials

  • Huai M. Ooi;Pei L. Teh;Cheow K. Yeoh;Wee C. Wong;Chong H. Yew;Xue Y. Lim;Kai K. Yeoh;Nor A. Abdul Rahim;Chun H. Voon
    • Advances in materials Research
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    • v.13 no.3
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    • pp.221-232
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    • 2024
  • Waste tire management and recycling have grown to be significant issues because they bring up a global environmental concern. Thus, turning recycled waste tires into useful products may help tackle the environmental issue. This research aims to study and compare the effect of recycled carbon black (rCB) and commercial carbon black (CB) at certain 15 vol. % of filler loading on the mechanical, thermal, morphology and electrical properties of epoxy/CB composites. For this project, epoxy resin, diethyltoluenediamine (DETDA), recovered carbon black (rCB) and commercial carbon black (CB) graded N330, N550, N660 and N774 were mixed and compared accordingly to the formulation determined. The CB content was dispersed in the epoxy matrix using the mechanical mixing technique. The distribution and dispersion of CB in the epoxy matrix affect the characteristics of the conductive composites. rCB content at 15 vol% was selected at fixed content for comparison purposes due to the optimum value in electrical conductivity results. The flexural strength results followed the sequence of rCB>N774>N660>N550>N330. As for electrical conductivity results, epoxy/N330 exhibited the highest conductivity value, while the others achieved a magnitude of X10-3 due to the highest external surface area of N330. In terms of thermal stability, epoxy/N330 and epoxy/N774 were slightly more stable than epoxy/rCB.

Electromagnetic Interference Reflectivity of Nanostructured Manganese Ferrite Reinforced Polypyrrole Composites

  • Chakraborty, Himel;Chabri, Sumit;Bhowmik, Nandagopal
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.6
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    • pp.295-298
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    • 2013
  • Nano-size manganese ferrite reinforced conductive polypyrrole composites reveal a core-shell structure by in situ polymerization, in the presence of dodecyl benzene sulfonic acid as the surfactant and dopant, and iron chloride as the oxidant. The structure and magnetic properties of manganese ferrite nano-fillers were measured, by using X-ray diffraction and vibrating sample magnetometer. The morphology, microstructure, and conductivity of the composite were characterized by transmission electron microscopy, Fourier transform infrared spectroscopy, and four-wire technique. The microwave-absorbing properties of composites reinforcement dispersed in resin coating with the coating thickness of 1.2 nm were investigated, by using vector network analyzers, in the frequency range of 8~12 GHz. A reflection loss of -8 dB was observed at 10.5 GHz.

Fabrication of Electrically Conductive $TiB_2$-BN-AlN Composites (전기 전도성 $TiB_2$-BN-AlN 복합체의 제조)

  • 배동식;한경섭;최상홀
    • Journal of the Korean Ceramic Society
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    • v.33 no.5
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    • pp.524-530
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    • 1996
  • TiB2-BN-AlN composite was fabricated with the addition of 0~12 wt% WC by HP-sintering. Their sinterability. microstructure mechanical and electrical properties were studied as a function of the WC content. The addition of WC up to 12 wt% increased the flexural strength and decreased electrical resistivity as compared with those of the TiB2-BN-AlN composites. The electrical resistivity of TiB2-BN-AlN composite with 4.3 wt% WC was 640$\mu$$\Omega$-cm. It was found that the TiB2-BN-AlN composites with WC addition more than 4wt% was suitable for the application to the Al evaporation boat.

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Mechanical Properties of the Pressureless Sintered Si3N4-TiN Ceramic Composities (상압소결 Si3N4-TiN 복합재료의 기계적성질)

  • 송진수;손용배;김종희
    • Journal of the Korean Ceramic Society
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    • v.26 no.3
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    • pp.409-415
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    • 1989
  • Si3N4-TiN electro-conductive ceramic composites with 7wt% Al2O3+3wt% Y2O3 or 5wt% MgO as sintering aids were fabricated by pressureless sintering at 1,80$0^{\circ}C$ for 1h. The 3pt. flexural strength, KIC and Vickers hardness were measrued in order to investigate the effects of TiN on the mechanical properties. Also oxidation behavior was observed by measuring the weight gain after exposure to air at 1,10$0^{\circ}C$ for 100h. the reaction products between Si3N4 and TiN was not detected by XRD and EDS. Mechanical properties of the composites were not influenced by the addition of TiN less than 30vol%, but oxidation resistance of the composites was rapidly decreased with the amount of added TiN.

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Correlation between Electrical Conductivity and Shielding Effectiveness of Cementitous Composites according to length and volume fraction of steel fiber (강섬유의 길이 및 혼입률에 따른 시멘트 복합체의 전기전도도와 차폐효과의 상관관계)

  • Lee, Yae-Chan;Kim, Gyu-Yong;Eu, Ha-Min;Choi, Byung-Cheol;Sasui, Sasui;Nam, Jeong-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.11a
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    • pp.213-214
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    • 2022
  • The purpose of this study is to compare and analyze the effect of the length and volume fraction of smooth steel fiber on the electrical conductivity and shielding effectiveness of cementitious composites. As the length and volume fraction of the fiber increase, the movement of electrons becomes active and the formation of a conductive path becomes advantageous, thereby increasing electrical conductivity. Accordingly, the electrical conductivity and the shielding effectiveness showed a very close relationship. Thereafter, it is judged that research is needed to increase the shielding effect.

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Correlation between Electrical Conductivity and Shielding Effectiveness of Cementitous Composites according to Length and Volume Fraction of Steel Fiber (섬유 종류에 따른 섬유 보강 시멘트 복합체의 전기적 특성에 대한 실험적 연구)

  • Lee, Yae-Chan;Kim, Gyu-Yong;Han, Seung-Hyeon;Choi, Youn-Sung;Kim, Moon-Kyu;Nam, Jeong-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.183-184
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    • 2023
  • The purpose of this study is to compare and analyze the effect of type and volume fraction of fiber on the electrical conductivity and shielding effectiveness of cementitious composites. The large specific surface area of amorphous metallic fiber, as well as the high number of fibers per unit weight, provided an advantage in the formation of conductive path. As the result, the electrical conductivity of amorphous metallic fiber was evaluated to be higher, and the shielding effectiveness was also higher. However, the shielding effectiveness according to electrical conductivity was confirmed to have a threshold point, and further research is needed to improve it.

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Percolation Threshold and Critical Exponent of Dielectric Breakdown Strength of Polyethylene Matrix Composites added Carbon Black (카본블랙 첨가 PMC(Polyethylene Matrix Composites)의 문턱스며들기(Percolation Threshold)와 절연파괴 강도 임계지수)

  • Shin, Soon-Gi
    • Korean Journal of Materials Research
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    • v.21 no.9
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    • pp.477-481
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    • 2011
  • Composites of insulating polyethylene and carbon black are widely used in switching elements, conductive paint, and other applications due to the large gap of resistance value. This research addresses the critical exponent of dielectric breakdown strength of polymer matrix composites (PMC) made with carbon black and polyethylene below the percolation threshold (Pt) for the first time. Here, Pt means the volume fraction of carbon black of which the resistance of the PMC is transferred from its sharp decrease to gradual decrease in accordance with the increase of carbon-black-filled content. First, the Pt is determined based on the critical exponents of resistivity and relative permittivity. Although huge cohesive bodies of carbon black are formed in case of being less than the Pt, a percolation path connecting the conducting phases is not formed. The dielectric breakdown strength (Dbs) of the PMC below Pt is measured by using an impulse voltage in the range from 10 kV to 40 kV to avoid the effect of joule heating. Although the observed Dbs data seems to be well fitted to a straight line with a slope of 0.9 on a double logarithm of (Pt-$V_{CB}$) and Dbs, the least squares method gives a slope of 0.97 for the PMC. It has been found that finite carbon-black clusters play an important role in dielectric breakdown.